KR101668391B1 - High Density carbon Nano-fiber Felt with Unidirectional Orientation and Application to Supercapacitor Electrode - Google Patents

Abstract

The present invention relates to a high density carbon nanofiber felt, and more particularly to a unidirectional carbon nanofiber felt, a method for manufacturing the carbon nanofiber felt, and an application product including the carbon nanofiber felt.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a high-density carbon nano-fiber felt and a carbon nanofiber felt application including the carbon nanofiber felt,

The present invention relates to a high density carbon nanofiber felt, and more particularly to a unidirectional carbon nanofiber felt, a method for manufacturing the carbon nanofiber felt, and an application product including the carbon nanofiber felt.

Electrospinning is a fiber fabrication technique that produces nanofibers with a thickness of 10-1000 nm, because the fluid of the polymer material flowing through the nozzle is tapered under the high voltage and the fluid becomes unstable and divided into several branches .

In the conventional electrospinning method, since the formation rate of the fibers is relatively large compared to the winding speed, the fibers can not be wound in the oriented state, and the fibers in the unoriented state can be formed by the fibers in the subsequent heat treatment process for producing carbon nanofibers It is difficult to realize mechanical properties because the constituent molecules are not constrained. In contrast, conventional carbon fibers are made of precursor fibers made of polyacrlyonitrile (PAN), Rayon, pitch, etc. by filament, stretched through hydrothermal treatment, and subjected to heat treatment, ie stabilization carbonization, The carbon fiber with high strength and high elasticity was manufactured. In case of PAN, the carbon fiber having the strength of 3.5-6.3 GPa and the tensile elastic modulus of 230-294 GPa (T300, T1000 grade) was commercialized.

As a method for manufacturing a high-strength fiber by a known electrospinning method, a method of winding the fiber at high speed and heat-treating the fiber at 2200 ° C in a wound state (Zhengping Zhou et al., Polymer 50 (2009) 2999-3006) The carbon fiber obtained by the above method had a tensile strength of 0.3-0.6 GPa and a tensile elastic modulus of 30-60 GPa. As a result, it is not suitable for use as a high-strength carbon fiber because it is not much different from the properties of existing carbon fibers.

On the other hand, a nano carbon fiber web with a large specific surface area and controlled pore size was manufactured by using the electrospinning method, and a super capacitor electrode material having an energy density of 22 Wh / kg (half cell basis) at a power density of 100 kW / kg was manufactured (Electrochemistry Communications 13, 2011, 1042) is known, but the nanocarbon fiber electrode thus produced has a high energy storage density per weight, but has a low packing density per volume (0.3 g / cm ³ ) It requires a large volume to store, which is a hindrance to commercialization.

Activated carbon fibers currently being produced and sold are produced by fibrousizing the precursor mainly by an expensive melt-spinning or melt-blown spinning apparatus and then oxidizing, stabilizing, carbonizing or activating the precursor. The method is complicated in process, and since the diameter of the fiber is large, there is a limit to effectively increase the specific surface area relative to the volume. When used as an electrode active material, it is necessary to carry out a step of pulverizing the fibers to add a binder or a conductive material. In the case of a fabric, since the fiber diameter of the fabricated fiber is relatively large and density is low, The charge transfer distance is large and the density of the electrode is low, so that high-speed charge / discharge and high output characteristics are deteriorated.

The present inventors have completed the present invention by developing a process of orienting fibers in one direction to increase the density and restricting the polymeric materials constituting the fibers in the process of manufacturing carbon nanofibers by electrospinning.

Accordingly, it is an object of the present invention to provide a carbon nanofiber which is composed of carbon nanofibers oriented in one direction and has a high density characteristic close to a commercialized carbon fiber, and has a large specific surface area and high energy density and power density characteristic per unit volume And a carbon nanofiber layer formed on the carbon nanofiber layer.

