TWM554016U - Tubular membrane structure - Google Patents

Tubular membrane structure Download PDF

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Publication number
TWM554016U
TWM554016U TW106212893U TW106212893U TWM554016U TW M554016 U TWM554016 U TW M554016U TW 106212893 U TW106212893 U TW 106212893U TW 106212893 U TW106212893 U TW 106212893U TW M554016 U TWM554016 U TW M554016U
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Taiwan
Prior art keywords
tubular
tubular membrane
membrane structure
shape
structure according
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TW106212893U
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Chinese (zh)
Inventor
鄭石治
扶亞民
陳倫慶
呂權訓
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華懋科技股份有限公司
上海華懋環保節能設備有限公司
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Priority to TW106212893U priority Critical patent/TWM554016U/en
Priority to CN201721382949.8U priority patent/CN207680382U/en
Publication of TWM554016U publication Critical patent/TWM554016U/en

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Description

管式膜結構 Tubular membrane structure

本創作係有關於一種管式膜結構,尤指一種透過該管式膜之管狀體為六角形之態樣,讓該管式膜之管狀體在排列結合時能形成緊密狀態,以具有較佳的吸附及過濾效能,而適用於吸附用或過濾用之管式膜或類似結構者。 The present invention relates to a tubular membrane structure, in particular to a tubular body through which the tubular membrane is hexagonal, so that the tubular body of the tubular membrane can be formed into a compact state when aligned and integrated. The adsorption and filtration performance is suitable for tubular membranes or similar structures for adsorption or filtration.

習知的管式膜吸附材料之吸附效率與特性比傳統顆粒吸附材料高出2至3倍吸附能力,並具有低的傳質阻力特性,其壓力損失更是比傳統填充管柱低於數十倍乃至百倍。 The adsorption efficiency and characteristics of the conventional tubular membrane adsorbent are 2 to 3 times higher than that of the conventional particulate adsorbent, and have low mass transfer resistance characteristics, and the pressure loss is lower than that of the conventional filled tubular string. It is even a hundred times.

然而,目前的管式膜之管體其外型都是圓形管狀,而當該為圓形管狀之管式膜與該為圓形管狀之管式膜靠在一起時,其中間就會出現縫隙,而該縫隙會造成在吸附或過濾的過程中的氣體或液體之洩漏,進而造成氣流體分布不均,所以業界的做法就是透過粘著劑來填入該縫隙中,讓該縫隙能被填滿降低氣體或液體之洩漏。 However, the tubular body of the current tubular membrane has a circular tubular shape, and when the tubular membrane of the circular tubular shape is closed with the tubular membrane of the circular tubular shape, it appears in the middle. a gap, which causes leakage of gas or liquid during adsorption or filtration, which results in uneven distribution of the gas fluid. Therefore, the industry practice is to fill the gap through an adhesive to allow the gap to be Fill the leak of reduced gas or liquid.

因此,本創作人有鑑於上述缺失,期能提出一種具有能形成較緊密排列狀態及較佳的吸附及過濾效能之管式膜結構,令使用者可輕易 操作組裝,乃潛心研思、設計組製,以提供使用者便利性,為本創作人所欲研創之創作動機者。 Therefore, in view of the above-mentioned deficiencies, the present author can propose a tubular membrane structure which can form a tightly arranged state and better adsorption and filtration performance, so that the user can easily Operational assembly is a painstaking research and design system to provide user convenience and is the creative motive for the creators.

本創作之主要目的,在於提供一種管式膜結構,其主要該管式膜係為一管狀體,該管式膜之管狀體係呈六角形,而該管式膜之管狀體內部係設有至少一孔通道,且該管式膜之管狀體的外徑係為0.5mm以上,透過該管式膜之管狀體為六角形,讓該管式膜之管狀體在排列結合時能形成緊密狀態,且同體積能排列堆積較大的重量,以具有較佳的吸附及過濾效能,進而增加整體之實用性者。 The main purpose of the present invention is to provide a tubular membrane structure, wherein the tubular membrane is a tubular body, the tubular membrane has a hexagonal shape, and the tubular membrane has at least a tubular body. a hole passage, and the tubular body of the tubular film has an outer diameter of 0.5 mm or more, and the tubular body passing through the tubular film has a hexagonal shape, so that the tubular body of the tubular film can form a tight state when aligned. Moreover, the same volume can be arranged to accumulate a large weight, so as to have better adsorption and filtration efficiency, thereby increasing the overall utility.

