1320025 九、發明說明： 【發明所屬之技術領域】 本發明涉及-種奈米膠帶及其製造方法，1320025 IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to a nano-tape tape and a method of manufacturing the same,
碳管之奈輝料其製砂法。 輯U 【先前技術】 碳原子具有良好之成鍵性能，其外層電子可形成不同之雜化 ί缺Γ柯可形成結構完善之金临與石墨，亦可形成具有豐富結 吸附性、無定形之多孔炭。傳統多孔碳之孔徑體系主要由 =豆虽之結構缺_成，與彿石分子_完全由結構孔構築之孔 =同，其孔徑體系具有-定之隨意形，因此，其成孔過程與最終之 H結_於浦。碳家族之新㈣— 構中形成完全規整之孔隙結構成為可能。 奈米碳管係1991年才被發現之一種新型碳結構，它係由碳原子形 ^石墨制卷成之-種無縫、巾空m可分為單壁納米碳 目（ingle-walled Carton Nanotube)财縣米碳f(Multi_walledThe carbon tube is made of the sand method. Series U [Prior Art] Carbon atoms have good bonding properties, and the outer electrons can form different hybridizations. Γ 可 Ke can form a well-structured Jinlin and graphite, and can also form a rich adsorption and amorphous. Porous carbon. The pore system of the traditional porous carbon is mainly composed of the structure of the bean, and the pores of the structure are completely different from the pores of the structure. Therefore, the pore-forming process and the final H knot _ Yu Pu. New in the carbon family (IV) - It is possible to form a completely regular pore structure in the structure. Nano carbon tube is a new type of carbon structure discovered in 1991. It is made of carbon atom shape and graphite. It is seamless and can be divided into single-walled carbon nanotubes (ingle-walled Carton Nanotube). ) Caixian rice carbon f (Multi_walled
Carbon N細tube)。-般單㈣米碳管之餘為Q 4〜2奈米，多辟太 f炭管之直徑也不超過50奈米，長度則可達數微米至數毫米，因: 有極大之長徑比，係一種準一維之奈米線。 八 奈米碳％•’制係單壁奈米碳#，由於所縣之碳原子基本上皆 處於表面位置，故具有較大之比表面積。理論計算表明，奈米碳管之 $表面積可於5G〜1315mVg之較大翻内變化。單壁奈米碳管之表面積 值要比多壁奈米碳管大-錄量級。由於單壁奈米碳管中間有一光 滑、平直之空管，故其密度相當低，僅為〇 6g/cm3，具有規整之 奈米級孔隙。多壁奈米碳管之密度隨其結構變化，在卜2_3之間。 ，於奈米碳管奈核之尺度舰整之微赌構，奈米碳管具有接近理 ‘!'之氣體吸附能力’對其他之原子與分子具有很強之吸附作用。 —然而，近年來對奈米碳管氣體吸隨能之研究主要集巾於奈米碳 ^之儲氫性能以及絲碳管之驗概_。猶著科技不斷發展， 月源與壤保逐漸成為世界發展之主題。其中，環境保護已成爲當前經 5 1320025 濟發展中之-個減重要之問題’可_發展要求在偏梅濟高速發 展之同時，必須保護好人類賴以生存之環境β x 有鑒於此，提供一種使用奈米碳管之具有空氣淨化作用之奈米膠 帶及其製造方法實為必要。 、〜 【發明内容】 以下，將以若干實施例說明一種具有空氣淨化作用之奈米膠帶。 以及，一種具有空氣淨化作用之奈米膠帶之製造方法。 爲貝現上述内谷，提供一種奈米膠帶，其包括：_雙面勝帶，該 雙面膠帶具有雙面黏性；一耐高溫膜，其設置於上述雙面膠帶之一面1 以及-奈米碳材料層設置於雙面膠帶之另—面，該奈米碳材料層包括 奈米碳管、奈米碳球或兩者之混合物。 以及k供一種奈米勝帶之製造方法，其包括以下步驟··提供一 基底，形成一奈米碳材料層於上述基底上；將一具有雙面黏性之雙面 膠帶一面黏附於上述奈米碳材料層，另一面設置—耐高溫膜去ς基 底以獲得奈輝帶，該奈米碳材料層包括奈米碳f、奈米碳球或兩ς 之混合物。 本技術方案所提供之奈錄帶及絲造方法餘傳_帶上進行 加工，利用目前已經非常成熟之奈米碳材料層生長技術，方法簡單， ^性強。通過本發明方法獲得之奈米膠帶_奈米碳材料層如奈米 碳管之極強之氣體吸附能力，於應用中可以廣泛吸附空氣中之氫氣、 碳氫化合物以及自由基，@而能财效地淨化魏錢空間氣氛，適 應目前不斷發展之環保要求。 【實施方式】 請-併參閱第-至第五圖，本技術方案提供一種秦米膠帶之製造 方法，其包括以下步驟： 提供一具有一清潔拋光面之基底u，該基底u設置於一基座ι〇 ^基底11之清潔拋光面可通賴基底U之—面抛光後並用去離 H進行洗絲制，該拋光面麟生長奈米碳管或奈米碳球。基底 材料翻玻璃，也可其他材料，如矽、石英等，本實施例選用 6 1320025 之玻璃基板11之厚度為〇· 3毫米或以下。 於6亥基底11將要生長奈米碳管之拋光面均勻形成—層催化劑層 12 ’該催化_ 12之形成可彻熱沈積、電子束沈積、蒸誠藏射法 來完成。催化劑層12材料選用鐵，也可選用其他材料，減、鎳或鐵、 始、鎳二種物質任意組合之合金材料等。 、，山生長冋岔度之奈米碳材料層13於基底11之催化劑層12上，該奈 米奴材料層13包括奈米碳t、奈米碳球或兩者之混合物，該奈米碳管 包括^壁奈米碳管、多壁奈米碳f或兩者之混合物。 