 It is still another object of the present invention to provide a carbon nanofiber material having a high filling density per volume such as a high density super capacitor electrode, a high performance filter and an electrode material by using a high density characteristic and a large specific surface area of a unidirectional carbon nanofiber felt and a high energy density and a power density per unit volume And to provide applications of various kinds of unidirectional carbon nanofiber felt as an energy component material.

The objects of the present invention are not limited to the above-mentioned objects, and other objects not mentioned can be clearly understood by those skilled in the art from the following description.

In order to achieve the object of the present invention described above, the present invention provides a unidirectional carbon nanofiber felt comprising carbon nanofibers formed to have an orientation in one direction.

In a preferred embodiment, the carbon nanofibers have a diameter of 50 to 400 nm.

In a preferred embodiment, the carbon nanofiber felt has an apparent density of 0.7407 g / cm < ³ > to 2.0 g / cm < ^{3 &} gt ;.

In a preferred embodiment, it further comprises at least one of SiOx (0 < x < 2), metal oxide, metal alkoxide, graphene, carbon nanotubes, graphite particles or carbon black particles.

In a preferred embodiment, the electrical conductivity is at least 2.0 S / cm.

In a preferred embodiment, the size of the pores formed in the carbon nanofibers is 0.5-3 nm.

The present invention also provides a unidirectional carbon fiber felt application comprising any one of the above-described unidirectional carbon nanofiber felts.

In a preferred embodiment, the carbon fiber felt application is a supercapacitor or high strength carbon nanofiber composite material.

The present invention has the following excellent effects.

First, according to the unidirectional carbon nanofiber felt of the present invention, carbon nanofibers formed by orienting in one direction have high density characteristics close to commercialized carbon fibers, and at the same time, a large specific surface area of the nanofiber and a high energy per unit volume Density and power density.

Also, according to the present invention, it is possible to apply to a high-strength carbon nanofiber composite material which can not be realized by the conventional electrospinning carbon nanofibers by using the high density characteristic, large specific surface area, high energy density per unit volume and power density of the unidirectional carbon nanofiber felt And can be applied to various high-energy parts such as high-performance filters, supercapacitors, and lithium-ion-based carbon nanofiber-based electrode materials with high filling density and electric conductivity per unit volume.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view of the application of the unidirectional carbon nanofiber felt of the present invention,
2 is a graph showing the viscosity of the spinning solution of various concentrations according to the present invention,
FIG. 3 (a) is a scanning electron microscope (SEM) image showing the unidirectional orientation of the unidirectional carbon nanofiber felt according to an embodiment of the present invention, and FIG. 3 Electron microscope photograph,
4 is a graph showing tensile strength measurement results of unidirectional PAN prepolymer & PAN copolymer nanofiber felts according to another embodiment of the present invention.
5 is a graph showing the charge and discharge of the super capacitor electrode including the unidirectional PNA / TEOS carbon nanofiber felt obtained in another embodiment of the present invention.

Although the terms used in the present invention have been selected as general terms that are widely used at present, there are some terms selected arbitrarily by the applicant in a specific case. In this case, the meaning described or used in the detailed description part of the invention The meaning must be grasped.

Hereinafter, the technical structure of the present invention will be described in detail with reference to the accompanying drawings and preferred embodiments.

However, the present invention is not limited to the embodiments described herein but may be embodied in other forms. Like reference numerals used to describe the present invention throughout the specification denote like elements.

The first technical feature of the present invention resides in that the carbon nanofibers contained in the carbon nanofiber felt produced by the electrospinning method are unidirectionally oriented in one direction. Unidirectional carbon nanofiber felt composed of carbon nanofibers oriented in one direction as described above has a high density characteristic close to commercialized carbon fiber and has high specific surface area of nanofiber and high energy density and power density per unit volume .

As a result, it is difficult to reproduce physical characteristics such as tensile strength because carbon fibers having a diameter of about 5 to 9 μm are entangled with each other. However, in the unidirectional carbon nanofiber felt according to the present invention, fibers are oriented in one direction So that the density can be high and the physical strength can be realized.

Accordingly, the present invention provides a unidirectional carbon nanofiber felt characterized by comprising carbon nanofibers formed to have an orientation in one direction.

