CN110346078A - Capacitive pliable pressure sensor and its preparation method and application - Google Patents
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B5/00—Measuring for diagnostic purposes; Identification of persons
- A61B5/02—Detecting, measuring or recording pulse, heart rate, blood pressure or blood flow; Combined pulse/heart-rate/blood pressure determination; Evaluating a cardiovascular condition not otherwise provided for, e.g. using combinations of techniques provided for in this group with electrocardiography or electroauscultation; Heart catheters for measuring blood pressure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B5/00—Measuring for diagnostic purposes; Identification of persons
- A61B5/68—Arrangements of detecting, measuring or recording means, e.g. sensors, in relation to patient
- A61B5/6801—Arrangements of detecting, measuring or recording means, e.g. sensors, in relation to patient specially adapted to be attached to or worn on the body surface
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
- G01L9/00—Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means
- G01L9/12—Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means by making use of variations in capacitance, i.e. electric circuits therefor
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B2562/00—Details of sensors; Constructional details of sensor housings or probes; Accessories for sensors
- A61B2562/02—Details of sensors specially adapted for in-vivo measurements
- A61B2562/0247—Pressure sensors
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Abstract
The invention discloses a kind of capacitive pliable pressure sensors and its preparation method and application, capacitive pliable pressure sensor includes: solid-state dimethyl silicone polymer layer, the lower electrode layer positioned at the upper electrode layer of the top surface of solid-state dimethyl silicone polymer layer and positioned at the bottom surface of solid-state dimethyl silicone polymer layer, the material of solid-state dimethyl silicone polymer layer is dimethyl silicone polymer, and solid-state dimethyl silicone polymer layer is made of the dimethyl silicone polymer micro-pillar array of a plate-like structure and the top for being connected to the plate-like structure.Present invention firstly provides capacitive pliable pressure sensor is prepared using polycarbonate template method, the sensitivity of capacitive pliable pressure sensor of the invention reaches 5.8kPa‑1, under the premise of pulse is fainter, capacitive pliable pressure sensor of the invention can still be come out pulse signal accurate detection, and can recognize that the waveform of pulse.
Description
Technical field
The invention belongs to pliable pressure sensor technical fields, relate in particular to a kind of capacitive pliable pressure sensor
And its preparation method and application.
Background technique
In recent years, wearable electronic product is used widely in biologic medical field, including wearable bracelet, intelligent hand
Table and intelligent glasses etc..However, the hard shell of these products hinders it and is more widely applied, and therefore, flexible electronic neck
Domain is intended to design and study the senser element with highly flexible, for the detection to physiology signal.
In many physiological signals of human body, pulse is one of most important physiological signal.TCM in Ancient China can lead to
A variety of diseases that pulse diagnosis goes out human body are crossed, accuracy rate is very high.In doctor trained in Western medicine, pulse signal also reflects heart and blood vessel
The important indicator of system health.Therefore, it is of great significance for the detection of pulse with real-time monitoring.
Pulse signal essence is a kind of pressure signal, therefore many people propose to realize using pliable pressure sensor to pulse
Real-time monitoring.However, the poor pliable pressure sensor of sensitivity is difficult that pulse signal is accurate since pulse is fainter
It detected.Even if particular sensor can detecte out the frequency of pulse, it can not but identify the accurate waveform of pulse, cause to lose
Leak important physiologic information.
Summary of the invention
In view of the deficiencies of the prior art, the purpose of the present invention is to provide a kind of preparations of capacitive pliable pressure sensor
Method, the preparation method are based on polycarbonate template method, are prepared for highly sensitive pliable pressure sensor dielectric layer, dielectric layer
There is the dimethyl silicone polymer micro-pillar array of lodging on surface, by being assembled with upper and lower electrode, forms capacitive flexible pressure
Force snesor.
It is a further object of the present invention to provide a kind of capacitive pliable pressure sensor, the capacitive pliable pressure sensors
Pulse signal can be monitored.
The purpose of the present invention is what is be achieved by following technical proposals.