本創作之另一目的,在於提供一種管式膜結構,透過於該管式膜之管狀體內部設有至少一孔通道,且該至少一孔通道係能設於該管式膜之管狀體的中間或是任一處,而該至少一孔通道可以是設為三角形、四角形、五角形、六角形或多角形之其中任一種或是圓形、橢圓形、正方形或長方形之其中任一種,使該管式膜之管狀體具有提高氣體或液體之吸附與分離的效率,進而增加整體之使用性者。 Another object of the present invention is to provide a tubular membrane structure through which at least one pore passage is provided in the tubular body of the tubular membrane, and the at least one orifice passage can be disposed on the tubular body of the tubular membrane. In the middle or anywhere, the at least one hole channel may be any one of a triangle, a quadrangle, a pentagon, a hexagon or a polygon, or any one of a circle, an ellipse, a square or a rectangle. The tubular body of the tubular membrane has an efficiency of improving the adsorption and separation of gas or liquid, thereby increasing the overall usability.

為達上述目的,本創作為一種管式膜結構,該管式膜係為一管狀體,其特徵在於:該管式膜之管狀體係呈六角形,而該管式膜之管狀體內部係設有至少一孔通道,且該管式膜之管狀體的外徑係為0.5mm以上者。 In order to achieve the above object, the present invention is a tubular membrane structure which is a tubular body characterized in that the tubular system of the tubular membrane has a hexagonal shape, and the tubular body of the tubular membrane is internally provided. There is at least one hole passage, and the tubular body of the tubular film has an outer diameter of 0.5 mm or more.

為了能夠更進一步瞭解本創作之特徵、特點和技術內容,請參閱以下有關本創作之詳細說明與附圖,惟所附圖式僅提供參考與說明用,非用以限制本創作。 In order to further understand the features, features and technical contents of the present invention, please refer to the following detailed description of the present invention and the accompanying drawings, which are only for reference and description, and are not intended to limit the present invention.

10‧‧‧管式膜 10‧‧‧ tubular membrane

11‧‧‧六角形 11‧‧‧ hexagon

20‧‧‧孔通道 20‧‧‧ hole channel

21‧‧‧六角形 21‧‧‧ hexagon

22‧‧‧圓形 22‧‧‧round

第1圖係為本創作之立體外觀示意圖。 The first picture is a schematic view of the three-dimensional appearance of the creation.

第2圖係為本創作之孔通道為圓形示意圖。 The second picture is a circular schematic diagram of the hole channel of the creation.

第3圖係為本創作之孔通道為六角形示意圖。 The third figure is a hexagonal schematic diagram of the hole channel of the present creation.

第4圖係為本創作之管式膜之管狀體接合示意圖。 Figure 4 is a schematic view of the tubular body of the tubular film of the present invention.

第5圖係為本創作之複數孔通道為圓形示意圖。 Figure 5 is a circular schematic diagram of the plural hole channels of the present creation.

第6圖係為本創作之複數孔通道為六角形示意圖。 Figure 6 is a schematic diagram of the hexagonal shape of the plural aperture channel of the present creation.

第7圖係為本創作之另一複數孔通道為圓形示意圖。 Figure 7 is a circular schematic diagram of another plural aperture channel of the present creation.

第8圖係為本創作之另一複數孔通道為六角形示意圖。 Figure 8 is a schematic diagram of another multi-hole channel in the creation of a hexagon.