Single-orientation carbon nano fiber felt of the present invention as compared with the conventional carbon nano fiber felt produced by the electrospinning process gatneunde high-density characteristics, and to a large and 2.0 g / cm ³ range, rather than an apparent density of at least 0.7407g / cm ^3.

Considering that the specific gravity of the PAN-based carbon fiber is 1.7-1.9 g / cm ³ , the filling density is 0.9069, assuming that the fibers are laminated in one direction to produce the felt. The density is 1.54-1.73 g / cm &lt; ³ &gt; density.

Further, since the pores formed in the carbon nanofiber are 0.5-3 nm in size as well as the carbon nanofibers having a diameter in the range of 50-400 nm, the nanofibers have a large specific surface area and high energy density and power density per unit volume .

The unidirectional carbon nanofiber felt of the present invention has a very high electrical conductivity of about 9 times or more as compared with the conventional carbon nanofiber felt produced by electrospinning, and has a conductivity of 2.0 S / cm or more (at 800 ° C carbonization), preferably 5.0 It is preferable to show an electric conductivity of S / cm or more.

Further, the carbon nanofibers may further include constituent components for improving the characteristics of the unidirectional carbon nanofiber felt of the present invention. In particular, it is possible to improve the energy density or power density or to suitably control the chemical and / Further comprises at least one of SiOx (0 < x < 2), a metal oxide, a metal alkoxide, a graphene, a carbon nanotube, a graphite particle or a carbon black particle.

The second technical feature of the present invention is that carbon fiber is oriented in one direction in the process of manufacturing carbon nanofibers by electrospinning and the polymer material constituting carbon fibers is constrained to manufacture unidirectional carbon nanofiber felt In a manufacturing method that can be performed.

Accordingly, the method for producing a unidirectional carbon nanofiber felt of the present invention comprises: preparing a spinning solution containing a carbon fiber precursor material; Spinning and spinning the spinning solution at high speed to produce a precursor fiber felt oriented in one direction; Oxidizing and stabilizing the precursor fiber felt to produce a chlorinated fiber felt; And carbonizing the chlorinated fibers, or activating the chlorinated fibers.

It is preferable that the spinning solution has a viscosity of 3000 cP to 28000 cP. If the viscosity of the spinning solution is high, it may slow down the formation rate of the fiber even when a high voltage is applied during the electrospinning, It is because.

The spinning solution may be prepared by selecting a polymer material having a proper molecular weight and a chemical component from known materials used as a carbon fiber precursor material so as to have the above-mentioned viscosity. For example, in the case of using a polyacrylonitrile (PAN) system for fiber molding as a carbon fiber precursor material, if it has a molecular weight of 150,000 or more, not only a homopolymer but also a copolymer containing 5-15% Modified acrylic can be used. At this time, as the composition of the copolymer, itaconic acid, methylacrylate (MA) and the like can be used as a copolymer material. The solvent is not limited as long as the carbon fiber remover is dissolved, but it is preferable to use dimethylformamide (DMF) or dimethyl sulfoxide (DMSO).

The fiber-forming polymer used as a carbon fiber precursor material is a polyvinyl alcohol (PVA), a polyimide (PI), a polybenzimidazole (PBI), a phenol resin, an epoxy resin epoxy resin, polyethylene (PE), polypropylene (PP), polyvinylchloride (PVC), polystyrene (PS), polyanaline (PA), polymethyl methacrylate (PMMA) (0 < x < 2), a metal such as polyvinylidene chloride, polyvinylidene chloride (PVDF), various kinds of pitches, Oxide, metal alkoxide, graphene, carbon nanotubes, graphite particles or carbon black particles.

High-speed spun electrospinning for the production of precursor fiber felt is carried out at a speed of 1000 ~ 2040 m / min while electrospinning at a voltage of 10 ~ 30 kV when the distance between the spinneret and the collector is 5 ~ 20 cm The condition is an experimentally determined value through a number of repeated experiments as a condition for causing the electrospun carbon nanofibers to have unidirectional orientation.

