US20180274783A1 - Auxetic Structures With Angled Slots In Engineered Patterns For Customized NPR Behavior And Improved Cooling Performance - Google Patents

Auxetic Structures With Angled Slots In Engineered Patterns For Customized NPR Behavior And Improved Cooling Performance Download PDF

Info

Publication number
US20180274783A1
US20180274783A1 US15/542,636 US201615542636A US2018274783A1 US 20180274783 A1 US20180274783 A1 US 20180274783A1 US 201615542636 A US201615542636 A US 201615542636A US 2018274783 A1 US2018274783 A1 US 2018274783A1
Authority
US
United States
Prior art keywords
elongated apertures
rigid body
apertures
npr
elongated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US15/542,636
Inventor
Katia Bertoldi
Christopher Booth-Morrison
Mehran Farhangi
Matthew Christopher Innes
Farhad Javid
Megan Schaenzer
Ali Shanian
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens Canada Ltd
Harvard College
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US15/542,636 priority Critical patent/US20180274783A1/en
Assigned to PRESIDENT AND FELLOWS OF HARVARD COLLEGE reassignment PRESIDENT AND FELLOWS OF HARVARD COLLEGE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BERTOLDI, KATIA, FARHAD, JAVID
Assigned to PRESIDENT AND FELLOWS OF HARVARD COLLEGE reassignment PRESIDENT AND FELLOWS OF HARVARD COLLEGE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BERTOLDI, KATIA, FARHAD, JAVID
Assigned to SIEMENS CANADA LIMITED reassignment SIEMENS CANADA LIMITED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SCHAENZER, Megan, BOOTH-MORRISON, CHRISTOPHER, FARHANGI, Mehran, INNES, MATTHEW CHRISTOPHER, SHANIAN, Ali
Publication of US20180274783A1 publication Critical patent/US20180274783A1/en
Assigned to PRESIDENT AND FELLOWS OF HARVARD COLLEGE reassignment PRESIDENT AND FELLOWS OF HARVARD COLLEGE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: JAVID, Farhad
Abandoned legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/002Wall structures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/02Continuous combustion chambers using liquid or gaseous fuel characterised by the air-flow or gas-flow configuration
    • F23R3/04Air inlet arrangements
    • F23R3/06Arrangement of apertures along the flame tube
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R2900/00Special features of, or arrangements for continuous combustion chambers; Combustion processes therefor
    • F23R2900/00005Preventing fatigue failures or reducing mechanical stress in gas turbine components
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R2900/00Special features of, or arrangements for continuous combustion chambers; Combustion processes therefor
    • F23R2900/00014Reducing thermo-acoustic vibrations by passive means, e.g. by Helmholtz resonators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R2900/00Special features of, or arrangements for continuous combustion chambers; Combustion processes therefor
    • F23R2900/03041Effusion cooled combustion chamber walls or domes