A kind of capacitive pliable pressure sensor, comprising: solid-state dimethyl silicone polymer layer is located at the poly- diformazan of the solid-state
The upper electrode layer of the top surface of radical siloxane layer and lower electrode layer positioned at the bottom surface of the solid-state dimethyl silicone polymer layer, it is described
The material of solid-state dimethyl silicone polymer layer is dimethyl silicone polymer, and the solid-state dimethyl silicone polymer layer is by a tabular
The dimethyl silicone polymer micro-pillar array composition of structure and the top for being connected to the plate-like structure, the upper electrode layer include:
First Kapton and the silver nanowires for being adhered to the first Kapton upper surface at random, the lower electrode layer
Include: the second Kapton and is adhered to the silver nanowires of the second Kapton lower surface at random.
In the above-mentioned technical solutions, the height of the dimethyl silicone polymer micro-pillar array is 7~20 μm.
In the above-mentioned technical solutions, polydimethylsiloxanes in dimethyl silicone polymer micro-pillar array on the plate-like structure
The density of alkane microtrabeculae is 1 × 106~6 × 106A/cm2。
In the above-mentioned technical solutions, the diameter of the dimethyl silicone polymer microtrabeculae is 5~10 μm.
In the above-mentioned technical solutions, the plate-like structure with a thickness of 130~170 μm.
In the above-mentioned technical solutions, the dimethyl silicone polymer microtrabeculae is lodging shape.
In the above-mentioned technical solutions, the length of the silver nanowires is 20~50 μm, and diameter is 25~35nm.
The preparation method of above-mentioned capacitive pliable pressure sensor, comprising the following steps:
1) polydimethylsiloxanefilm film is prepared:
Dimethyl silicone polymer host agent is uniformly mixed with curing agent, obtains mixture A, by the mixture A in substrate
Upper berth open form at film, then at 75-80 DEG C solidification 3.5-4 hours, it is small that the substrate is immersed in methylene chloride aqueous solution at least 6
When, the isolated polydimethylsiloxanefilm film in the substrate, wherein according to the mass fraction, the poly dimethyl silicon
The ratio of oxygen alkane host agent and curing agent is (8~10): 1；
In the step 1), uniformly spread out the mixture A to form the film.
In the step 1), the polydimethylsiloxanefilm film with a thickness of 100~120 μm.
In the step 1), the mixture A is spread out into the method to form film are as follows: the mixture A is placed in base
On bottom, is rotated using sol evenning machine with the revolving speed of 500-550rpm, obtain the film on the substrate.
In the step 1), the dimethyl silicone polymer host agent is mixed with curing agent, is stirred 3~5 minutes, with reality
The existing uniform mixing.
In the step 1), the time that the substrate immerses in methylene chloride aqueous solution is 5~10 hours.
In the step 1), the concentration of methylene chloride is 98~99wt% in the methylene chloride aqueous solution.
2) dimethyl silicone polymer of liquid is spread out on the surface of the polydimethylsiloxanefilm film, described poly- two
Polydimethylsiloxanefilm film liquid level is obtained on methylsiloxane film；
In the step 2), the dimethyl silicone polymer of liquid is spread on the surface of the polydimethylsiloxanefilm film
The method opened are as follows: the dimethyl silicone polymer of liquid is placed in the surface of the polydimethylsiloxanefilm film, utilizes sol evenning machine
With the rotation of 2000-2200rpm revolving speed, the poly dimethyl with a thickness of 30~50 μm is obtained in the polydimethylsiloxanefilm film
Siloxane film liquid level.
In the step 2), every 1cm2The polydimethylsiloxanefilm film spreads out the polydimethylsiloxanes of the liquid
The quality of alkane is 0.3~0.5g.
3) prepare a template, multiple through-holes that aperture is 5-10 μm are formed in the template, template is placed on described
The surface of polydimethylsiloxanefilm film liquid level, so that polydimethylsiloxanes in the polydimethylsiloxanefilm film liquid level
Alkane is filled under the action of capillary force to the through-hole, is formed dimethyl silicone polymer microtrabeculae after solidification in the through-hole, is taken
Under the template, whole dimethyl silicone polymer microtrabeculaes form dimethyl silicone polymer micro-pillar arrays, obtain solid-state poly dimethyl
Siloxane layer；
In the step 3), the cured time is 3~4 hours.
In the step 3), the method for removing the template are as follows: use methylene chloride aqueous cleaning.
In the step 3), the porosity of through-hole is 4~20% in the template.