The oxidation stabilization is preferably carried out by maintaining a temperature of 200 ° C to 300 ° C for 1 hour at a heating rate of 1 ° C per minute under an air atmosphere while applying a load of 1.5-4.0 MPa to the precursor fiber felt. The oxidative stabilization conditions were also selected through a number of repeated experiments. Polymer materials constituting the precursor fiber felt oriented in one direction were found to be constrained to the fibril state without going to the lamellar crystal structure while being stretched during the heat treatment.

The carbonization is carried out in an inert atmosphere at a heating rate of 5 ° C / min up to 800 - 1500 ° C and then maintained for 1 hour. Carbonization conditions can be set within a predetermined range according to tensile strength, tensile elastic modulus and electric conductivity .

On the other hand, the activation is performed in an inert atmosphere at a heating rate of 5 ° C / min to a temperature of 800 ° C to 1500 ° C and then for 1 hour in a steam atmosphere or in a CO ₂ atmosphere. Depending on the tensile strength, tensile elastic modulus and electric conductivity The activation condition can be set within a predetermined range.

The unidirectional carbon nanofiber felt of the present invention described above has a high density characteristic close to that of commercialized carbon fibers and has a large specific surface area and a high energy density and power density per unit volume of the nanofiber, Likewise, the unidirectional carbon nanofiber felt of the present invention can be applied to various carbon nanofiber applications including high-energy electrode materials such as supercapacitors and lithium ion batteries, catalyst supports, high-strength stiffeners, and high-strength filters.

Example 1

1. Preparation of spinning solution: preparation of PAN polymer solution with high viscosity

PAN (polyacrylonitrile) having a molecular weight of 150,000 was used as the carbon nanofiber precursor material. PAN was dissolved in Dimethylformamide (DMF) as a solvent in a total weight ratio of 13% to prepare a spinning solution. The prepared PAN solution had a viscosity of 5999 cP.

2. High-speed wound electrospinning: Manufacture of PAN-based precursor fiber felt with unidirectional orientation

PAN - based precursor fiber felt with unidirectional orientation was prepared by electrospinning the prepared PAN polymer spinning solution. As a condition of electrospinning, the applied voltage of 18 kV was applied. The distance between the spinneret and the collector was 7 cm and the fiber orientation was induced by winding at a high speed of 2040 m / min.

3. Weight Stretch Oxidation Stabilization: Manufacture of Chlorinated Fiber Felt in PAN System with Uniform Orientation

The PAN-based precursor fiber felt having a unidirectional property was kept at 200 to 300 DEG C for 1 hour at a temperature raising rate of 1 DEG C per minute under an air atmosphere while a load of 3.6 MPa was applied to stabilize the fiber to thereby stabilize the fiber, Insoluble dechlorinated fiber felt having improved mechanical properties was obtained.

4. Carbonization: Manufacture of PAN-based carbon nanofiber felt with unidirectional orientation

The oxidation resistant chlorinated fiber felts were heated in an inert atmosphere to a temperature of 800 ° C at a heating rate of 5 ° C per minute and then carbonized while keeping them for 1 hour to produce a PAN-based carbon nanofiber felt 1 having a unidirectional orientation.

Example 2

PAN-based carbon nanofiber felt 2 having a unidirectional property was produced in the same manner as in Example 1 except that the carbonization temperature was 1400 ° C.

Example 3

(Viscosity 15015 cP) was prepared by using a PAN copolymer (PAN-itaconic acid (IA), PAN-Methyl Acrylate (MA), etc.) having a molecular weight of 150,000 as a carbon nanofiber precursor material. , A PAN-based carbon nanofiber felt 3 having a unidirectional characteristic was produced by performing the same method as in Example 1. The PAN-

Comparative Example 1

General carbon nanofiber felt 1 was prepared in the same manner as in Example 1, except that the general electrospinning method (winding speed <500 m / min, spinning solution viscosity <2000 cP) was used instead of high speed winding electrospinning.