Definitions

  • the present disclosure relates generally to porous materials and cellular solids with tailored isotropic and anisotropic Poisson's ratios. More particularly, aspects of this disclosure relate to auxetic structures with engineered patterns that exhibit negative Poisson's Ratio (NPR) behavior, as well as systems, methods and devices using such structures.
  • NPR Poisson's Ratio
  • Poisson's Ratio When materials are compressed along a particular axis, they are most commonly observed to expand in directions transverse to the applied axial load. Conversely, most materials contract along a particular axis when a tensile load is applied along an axis transverse to the axis of contraction.
  • the material property that characterizes this behavior is known as the Poisson's Ratio, which can be defined as the negative of the ratio of transverse/lateral strain to axial/longitudinal strain under axial loading conditions.
  • the majority of materials are characterized by a positive Poisson's Ratio, which is approximately 0.5 for rubber, approximately 0.3 for aluminum, brass and steel, and approximately 0.2 for glass.
  • auxetic Materials with a negative Poisson's Ratio (NPR), on the other hand, will contract (or expand) in the transverse direction when compressed (or stretched) in the axial direction.
  • NPR negative Poisson's Ratio
  • auxetic behavior involves an interplay between the microstructure of the material and its deformation. Examples of this are provided by the discovery that metals with a cubic lattice, natural layered ceramics, ferroelectric polycrystalline ceramics, and zeolites may all exhibit negative Poisson's Ratio behavior.
  • auxetic materials A significant challenge in the fabrication of auxetic materials is that it usually involves embedding structures with intricate geometries within a host matrix. As such, the manufacturing process has been a bottleneck in the practical development towards applications.
  • a structure which forms the basis of many auxetic materials is that of a cellular solid. Research into the deformation of these materials is a relatively mature field with primary emphasis on the role of buckling phenomena, on load carrying capacity, and energy absorption under compressive loading. Very recently, the results of a combined experimental and numerical investigation demonstrated that mechanical instabilities in 2D periodic porous structures can trigger dramatic transformations of the original geometry.
  • uniaxial loading of a square array of circular holes in an elastomeric matrix is found to lead to a pattern of alternating mutually orthogonal ellipses while the array is under load.
  • the geometric reorganization observed at the instability is both reversible and repeatable and it occurs over a narrow range of the applied load.
  • the pattern transformation leads to unidirectional negative Poisson's Ratio behavior for the 2D structure, i.e., it only occurs under compression.
  • U.S. Pat. No. 5,233,828 (“828 patent”) shows an example of an engineered void structure—a combustor liner or “heat shield”—utilized in high temperature applications.
  • Combustor liners are typically used in the combustion section of a gas turbine. Combustor liners can also be used in the exhaust section or in other sections or components of the gas turbine, such as the turbine blades.
  • combustors burn gas at intensely high temperatures, such as around 3,000° F. or higher. To prevent this intense heat from damaging the combustor before it exits to a turbine, the combustor liner is provided in the interior of the combustor to insulate the surrounding engine.
  • cooling feature have conventionally been provided, such as is shown in the '828 patent, in the form of spaced cooling holes disposed in a continuous pattern.
  • U.S. Pat. No. 8,066,482 B2 presents an engineered structural member having elliptically-shaped cooling holes to enhance the cooling of a desired region of a gas turbine while reducing stress levels in and around the cooling holes.
  • European Patent No. EP 0971172 A1 likewise shows another example of a perforated liner used in a combustion zone of a gas turbine. None of the above patent documents, however, provide examples disclosed as exhibiting auxetic behavior or being engineered to provide NPR effects.
  • U.S. Patent Application Pub. No. 2010/0009120 A1 discloses various transformative periodic structures which include elastomeric or elasto-plastic periodic solids that experience transformation in the structural configuration upon application of a critical macroscopic stress or strain. Said transformation alters the geometric pattern, changing the spacing and the shape of the features within the transformative periodic structure. Upon removal of the critical macroscopic stress or strain, these elastomeric periodic solids recover their original form.
  • U.S. Patent Application Pub. No. 2011/0059291 A1 discloses structured porous materials, where the porous structure provides a tailored Poisson's ratio behavior.
  • porous structures consist of a pattern of elliptical or elliptical-like voids in an elastomeric sheet which is tailored, via the mechanics of the deformation of the voids and the mechanics of the deformation of the material, to provide a negative or a zero Poisson's ratio.
  • auxetic structures with repeating patterns of elongated apertures (also referred to herein as “voids” or “slots”) that are engineered to provide a desired negative Poisson's Ratio (NPR) behavior and improved cooling performance.
  • NPR negative Poisson's Ratio
  • aspects of the present disclosure are directed to multi-functional NPR structures with angled air passages in the hot section of a gas turbine. Additional aspects are directed towards gas turbine combustors that are made with walls from a material with engineered angled void features that provide particular thermal, damping and/or acoustic functionalities. Such functionalities include, for example, acoustic attenuation (or noise damping), stress reduction (or load damping), and thermal cooling (or heat damping).
  • an auxetic structure includes an elastically rigid body, such as a metallic sheet or other sufficiently elastic solid material, with opposing top and bottom surfaces.
  • First and second pluralities of elongated apertures extend through the elastically rigid body from the top surface to the bottom surface.
  • the first plurality of elongated apertures extends transversely (e.g., orthogonally) with respect to the second plurality of elongated apertures.
  • the first and/or second pluralities of elongated apertures are obliquely angled with the top and/or bottom surfaces of the elastically rigid body.
  • each slot traverses the thickness of a sheet material at an angle that is oblique (e.g., approximately 40-70 degrees) to the material's plane.
  • the elongated apertures are cooperatively configured to provide a desired or minimum cooling performance while exhibiting stress reduction through negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions.
  • NPR negative Poisson's Ratio
  • the elongated apertures are engineered with a predefined porosity, a predetermined pattern, and/or a predetermined aspect ratio to achieve the desired NPR behavior.
  • the auxetic structure may exhibit an effusion cooling effectiveness of approximately 30-50%, a porosity of about 0.3 to about 9%, and a Poisson's Ratio of approximately ⁇ 0.2 to ⁇ 0.9%.
  • an effusion-cooling auxetic sheet structure which includes a metallic sheet with opposing top and bottom surfaces.
  • First and second pluralities of elongated apertures extend through the metallic sheet from the top surface to the bottom surface.
  • the first plurality of elongated apertures has a first set of geometric characteristics and is arranged in a first pattern.
  • the second plurality of elongated apertures has a second set of geometric characteristics and is arranged in a second pattern.
  • the elongated apertures of the first plurality are orthogonally oriented with respect to the elongated apertures of the second plurality.
  • Each of the elongated apertures is obliquely angled with respect to the top surface of the elastically rigid body.
  • the geometric characteristics and pattern of the first plurality of elongated apertures are cooperatively configured with the geometric characteristics and pattern of the second plurality of elongated apertures to provide a desired or minimum cooling performance while exhibiting negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions.
  • NPR Poisson's Ratio
  • a method for manufacturing an auxetic structure includes: providing an elastically rigid body with opposing top and bottom surfaces; adding to the elastically rigid body a first plurality of apertures extending through the elastically rigid body from the top surface to the bottom surface, the first plurality of apertures being arranged in rows and columns; and, adding to the elastically rigid body a second plurality of apertures extending through the elastically rigid body from the top surface to the bottom surface, the second plurality of apertures being arranged in rows and columns.
  • Each aperture of the first and/or second pluralities of elongated apertures is obliquely angled with the top surface of the elastically rigid body.
  • the first and second pluralities of apertures are cooperatively configured to provide a desired or minimum cooling performance while exhibiting a negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions.
  • NPR negative Poisson's Ratio
  • the elongated apertures are engineered with a predefined porosity, a predetermined pattern, and/or a predetermined aspect ratio to achieve the desired NPR behavior.
  • the auxetic structure may exhibit an effusion cooling effectiveness of approximately 30-50% and a Poisson's Ratio of approximately ⁇ 0.2 to ⁇ 0.9%.
  • the elastically rigid body may take on various forms, such as a metallic sheet or other sufficiently elastic solid material.
  • FIG. 1 is a graph of Nominal Strain vs. Poisson's Ratio illustrating the Poisson's Ratio behavior of representative structures with elongated through holes according to aspects of the present disclosure.
  • FIGS. 2A-2C are illustrations of the representative structures of FIG. 1 corresponding to specific data points from the graph.
  • FIGS. 3A and 3B are side-view and perspective-view illustrations, respectively, of an angled NPR S-slot according to aspects of the present disclosure.
  • FIGS. 4A-4D are perspective-view illustrations of other angled NPR slots in accordance with aspects of the present disclosure.
  • FIGS. 5A and 5B are plan-view illustrations of an angled NPR S-slot and an angled NPR Z-slot, respectively, with variable cap rotation in accordance with aspects of the present disclosure.
  • FIGS. 6A-6D are plan-view illustrations of angled NPR S-slots exhibiting a 0-degree angle, a 45-degree angle, a 55-degree angle, and a 65-degree angle, respectively, in accordance with aspects of the present disclosure.
  • FIGS. 7A-7C are graphical illustrations of the cooling behaviors for non-NPR normal cooling holes, normal NPR cooling slots, and angled NPR cooling slots, respectively, in accordance with aspects of the present disclosure.
  • auxetic structures which include repeating patterns of angled slots that provide negative Poisson's Ratio (NPR) behavior when macroscopically loaded.
  • Poisson's Ratio (or “Poisson coefficient”) can be generally typified as the ratio of transverse contraction strain to longitudinal extension strain in a stretched object.
  • Poisson's Ratio is typically positive for most materials, including many alloys, polymers, polymer foams and cellular solids, which become thinner in cross section when stretched.
  • the auxetic structures disclosed herein exhibit a negative Poisson's Ratio behavior.
  • an auxetic structure when compressed along one axis (e.g., in the Y-direction), coaxial strain results in a moment around the center of each cell because of the way the adjacent apertures are arranged. This, in turn, causes the cells to rotate. Each cell rotates in a direction opposite to that of its immediate neighbors. This rotation results in a reduction in the transverse axis (X-direction) distance between horizontally adjacent cells.
  • X-direction transverse axis
  • the unadulterated material itself may have a positive Poisson's Ratio, but by modifying the structure with the introduction of the angled-slot patterns disclosed herein, the structure behaves as having a negative Poisson's Ratio.
  • FIG. 1 is a graph of Poisson's Ratio (PR) against Nominal Strain illustrating the Poisson's Ratio behavior of three representative void structures shown in FIGS. 2A-2C .
  • the chart of FIG. 1 shows the Poisson's Ratio of each test piece under load.
  • the “instantaneous” PR can be determined and plotted against a parameter (e.g., nominal strain) representing the level of deformation.
  • a parameter e.g., nominal strain
  • the NPR aperture patterns can consist of horizontally and vertically oriented, elongated holes (also referred to as “apertures” or “voids” or “slots”), shown as elliptical through slots.
  • the center of each slot is on the crossing point of two of the lines.
  • Horizontally oriented and vertically oriented slots alternate on the vertical and horizontal lines such that any vertically oriented slot is surrounded by horizontally oriented slots (and vice versa), while the next vertically oriented slots are found on both diagonals.
  • These voids can also act as cooling and/or damping holes and, due to their arrangement, also as stress reduction features.
  • One or more of the slots shown herein can be replaced by elongated NPR protrusions or semispherical NPR dimples.
  • gas turbine combustors that are made with one or more walls from a material with any of the specific auxetic structure configurations disclosed herein.
  • the angled slots are generated in a metal body directly in a stress-free state such that the apertures are equivalent in shape to collapsed void shapes found in rubber under external load in order to get NPR behavior in the metal body without collapsing the metallic structure in manufacturing.
  • Various manufacturing routes can be used to replicate the void patterns in the metallic component. The manufacturing does not necessarily contain buckling as one of the process steps.
  • the auxetic structures disclosed herein are not limited to the combustor wall; rather, these features can be incorporated into other sections of a turbine (e.g., a blade, a vane, etc.).
  • holes used for cooling air flow and damping also act as stress risers.