提供-雙面膠帶14，該雙面膠帶14具有雙面黏性以及雙面耐高溫Carbon N thin tube). - The average single (four) meter carbon tube is Q 4~2 nanometer, the diameter of the carbon tube is not more than 50 nanometers, and the length can be several micrometers to several millimeters, because: there is a great aspect ratio , is a quasi-one-dimensional nanowire. Eight nanometer carbon %•' system single-walled nanocarbon #, because the carbon atoms of the county are basically at the surface position, it has a large specific surface area. Theoretical calculations show that the surface area of the carbon nanotubes can vary from 5G to 1315mVg. The surface area of a single-walled carbon nanotube is larger than that of a multi-walled carbon nanotube. Since there is a smooth, straight hollow tube in the middle of the single-walled carbon nanotube, the density is quite low, only 〇 6g/cm3, with regular nano-scale pores. The density of multi-walled carbon nanotubes varies with their structure, between 2 and 3. In the micro-gambling structure of the carbon nanotubes on the scale of the carbon nanotubes, the carbon nanotubes have a gas adsorption capacity close to the ‘!’, which has a strong adsorption effect on other atoms and molecules. - However, in recent years, the research on the gas absorption of carbon nanotubes has mainly focused on the hydrogen storage performance of nanocarbons and the examination of carbon nanotubes. Judging by the continuous development of science and technology, Yueyuan and Libao have gradually become the theme of world development. Among them, environmental protection has become an important issue in the current development of 5 1320025. 'Development requirements. At the same time as the rapid development of Meiji, it is necessary to protect the environment on which humans depend. β x In view of this, A nano-tape having an air purifying effect using a carbon nanotube and a method for producing the same are necessary. ~ [Explanation] Hereinafter, a nano tape having an air purifying effect will be described in several embodiments. And a method for producing a nano tape having an air purifying effect. For the above-mentioned inner valley, a nano tape is provided, which comprises: a double-sided tape, the double-sided tape has double-sided adhesiveness; and a high-temperature resistant film, which is disposed on one side of the double-sided tape 1 and The layer of carbonaceous material is disposed on the other side of the double-sided tape, and the layer of nanocarbon material includes a carbon nanotube, a carbon sphere, or a mixture of the two. And a method for manufacturing a nano-belt, comprising the steps of: providing a substrate to form a layer of nano-carbon material on the substrate; and adhering a double-sided adhesive tape having double-sided adhesiveness to the surface The carbonaceous material layer is disposed on the other side, and the high temperature resistant film is used to remove the substrate to obtain a Neihui belt, and the nanocarbon material layer comprises a nanocarbon f, a nanocarbon sphere or a mixture of two. The technical tape solution provided by the technical solution and the method of silk production are processed on the belt, and the nano carbon material layer growth technology which