Comparative Example 2

The general carbon nanofiber felt 2 was prepared in the same manner as in Comparative Example 1, except that the carbonization temperature was 1400 ° C.

Experimental Example 1

The viscosity values of the PAN solution prepared at various weight ratios were tested and the results are shown in Fig. In FIG. 2, (a) is the viscosity of the PAN polymer solution at 25 ° C., and (b) is the viscosity of the PAN co-polymer solution at 25 ° C.

The spinning solution having the viscosity value shown in Fig. 2 was subjected to electrospinning at an applied voltage of 10 to 30 kV at a distance of 5 to 20 cm between the spinneret and the collector at a speed of 1000 to 2040 m / min It was confirmed that the fibers were formed so as to have high orientation in the spinning solution having a viscosity of 6000 to 28000 cP when rolled up, and showed almost unidirectional orientation.

Experimental Example 2

The unidirectional carbon nanofiber felt 1 produced in Example 1 and the common carbon nanofiber felt produced in Comparative Example 1 were observed with a scanning electron microscope and the results are shown in FIGS. 3 (a) and 3 (b), respectively .

As shown in FIG. 3 (b), the PAN carbon nanofibers included in the general carbon nanofiber felt 1 produced by the general electrospinning method are randomly oriented, while the unidirectional The PAN-based carbon nanofibers contained in the carbon nanofiber felt 1 were observed from FIG. 3 (a) that the fibers were laminated in one direction.

Experimental Example 3

(Precursor), unidirectional carbon nanofiber felt 1 (800 DEG C) produced in Example 1, and unidirectional carbon nanofiber felt 2 (1400 DEG C) prepared in Example 2 and Comparative Example 1 The apparent density and fiber density of the precursor fiber precursor (precursor), general carbon nanofiber felt 1 (800 ° C) and general carbon nanofiber felt 2 (1400 ° C) prepared in Comparative Example 2 were measured as follows The results are shown in Table 1. Apparent densities were calculated by measuring the weight and thickness after preparing samples (1 cm x 1 cm). The fiber density was measured by density gradient method (KS L 6801) using Ray-Ran test equipment LTD., (3 column) density measurement equipment. The density measurement range was 1.16 to 2.2 g / cm 3 (1.16 to 1.28, 1.28 to 1.42, 1.50 to 2.20 g / cm 3).

carbonization
Temperature Apparent density (g / cm ³ ) Fiber density (g / cm ³ ) Example 1 Example 2 Comparative Example 1 Comparative Example 2 Example 1 Example 2 Comparative Example 1 Comparative Example 2 free
Cursor 0.5231 - 0.3098 - <1.1795 - <1.1600 - 800 ° C 1.3090 - 0.4580 - 1.7373 - 1.6858 - 1400 ° C - 0.7407 - - 1.5307 - -

It can be seen from Table 1 that the fiber density of the unidirectional carbon nanofiber felt produced by restricting the polymeric substance constituting the precursor fiber is higher than that of the comparative example. In particular, the density of the result of comparison by measuring the apparent density to high density felt is carbonized at 800 ℃ was observed four times greater than the density of 0.3098 prepared in general electrospinning process to 1.3090g / cm ^3.

Experimental Example 4

The tensile strengths of the PAN pure polymer precursor felt and the PAN copolymer precursor felt produced in Example 1 were measured. Tensile strength specimens were prepared in width (2.5 cm) X length (6 cm). The prepared sample was measured by ASTM D 882 method under conditions of Gauge length: 40 mm, Crosshead speed: 25 mm / min, 20 ° C, and humidity 65% RH. The tensile strength measurement results are shown in Fig. 4 (a) is a stress-strain graph of the PAN pure polymer nanofiber felts, and (b) is a graph of the stress strain of the PAN copolymer nanofiber felt.

As shown in FIG. 4, the nanofiber felt using the PAN pure polymer and the nanofiber felt using the PAN copolymer showed 160 Mpa and 161 Mpa, respectively, indicating that the two types of precursors have similar tensile strengths .