  • the negative Poisson's Ratio will make the wall material contract in the horizontal direction, and vice versa. This behavior will reduce the stresses at the hotspot significantly. This effect is stronger than just the impact of the reduced stiffness. Stress at hot spot gets reduced, for example, by 50% which, in turn, leads to an increase in stress fatigue life by several orders of magnitude.
  • the stress reduction by the NPR behavior does not increase the air consumption of the combustor wall. The longer life could be used as such or the wall material could be replaced by a cheaper one in order to reduce raw material costs.
  • the superalloy may be a nickel-based superalloy, such as Inconel (e.g. IN100, IN600, IN713), Waspaloy, Rene alloys (e.g. Rene 41, Rene 80, Rene 95, Rene N5), Haynes alloys, Incoloy, MP98T, TMS alloys, and CMSX (e.g. CMSX-4) single crystal alloys.
  • Inconel e.g. IN100, IN600, IN713
  • Waspaloy Rene alloys
  • Rene alloys e.g. Rene 41, Rene 80, Rene 95, Rene N5
  • Haynes alloys e.g. Rene 41, Rene 80, Rene 95, Rene N5
  • Haynes alloys e.g. Rene 41, Rene 80, Rene 95, Rene N5
  • Haynes alloys e.g. Rene 41, Rene 80, Rene 95, Rene N5
  • Haynes alloys e.g. Rene 41
  • an optimal aspect ratio for the elongated apertures may be a predetermined optimal aspect ratio for the elongated apertures to provide a desired NPR behavior.
  • “aspect ratio” of the apertures can be defined to mean the length divided by the width of the apertures, or the length of the major axis divided by the length of the minor axis of the apertures. It may be desirable, in some embodiments, that the aspect ratio of the apertures be approximately 5-40 or, in some embodiments, approximately 20-30.
  • An optimal NPR may comprise, for example, a PR of about ⁇ 0.2 to about ⁇ 0.9 or, for some embodiments, about ⁇ 0.5.
  • aspects of the disclosed concepts can be demonstrated on structural patterns created with a pattern lengthscale at the millimeter, and are equally applicable to structures possessing the same periodic patterns at a smaller lengthscale (e.g., micrometer, submicrometer, and nanometer lengthscales) or larger lengthscales so far as the unit cells fit in the structure.
  • a smaller lengthscale e.g., micrometer, submicrometer, and nanometer lengthscales
  • larger lengthscales so far as the unit cells fit in the structure.
  • FIGS. 3A and 3B illustrate an auxetic structure, designated generally at 300 , which utilizes an alternating pattern of elongated asymmetrical slots.
  • the foregoing slots are elongated in that each has a major axis (e.g., a length) that is larger than and perpendicular to a minor axis (e.g., a width).
  • the auxetic structure 300 comprises an elastically rigid body 310 , which may be in the form of a metallic sheet or other solid material with adequate elasticity to return substantially or completely to its original form once macroscopic loading conditions are sufficiently reduced or eliminated.
  • Elastically rigid body 310 has a first (top) surface 314 in opposing spaced relation to a second (bottom) surface 316 .
  • Fabricated into the elastically rigid body 310 is a first plurality of S-shaped through slots (also referred to herein as “apertures” or “voids” or “slots”), represented herein by slot 312 , which extend through the body 310 from the top surface 314 to the bottom surface 316 .
  • a second plurality of S-shaped through slots/apertures also extends through the elastically rigid body 310 from the top surface 314 to the bottom surface 316 .
  • the pattern of elongated apertures present in the elastically rigid body 310 may be similar in arrangement to what is seen in FIGS. 2B and 2C .
  • S-shaped through slots 312 , 318 are arranged in an array or matrix of rows and columns, with the first plurality of elongated apertures 312 extending transversely with respect to the second plurality of elongated apertures 318 .
  • hidden lines indicating the internal structural configuration of slots 318 have been omitted from FIGS. 3A and 3B for clarity to better show the internal structural configuration of slots 312 .
  • the rows are equally spaced from each other and, likewise, the columns are equally spaced from each other.
  • each row and each column comprises vertically oriented S-shaped through slots 312 interleaved with horizontally oriented S-shaped through slots 318 .
  • each vertically oriented through slot 312 is neighbored on four sides by horizontally oriented through slots 318
  • each horizontally oriented through slot 318 is neighbored on four sides by vertically oriented through slots 312 .
  • the minor axes of the first plurality of S-shaped through slots 312 are parallel to the rows of the array
  • the minor axes of the second plurality of S-shaped through slots 318 are parallel to the columns of the array.
  • the major axes of the through slots 318 which are parallel to the rows of the array, are perpendicular to the major axes of the through slots 312 , which are parallel to the columns of the array. It is also envisioned that other patterns and arrangements for achieving stress reduction through NPR behavior are within the scope and spirit of the present disclosure.
  • the illustrated pattern of elongated, angled slots provides a specific porosity (e.g., a porosity of about 0.3 to about 9.0%) and a desired cooling performance (e.g., an effusion cooling effectiveness of approximately 30-50%) while exhibiting a desired negative Poisson's Ratio behavior (e.g., a PR of about ⁇ 0.2 to about ⁇ 0.9) under macroscopic planar loading conditions (e.g., when tension or compression is applied in the plane of the sheet).
  • a specific porosity e.g., a porosity of about 0.3 to about 9.0%
  • a desired cooling performance e.g., an effusion cooling effectiveness of approximately 30-50%)
  • a desired negative Poisson's Ratio behavior e.g., a PR of about ⁇ 0.2 to about ⁇ 0.9
  • macroscopic planar loading conditions e.g., when tension or compression is applied in the plane of the sheet.
  • a cell may consist of two laterally adjacent vertical slots aligned with two vertically adjacent horizontal slots to form a square-shaped unit. Each cell rotates in a direction opposite to that of its immediate neighboring cells. This rotation increases the X-direction distance between horizontally adjacent cells such that stretching the structure in the Y-direction causes it to stretch in the X-direction.
  • the first plurality of S-shaped through slots 312 have (first) engineered geometric characteristics, including a predefined geometry and a predefined aspect ratio, while the second plurality of S-shaped through slots 318 have (second) engineered geometric characteristics, including a predefined geometry and a predefined aspect ratio, that are cooperatively configured with (third) engineered geometric characteristics of the aperture pattern, including NPR-slot density and cell arrangement, to achieve a desired NPR behavior under macroscopic loading conditions.
  • Each slot of the first and/or second pluralities of elongated S-shaped through slots 312 , 318 can be obliquely angled with respect to the top surface 314 or bottom surface 316 , or both, of the auxetic structure's 300 elastically rigid body 310 .
  • slot 312 is shown in FIG. 3A traversing the entire thickness of the material at an angle that is oblique to the material's horizontal plane.
  • each aperture has an angle ⁇ of approximately 20-80 degrees or, in some embodiments, approximately 40-70 degrees with the top and bottom surfaces 314 , 316 of the auxetic structure's body 310 .
  • Inclination angle ⁇ can be defined as the angle between the injection vector and its projection on the material plane. This inclination angle can be varied in a 360° rotational angle of freedom to achieve numerous desired combinations of auxetic behavior and film cooling performance.
  • Patterned angled NPR-slot features such as those disclosed in FIGS. 3-6 , have been shown to cool significantly better than conventional right-angled (normal) circular holes and cooling slots as the internal surface area of the slots is larger than that of normal circular holes or slots.
  • Angled NPR-slot film can benefit from the Coanda Effect, which causes the coolant jet to better adhere to the wall, rather than lifting off and penetrating the mainstream flow. This helps to decrease the inclination angle, which in turn decreases coolant jet penetration and increases cooling performance of NPR slots. From an aerodynamic perspective, the reduced penetration of the coolant jet of angled NPR slots decreases aerodynamic losses due to film cooling compared with normal coolant slot flow.
  • the inclination angle can be varied to achieve a desired combination of auxetic behavior and film cooling performance.
  • a combustor liner with sheet metal walls in which conventional round effusion holes or normal effusion slots are replaced with a pattern of angled S-shaped NPR slots forming an auxetic structure. Cooling air fed through these angled S-shaped slots removes heat from the structure and produces an even distribution of cooling air over the surface.
  • These angled slots which have an increased internal surface area, enhance film cooling performance and improve mechanical response.
  • angled NPR slots are capable of sustaining higher flame temperatures, and help impart to the sheet a much longer life compared to conventional sheet metal walls with normal effusion holes.
  • FIGS. 4A-4D are perspective-view illustrations of other auxetic structures, designated generally at 400 A, 400 B, 400 C and 400 D, respectively, with angled NPR slots in accordance with aspects of the present disclosure.
  • the auxetic structures 400 A- 400 D may include any of the features, options, and alternatives described herein with respect to the other auxetic structures.
  • any of the auxetic structures disclosed herein can share features, options and alternatives with the other disclosed embodiments.
  • Auxetic structures 400 A- 400 D each comprises an elastically rigid body 410 A, 410 B, 410 C and 410 D, respectively, fabricated with a plurality of elongated and angled apertures 412 A, 412 B, 412 C and 412 D, respectively, arranged in a pattern to provide a desired cooling performance while exhibiting a predetermined NPR behavior under macroscopic planar loading conditions.
  • elongated apertures 412 A have an S-shaped plan-view profile
  • the elongated apertures 412 B in FIG. 4B have an I-shaped plan-view profile, which includes a pair of spaced semicircular slots connected by an elongated linear slot.
  • any of the foregoing angled NPR slots can be manufactured by laser cutting, for example, by laying out a linear pattern of NPR slots along the inclination angle to the surface.
  • the profile of the angled NPR slots that appears on the outer (top) surface can be designed as a projection of a standard shape—e.g., a standard “S” 414 A, a standard “I” 414 B with rounded arms, a standard barbell 414 C with circular ends, and a standard ellipse 414 D.
  • a standard shape e.g., a standard “S” 414 A, a standard “I” 414 B with rounded arms, a standard barbell 414 C with circular ends, and a standard ellipse 414 D.
  • the profile of the angled NPR slots that appears on the outer (top) surface can be highly distorted from the original image depending, for example, on the desired angle and/or orientation of the slot.
  • FIGS. 6A-6D illustrate slot distortion on an outer surface of a tubular auxetic structure: FIG.
  • FIG. 6A illustrating normal NPR S-slots exhibiting a 0-degree angle
  • FIG. 6B illustrating angled NPR S-slots exhibiting a 45-degree angle
  • FIG. 6C illustrating angled NPR S-slots exhibiting a 55-degree angle
  • FIG. 6D illustrating angled NPR S-slots exhibiting a 65-degree angle.
  • a new NPR slot shape for instance, Z-shaped slots 512 A ( FIG. 5A ) and S-shaped slots ( FIG. 5B ), can be developed by reducing cap length 511 A and 511 B and/or cap height 513 A and 513 B to provide a horizontal projection similar to an existing or “standard” S-shape/Z-shape.
  • the size and shape of the caps can be varied to achieve a desired combination of auxetic behavior and film cooling performance.
  • Film cooling performance of angled effusion S-shaped slots or, equivalently, Z-shaped slots can be improved by producing a longer cooling thermal layer above the hot surface.
  • a longer cooling thermal layer can be created by increasing the lateral area of the slots normal to the free mainstream fluid by rotating the S-shaped slot cap in the counter-clockwise direction (or clockwise direction for Z-shaped slot caps).
  • This cap rotation angle 515 A and 515 B can be varied to achieve a desired combination of auxetic behavior and film cooling performance.
  • aspects of this disclosure are also directed to methods of manufacturing and methods of using auxetic structures.
  • a method is presented for manufacturing an auxetic structure, such as the auxetic structures described above with respect to FIGS. 3-6 .
  • the method includes, as an inclusive yet non-exclusive set of acts: providing an elastically rigid body, such as the elastically rigid body 310 of FIGS. 3A and 3B , with opposing top and bottom surfaces; adding to the elastically rigid body a first plurality of apertures, such as the elongated S-shaped slots 312 of FIGS.
  • the first and second pluralities of apertures are arranged in rows and columns. Each aperture of the first and/or second plurality is obliquely angled with the top surface of the elastically rigid body.
  • the first and second pluralities of apertures are cooperatively configured to provide a predefined cooling performance while exhibiting a predetermined negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions.
  • NPR negative Poisson's Ratio
  • the elongated apertures are engineered with a predefined porosity, a predetermined pattern, and/or a predetermined aspect ratio to achieve the desired NPR behavior.
  • the auxetic structure may exhibit an effusion cooling effectiveness of approximately 30-50% and a Poisson's Ratio of approximately ⁇ 0.2 to ⁇ 0.9%.
  • the elastically rigid body may take on various forms, such as a metallic sheet or other sufficiently elastic solid material.
  • the method includes at least those steps enumerated above and illustrated in the drawings. It is also within the scope and spirit of the present invention to omit steps, include additional steps, and/or modify the order presented above. It should be further noted that the foregoing method can be representative of a single sequence for designing and fabricating an auxetic structure. However, it is expected that the method will be practiced in a systematic and repetitive manner.