is already very mature is used, and the method is simple and strong. The nanometer tape obtained by the method of the invention has a very strong gas adsorption capacity of a nanocarbon material layer such as a carbon nanotube, and can widely adsorb hydrogen, hydrocarbons and free radicals in the air in the application, @能能财Effectively purify the Weiqian space atmosphere and adapt to the current environmental protection requirements. [Embodiment] Please - and refer to the first to fifth figures, the technical solution provides a method for manufacturing a Qin tape, comprising the steps of: providing a substrate u having a clean polishing surface, the substrate u being disposed on a base The cleaning and polishing surface of the base 11 can be cleaned by the surface of the substrate U and then polished to remove the H, which is a carbon nanotube or a nano carbon sphere. The substrate material is turned into a glass, and other materials, such as ruthenium, quartz, etc., in the present embodiment, the thickness of the glass substrate 11 of 6 1320025 is 〇·3 mm or less. The polished surface of the carbon nanotube to be grown is uniformly formed on the substrate 7 of the 6th layer - the catalyst layer 12'. The formation of the catalyst 12 can be completed by thermal deposition, electron beam deposition, and vapor deposition. The material of the catalyst layer 12 is iron, and other materials, alloy materials of any combination of nickel, iron or iron, and nickel and nickel may be used. The nano-carbon material layer 13 of the mountain growth intensity is on the catalyst layer 12 of the substrate 11, and the nano-material layer 13 comprises a nano carbon t, a nano carbon sphere or a mixture of the two, the nano carbon The tube comprises a walled carbon nanotube, a multi-walled nanocarbon f or a mixture of the two. Provided - double-sided tape 14 having double-sided adhesiveness and double-sided heat resistance
保護膜16。雙轉帶14撕去-面保顏，並使其_於奈米碳材 料層13上加熱基座1〇以增進奈米碳材料層a與雙面膠帶μ之附 著性。 、將基底11連同奈米碳材料層13與雙面膠帶14從基座10上取下 並反，，通過化學方法去除基底u與催化觸12。具體方法包括：利 用四氟化碳㈣電毁乾姓刻錢化氫⑽溶液·刻去除基底u ;將 ，面膠帶14浸泡於稀釋之酸溶液中去除催化劑層12;將剩餘的雙面膠 π 14與不麵材料層13清洗後乾燥，獲得本技術方案奈轉帶^成 品0Protective film 16. The double belt 14 is peeled off and the face is protected, and the base 1 is heated on the nano carbon material layer 13 to enhance the adhesion of the nano carbon material layer a to the double-sided tape μ. The substrate 11 is removed from the susceptor 10 together with the nano-carbon material layer 13 and the double-sided tape 14, and the substrate u and the catalytic contact 12 are chemically removed. The specific method comprises: using carbon tetrafluoride (4) to destroy the surname of the hydrogen (10) solution and removing the substrate u; immersing the surface tape 14 in the diluted acid solution to remove the catalyst layer 12; and leaving the remaining double-sided adhesive π 14 and the non-face material layer 13 is cleaned after washing, and the technical solution of the present invention is obtained.