Experimental Example 5

The electrical conductivity of the PAN-based unidirectional carbon nanofiber Felt 2 prepared in Example 2 was measured. The electrical conductivity of the sample was measured by a 4-pole method using a 1 × 4 cm sample. The results are shown in Table 2. The comparison value is Adv. Funct. Mater. 2006 , 16, 2393? 397 , which is the result of measurement of 1500 占 폚 heat-treated general electrospun carbon nanofibers.

It can be seen from the following Table 2 that the electrical conductivity value of the unidirectional carbon nanofiber Felt 2 of the present invention is about 136.78 S / cm in the direction of fiber orientation, so that compared with the electrical conductivity of general electrospun carbon nanofiber 14.86 S / cm 9 times. This difference in electrical conductivity can be attributed to the difference in density in the fiber orientation direction. That is, the density of carbon nanofibers is increased through orientation. In the present invention, the number of carbon nanofibers, which are conductive materials, increases not only by the unit area but also by imposing a load to stabilize the carbon nanofibers. The pores between the carbon nanofibers serving as resistors decrease and exhibit high electrical conductivity.

Unidirectional
Carbon nanofiber Felt 2 1500 캜 Heat treated general electrospun carbon nanofiber Electrical conductivity
(S / cm) 136.78 14.86

Example 4

1. Preparation of spinning solution: preparation of PAN polymer solution with high viscosity

PAN (polyacrylonitrile) and tetraethoxysilane (TEOS) having a molecular weight of 150,000 were mixed at a weight ratio of 8: 2 as the carbon nanofiber precursor material. PAN / TEOS, which is 13% in total weight ratio, was dissolved in dimethylformamide (DMF) as a solvent to prepare a spinning solution. The prepared PAN solution had a viscosity of 3000 cP.

2. High-speed wound electrospinning: Manufacture of PAN-based precursor fiber felt with unidirectional orientation

PAN - based precursor fiber felt with unidirectional orientation was prepared by electrospinning the prepared PAN polymer spinning solution. As a condition of electrospinning, the applied voltage of 18 kV was applied. The distance between the spinneret and the collector was 7 cm and the fiber orientation was induced by winding at a high speed of 2040 m / min.

3. Weight Stretch Oxidation Stabilization: Manufacture of Chlorinated Fiber Felt in PAN System with Uniform Orientation

The PAN-based precursor fiber felt having a unidirectional property was kept at 200 to 300 DEG C for 1 hour at a temperature raising rate of 1 DEG C per minute under an air atmosphere while a load of 3.6 MPa was applied to stabilize the fiber to thereby stabilize the fiber, Insoluble dechlorinated fiber felt having improved mechanical properties was obtained.

4. Activation: Manufacture of PAN / TEOS carbon nanofiber felt with unidirectional orientation

The oxidized and stabilized chlorinated fiber felts were heated in an inert atmosphere to a temperature of 800 ° C at a rate of 5 ° C per minute and then activated in a steam atmosphere for 1 hour to prepare a unidirectional PAN / TEOS carbon nanofiber felt 1.

Example 5

The PAN / TEOS carbon nanofiber Felt 2 with unidirectional orientation was prepared in the same manner as in Example 4, except that the activated carbon was activated in a CO ₂ atmosphere.

Example 6

The unidirectional PAN / TEOS carbon nanofiber Felt 3 was prepared in the same manner as in Example 4, except that the temperature was elevated to 900 ° C and then activated in a CO ₂ atmosphere.

Experimental Example 6

The yield and pore characteristics of the unidirectional PAN / TEOS based carbon nanofiber felt 1 to 3 obtained in Examples 4 to 6 were tested and the results are shown in Table 3.

As can be seen from the following Table 3, the BET specific surface area was as large as 750-1,410 m ² / g and the diameter of the pores was 1.8-2.0 nm. Most of them had micropores (<2.0 nm) and some mesopores ) Was generated. At this time, the activation yield is in the range of 16 to 28%, which is 40 to 70% in terms of the yield after carbonization (40%).