請參閱第1圖至第8圖,係為本創作實施例之示意圖,而本創作之管式膜結構的最佳實施方式係運用於吸附用或過濾用之管式膜10,以具有較佳的吸附及過濾效能。 Please refer to FIG. 1 to FIG. 8 , which are schematic diagrams of the present embodiment, and the preferred embodiment of the tubular membrane structure of the present invention is applied to the tubular membrane 10 for adsorption or filtration. Adsorption and filtration efficiency.

而本創作之管式膜結構,主要係設有至少一管式膜10,而該管式膜10係為一管狀體(如第1圖所示),且該管式膜10之管狀體的外徑係為0.5mm以上,其中該管式膜10之管狀體係包括聚合物及吸附劑(圖未示),而該聚合物係為由聚碸(polysulfone,PSF)、聚醚碸 (polyethersulfone,PESF)、聚偏二氟乙烯(polyvinylidene fluoride,PVDF)、聚苯碸(polyphenylsulfone,PPSU)、聚丙烯腈(polyacrylonitrile)、醋酸纖維素、二醋酸纖維素、聚亞醯胺(polyimide,PI)、聚醚醯亞胺、聚醯胺、聚乙烯醇、聚乳酸、聚乙醇酸、聚(乳酸-乙醇酸)(poly(lactic-co-glycolic acid))、聚幾內酯、聚乙烯氫吡咯酮(polyvinyl pyrrolidone)、乙烯-乙烯醇(ethylene vinyl alcohol)、聚二甲基矽氧烷、聚四氟乙烯及乙酸纖維素(cellulose acetate,CA)所組成群組之至少一。另以該管式膜10之管狀體的總重量來計算,其該吸附劑含量為30至95wt%,且該吸附劑係為粉體,該粉體之複數粒子係具有0.005至500um之粒徑,而該粉體之複數粒子具有二維或三維的孔洞結構,且孔洞係為規則或不規則之形體,其中該吸附劑係為由分子篩、活性碳、A型沸石(例如3A、4A或5A)、X型沸石(例如10X)、Y型沸石(例如13X)、高矽分子篩(例如ZSM-5、矽土石(silicalite)、HiSiv1000、HiSiv3000、HiSiv6000、Abscent1000、Abscent2000、Abscent3000、USKY-700、USKY-790及USKZ2000)、中孔洞分子篩(例如MCM-41、48、50及SBA-15)、金屬有機骨架(Metal Organic Frameworks:MOF)或石墨烯所組成群組之至少一。 The tubular membrane structure of the present invention is mainly provided with at least one tubular membrane 10, and the tubular membrane 10 is a tubular body (as shown in FIG. 1), and the tubular membrane of the tubular membrane 10 is The outer diameter is 0.5 mm or more, wherein the tubular system of the tubular membrane 10 comprises a polymer and an adsorbent (not shown), and the polymer is composed of polysulfone (PSF), polyether oxime. (polyethersulfone, PESF), polyvinylidene fluoride (PVDF), polyphenylsulfone (PPSU), polyacrylonitrile, cellulose acetate, cellulose diacetate, polyimide (polyimide, PI), polyether phthalimide, polyamine, polyvinyl alcohol, polylactic acid, polyglycolic acid, poly(lactic-co-glycolic acid), polylactone, polyethylene At least one of the group consisting of polyvinyl pyrrolidone, ethylene vinyl alcohol, polydimethyl siloxane, polytetrafluoroethylene, and cellulose acetate (CA). Further, the adsorbent content is 30 to 95% by weight based on the total weight of the tubular body of the tubular film 10, and the adsorbent is a powder, and the plurality of particles of the powder have a particle diameter of 0.005 to 500 μm. And the plurality of particles of the powder have a two-dimensional or three-dimensional pore structure, and the pores are regular or irregular shapes, wherein the adsorbent is composed of molecular sieves, activated carbon, and type A zeolite (for example, 3A, 4A or 5A). ), X-type zeolite (eg 10X), Y-type zeolite (eg 13X), sorghum molecular sieve (eg ZSM-5, silicalite, HiSiv1000, HiSiv3000, HiSiv6000, Abscent1000, Abscent2000, Abscent3000, USKY-700, USKY) -790 and USKZ2000), at least one of a group consisting of a mesoporous molecular sieve (for example, MCM-41, 48, 50, and SBA-15), a metal organic framework (MOF), or graphene.

