CN1887965A - Prepn of carbon naotube-polyaniline composite material for super capacitor - Google Patents
Prepn of carbon naotube-polyaniline composite material for super capacitor Download PDFInfo
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- CN1887965A CN1887965A CNA2006100193226A CN200610019322A CN1887965A CN 1887965 A CN1887965 A CN 1887965A CN A2006100193226 A CNA2006100193226 A CN A2006100193226A CN 200610019322 A CN200610019322 A CN 200610019322A CN 1887965 A CN1887965 A CN 1887965A
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- composite material
- carbon nanotube
- polyaniline
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- polyaniline composite
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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Abstract
In the preparation process of carbon nanotube-polyaniline composite material for super capacitor, polyaniline is deposited onto the surface of carbon nanotube. During charging and discharging, polyaniline produces electrochemical doping-dedoping effect to generate false capacitance and to increase the specific capacitance of carbon nanotube. By means of the selection of the deposited material and the control of the deposition process, the present invention prepares carbon nanotube-polyaniline composite material with excellent performance and greatly raised specific capacitance.
Description
Technical field
The present invention relates to a kind of preparation method who is used for the carbon naotube-polyaniline composite material of ultracapacitor.
Background technology
Electrochemical capacitor becomes the research focus in international energy field with enormous and latent market owing to being with a wide range of applications.Carbon nanotube (CNTs) becomes the ideal electrode material of electrochemical capacitor owing to having high conductivity, high mesopore content, nothing " dead hole ", good electrochemical stability.But, cause its specific volume also lower because the specific surface area of carbon nanotube is lower.The low specific volume problem of carbon nanotube has become its bottleneck as electrode material for super capacitor of restriction.
Summary of the invention
The purpose of this invention is to provide a kind of preparation method who is used for the carbon naotube-polyaniline composite material of ultracapacitor, this method has the effect of highly significant on the specific volume that improves carbon nanotube.
The present invention is achieved like this, its processing step is: accurately take by weighing 1g CNTs and join in the HCl solution and abundant ultrasonic dispersion, be dissolved into a certain amount of aniline in the HCl solution then and pour ultrasonic dispersion in the CNTs suspension into, the concentration of HCl is controlled at 0.5~1.5mol/L, after treating that CNTs suspension is uniformly dispersed, with (the NH in a certain amount of HCl solution that is dissolved in 0.5~1.5mol/L
4)
2S
2O
8Slowly be added drop-wise in the reactant liquor and under 0 ℃ of condition stirring reaction 2h, product is filtered, with deionized water rinsing and in 60 ℃ of vacuum drying 24h, obtain the CNTs-PANI composite, the mass fraction of PANI is 50~60% in this moment composite.
The present invention has prepared the carbon naotube-polyaniline composite material of function admirable by to the selection of deposition materials and to the control of depositing operation, has improved significantly the specific volume of CNT, has effectively solved the low bulking value problem of CNT.
Embodiment
Embodiment 1
Accurately take by weighing in the HCl solution that 1g CNTs joins 0.5mol/L and abundant ultrasonic dispersion, then 1mL aniline is dissolved in the HCl solution of 1mol/L and pours ultrasonic dispersion in the CNTs suspension into, after treating that CNTs suspension is uniformly dispersed, 3.42g is dissolved in the (NH in the HCl solution of 0.5mol/L
4)
2S
2O
8Slowly be added drop-wise in the reactant liquor and under 0 ℃ of condition stirring reaction 2h, product is filtered, with deionized water rinsing and in 60 ℃ of vacuum drying 24h, obtain the CNTs-PANI composite, the mass fraction of PANI is 50% in this moment composite.
The performance of the carbon naotube-polyaniline composite material of preparation:
Carbon nanotube specific volume F/g:46
Carbon naotube-polyaniline specific volume F/g:163
Embodiment 2
Accurately take by weighing in the HCl solution that 0.82g CNTs joins 1mol/L and abundant ultrasonic dispersion, then 1mL aniline is dissolved in the HCl solution of 1mol/L and pours ultrasonic dispersion in the CNTs suspension into, after treating that CNTs suspension is uniformly dispersed, 3.42g is dissolved in the (NH in the HCl solution of 0.5mol/L
4)
2S
2O
8Slowly be added drop-wise in the reactant liquor and under 0 ℃ of condition stirring reaction 2h, product is filtered, with deionized water rinsing and in 60 ℃ of vacuum drying 24h, obtain the CNTs-PANI composite, the mass fraction of PANI is 55% in this moment composite.
The performance of the carbon naotube-polyaniline composite material of preparation:
Carbon nanotube specific volume F/g:46
Carbon naotube-polyaniline specific volume F/g:197
Claims (6)
1, a kind of preparation method of the CNT-polyaniline composite material for ultracapacitor, it is characterized in that the preparation method is: accurately take by weighing a certain amount of CNTs and join in the HCl solution and abundant ultrasonic dispersion, be dissolved into a certain amount of aniline in the HCl solution then and pour ultrasonic dispersion in the CNTs suspension into, the concentration of HCl is controlled at 0.5~1.5mol/L, after treating that CNTs suspension is uniformly dispersed, with (the NH in a certain amount of HCl solution that is dissolved in 0.5~1.5mol/L
4)
2S
2O
8Slowly be added drop-wise in the reactant liquor and under 0 ℃ of condition stirring reaction 2h, product is filtered, with deionized water rinsing and in 60 ℃ of vacuum drying 24h, obtain the CNTs-PANI composite.
