WO2019070568A3 - Lithium ion- or sodium ion-based internal hybrid electrochemical energy storage cell - Google Patents

Lithium ion- or sodium ion-based internal hybrid electrochemical energy storage cell Download PDF

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Publication number
WO2019070568A3
WO2019070568A3 PCT/US2018/053728 US2018053728W WO2019070568A3 WO 2019070568 A3 WO2019070568 A3 WO 2019070568A3 US 2018053728 W US2018053728 W US 2018053728W WO 2019070568 A3 WO2019070568 A3 WO 2019070568A3
Authority
WO
WIPO (PCT)
Prior art keywords
sodium
energy storage
storage cell
hybrid electrochemical
electrochemical energy
Prior art date
Application number
PCT/US2018/053728
Other languages
French (fr)
Other versions
WO2019070568A2 (en
Inventor
Aruna Zhamu
Bor Z. Jang
Songhai Chai
Yen-Po Lin
Original Assignee
Nanotek Instruments, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US15/722,497 external-priority patent/US20190103231A1/en
Priority claimed from US15/724,892 external-priority patent/US10707025B2/en
Priority claimed from US15/727,900 external-priority patent/US10566668B2/en
Priority claimed from US15/728,488 external-priority patent/US10727002B2/en
Application filed by Nanotek Instruments, Inc. filed Critical Nanotek Instruments, Inc.
Publication of WO2019070568A2 publication Critical patent/WO2019070568A2/en
Publication of WO2019070568A3 publication Critical patent/WO2019070568A3/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/32—Carbon-based
    • H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/04—Hybrid capacitors
    • H01G11/06—Hybrid capacitors with one of the electrodes allowing ions to be reversibly doped thereinto, e.g. lithium ion capacitors [LIC]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/32—Carbon-based
    • H01G11/38—Carbon pastes or blends; Binders or additives therein
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/50—Electrodes characterised by their material specially adapted for lithium-ion capacitors, e.g. for lithium-doping or for intercalation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

Provided is an internal hybrid electrochemical cell comprising a pseudocapacitance-like cathode. The cathode active material contains a conductive carbon material or carbon nanosheets and a porphyrin compound, wherein the porphyrin compound is bonded to or supported by the carbon material to form a redox pair for pseudocapacitance; and also contains a battery-like anode active material selected from lithium metal, lithium metal alloy, a prelithiated anode active material, sodium metal, a sodium metal alloy, a sodium intercalation compound, a sodium-containing compound, and combinations thereof; and a lithium-containing or sodium-containing electrolyte in physical contact with the anode and the cathode.
PCT/US2018/053728 2017-10-02 2018-10-01 Lithium ion- or sodium ion-based internal hybrid electrochemical energy storage cell WO2019070568A2 (en)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US15/722,497 2017-10-02
US15/722,497 US20190103231A1 (en) 2017-10-02 2017-10-02 Internal hybrid electrochemical energy storage cell
US15/724,892 US10707025B2 (en) 2017-10-04 2017-10-04 Internal hybrid electrochemical energy storage cell having both high power and high energy density
US15/724,892 2017-10-04
US15/728,488 2017-10-09
US15/727,900 2017-10-09
US15/727,900 US10566668B2 (en) 2017-10-09 2017-10-09 Sodium ion-based internal hybrid electrochemical energy storage cell
US15/728,488 US10727002B2 (en) 2017-10-09 2017-10-09 Lithium ion-based internal hybrid electrochemical energy storage cell

Publications (2)

Publication Number Publication Date
WO2019070568A2 WO2019070568A2 (en) 2019-04-11
WO2019070568A3 true WO2019070568A3 (en) 2019-06-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2018/053728 WO2019070568A2 (en) 2017-10-02 2018-10-01 Lithium ion- or sodium ion-based internal hybrid electrochemical energy storage cell

Country Status (1)

Country Link
WO (1) WO2019070568A2 (en)