另如果用於過濾之管式膜10,該管式膜10係由無機材料所製成(圖未示),其中該添加之無機材料可包含吸附劑,如含有吸附劑時,其吸附劑與該無機材料比例為1:20至20:1,而上述之無機材料係為氧化鐵、氧化銅、鈦酸鋇、鈦酸鉛、氧化鋁、二氧化矽、氣凝膠(silica aerogel)、皂土(例如鉀皂土、鈉皂土、鈣皂土及鋁皂土)、瓷土(例如Al2O3.2SiO2.2H2O)、hyplas土(例如20%Al2O3.70%SiO2.0.8%Fe2O3.2.3%K2O. 1.6%Na2O)、矽酸鈣(例如Ca3SiO5、Ca3Si2O7及CaSiO3)、矽酸鎂(例如Mg3Si4O10(OH)2)、矽酸鈉(例如Na2SiO3及其水合物(hydrate))、無水硫酸鈉、矽酸鋯(例如ZrSiO4)、不透明鋯(例如53.89%SiO2.4.46%Al2O3.12.93%ZrO2.9.42%CaO.2.03%MgO.12.96%ZnO.3.73%K2O.0.58%Na2O)及碳化矽所組成群組之至少一。 In addition, if the tubular membrane 10 is used for filtration, the tubular membrane 10 is made of an inorganic material (not shown), wherein the added inorganic material may contain an adsorbent, such as an adsorbent, and an adsorbent thereof. The inorganic material ratio is 1:20 to 20:1, and the above inorganic materials are iron oxide, copper oxide, barium titanate, lead titanate, aluminum oxide, cerium oxide, silica aerogel, soap. Soil (such as potassium bentonite, sodium bentonite, calcareous earth and aluminocarbonate), porcelain clay (such as Al2O3.2SiO2.2H2O), hyplas soil (for example, 20% Al2O 3.70% SiO2.0.8% Fe2O3.2.3% K2O. 1.6% Na2O), calcium citrate (such as Ca3SiO5, Ca3Si2O7 and CaSiO3), magnesium citrate (such as Mg3Si4O10(OH)2), sodium citrate (such as Na2SiO3 and its hydrate), anhydrous sodium sulfate, citric acid Zirconium (eg ZrSiO4), opaque zirconium (eg 53.89% SiO2.4.46% Al2O3.12.93% ZrO2.9.42% CaO.2.03% MgO. 12.96% ZnO.3.73% K2O.0.58% Na2O) and tantalum carbide At least one.

而上述該管式膜10之管狀體係呈六角形11(如第1圖所示),當該管式膜10之管狀體在於與其他的管式膜10之管狀體進行排列接合時(如第4圖所示),能因為該管式膜10之管狀體為六角形11而能具有緊密接合狀態,達到方便進行組合之效能,以具有較佳的吸附及過濾功效。 The tubular system of the tubular membrane 10 has a hexagonal shape 11 (as shown in FIG. 1), and when the tubular body of the tubular membrane 10 is aligned with the tubular body of the other tubular membrane 10 (eg, As shown in Fig. 4, the tubular body of the tubular membrane 10 can be in a tightly joined state because of its hexagonal shape 11 to achieve a convenient combination for better adsorption and filtration.