本技術方賴得之奈米轉15包括—雙面料14，該雙面膠帶 14具有雙雜性。該雙面膠帶之—面設置有_耐高溫保護膜16，於應 用時可以撕故⑽奈米料15_於預定材料上，另―面形成有一 奈米碳材料層13，該奈米碳材料層13具有極強之氣體吸，可以 用來及附空氣中之虱氣、碳氫化合物以及自由基等。 本領域之技術人員應明白，本技術方案納米膠帶之製造方法中奈 米碳材料層之形成實際上係—種化學氣相沈積法，由於本技術方案奈 米膠帶僅需應用奈米碳材料層之氣體吸附能力嗜， 形成方法亦可採用其他如電弧放電法、#射燒触等^需形成^密 度之奈米破材料層如奈米碳管於基底表面即可。 本技術方案之奈米膠帶及其製造方法係於傳統勝帶上進行加工， 7 1320025 利用目前已經非常成熟之奈米碳材料層生長技術，方法簡單，可控性 強。通過本發明方法獲得之奈米膠帶利用奈米碳材料層如奈米碳^之 =強之氣體吸附能力，於應用中可以廣泛吸附空氣中之氫氣、碳^化 合物以及自由基，因而能夠有效地淨化環境以及空間氣氛，適應目扩 不斷發展之環保要求。 則 综上所述，本發明符合發明專利之要件，爰依法提出專利申請。 惟，以上所述者僅為本發明之較佳實施例，舉凡熟悉本案技藝之人士， 在援依本案發明精神所作之等效修飾或變化，皆應包含於以下之 專利範圍内。The nanometer turn 15 of the present technology includes a double fabric 14, and the double-sided tape 14 has double impurities. The double-sided tape is provided with a _ high temperature protection film 16 which can be torn during application (10) of the nano material 15_ on the predetermined material, and a nano carbon material layer 13 is formed on the other surface, the nano carbon material Layer 13 has a very strong gas absorption and can be used to attach helium, hydrocarbons and free radicals in the air. It should be understood by those skilled in the art that the formation of the nano-carbon material layer in the manufacturing method of the nano-adhesive tape of the technical solution is actually a chemical vapor deposition method, and the nano-carbon material layer only needs to be applied to the nano-adhesive tape of the technical solution. The gas adsorption capacity may be formed by using other methods such as arc discharge method, #射烧触, etc. to form a nano-breaking material layer such as a carbon nanotube on the surface of the substrate. The nano tape of the technical solution and the manufacturing method thereof are processed on the traditional winning belt, and 7 1320025 utilizes the currently mature nano carbon material layer growth technology, and the method is simple and controllable. The nano-adhesive tape obtained by the method of the invention can utilize the nano carbon material layer such as nano carbon carbon to have a strong gas adsorption capacity, and can widely adsorb hydrogen, carbon compounds and free radicals in the air in the application, thereby being effective Purify the environment and the space atmosphere to meet the environmental requirements of expanding and expanding. In summary, the present invention complies with the requirements of the invention patent and submits a patent application according to law. The above description is only the preferred embodiment of the present invention, and equivalent modifications or variations made by those skilled in the art will be included in the following patents.
【圖式簡單說明】 第一圖係本技術方案之奈米膠帶之製造方法之流程示意圖。 第二圊係本技術方案於基底表面形成奈米碳材料層之示意圖。 第三圖係於第二圖形成之奈米碳材料層上黏附雙面膠帶之示意圖。 第四圊係將第三圖之基底連同雙面膠帶反置之示意圖。 第五圖係本技術方案獲得之奈米膠帶之示意圖。BRIEF DESCRIPTION OF THE DRAWINGS The first figure is a schematic flow chart of a method for manufacturing a nano tape of the present technical solution. The second aspect is a schematic diagram of the present technical solution forming a layer of nano carbon material on the surface of the substrate. The third figure is a schematic view of the double-sided tape adhered to the nano-carbon material layer formed in the second figure. The fourth line is a schematic view of the base of the third figure together with the double-sided tape. The fifth figure is a schematic diagram of the nano tape obtained by the technical solution.
【主要元件符號說明】 基座 10 基底 11 催化劑層 12 奈米碳材料層 13 雙面膠帶 14 奈米膠帶 15 保護膜 16 8[Main component symbol description] Base 10 Base 11 Catalyst layer 12 Nano carbon material layer 13 Double-sided tape 14 Nano tape 15 Protective film 16 8