Abstract

Auxetic structures, effusion-cooling auxetic sheets, systems and devices with auxetic structures, and methods of using and methods of making auxetic structures are disclosed. An auxetic structure is disclosed which includes an elastically rigid body with opposing top and bottom surfaces. First and second pluralities of elongated apertures extend through the elastically rigid body from the top surface to the bottom surface. The first plurality of elongated apertures extends transversely with respect to the second plurality of elongated apertures. The first and/or second pluralities of elongated apertures are obliquely angled with the top surface of the elastically rigid body. The elongated apertures are cooperatively configured to provide a desired cooling performance while exhibiting stress reduction through negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions. For example, the auxetic structure may exhibit an effusion cooling effectiveness of approximately 30-50 Eta and a Poisson's Ratio of approximately −0.2 to −0.9%.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application claims the right of priority to U.S. Provisional Patent Application No. 62/118,826, filed on Feb. 20, 2015, and U.S. Provisional Patent Application No. 62/101,840, filed on Jan. 9, 2015, both of which are incorporated herein by reference in their respective entireties.
  • TECHNICAL FIELD
  • The present disclosure relates generally to porous materials and cellular solids with tailored isotropic and anisotropic Poisson's ratios. More particularly, aspects of this disclosure relate to auxetic structures with engineered patterns that exhibit negative Poisson's Ratio (NPR) behavior, as well as systems, methods and devices using such structures.
  • BACKGROUND
  • When materials are compressed along a particular axis, they are most commonly observed to expand in directions transverse to the applied axial load. Conversely, most materials contract along a particular axis when a tensile load is applied along an axis transverse to the axis of contraction. The material property that characterizes this behavior is known as the Poisson's Ratio, which can be defined as the negative of the ratio of transverse/lateral strain to axial/longitudinal strain under axial loading conditions. The majority of materials are characterized by a positive Poisson's Ratio, which is approximately 0.5 for rubber, approximately 0.3 for aluminum, brass and steel, and approximately 0.2 for glass.
  • Materials with a negative Poisson's Ratio (NPR), on the other hand, will contract (or expand) in the transverse direction when compressed (or stretched) in the axial direction. Materials that exhibit negative Poisson's Ratio behavior are oftentimes referred to as “auxetic” materials. The results of many investigations suggest that auxetic behavior involves an interplay between the microstructure of the material and its deformation. Examples of this are provided by the discovery that metals with a cubic lattice, natural layered ceramics, ferroelectric polycrystalline ceramics, and zeolites may all exhibit negative Poisson's Ratio behavior. Moreover, several geometries and mechanisms have been proposed to achieve negative values for the Poisson's Ratio, including foams with reentrant structures, hierarchical laminates, polymeric and metallic foams. Negative Poisson's Ratio effects have also been demonstrated at the micrometer scale using complex materials which were fabricated using soft lithography and at the nanoscale with sheet assemblies of carbon nanotubes.
  • A significant challenge in the fabrication of auxetic materials is that it usually involves embedding structures with intricate geometries within a host matrix. As such, the manufacturing process has been a bottleneck in the practical development towards applications. A structure which forms the basis of many auxetic materials is that of a cellular solid. Research into the deformation of these materials is a relatively mature field with primary emphasis on the role of buckling phenomena, on load carrying capacity, and energy absorption under compressive loading. Very recently, the results of a combined experimental and numerical investigation demonstrated that mechanical instabilities in 2D periodic porous structures can trigger dramatic transformations of the original geometry. Specifically, uniaxial loading of a square array of circular holes in an elastomeric matrix is found to lead to a pattern of alternating mutually orthogonal ellipses while the array is under load. This results from an elastic instability above a critical value of the applied strain. The geometric reorganization observed at the instability is both reversible and repeatable and it occurs over a narrow range of the applied load. Moreover, it has been shown that the pattern transformation leads to unidirectional negative Poisson's Ratio behavior for the 2D structure, i.e., it only occurs under compression.
  • U.S. Pat. No. 5,233,828 (“828 patent”) shows an example of an engineered void structure—a combustor liner or “heat shield”—utilized in high temperature applications. Combustor liners are typically used in the combustion section of a gas turbine. Combustor liners can also be used in the exhaust section or in other sections or components of the gas turbine, such as the turbine blades. In operation, combustors burn gas at intensely high temperatures, such as around 3,000° F. or higher. To prevent this intense heat from damaging the combustor before it exits to a turbine, the combustor liner is provided in the interior of the combustor to insulate the surrounding engine. To minimize temperature and pressure differentials across a combustor liner, cooling feature have conventionally been provided, such as is shown in the '828 patent, in the form of spaced cooling holes disposed in a continuous pattern. As another example, U.S. Pat. No. 8,066,482 B2 presents an engineered structural member having elliptically-shaped cooling holes to enhance the cooling of a desired region of a gas turbine while reducing stress levels in and around the cooling holes. European Patent No. EP 0971172 A1 likewise shows another example of a perforated liner used in a combustion zone of a gas turbine. None of the above patent documents, however, provide examples disclosed as exhibiting auxetic behavior or being engineered to provide NPR effects.
  • U.S. Patent Application Pub. No. 2010/0009120 A1 discloses various transformative periodic structures which include elastomeric or elasto-plastic periodic solids that experience transformation in the structural configuration upon application of a critical macroscopic stress or strain. Said transformation alters the geometric pattern, changing the spacing and the shape of the features within the transformative periodic structure. Upon removal of the critical macroscopic stress or strain, these elastomeric periodic solids recover their original form. By way of comparison, U.S. Patent Application Pub. No. 2011/0059291 A1 discloses structured porous materials, where the porous structure provides a tailored Poisson's ratio behavior. These porous structures consist of a pattern of elliptical or elliptical-like voids in an elastomeric sheet which is tailored, via the mechanics of the deformation of the voids and the mechanics of the deformation of the material, to provide a negative or a zero Poisson's ratio. All of the foregoing patent documents are incorporated herein by reference in their respective entireties and for all purposes.
  • SUMMARY
  • Aspects of the present disclosure are directed towards auxetic structures with repeating patterns of elongated apertures (also referred to herein as “voids” or “slots”) that are engineered to provide a desired negative Poisson's Ratio (NPR) behavior and improved cooling performance. Unlike prior art NPR void shapes that extend through the plane of the structure material, traversing the thickness of the material in a direction normal to the material's plane, NPR voids disclosed herein traverse the thickness of the material at an angle that is oblique to the materials' plane. These angled void configurations enhance the cooling performance of the structure while retaining a low porosity and providing a desired NPR behavior. Other aspects of the present disclosure are directed to multi-functional NPR structures with angled air passages in the hot section of a gas turbine. Additional aspects are directed towards gas turbine combustors that are made with walls from a material with engineered angled void features that provide particular thermal, damping and/or acoustic functionalities. Such functionalities include, for example, acoustic attenuation (or noise damping), stress reduction (or load damping), and thermal cooling (or heat damping).
  • According to aspects of the present disclosure, auxetic structures with angled NPR slots are disclosed. In an example, an auxetic structure includes an elastically rigid body, such as a metallic sheet or other sufficiently elastic solid material, with opposing top and bottom surfaces. First and second pluralities of elongated apertures extend through the elastically rigid body from the top surface to the bottom surface. The first plurality of elongated apertures extends transversely (e.g., orthogonally) with respect to the second plurality of elongated apertures. The first and/or second pluralities of elongated apertures are obliquely angled with the top and/or bottom surfaces of the elastically rigid body. In an example, each slot traverses the thickness of a sheet material at an angle that is oblique (e.g., approximately 40-70 degrees) to the material's plane. The elongated apertures are cooperatively configured to provide a desired or minimum cooling performance while exhibiting stress reduction through negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions. By way of example, the elongated apertures are engineered with a predefined porosity, a predetermined pattern, and/or a predetermined aspect ratio to achieve the desired NPR behavior. The auxetic structure may exhibit an effusion cooling effectiveness of approximately 30-50%, a porosity of about 0.3 to about 9%, and a Poisson's Ratio of approximately −0.2 to −0.9%. Cooling effectiveness (Eta) can be defined as the difference of the hot gas temperature to the wall temperature in the presence of a cooling device divided by the difference of the hot gas temperature to the temperature of the supplied cooling gas: Eta=(T_hotgas−T_wall)/(T_hotgas−T_coolant).
  • In accordance with other aspects of this disclosure, effusion-cooling auxetic sheet structures are featured. In an example, an effusion-cooling auxetic sheet structure is presented which includes a metallic sheet with opposing top and bottom surfaces. First and second pluralities of elongated apertures extend through the metallic sheet from the top surface to the bottom surface. The first plurality of elongated apertures has a first set of geometric characteristics and is arranged in a first pattern. Likewise, the second plurality of elongated apertures has a second set of geometric characteristics and is arranged in a second pattern. The elongated apertures of the first plurality are orthogonally oriented with respect to the elongated apertures of the second plurality. Each of the elongated apertures is obliquely angled with respect to the top surface of the elastically rigid body. The geometric characteristics and pattern of the first plurality of elongated apertures are cooperatively configured with the geometric characteristics and pattern of the second plurality of elongated apertures to provide a desired or minimum cooling performance while exhibiting negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions.
  • Other aspects of the present disclosure are directed to methods of manufacturing and methods of using auxetic structures. In an example, a method is presented for manufacturing an auxetic structure. Said method includes: providing an elastically rigid body with opposing top and bottom surfaces; adding to the elastically rigid body a first plurality of apertures extending through the elastically rigid body from the top surface to the bottom surface, the first plurality of apertures being arranged in rows and columns; and, adding to the elastically rigid body a second plurality of apertures extending through the elastically rigid body from the top surface to the bottom surface, the second plurality of apertures being arranged in rows and columns. Each aperture of the first and/or second pluralities of elongated apertures is obliquely angled with the top surface of the elastically rigid body. The first and second pluralities of apertures are cooperatively configured to provide a desired or minimum cooling performance while exhibiting a negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions. By way of example, the elongated apertures are engineered with a predefined porosity, a predetermined pattern, and/or a predetermined aspect ratio to achieve the desired NPR behavior. The auxetic structure may exhibit an effusion cooling effectiveness of approximately 30-50% and a Poisson's Ratio of approximately −0.2 to −0.9%. The elastically rigid body may take on various forms, such as a metallic sheet or other sufficiently elastic solid material.
  • The above summary is not intended to represent every embodiment or every aspect of the present disclosure. Rather, the foregoing summary merely provides an exemplification of some of the novel aspects and features set forth herein. The above features and advantages, and other features and advantages of the present disclosure, which are considered to be inventive singly or in any combination, will be readily apparent from the following detailed description of representative embodiments and modes for carrying out the present invention when taken in connection with the accompanying drawings and the appended claims.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a graph of Nominal Strain vs. Poisson's Ratio illustrating the Poisson's Ratio behavior of representative structures with elongated through holes according to aspects of the present disclosure.