2, according to the said preparation method who is used for the carbon nanotube-polyaniline composite material of ultracapacitor of claim 1, the material that it is characterized in that being deposited on the carbon nanotube is a polyaniline.
3, according to the preparation method of the said CNT-polyaniline composite material for ultracapacitor of claim 1, employed acid medium was HCl during polyaniline was synthetic, and oxidant is (NH
4)
2S
2O
8
4, according to the said preparation method who is used for the carbon nanotube-polyaniline composite material of ultracapacitor of claim 1, it is characterized in that the concentration of HCl is controlled at 0.5~1.5mol/L.
5, according to the said preparation method who is used for the carbon nanotube-polyaniline composite material of ultracapacitor of claim 1, its feature is controlled at 0 ℃ in the temperature of polyreaction.
6, according to the said preparation method who is used for the carbon nanotube-polyaniline composite material of ultracapacitor of claim 1, the massfraction of PANI is controlled at 50~60% in the matrix material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNA2006100193226A CN1887965A (en) | 2006-06-09 | 2006-06-09 | Prepn of carbon naotube-polyaniline composite material for super capacitor |
Applications Claiming Priority (1)
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CNA2006100193226A CN1887965A (en) | 2006-06-09 | 2006-06-09 | Prepn of carbon naotube-polyaniline composite material for super capacitor |
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CN1887965A true CN1887965A (en) | 2007-01-03 |
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CNA2006100193226A Pending CN1887965A (en) | 2006-06-09 | 2006-06-09 | Prepn of carbon naotube-polyaniline composite material for super capacitor |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102306552A (en) * | 2011-06-21 | 2012-01-04 | 中国铝业股份有限公司 | Electrode of capacitor and preparation method thereof |
CN102134317B (en) * | 2010-01-27 | 2012-12-12 | 中国科学院合肥物质科学研究院 | Preparation method of carbon nano tube/polyaniline nano composite conductive powder |
CN102826538A (en) * | 2012-09-17 | 2012-12-19 | 辽宁科技大学 | Method for preparing nitrogen-doped carbonaceous material by modifying polymer |
CN103366972A (en) * | 2013-07-10 | 2013-10-23 | 合肥工业大学 | Manufacturing method of multi-wall carbon nanotube and polyaniline nano fiber composite supercapacitor electrode |
CN109336083A (en) * | 2018-10-15 | 2019-02-15 | 福州大学 | A kind of method of High Internal Phase Emulsion template controllable preparation foamy carbon/carbon nano tube compound material |
DE102007056975B4 (en) * | 2006-11-28 | 2020-10-22 | The Yokohama Rubber Co., Ltd. | Polyaniline / carbon composite material and its use |
CN114622105A (en) * | 2022-04-08 | 2022-06-14 | 内蒙古科技大学 | Composite material for extracting niobium and preparation method and application method thereof |
-
2006
- 2006-06-09 CN CNA2006100193226A patent/CN1887965A/en active Pending
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007056975B4 (en) * | 2006-11-28 | 2020-10-22 | The Yokohama Rubber Co., Ltd. | Polyaniline / carbon composite material and its use |
CN102134317B (en) * | 2010-01-27 | 2012-12-12 | 中国科学院合肥物质科学研究院 | Preparation method of carbon nano tube/polyaniline nano composite conductive powder |
CN102306552A (en) * | 2011-06-21 | 2012-01-04 | 中国铝业股份有限公司 | Electrode of capacitor and preparation method thereof |
CN102826538A (en) * | 2012-09-17 | 2012-12-19 | 辽宁科技大学 | Method for preparing nitrogen-doped carbonaceous material by modifying polymer |
CN103366972A (en) * | 2013-07-10 | 2013-10-23 | 合肥工业大学 | Manufacturing method of multi-wall carbon nanotube and polyaniline nano fiber composite supercapacitor electrode |
CN103366972B (en) * | 2013-07-10 | 2016-01-20 | 合肥工业大学 | The preparation method of a kind of multi-walled carbon nano-tubes/polyaniline nano fiber composite supercapacitor electrode |
CN109336083A (en) * | 2018-10-15 | 2019-02-15 | 福州大学 | A kind of method of High Internal Phase Emulsion template controllable preparation foamy carbon/carbon nano tube compound material |
CN109336083B (en) * | 2018-10-15 | 2021-11-26 | 福州大学 | Method for controllably preparing foam carbon/carbon nanotube composite material by high internal phase emulsion template method |
CN114622105A (en) * | 2022-04-08 | 2022-06-14 | 内蒙古科技大学 | Composite material for extracting niobium and preparation method and application method thereof |
CN114622105B (en) * | 2022-04-08 | 2023-11-10 | 内蒙古科技大学 | Composite material for extracting niobium and preparation method and application method thereof |
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Open date: 20070103 |