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CN109994732A (en) * 2019-04-15 2019-07-09 上海电气国轩新能源科技有限公司 The application of phenols lithium salt compound, lithium ion secondary battery and preparation method thereof
US11515564B2 (en) 2019-09-04 2022-11-29 The Regents Of The University Of Michigan Surface treatment of a solid electrolyte to lower the interfacial resistance between the solid electrolyte and an electrode
CN110817876B (en) * 2019-11-05 2022-09-27 武汉工程大学 Preparation method and application of eggshell membrane derived carbon/MXene/manganese dioxide composite material
CN112186150B (en) * 2020-09-16 2022-03-04 合肥国轩高科动力能源有限公司 Carbon-coated silicon/metal/carbon nanotube negative electrode composite material and preparation method thereof
CN112390249A (en) * 2020-11-23 2021-02-23 陕西理工大学 Boron-doped graphene aerogel and preparation method and application thereof
CN112952055A (en) * 2021-01-15 2021-06-11 贵州民族大学 Two-dimensional structure selenium telluride modified carbon fiber electrode material and preparation method thereof
CN113105671A (en) * 2021-04-13 2021-07-13 浙江大学 Preparation method of graphene aerogel continuous curved surface network
CN113447550B (en) * 2021-06-22 2024-03-19 浙江理工大学 Preparation method of electrochemical sensor modified electrode for detecting glucose as degradation product of cotton-flax relics
WO2023076239A1 (en) * 2021-10-25 2023-05-04 Carnegie Mellon University Simple, scalable method for dispersing mxenes in nonpolar organic solvents
CN114388802B (en) * 2021-12-24 2023-03-10 合肥国轩高科动力能源有限公司 Monoatomic-load nitrogen-phosphorus-codoped carbon composite-material-coated lithium iron phosphate, and preparation method and application thereof
CN114899432B (en) * 2022-05-11 2023-08-22 黑龙江哈船碳材料科技有限公司 Composite electrode material for direct sodium borohydride fuel cell and preparation method thereof
CN115162053B (en) * 2022-07-26 2023-08-29 陕西煤业化工技术研究院有限责任公司 High-conductivity carbon fiber paper and preparation method thereof

Citations (6)

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US9437372B1 (en) * 2016-01-11 2016-09-06 Nanotek Instruments, Inc. Process for producing graphene foam supercapacitor electrode
US9564656B1 (en) * 2015-09-14 2017-02-07 Nanotek Instruments, Inc. Process for producing alkali metal or alkali-ion batteries having high volumetric and gravimetric energy densities
US9640334B2 (en) * 2010-01-25 2017-05-02 Nanotek Instruments, Inc. Flexible asymmetric electrochemical cells using nano graphene platelet as an electrode material
WO2017095512A1 (en) * 2015-12-03 2017-06-08 Angstron Materials, Inc. Chemical-free production of graphene materials
US9905373B2 (en) * 2016-01-04 2018-02-27 Nanotek Instruments, Inc. Supercapacitor having an integral 3D graphene-carbon hybrid foam-based electrode

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US20130171502A1 (en) * 2011-12-29 2013-07-04 Guorong Chen Hybrid electrode and surface-mediated cell-based super-hybrid energy storage device containing same
US9564656B1 (en) * 2015-09-14 2017-02-07 Nanotek Instruments, Inc. Process for producing alkali metal or alkali-ion batteries having high volumetric and gravimetric energy densities
WO2017095512A1 (en) * 2015-12-03 2017-06-08 Angstron Materials, Inc. Chemical-free production of graphene materials
US9905373B2 (en) * 2016-01-04 2018-02-27 Nanotek Instruments, Inc. Supercapacitor having an integral 3D graphene-carbon hybrid foam-based electrode
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Title
JAHAN ET AL.: "Electrocatalytically Active Graphene-Porphyrin MOF Composite for Oxygen Reduction Reaction", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 134, 22 March 2012 (2012-03-22), pages 6707 - 6713, XP55615169 *
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