  • FIGS. 2A-2C are illustrations of the representative structures of FIG. 1 corresponding to specific data points from the graph.
  • FIGS. 3A and 3B are side-view and perspective-view illustrations, respectively, of an angled NPR S-slot according to aspects of the present disclosure.
  • FIGS. 4A-4D are perspective-view illustrations of other angled NPR slots in accordance with aspects of the present disclosure.
  • FIGS. 5A and 5B are plan-view illustrations of an angled NPR S-slot and an angled NPR Z-slot, respectively, with variable cap rotation in accordance with aspects of the present disclosure.
  • FIGS. 6A-6D are plan-view illustrations of angled NPR S-slots exhibiting a 0-degree angle, a 45-degree angle, a 55-degree angle, and a 65-degree angle, respectively, in accordance with aspects of the present disclosure.
  • FIGS. 7A-7C are graphical illustrations of the cooling behaviors for non-NPR normal cooling holes, normal NPR cooling slots, and angled NPR cooling slots, respectively, in accordance with aspects of the present disclosure.
  • The present disclosure is susceptible to various modifications and alternative forms, and some representative embodiments have been shown by way of example in the drawings and will be described in detail herein. It should be understood, however, that the inventive aspects of this disclosure are not limited to the particular forms illustrated in the drawings. Rather, the disclosure is to cover all modifications, equivalents, combinations and subcombinations, and alternatives falling within the spirit and scope of the invention as defined by the appended claims.
  • DETAILED DESCRIPTION OF THE ILLUSTRATED EMBODIMENTS
  • This disclosure is susceptible of embodiment in many different forms. There are shown in the drawings, and will herein be described in detail, representative embodiments with the understanding that the present disclosure is to be considered as an exemplification of the principles of the present disclosure and is not intended to limit the broad aspects of the disclosure to the embodiments illustrated. To that extent, elements and limitations that are disclosed, for example, in the Abstract, Summary, and Detailed Description sections, but not explicitly set forth in the claims, should not be incorporated into the claims, singly or collectively, by implication, inference or otherwise. For purposes of the present detailed description, unless specifically disclaimed or logically prohibited: the singular includes the plural and vice versa; and the words “including” or “comprising” or “having” means “including without limitation.” Moreover, words of approximation, such as “about,” “almost,” “substantially,” “approximately,” and the like, can be used herein in the sense of “at, near, or nearly at,” or “within 3-5% of,” or “within acceptable manufacturing tolerances,” or any logical combination thereof, for example.
  • Aspects of the present disclosure are directed towards auxetic structures which include repeating patterns of angled slots that provide negative Poisson's Ratio (NPR) behavior when macroscopically loaded. Poisson's Ratio (or “Poisson coefficient”) can be generally typified as the ratio of transverse contraction strain to longitudinal extension strain in a stretched object. Poisson's Ratio is typically positive for most materials, including many alloys, polymers, polymer foams and cellular solids, which become thinner in cross section when stretched. The auxetic structures disclosed herein exhibit a negative Poisson's Ratio behavior.
  • According to aspects of the disclosed concepts, when an auxetic structure is compressed along one axis (e.g., in the Y-direction), coaxial strain results in a moment around the center of each cell because of the way the adjacent apertures are arranged. This, in turn, causes the cells to rotate. Each cell rotates in a direction opposite to that of its immediate neighbors. This rotation results in a reduction in the transverse axis (X-direction) distance between horizontally adjacent cells. In other words, compressing the structure in the Y-direction causes it to contract in the X-direction. Conversely, tension in the Y-direction results in expansion in the X-direction. At the scale of the entire structure, this mimics the behavior of an auxetic material. But many of the structures disclosed herein are composed of conventional materials. Thus, the unadulterated material itself may have a positive Poisson's Ratio, but by modifying the structure with the introduction of the angled-slot patterns disclosed herein, the structure behaves as having a negative Poisson's Ratio.
  • FIG. 1 is a graph of Poisson's Ratio (PR) against Nominal Strain illustrating the Poisson's Ratio behavior of three representative void structures shown in FIGS. 2A-2C. The chart of FIG. 1 shows the Poisson's Ratio of each test piece under load. At a certain level of deformation, the “instantaneous” PR can be determined and plotted against a parameter (e.g., nominal strain) representing the level of deformation. When a designer has a desired NPR for an intended application, the level of deformation corresponding to that PR can be determined and the geometry of the holes at that condition determined. This hole shape pattern can then be machined (manufactured) on an unstressed part to achieve a component with the desired PR.
  • As seen in FIGS. 2B and 2C, the NPR aperture patterns can consist of horizontally and vertically oriented, elongated holes (also referred to as “apertures” or “voids” or “slots”), shown as elliptical through slots. These elongated holes are arranged on horizontal and vertical lines (e.g., rows and columns of a square array in FIG. 2B) in a way that the vertical lines are equally spaced and the horizontal in both dimensions lines are equally spaced (also Δx=Δy). The center of each slot is on the crossing point of two of the lines. Horizontally oriented and vertically oriented slots alternate on the vertical and horizontal lines such that any vertically oriented slot is surrounded by horizontally oriented slots (and vice versa), while the next vertically oriented slots are found on both diagonals. These voids can also act as cooling and/or damping holes and, due to their arrangement, also as stress reduction features. One or more of the slots shown herein can be replaced by elongated NPR protrusions or semispherical NPR dimples.
  • Also disclosed are gas turbine combustors that are made with one or more walls from a material with any of the specific auxetic structure configurations disclosed herein. In some embodiments, the angled slots are generated in a metal body directly in a stress-free state such that the apertures are equivalent in shape to collapsed void shapes found in rubber under external load in order to get NPR behavior in the metal body without collapsing the metallic structure in manufacturing. Various manufacturing routes can be used to replicate the void patterns in the metallic component. The manufacturing does not necessarily contain buckling as one of the process steps. The auxetic structures disclosed herein are not limited to the combustor wall; rather, these features can be incorporated into other sections of a turbine (e.g., a blade, a vane, etc.).
  • In a conventional combustor wall, holes used for cooling air flow and damping also act as stress risers. In some of the disclosed embodiments, as the wall material at a hot spot presses against its surrounding material, e.g., in a vertical direction, the negative Poisson's Ratio will make the wall material contract in the horizontal direction, and vice versa. This behavior will reduce the stresses at the hotspot significantly. This effect is stronger than just the impact of the reduced stiffness. Stress at hot spot gets reduced, for example, by 50% which, in turn, leads to an increase in stress fatigue life by several orders of magnitude. The stress reduction by the NPR behavior does not increase the air consumption of the combustor wall. The longer life could be used as such or the wall material could be replaced by a cheaper one in order to reduce raw material costs.
  • It has also been demonstrated that the replacement of circular combustor cooling holes with a fraction of elongated and angled air passages of 2-3% reduces thermo-mechanical stress by a factor of at least five, while maintaining the cooling and damping performance. For example, elliptical cooling holes in the combustor have been predicted to result in a five-fold decrease in the worst principal stress. Inducing NPR behavior, thus, adds further functionality to the cooling holes of the combustor in that the NPR behavior generates a five-fold reduction in worst principal stress as compared to traditional cooling holes. In stress fatigue of a combustor-specific superalloy, halving the component stress increases the fatigue life by more than an order of magnitude. In some embodiments, the superalloy may be a nickel-based superalloy, such as Inconel (e.g. IN100, IN600, IN713), Waspaloy, Rene alloys (e.g. Rene 41, Rene 80, Rene 95, Rene N5), Haynes alloys, Incoloy, MP98T, TMS alloys, and CMSX (e.g. CMSX-4) single crystal alloys.
  • It has been shown that optimized porosity offers increased cooling function. As used herein, “porosity” can be defined to mean the surface area of the apertures, AA, divided by the surface area of the structure, AS, or Porosity=AA/AS. It may be desirable, in some embodiments, that the porosity of a given void structure be approximately 0.3-9.0% or, in some embodiments, approximately 1-4% or, in some embodiments, approximately 2%. By comparison, many prior art arrangements require a porosity of 40-50%.
  • There may be a predetermined optimal aspect ratio for the elongated apertures to provide a desired NPR behavior. As used herein, “aspect ratio” of the apertures can be defined to mean the length divided by the width of the apertures, or the length of the major axis divided by the length of the minor axis of the apertures. It may be desirable, in some embodiments, that the aspect ratio of the apertures be approximately 5-40 or, in some embodiments, approximately 20-30. An optimal NPR may comprise, for example, a PR of about −0.2 to about −0.9 or, for some embodiments, about −0.5. Aspects of the disclosed concepts can be demonstrated on structural patterns created with a pattern lengthscale at the millimeter, and are equally applicable to structures possessing the same periodic patterns at a smaller lengthscale (e.g., micrometer, submicrometer, and nanometer lengthscales) or larger lengthscales so far as the unit cells fit in the structure.
  • Turning next to FIGS. 3-6, there are shown various examples of angled-slot auxetic structures which exhibit desired NPR behaviors and enhanced cooling performance in accordance with the present disclosure. FIGS. 3A and 3B, for example, illustrate an auxetic structure, designated generally at 300, which utilizes an alternating pattern of elongated asymmetrical slots. The foregoing slots are elongated in that each has a major axis (e.g., a length) that is larger than and perpendicular to a minor axis (e.g., a width). As shown, the auxetic structure 300 comprises an elastically rigid body 310, which may be in the form of a metallic sheet or other solid material with adequate elasticity to return substantially or completely to its original form once macroscopic loading conditions are sufficiently reduced or eliminated. Elastically rigid body 310 has a first (top) surface 314 in opposing spaced relation to a second (bottom) surface 316. Fabricated into the elastically rigid body 310 is a first plurality of S-shaped through slots (also referred to herein as “apertures” or “voids” or “slots”), represented herein by slot 312, which extend through the body 310 from the top surface 314 to the bottom surface 316. A second plurality of S-shaped through slots/apertures, represented herein by slots 318, also extends through the elastically rigid body 310 from the top surface 314 to the bottom surface 316. The pattern of elongated apertures present in the elastically rigid body 310 may be similar in arrangement to what is seen in FIGS. 2B and 2C.
  • S-shaped through slots 312, 318 are arranged in an array or matrix of rows and columns, with the first plurality of elongated apertures 312 extending transversely with respect to the second plurality of elongated apertures 318. Note that hidden lines indicating the internal structural configuration of slots 318 have been omitted from FIGS. 3A and 3B for clarity to better show the internal structural configuration of slots 312. For at least some embodiments, the rows are equally spaced from each other and, likewise, the columns are equally spaced from each other. According to the illustrated embodiment of FIGS. 3A and 3B, for example, each row and each column comprises vertically oriented S-shaped through slots 312 interleaved with horizontally oriented S-shaped through slots 318. In effect, each vertically oriented through slot 312 is neighbored on four sides by horizontally oriented through slots 318, while each horizontally oriented through slot 318 is neighbored on four sides by vertically oriented through slots 312. With this arrangement, the minor axes of the first plurality of S-shaped through slots 312 are parallel to the rows of the array, whereas the minor axes of the second plurality of S-shaped through slots 318 are parallel to the columns of the array. Thus, the major axes of the through slots 318, which are parallel to the rows of the array, are perpendicular to the major axes of the through slots 312, which are parallel to the columns of the array. It is also envisioned that other patterns and arrangements for achieving stress reduction through NPR behavior are within the scope and spirit of the present disclosure.