In the step 3), the template with a thickness of 7~20 μm.
4) top electrode is placed in the top surface of the solid-state dimethyl silicone polymer layer, lower electrode is placed in the solid-state poly- two
The bottom surface of methylsiloxane layer, wherein the top electrode the preparation method comprises the following steps: the first Kapton upper surface coat
Silver nanowires ethanol solution, the lower electrode the preparation method comprises the following steps: the second Kapton lower surface coat silver nanoparticle
Line ethanol solution.
In the step 4) in, the thickness of first Kapton and the second Kapton is 20-25 μm.
In the step 4) in, in the top electrode and lower electrode preparation method, each coating silver nanowires ethanol solution
Number be 2~3 times, coated every time it is 10-15 minutes dry after be coated with next time.
In the step 4), the concentration of silver nanowires is 19.5~20.5mg/mL in the silver nanowires ethanol solution.
Above-mentioned preparation method is improving the application in Sensitivity in Pressure Sensors.
Compared with the prior art, the beneficial effect of capacitive pliable pressure sensor of the invention and preparation method thereof is such as
Under:
Present invention firstly provides prepare capacitive pliable pressure sensor, preparation of the invention using polycarbonate template method
Method by polycarbonate template take from bottom to top in the way of prepare sensor dielectric layer, it is simple and effective.The capacitor produced
The sensitivity of type pliable pressure sensor reaches 5.8kPa-1, under the premise of pulse is fainter, capacitive flexible pressure of the invention
Force snesor can still come out pulse signal accurate detection, and can recognize that the waveform of pulse.
Detailed description of the invention
Fig. 1 is the pulse wave that the capacitive pliable pressure sensor of the preparation gained of the embodiment of the present invention 1 measures；
Fig. 2 is the enlarged drawing of Fig. 1；
Fig. 3 is the Sensitivity comparison of sensor in the capacitive pliable pressure sensor of 1 gained of embodiment and comparative example 1~5
Figure.
Specific embodiment
Technical solution of the present invention is further illustrated combined with specific embodiments below.
In the following embodiments, the purchase source of involved reagent and characterization test device is as follows:
(1) 184 dimethyl silicone polymer host agent of DOW CORNING SYLGARD and curing agent, with Lu trade (Shanghai) limited public affairs
Department.
(2) methylene chloride aqueous solution, Tianjin Yuan Li Chemical Co., Ltd., the concentration of methylene chloride in methylene chloride aqueous solution
For 98wt%.
(3) Whatman polycarbonate template, Shanghai Gen Sheng Biotechnology Co., Ltd.
(4) silver nanowires ethanol solution, Nanjing Xian Feng nanometers of Co., Ltd.
(5) polyimide transparent membrane, Baoying County Zhong jing electrical material factory.
In the following embodiments, the model of involved instrument is as follows:
(1) KW-4A sol evenning machine, Beijing Saden Keyes's electronics responsibility Co., Ltd.
(2) AIGU-ZP-200 pressure gauge, ETOOL Co., Ltd
(3) LCR digital electric bridge
Examples 1 to 3
A kind of capacitive pliable pressure sensor, comprising: solid-state dimethyl silicone polymer layer is located at solid-state poly dimethyl silicon
The upper electrode layer of the top surface of oxygen alkane layer and lower electrode layer positioned at the bottom surface of solid-state dimethyl silicone polymer layer, solid-state poly dimethyl
The material of siloxane layer is dimethyl silicone polymer, and solid-state dimethyl silicone polymer layer is by a plate-like structure and connection (one
Constitute) the top of the plate-like structure dimethyl silicone polymer micro-pillar array form, dimethyl silicone polymer micro-pillar array:
Multiple dimethyl silicone polymer microtrabeculaes of random alignment, plate-like structure with a thickness of 139 μm, dimethyl silicone polymer microtrabeculae battle array
The height of column is 11 μm.The density of dimethyl silicone polymer microtrabeculae is in dimethyl silicone polymer micro-pillar array on plate-like structure
3×106A/cm2, dimethyl silicone polymer microtrabeculae is lodging shape.Upper electrode layer includes: the first Kapton and random
Be adhered to the silver nanowires of the first Kapton upper surface, lower electrode layer include: the second Kapton and with
Machine is adhered to the silver nanowires of the second Kapton lower surface.The length of silver nanowires is 20~50 μm, diameter 25
~35nm.The diameter of dimethyl silicone polymer microtrabeculae is X μm.