另該上述該管式膜10之管狀體係設有至少一孔通道20(如第2圖及第3圖所示),而該孔通道20係由該管式膜10之管狀體的一端設至另一端以形成通道,且該孔通道20係設於該管式膜10之管狀體的中間,也可以是在該管式膜10之管狀體的任一處,或者是設於該管式膜10之管狀體的中間及周圍環繞皆可(如第5圖及第6圖所示),其中該孔通道20之設計態樣不限於上述之態樣,也可以是其他如兩個、三個、四個或五個等之孔通道20的設計方式。 Further, the tubular system of the tubular film 10 is provided with at least one hole passage 20 (as shown in FIGS. 2 and 3), and the hole passage 20 is provided by one end of the tubular body of the tubular film 10 to The other end is formed to form a channel, and the hole channel 20 is disposed in the middle of the tubular body of the tubular film 10, or may be at any position of the tubular body of the tubular film 10, or may be disposed on the tubular film The middle and surrounding of the tubular body of 10 can be surrounded (as shown in FIG. 5 and FIG. 6), wherein the design of the hole passage 20 is not limited to the above-mentioned aspects, and may be other two or three. , four or five, etc., the design of the hole channel 20.

再者,上述的孔通道20之形狀可以是三角形(圖未示)、四角形(圖未示)、五角形(圖未示)、六角形(如第3圖所示)或多角形(圖未示)之其中任一種或是圓形(如第2圖所示)、橢圓形(圖未示)、正方形(圖未示)或長方形(圖未示)之其中任一種,其中該孔通道20之形狀除了上述之 形狀也可以是不規則形狀或是其他形狀不以上述為限,且該孔通道20的形狀可以是一樣大小(如第7圖及第8圖所示)也可以是不一樣大小(如第5圖及第6圖所示),藉此,透過該孔通道20之形狀,使該管式膜10之管狀體具有提高氣體或液體之吸附與分離的效率,進而增加整體之使用性。 Furthermore, the shape of the above-mentioned hole channel 20 may be a triangle (not shown), a quadrangle (not shown), a pentagon (not shown), a hexagon (as shown in FIG. 3) or a polygon (not shown). Any one of either a circular shape (as shown in FIG. 2), an elliptical shape (not shown), a square (not shown), or a rectangular shape (not shown), wherein the hole channel 20 Shape in addition to the above The shape may also be an irregular shape or other shapes not limited to the above, and the shape of the hole channel 20 may be the same size (as shown in FIGS. 7 and 8) or may be different (eg, 5th). As shown in Fig. 6 and Fig. 6, the tubular body of the tubular membrane 10 has the effect of improving the adsorption and separation of gas or liquid through the shape of the pore passage 20, thereby increasing the overall usability.

藉由以上詳細說明,可使熟知本項技藝者明瞭本創作的確可達成前述目的,實已符合專利法之規定,爰提出專利申請。 By the above detailed description, it will be apparent to those skilled in the art that the present invention can achieve the foregoing objectives, and has been in compliance with the provisions of the Patent Law, and has filed a patent application.

惟以上所述者,僅為本創作之較佳實施例而已,當不能以此限定本創作實施之範圍;故,凡依本創作申請專利範圍及創作說明書內容所作之簡單的等效變化與修飾,皆應仍屬本創作專利涵蓋之範圍內。 However, the above is only the preferred embodiment of the present invention, and the scope of the creation of the present invention cannot be limited by this; therefore, the simple equivalent changes and modifications made by the scope of the patent application and the content of the creation specification are All should remain within the scope of this creation patent.

10‧‧‧管式膜 10‧‧‧ tubular membrane

11‧‧‧六角形 11‧‧‧ hexagon

20‧‧‧孔通道 20‧‧‧ hole channel

22‧‧‧圓形 22‧‧‧round

Claims (10)