  • The illustrated pattern of elongated, angled slots provides a specific porosity (e.g., a porosity of about 0.3 to about 9.0%) and a desired cooling performance (e.g., an effusion cooling effectiveness of approximately 30-50%) while exhibiting a desired negative Poisson's Ratio behavior (e.g., a PR of about −0.2 to about −0.9) under macroscopic planar loading conditions (e.g., when tension or compression is applied in the plane of the sheet). When the auxetic structure 300 is stretched, for example via tensile force FT along a vertical axis Y, axial strain in the vertical direction results in a moment around the center of each cell, which causes the cells to rotate. A cell may consist of two laterally adjacent vertical slots aligned with two vertically adjacent horizontal slots to form a square-shaped unit. Each cell rotates in a direction opposite to that of its immediate neighboring cells. This rotation increases the X-direction distance between horizontally adjacent cells such that stretching the structure in the Y-direction causes it to stretch in the X-direction. The first plurality of S-shaped through slots 312 have (first) engineered geometric characteristics, including a predefined geometry and a predefined aspect ratio, while the second plurality of S-shaped through slots 318 have (second) engineered geometric characteristics, including a predefined geometry and a predefined aspect ratio, that are cooperatively configured with (third) engineered geometric characteristics of the aperture pattern, including NPR-slot density and cell arrangement, to achieve a desired NPR behavior under macroscopic loading conditions.
  • Each slot of the first and/or second pluralities of elongated S-shaped through slots 312, 318 can be obliquely angled with respect to the top surface 314 or bottom surface 316, or both, of the auxetic structure's 300 elastically rigid body 310. In an example, slot 312 is shown in FIG. 3A traversing the entire thickness of the material at an angle that is oblique to the material's horizontal plane. For at least some embodiments, each aperture has an angle Φ of approximately 20-80 degrees or, in some embodiments, approximately 40-70 degrees with the top and bottom surfaces 314, 316 of the auxetic structure's body 310. These macroscopically patterned NPR voids—S-shaped angled slots (FIGS. 3A, 3B, 4A and 5A) or, equivalently, I-shaped angled slots (FIG. 4B), barbell-shaped angled slots (FIG. 4C), elliptical angled slots (FIG. 4D), Z-shaped angled slots (FIG. 5B), C-shaped angled slots, etc.—serve as effusion cooling holes which allow a cooling fluid FL to traverse one surface of the auxetic structure, pass through the body at an inclination angle α, as shown in FIG. 3A, and traverse the opposing surface of the auxetic structure. This configuration enhances film cooling performance as compared to traditional cooling slots/holes that are normal to the thickness of the body and, thus, more restrictive of cooling fluid flow. Inclination angle α can be defined as the angle between the injection vector and its projection on the material plane. This inclination angle can be varied in a 360° rotational angle of freedom to achieve numerous desired combinations of auxetic behavior and film cooling performance. Cooling effectiveness (Eta) can be typified as a non-dimensional value that quantitatively represents how effectively a fluid flowing over a porous surface protects that surface from a high temperature mainstream flow. Cooling effectiveness can be defined as the difference of the hot gas temperature to the wall temperature in the presence of a cooling device divided by the difference of the hot gas temperature to the temperature of the supplied cooling gas: Eta=(T_hotgas−T_wall)/(T_hotgas−T_coolant).
  • Patterned angled NPR-slot features, such as those disclosed in FIGS. 3-6, have been shown to cool significantly better than conventional right-angled (normal) circular holes and cooling slots as the internal surface area of the slots is larger than that of normal circular holes or slots. Adiabatic film cooling effectiveness is also increased compared to traditional normal cooling holes and slots, for example, due to a more even distribution of cooling air over the surface and reduced coolant jet penetration into the mainstream flow. This can be seen when comparing the cooling behaviors for representative non-NPR normal cooling holes (Eta=17%), normal NPR cooling slots (Eta=36%), and angled NPR S-slots (Eta=44%) of FIGS. 7A, 7B and 7C, respectively. Angled NPR-slot film can benefit from the Coanda Effect, which causes the coolant jet to better adhere to the wall, rather than lifting off and penetrating the mainstream flow. This helps to decrease the inclination angle, which in turn decreases coolant jet penetration and increases cooling performance of NPR slots. From an aerodynamic perspective, the reduced penetration of the coolant jet of angled NPR slots decreases aerodynamic losses due to film cooling compared with normal coolant slot flow. The inclination angle can be varied to achieve a desired combination of auxetic behavior and film cooling performance.
  • It has been determined that having inclined cooling slots help to provide better film cooling effectiveness coverage in comparison to normal cooling holes with internal walls that are perpendicular to cooling flow. In addition, early investigation demonstrates that coolant ejection from an angled NPR slot is more efficient than ejection from normal cooling holes because the mixing process is less intensive for the closed film ejected from the slot. While the high thermal stresses encountered on gas turbine blades and vanes typically do not allow for the use of highly elongated slots, angled NPR slots help to reduce or otherwise eliminate high thermal stresses on turbine blades/vanes while enhancing film cooling performance. For at least some embodiments, it is generally desirable to minimize surface porosity and the amount of coolant used in a turbine engine; normal NPR slots can be replaced with a smaller number of angled NPR slots to minimize porosity. In this case, cooling flow consumption will be reduced while the film cooling performance of the effusion slots is maintained.
  • As an exemplary implementation of the disclosed features, one can consider a combustor liner with sheet metal walls in which conventional round effusion holes or normal effusion slots are replaced with a pattern of angled S-shaped NPR slots forming an auxetic structure. Cooling air fed through these angled S-shaped slots removes heat from the structure and produces an even distribution of cooling air over the surface. These angled slots, which have an increased internal surface area, enhance film cooling performance and improve mechanical response. Moreover, angled NPR slots are capable of sustaining higher flame temperatures, and help impart to the sheet a much longer life compared to conventional sheet metal walls with normal effusion holes.
  • Shown in FIGS. 4A-4D are perspective-view illustrations of other auxetic structures, designated generally at 400A, 400B, 400C and 400D, respectively, with angled NPR slots in accordance with aspects of the present disclosure. Although differing in appearance, the auxetic structures 400A-400D may include any of the features, options, and alternatives described herein with respect to the other auxetic structures. In the same vein, unless explicitly disclaimed or logically prohibited, any of the auxetic structures disclosed herein can share features, options and alternatives with the other disclosed embodiments. Auxetic structures 400A-400D each comprises an elastically rigid body 410A, 410B, 410C and 410D, respectively, fabricated with a plurality of elongated and angled apertures 412A, 412B, 412C and 412D, respectively, arranged in a pattern to provide a desired cooling performance while exhibiting a predetermined NPR behavior under macroscopic planar loading conditions. In FIG. 4A, elongated apertures 412A have an S-shaped plan-view profile, whereas the elongated apertures 412B in FIG. 4B have an I-shaped plan-view profile, which includes a pair of spaced semicircular slots connected by an elongated linear slot. By comparison, elongated apertures 412D in FIG. 4D have an elliptical plan-view profile, whereas the elongated apertures 412C in FIG. 4C have a barbell-shaped plan-view profile, which includes a pair of spaced, rounded boreholes connected by an elongated linear slot. Any of the foregoing angled NPR slots can be manufactured by laser cutting, for example, by laying out a linear pattern of NPR slots along the inclination angle to the surface.
  • With continuing reference to FIGS. 4A-4D, the profile of the angled NPR slots that appears on the outer (top) surface can be designed as a projection of a standard shape—e.g., a standard “S” 414A, a standard “I” 414B with rounded arms, a standard barbell 414C with circular ends, and a standard ellipse 414D. Optionally, the profile of the angled NPR slots that appears on the outer (top) surface can be highly distorted from the original image depending, for example, on the desired angle and/or orientation of the slot. FIGS. 6A-6D illustrate slot distortion on an outer surface of a tubular auxetic structure: FIG. 6A illustrating normal NPR S-slots exhibiting a 0-degree angle; FIG. 6B illustrating angled NPR S-slots exhibiting a 45-degree angle; FIG. 6C illustrating angled NPR S-slots exhibiting a 55-degree angle; and FIG. 6D illustrating angled NPR S-slots exhibiting a 65-degree angle.
  • A new NPR slot shape, for instance, Z-shaped slots 512A (FIG. 5A) and S-shaped slots (FIG. 5B), can be developed by reducing cap length 511A and 511B and/or cap height 513A and 513B to provide a horizontal projection similar to an existing or “standard” S-shape/Z-shape. The size and shape of the caps can be varied to achieve a desired combination of auxetic behavior and film cooling performance. Film cooling performance of angled effusion S-shaped slots or, equivalently, Z-shaped slots can be improved by producing a longer cooling thermal layer above the hot surface. A longer cooling thermal layer can be created by increasing the lateral area of the slots normal to the free mainstream fluid by rotating the S-shaped slot cap in the counter-clockwise direction (or clockwise direction for Z-shaped slot caps). This cap rotation angle 515A and 515B can be varied to achieve a desired combination of auxetic behavior and film cooling performance. By rotating the caps of the S-shaped slots in the counter-clockwise direction, the maximum mechanical stress at the top of the caps will be reduced and the film cooling performance of the effusion slots will be improved due to the increased coverage of the cooling thermal layer above the hot surface.
  • Aspects of this disclosure are also directed to methods of manufacturing and methods of using auxetic structures. By way of example, a method is presented for manufacturing an auxetic structure, such as the auxetic structures described above with respect to FIGS. 3-6. The method includes, as an inclusive yet non-exclusive set of acts: providing an elastically rigid body, such as the elastically rigid body 310 of FIGS. 3A and 3B, with opposing top and bottom surfaces; adding to the elastically rigid body a first plurality of apertures, such as the elongated S-shaped slots 312 of FIGS. 3A and 3B, extending through the elastically rigid body from the top surface to the bottom surface; and, adding to the elastically rigid body a second plurality of apertures, such as the elongated S-shaped slots 318 of FIGS. 3A and 3B, extending through the elastically rigid body from the top surface to the bottom surface. The first and second pluralities of apertures are arranged in rows and columns. Each aperture of the first and/or second plurality is obliquely angled with the top surface of the elastically rigid body. The first and second pluralities of apertures are cooperatively configured to provide a predefined cooling performance while exhibiting a predetermined negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions. By way of example, the elongated apertures are engineered with a predefined porosity, a predetermined pattern, and/or a predetermined aspect ratio to achieve the desired NPR behavior. The auxetic structure may exhibit an effusion cooling effectiveness of approximately 30-50% and a Poisson's Ratio of approximately −0.2 to −0.9%. The elastically rigid body may take on various forms, such as a metallic sheet or other sufficiently elastic solid material.
  • In some embodiments, the method includes at least those steps enumerated above and illustrated in the drawings. It is also within the scope and spirit of the present invention to omit steps, include additional steps, and/or modify the order presented above. It should be further noted that the foregoing method can be representative of a single sequence for designing and fabricating an auxetic structure. However, it is expected that the method will be practiced in a systematic and repetitive manner.
  • The present invention is not limited to the precise construction and compositions disclosed herein. Rather, any and all modifications, changes, combinations, permutations and variations apparent from the foregoing descriptions are within the scope and spirit of the invention as defined in the appended claims. Moreover, the present concepts expressly include any and all combinations and subcombinations of the preceding elements and aspects.