The preparation method of above-mentioned capacitive pliable pressure sensor, comprising the following steps:
1) polydimethylsiloxanefilm film is prepared:
Dimethyl silicone polymer host agent is mixed with curing agent, is stirred 5 minutes, to realize uniformly mixing, obtains mixture
1.5g mixture A is placed on glass slide by A, using sol evenning machine with the revolving speed rotation rotation 1min of 520rpm, on glass slide
To the film (area of film are as follows: 7.5cm2).It places into baking oven to solidify 4 hours in 80 DEG C, glass slide is immersed into methylene chloride water
It is impregnated 6 hours in solution, so that glass slide is separated with substance thereon, obtains the polydimethylsiloxanefilm film with a thickness of 110 μm,
Wherein, according to the mass fraction, the ratio of dimethyl silicone polymer host agent and curing agent is 10:1；
2) dimethyl silicone polymer of 1.5g liquid is placed in the surface of polydimethylsiloxanefilm film, using sol evenning machine with
2000rpm revolving speed rotates 1min, and the polydimethylsiloxanefilm film with a thickness of 40 μm is obtained in polydimethylsiloxanefilm film
Liquid level.Wherein, every 1cm2The quality that the polydimethylsiloxanefilm film spreads out the dimethyl silicone polymer of the liquid is
0.4g。
3) prepare one with a thickness of 11 μm of template, be formed with multiple through-holes that aperture is X μm, the arrangement mould of through-hole in template
Formula is random alignment, and the porosity of through-hole is 12% in template.Template is placed on polydimethylsiloxanefilm film liquid level
Surface 3min, so that dimethyl silicone polymer is filled under the action of capillary force to logical in polydimethylsiloxanefilm film liquid level
In hole, dimethyl silicone polymer microtrabeculae is formed after solidification 4 hours in through-hole, with methylene chloride aqueous cleaning template 10min
To remove template, whole dimethyl silicone polymer microtrabeculaes form dimethyl silicone polymer micro-pillar array, obtain solid-state poly dimethyl
Siloxane layer；
4) top electrode is placed in the top surface of solid-state dimethyl silicone polymer layer, lower electrode is placed in solid-state polydimethylsiloxanes
The bottom surface of alkane layer, wherein top electrode the preparation method comprises the following steps: the first Kapton upper surface coat silver nanowires ethyl alcohol
It solution 3 times, is coated with next time after having coated drying every time 15 minutes.Lower electrode the preparation method comprises the following steps: in the second polyimides
The lower surface of film coats silver nanowires ethanol solution 3 times, is coated with next time after having coated drying every time 15 minutes.First is poly-
The thickness of imide membrane and the second Kapton is 22 μm.The concentration of silver nanowires is in silver nanowires ethanol solution
20mg/mL。
| Embodiment | X (unit: μm) |
| Embodiment 1 | 5 |
| Embodiment 2 | 8 |
| Embodiment 3 | 10 |
The sensitivity of 1~3 capacitive pliable pressure sensor of gained of testing example, the 1 capacitive flexibility of gained of embodiment
The sensitivity of pressure sensor is 5.8kPa-1, the sensitivity of the 2 capacitive pliable pressure sensor of gained of embodiment is 4.5kPa-1, the sensitivity of the 3 capacitive pliable pressure sensor of gained of embodiment is 3.6kPa-1。
Sensitivity test method are as follows:
Capacitive pliable pressure sensor is placed on smooth desktop, capacitive pliable pressure is passed using pressure gauge probe
The pressure of sensor upper surface application special value.The top electrode of capacitive pliable pressure sensor and lower electrode draw lead respectively
Line is connect with LCR digital electric bridge, measures the capacitance of capacitive pliable pressure sensor.
Sensitivity S=Δ C/ (C × P), wherein Δ C is the variable quantity of capacitance, i.e. Δ C=C-C0, C0For initial capacitance, C
Apply the capacitance after pressure to capacitive pliable pressure sensor upper surface for pressure gauge probe.P is applied by pressure gauge probe
The pressure value added.The unit of capacitor is pF, and the numerical value of pressure is kPa.In general, sensitivity is related with column diameter.It is right
Dimethyl silicone polymer layer microtrabeculae in embodiment 1 is easier to that deformation occurs under pressure, therefore sensitivity is higher.