一種管式膜結構,該管式膜係為一管狀體,其特徵在於:該管式膜之管狀體係呈六角形,而該管式膜之管狀體內部係設有至少一孔通道,且該管式膜之管狀體的外徑係為0.5mm以上者。 A tubular membrane structure, wherein the tubular membrane has a tubular shape, and the tubular membrane has a hexagonal shape, and the tubular membrane has at least one pore passage therein. The tubular body of the tubular film has an outer diameter of 0.5 mm or more. 如申請專利範圍第1項所述之管式膜結構,其中該孔通道係進一步設於該管式膜之管狀體的中間者。 The tubular membrane structure of claim 1, wherein the pore channel is further disposed in the middle of the tubular body of the tubular membrane. 如申請專利範圍第1項所述之管式膜結構,其中該孔通道係進一步設於該管式膜之管狀體的任一處者。 The tubular membrane structure of claim 1, wherein the pore channel is further disposed at any one of the tubular bodies of the tubular membrane. 如申請專利範圍第1、2或3項所述之管式膜結構,其中該孔通道係進一步設為三角形、四角形、五角形、六角形或多角形之其中任一種者。 The tubular membrane structure according to claim 1, wherein the pore passage is further set to any one of a triangle, a quadrangle, a pentagon, a hexagon or a polygon. 如申請專利範圍第1、2或3項所述之管式膜結構,其中該孔通道係進一步設為圓形、橢圓形、正方形或長方形之其中任一種者。 The tubular membrane structure of claim 1, wherein the pore channel is further set to any one of a circular shape, an elliptical shape, a square shape, or a rectangular shape. 如申請專利範圍第1項所述之管式膜結構,其中該管式膜之管狀體係包括聚合物及吸附劑,而該吸附劑含量為30至95wt%者。 The tubular membrane structure of claim 1, wherein the tubular membrane tubular system comprises a polymer and an adsorbent, and the adsorbent content is from 30 to 95% by weight. 如申請專利範圍第6項所述之管式膜結構,其中該聚合物係進一步為聚碸、聚醚碸、聚偏二氟乙烯、聚苯碸、聚丙烯腈、醋酸纖維素、二醋酸纖維素、聚亞醯胺、聚醚醯亞胺、聚醯胺、聚乙烯醇、聚乳酸、聚乙醇酸、聚(乳酸-乙醇酸)、聚幾內酯、聚乙烯氫吡咯酮、乙烯-乙烯醇、聚二甲基矽氧烷、聚四氟乙烯及乙酸纖維素所組成群組之至少一者。 The tubular membrane structure according to claim 6, wherein the polymer is further polyfluorene, polyether oxime, polyvinylidene fluoride, polyphenyl hydrazine, polyacrylonitrile, cellulose acetate, diacetate , polytheneamine, polyether quinone imine, polyamine, polyvinyl alcohol, polylactic acid, polyglycolic acid, poly(lactic-glycolic acid), polylactone, polyvinylpyrrolidone, ethylene-ethylene At least one of the group consisting of alcohol, polydimethyl siloxane, polytetrafluoroethylene, and cellulose acetate. 如申請專利範圍第6項所述之管式膜結構,其中該吸附劑係進一步為分子篩、活性碳、A型沸石、X型沸石、Y型沸石、高矽分子篩、中孔洞分子篩、金屬有機骨架及石墨烯所組成群組之至少一者。 The tubular membrane structure according to claim 6, wherein the adsorbent further comprises molecular sieve, activated carbon, zeolite A, zeolite X, zeolite Y, sorghum molecular sieve, medium pore molecular sieve, metal organic framework. And at least one of the group consisting of graphene. 如申請專利範圍第1項所述之管式膜結構,其中該管式膜之管狀體係進一步由無機材料所製成者。 The tubular membrane structure according to claim 1, wherein the tubular membrane tubular system is further made of an inorganic material. 如申請專利範圍第9項所述之管式膜結構,其中該無機材料係進一步為氧化鐵、氧化銅、鈦酸鋇、鈦酸鉛、氧化鋁、二氧化矽、氣凝膠、皂土、瓷土、hyplas土、矽酸鈣、矽酸鎂、矽酸鈉、無水硫酸鈉、矽酸鋯、不透明鋯及碳化矽所組成群組之至少一者。 The tubular membrane structure according to claim 9, wherein the inorganic material is further iron oxide, copper oxide, barium titanate, lead titanate, alumina, cerium oxide, aerogel, bentonite, At least one of a group consisting of china clay, hypolas soil, calcium citrate, magnesium silicate, sodium citrate, anhydrous sodium sulfate, zirconium silicate, opaque zirconium and tantalum carbide.
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