Claims (21)

1. An auxetic structure comprising:
an elastically rigid body with opposing top and bottom surfaces and first and second pluralities of elongated apertures extending through the elastically rigid body from the top surface to the bottom surface, the first plurality of elongated apertures extending transversely with respect to the second plurality of elongated apertures, at least the first plurality of elongated apertures being obliquely angled with the top surface of the elastically rigid body,
wherein the first and second pluralities of elongated apertures are cooperatively configured to provide a desired cooling performance and exhibiting a desired stress performance through negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions.
2. The void structure of claim 1, wherein both the first and second pluralities of elongated apertures are obliquely angled with the top surface of the elastically rigid body.
3. The void structure of claim 1, wherein each aperture of the first plurality of elongated apertures is angled approximately 40-70 degrees with the top surface of the elastically rigid body.
4. The void structure of claim 1, wherein the cooling performance includes an effusion cooling effectiveness of approximately 30-50%.
5. The void structure of claim 1, wherein the NPR behavior includes a Poisson's Ratio of about −0.2 to about −0.9%.
6. The void structure of claim 1, wherein the elongated apertures are engineered with a predefined porosity, a predetermined pattern, or a predetermined aspect ratio, or any combination thereof, to achieve the NPR behavior.
7. The void structure of claim 1, wherein the elongated apertures have a predetermined porosity of about 0.3 to about 9%.
8. The void structure of claim 1, wherein each of the elongated apertures has an aspect ratio of approximately 5-40.
9. The void structure of claim 1, wherein the first or the second plurality of elongated apertures, or both, each has an S-shaped plan-view profile.
10. The void structure of claim 1, wherein the first or the second plurality of elongated apertures, or both, each has an elliptical plan-view profile.
11. The void structure of claim 1, wherein the first or the second plurality of elongated apertures, or both, each has a Z-shaped plan-view profile.
12. The void structure of claim 1, wherein the first or the second plurality of elongated apertures, or both, each has a barbell-shaped plan-view profile, the barbell-shaped plan-view profile including a pair of spaced boreholes connected by an elongated slot.
13. The void structure of claim 1, the first or the second plurality of elongated apertures, or both, each has an I-shaped plan-view profile, the I-shaped plan-view profile including a pair of spaced semicircular slots connected by an elongated slot.
14. The void structure of claim 1, wherein the first and second pluralities of elongated apertures are arranged in an array of rows and columns.
15. The void structure of claim 14, wherein the rows are equally spaced from each other and the columns are equally spaced from each other.
16. The void structure of claim 1, wherein each of the elongated apertures has a major axis perpendicular to a minor axis, the major axes of the first plurality of elongated apertures being substantially perpendicular to the major axes of the second plurality of elongated apertures.
17. An effusion-cooling auxetic sheet structure comprising:
a metallic sheet with opposing top and bottom surfaces and first and second pluralities of elongated apertures extending through the metallic sheet from the top surface to the bottom surface, the first plurality of elongated apertures having a first set of geometric characteristics and a first pattern, the second plurality of elongated apertures having a second set of geometric characteristics and a second pattern, the first plurality of elongated apertures being orthogonally oriented with respect to the second plurality of elongated apertures, each of the elongated apertures being obliquely angled with respect to the top surface of the elastically rigid body, wherein the first geometric characteristics and pattern of the first plurality of elongated apertures are cooperatively configured with the second geometric characteristics and pattern of the second plurality of elongated apertures to provide minimum cooling performance behavior while exhibiting negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions.
18. A method of manufacturing an auxetic structure, the method comprising:
providing an elastically rigid body with opposing top and bottom surfaces;
adding to the elastically rigid body a first plurality of apertures extending through the elastically rigid body from the top surface to the bottom surface, the first plurality of apertures being arranged in rows and columns, each aperture of the first plurality of elongated apertures being obliquely angled with the top surface of the elastically rigid body; and
adding to the elastically rigid body a second plurality of apertures extending through the elastically rigid body from the top surface to the bottom surface, the second plurality of apertures being arranged in rows and columns,
wherein the first and second pluralities of apertures are cooperatively configured to provide a cooling performance while exhibiting stress reduction through negative Poisson's Ratio (NPR) behavior under macroscopic planar loading conditions.
19. The method of claim 18, wherein each aperture of the second plurality of elongated apertures is obliquely angled with the top surface of the elastically rigid body.
20. The method of claim 18, wherein each aperture of the first plurality of elongated apertures is angled approximately 40-70 degrees with the top surface of the elastically rigid body.
21-33. (canceled)
US15/542,636 2015-01-09 2016-01-09 Auxetic Structures With Angled Slots In Engineered Patterns For Customized NPR Behavior And Improved Cooling Performance Abandoned US20180274783A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US15/542,636 US20180274783A1 (en) 2015-01-09 2016-01-09 Auxetic Structures With Angled Slots In Engineered Patterns For Customized NPR Behavior And Improved Cooling Performance