The capacitive pliable pressure sensor of the preparation gained of embodiment 1 is placed in wrist pulse bounce position, uses medical adhesive tape
Capacitive pliable pressure sensor is fixed, by the top electrode of capacitive pliable pressure sensor and lower electrode respectively with LCR number
Word electric bridge is connected, and continuous acquisition capacitance.Finally collected capacitance is obtained using Excel Software on Drawing at curve
Pulse wave, as shown in Figure 1.Fig. 2 is the enlarged drawing of the 6-7 waveform in Fig. 1.
For the clearer sensitivity for illustrating capacitive pliable pressure sensor obtained by the present invention, now the present invention is implemented
Compared with the 1 capacitive pliable pressure sensor of gained of example is made with comparative example, comparative example is as follows:
Comparative example 1
Y.Joo,J.Byun,N.Seong,J.Ha,H.Kim,S.Kim,T.Kim,H.Im,D.Kim,Y.Hong,
Nanoscale 2015,7,6208.
Comparative example 2
S.Kang,J.Lee,S.Lee,S.Kim,J.-K.Kim,H.Algadi,S.Al-Sayari,D.-E.Kim,
D.Kim,T.Lee,Adv.Electron.Mater.2016,2,1600356.
Comparative example 3
S.C.B.Mannsfeld,B.C.-K.Tee,R.M.Stoltenberg,C.V.H.-H.Chen,S.Barman,
B.V.O.Muir,A.N.Sokolov,C.Reese,Z.Bao,Nat.Mater.2010,9,859.
Comparative example 4
Y.Wan,Z.Qiu,Y.Hong,Y.Wang,J.Zhang,Q.Liu,Z.Wu,C.F.Guo,
Adv.Electron.Mater.2018,4,1700586.
Comparative example 5
Z.He,W.Chen,B.Liang,C.Liu,L.Yang,D.Lu,Z.Mo,H.Zhu,Z.Tang,X.Gui,
ACSAppl.Mater.Inter.2018,10,12816.
In the capacitive pliable pressure sensor of the gained of embodiment 1 and comparative example 1~5 sensor comparison diagram as shown in figure 3,
Capacitive pliable pressure sensor of the invention has higher sensitivity in small pressure (< 1.75kPa) range as seen from the figure, this
Feature has the capacitive pliable pressure sensor of the present invention very in the Detection of Weak Signals field including pulse signal
Good advantage.
Illustrative description has been done to the present invention above, it should explanation, the case where not departing from core of the invention
Under, any simple deformation, modification or other skilled in the art can not spend the equivalent replacement of creative work equal
Fall into protection scope of the present invention.
Claims (10)
1. a kind of capacitive pliable pressure sensor characterized by comprising solid-state dimethyl silicone polymer layer, be located at it is described
The upper electrode layer of the top surface of solid-state dimethyl silicone polymer layer and under the bottom surface of the solid-state dimethyl silicone polymer layer
Electrode layer, the material of the solid-state dimethyl silicone polymer layer are dimethyl silicone polymer, the solid-state dimethyl silicone polymer
Layer be made of the dimethyl silicone polymer micro-pillar array of a plate-like structure and the top for being connected to the plate-like structure, it is described on
Electrode layer includes: the first Kapton and is adhered to the silver nanowires of the first Kapton upper surface at random,
The lower electrode layer includes: the second Kapton and is adhered to the Yin Na of the second Kapton lower surface at random
Rice noodles.
2. capacitive pliable pressure sensor according to claim 1, which is characterized in that the dimethyl silicone polymer is micro-
The height of column array is 7~20 μm；
The density of dimethyl silicone polymer microtrabeculae is 1 × 10 in dimethyl silicone polymer micro-pillar array on the plate-like structure6~
6×106A/cm2；
The plate-like structure with a thickness of 130~170 μm；
The dimethyl silicone polymer microtrabeculae is lodging shape；
The length of the silver nanowires is 20~50 μm, and diameter is 25~35nm.