PAN / TEOS-based carbon nanofibers
Felt 1 PAN / TEOS-based carbon nanofibers
Felt 2 PAN / TEOS-based carbon nanofibers
Felt 3 BET specific surface area
(M &lt; 2 &gt; / g) 1007.2 748.39 1408 Total pore volume
(Cm3 / g) 0.4763 0.3460 0.6833 Pore volume ratio micro 84.9 80.6 83.7 meso 15.1 19.4 16.3 Average pore diameter
(Nm) 1.8916 1.8207 1.9412 Final yield%
(Radiated fiber → after final treatment) 16% 28% 18%

Example 7

The PAN / TEOS carbon nanofiber felt 1 obtained in Example 4 was mounted on a coin type jig and an ionic liquid (IL-IMI, KOEI chemicals) was injected to prepare a super capacitor electrode including the PAN / TEOS carbon nanofiber felt 1 Respectively.

Experimental Example 7

The super capacitor electrode obtained in Example 7 was charged for 3 minutes to 2.6 V at a rate of 0.1 mA / sec and discharged for 7 minutes. The results are shown in Table 4 and FIG.

characteristic Specific surface area (m &lt; 2 &gt; / g) Electrical conductivity
(S / cm) Electrolyte Cell resistance Capacity F / g *
(Cell capacity, F) Commercialization
product 1219 1.38 ionic liquid 16Ω 61.9 Example 7 > 800 2.54 (single fiber) ionic liquid 214.3

* Capacity is half cell capacity

It can be seen from Table 4 that when the unidirectional PAN / TEOS carbon nanofiber Felt 1 of the present invention is contained, electric conductivity of about twice and electric capacity of 3 times or more can be obtained as compared with commercialized products.

5 minutes after charging for 3 minutes at a discharge rate of 0.1 mA / sec and then discharging for 7 minutes. From the graph of FIG. 5 obtained, the discharge behavior was linear, showing that the unidirectional PAN / TEOS carbon nanofiber felt 1 of the present invention It can be understood that the electrode including the electrode is a low resistance electrode.

In addition, since the single-orientation carbon nano fiber felt of the present invention Although not presented in detail it has an apparent density in the 0.7407g / cm ³ to 2.0 g / cm ³ range, a single orientation density of the carbon nanofibers, 1.30 (g / cm ³ ), It is possible to realize the electrode density of at least 0.65 even when the electrode is manufactured after 50% activation, and it is predicted that the capacity of the electrode is 2.6 times that of the conventional product.

Due to such characteristics, the unidirectional carbon nanofiber felt of the present invention can be applied to a high-performance super capacitor and a high-strength carbon nanofiber composite material which have not been realized by the conventional electrospun carbon nanofiber. In the future, Nano carbon fiber-based electrode material, etc., can be applied to high energy component materials having a high filling density per unit volume and high electrical conductivity.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation, Various changes and modifications will be possible.

Claims (8)

Comprising carbon nano fibers formed have an orientation in one direction, and the single-oriented carbon nanofibers, characterized in that the apparent density of the nano-carbon fiber felt comprising the carbon nanofiber of 0.7407g / cm ³ to 2.0 g / cm ³ felt.
The method according to claim 1,
Wherein the carbon nanofibers have a diameter of 50 to 400 nm.
delete The method according to claim 1,
Wherein the carbon nanotube layer further comprises at least one of SiOx (0 < x < 2), metal oxide, metal alkoxide, graphene, carbon nanotube, graphite particle or carbon black particle. The method according to claim 1,
Wherein the electric conductivity is 2.0 S / cm or more.
The method according to claim 1,
Wherein the size of the pores formed in the carbon nanofibers is 0.5-3 nm.
6. A single-oriented carbon nanofiber felt application comprising the unidirectional carbon nanofiber felt of any one of claims 1, 2 and 4 to 6.
8. The method of claim 7,
Wherein the carbon fiber felt application product is a supercapacitor or a high strength carbon nanofiber composite material.

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