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201562101840P 2015-01-09 2015-01-09
US201562118826P 2015-02-20 2015-02-20
PCT/US2016/012769 WO2016112368A1 (en) 2015-01-09 2016-01-09 Auxetic structures with angled slots in engineered patterns for customized npr behavior and improved cooling performance
US15/542,636 US20180274783A1 (en) 2015-01-09 2016-01-09 Auxetic Structures With Angled Slots In Engineered Patterns For Customized NPR Behavior And Improved Cooling Performance

Publications (1)

Publication Number Publication Date
US20180274783A1 true US20180274783A1 (en) 2018-09-27

Family

ID=56356521

Family Applications (1)

Application Number Title Priority Date Filing Date
US15/542,636 Abandoned US20180274783A1 (en) 2015-01-09 2016-01-09 Auxetic Structures With Angled Slots In Engineered Patterns For Customized NPR Behavior And Improved Cooling Performance

Country Status (7)

Country Link
US (1) US20180274783A1 (en)
EP (1) EP3242758B1 (en)
JP (1) JP2018508738A (en)
CN (1) CN108367329B (en)
CA (1) CA2973378A1 (en)
RU (1) RU2017126597A (en)
WO (1) WO2016112368A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016112369A1 (en) * 2015-01-09 2016-07-14 President And Fellows Of Harvard College Auxetic structures with distorted projection slots in engineered patterns to provide npr behavior and improved stress performance
EP3655946B1 (en) * 2017-07-20 2022-12-28 President and Fellows of Harvard College Acoustic damper for gas turbine combustors
CN111299402A (en) * 2019-11-29 2020-06-19 湖南飞沃新能源科技股份有限公司 Hot mound production line

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6427446B1 (en) * 2000-09-19 2002-08-06 Power Systems Mfg., Llc Low NOx emission combustion liner with circumferentially angled film cooling holes
US7546737B2 (en) * 2006-01-24 2009-06-16 Honeywell International Inc. Segmented effusion cooled gas turbine engine combustor
US20110059291A1 (en) * 2009-09-07 2011-03-10 Boyce Christopher M Structured materials with tailored isotropic and anisotropic poisson's ratios including negative and zero poisson's ratios
GB201105790D0 (en) * 2011-04-06 2011-05-18 Rolls Royce Plc A cooled double walled article
JP6438000B2 (en) * 2013-03-15 2018-12-19 プレジデント アンド フェローズ オブ ハーバード カレッジ Low porosity auxetic sheet
US9353783B2 (en) * 2013-03-15 2016-05-31 Rolls-Royce Canada, Ltd. Auxetic locking pin
US9709274B2 (en) * 2013-03-15 2017-07-18 Rolls-Royce Plc Auxetic structure with stress-relief features

Also Published As

Publication number Publication date
CN108367329B (en) 2021-04-09
WO2016112368A1 (en) 2016-07-14
RU2017126597A3 (en) 2019-06-04
EP3242758A4 (en) 2018-07-18
EP3242758A1 (en) 2017-11-15
RU2017126597A (en) 2019-02-11
EP3242758B1 (en) 2019-09-11
JP2018508738A (en) 2018-03-29
CN108367329A (en) 2018-08-03
CA2973378A1 (en) 2016-07-14

Similar Documents

Publication Publication Date Title
US10823409B2 (en) Void structures with repeating elongated-aperture pattern
US10603866B2 (en) Hybrid dimple-and-void auxetic structures with engineered patterns for customized NPR behavior
US20160025344A1 (en) Low porosity auxetic sheet
US9709274B2 (en) Auxetic structure with stress-relief features
CN108367536B (en) Negative Poisson ratio waffle structure
US20180274783A1 (en) Auxetic Structures With Angled Slots In Engineered Patterns For Customized NPR Behavior And Improved Cooling Performance
US20170370581A1 (en) Auxetic Structures With Distorted Projection Slots In Engineered Patterns To Provide NPR Behavior And Improved Stress Performance
CN108472915B (en) Zero porosity NPR structure and tuning of location-specific NPR structure

Legal Events

Date Code Title Description
AS Assignment

Owner name: PRESIDENT AND FELLOWS OF HARVARD COLLEGE, MASSACHU

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:BERTOLDI, KATIA;FARHAD, JAVID;SIGNING DATES FROM 20171020 TO 20171023;REEL/FRAME:044003/0001

Owner name: PRESIDENT AND FELLOWS OF HARVARD COLLEGE, MASSACHU

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:BERTOLDI, KATIA;FARHAD, JAVID;SIGNING DATES FROM 20171020 TO 20171023;REEL/FRAME:044002/0770

AS Assignment

Owner name: SIEMENS CANADA LIMITED, CANADA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:BOOTH-MORRISON, CHRISTOPHER;FARHANGI, MEHRAN;INNES, MATTHEW CHRISTOPHER;AND OTHERS;SIGNING DATES FROM 20180517 TO 20180523;REEL/FRAME:046800/0949

AS Assignment

Owner name: PRESIDENT AND FELLOWS OF HARVARD COLLEGE, MASSACHU

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:JAVID, FARHAD;REEL/FRAME:047307/0593

Effective date: 20181024

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: ADVISORY ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STCV Information on status: appeal procedure

Free format text: NOTICE OF APPEAL FILED

STCV Information on status: appeal procedure

Free format text: APPEAL BRIEF (OR SUPPLEMENTAL BRIEF) ENTERED AND FORWARDED TO EXAMINER

STCV Information on status: appeal procedure

Free format text: EXAMINER'S ANSWER TO APPEAL BRIEF MAILED

STCV Information on status: appeal procedure

Free format text: ON APPEAL -- AWAITING DECISION BY THE BOARD OF APPEALS

STCB Information on status: application discontinuation

Free format text: ABANDONED -- AFTER EXAMINER'S ANSWER OR BOARD OF APPEALS DECISION