3. the preparation method of capacitive pliable pressure sensor as claimed in claim 1 or 2, which is characterized in that including following step
It is rapid:
1) polydimethylsiloxanefilm film is prepared:
Dimethyl silicone polymer host agent is uniformly mixed with curing agent, obtains mixture A, by the mixture A on substrate upper berth
Open form at film, then at 75-80 DEG C solidification 3.5-4 hours, the substrate is immersed in methylene chloride aqueous solution at least 6 hours,
The isolated polydimethylsiloxanefilm film in the substrate, wherein according to the mass fraction, the dimethyl silicone polymer
The ratio of host agent and curing agent is (8~10): 1；
2) dimethyl silicone polymer of liquid is spread out on the surface of the polydimethylsiloxanefilm film, in the poly dimethyl
Polydimethylsiloxanefilm film liquid level is obtained on siloxane film；
3) prepare a template, multiple through-holes that aperture is 5-10 μm are formed in the template, template is placed on described poly- two
The surface of methylsiloxane thin film fluid layer, so that dimethyl silicone polymer exists in the polydimethylsiloxanefilm film liquid level
Under the action of capillary force in filling to the through-hole, dimethyl silicone polymer microtrabeculae is formed after solidification in the through-hole, removes institute
Template is stated, whole dimethyl silicone polymer microtrabeculaes form dimethyl silicone polymer micro-pillar array, obtain solid-state polydimethylsiloxanes
Alkane layer；
4) top electrode is placed in the top surface of the solid-state dimethyl silicone polymer layer, lower electrode is placed in the solid-state poly dimethyl
The bottom surface of siloxane layer, wherein the top electrode is received the preparation method comprises the following steps: coating silver in the upper surface of the first Kapton
Rice noodles ethanol solution, the lower electrode the preparation method comprises the following steps: the second Kapton lower surface coat silver nanowires second
Alcoholic solution.
4. preparation method according to claim 3, which is characterized in that in the step 1), the mixture A is uniform
Spread out to form the film；
In the step 1), the polydimethylsiloxanefilm film with a thickness of 100~120 μm.
5. preparation method according to claim 3, which is characterized in that in the step 1), the mixture A is spread out
The method for forming film are as follows: the mixture A is placed in substrate, is rotated using sol evenning machine with the revolving speed of 500-550rpm,
The film is obtained in the substrate；
In the step 1), the dimethyl silicone polymer host agent is mixed with curing agent, is stirred 3~5 minutes, to realize
State uniform mixing；
In the step 1), the time that the substrate immerses in methylene chloride aqueous solution is 5~10 hours；
In the step 1), the concentration of methylene chloride is 98~99wt% in the methylene chloride aqueous solution.
6. preparation method according to claim 3, which is characterized in that in the step 2), by the poly dimethyl of liquid
The method that siloxanes is spread out on the surface of the polydimethylsiloxanefilm film are as follows: the dimethyl silicone polymer of liquid is placed in institute
The surface for stating polydimethylsiloxanefilm film, using sol evenning machine with the rotation of 2000-2200rpm revolving speed, in the poly dimethyl silicon
The polydimethylsiloxanefilm film liquid level with a thickness of 30~50 μm is obtained on oxygen alkane film.
7. preparation method according to claim 3, which is characterized in that in the step 2), every 1cm2The poly dimethyl
The quality that siloxane film spreads out the dimethyl silicone polymer of the liquid is 0.3~0.5g.
8. preparation method according to claim 3, which is characterized in that in the step 3), the cured time is 3
~4 hours；
In the step 3), the method for removing the template are as follows: use methylene chloride aqueous cleaning；
In the step 3), the porosity of through-hole is 4~20% in the template；
In the step 3), the template with a thickness of 7~20 μm.
9. preparation method according to claim 3, which is characterized in that in the step 4) in, first polyimides is thin
The thickness of film and the second Kapton is 20-25 μm；
In the step 4) in, in the top electrode and lower electrode preparation method, each number for coating silver nanowires ethanol solution
Be 2~3 times, coated every time it is 10-15 minutes dry after be coated with next time；
In the step 4), the concentration of silver nanowires is 19.5~20.5mg/mL in the silver nanowires ethanol solution.
10. preparation method is improving the application in Sensitivity in Pressure Sensors as described in any one of claim 3~9.
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