TWI326297B - Conductive ink composition and preparing method thereof - Google Patents

Description

1326297 IX. Description of the Invention: [Technical Field] The present invention relates to a conductive ink composition comprising a metal complex compound having a specific structure and an additive, and a method of preparing the same . [Prior Art] Recently, conductive inks can be used for lead-free electric/electronic circuits, low-resistance metal lines, printed circuit boards (PCBs), flexible printed circuit boards (FPCs), and radio frequency identification ( rfID) tag antenna, electromagnetic interference (EMI) shielding, plasma display (PDP), thin film liquid crystal display (TFT-LCD), organic light emitting diode (OLED), flexible display, and organic thin film transistor (OTFT) Attention is drawn to the formation of metal films or patterns and electrode printing. A conductive ink paste is disclosed in Japanese Patent Publication No. 2004-221006 (August 5, 2004) and Japanese Patent Publication No. 2004-273205 (September 30, 2004), which is a metal or metal alloy. Rice granules, powders or flakes are prepared using an adhesive resin or solvent. CTzem. Maier., 15, 2208 (2003), Japanese Patent Publication No. Hei 11-319538 (November 24, 1999), Japanese Patent Publication No. Hei 2004-256757 (September 10, 2004), and the United States Patent No. 4 762 56 ( (August 9, 1988) is disclosed in an aqueous solution or an organic solvent, and a metal compound such as silver nitrate, hydrogen tetrachloroaurate and copper ruthenate is reacted with other compounds to A method of forming a gel or nanoparticle. However, these methods are not economical and unstable, and require a complicated process. 1326297 In addition, the high drying temperatures make them unsuitable for use on a variety of different substrates. Carboxylates are a known ligand which forms complexes, especially organometallic complexes (Prog· / «org. C/iem·, 10, p. 233 (1968)). In general, since - the metal tetrate complex is less soluble in organic solvents (·/· CT^w. Soc·, (〇., ρ· 514 t (1971), US Patent No. 5,534,312 (1996) July 9)) and will decompose at high temperatures, although their preparation is easier but limited in application.

J. Inorg. Nucl. Chem., 40, p. 1599 (197^)^Ang. Chem., Int. Ed. Engl., 31, p. 770 (1992) ' Eur. J. Solid State Inorg. Chem. , 32, p. 25 (1995) 'J. Chem. Cryst., 26, p. 99 (1996) 'Chem. Vapor Deposition, • 7, 111 (2001), C/zem_ Maier·, 16, 2021 (2004) , U.S. Patent No. 5,705,661 (January 6, 1998), Japanese Patent Publication No. 2002-329419 (Il. No. 2002), and Korean Patent Publication No. 2003-0085357 (September 5, 2003) Several methods have been proposed to solve this problem. These methods use a monocarboxylate compound with a long alkyl chain or a monoamine compound or a phosphine compound. The inventors of the present invention have proposed a stable and highly soluble complex compound and a preparation method thereof in Korean Patent Application No. 2005-11475 and No. 2005/11478. In particular, in the Korean Patent Application No. 2005-18364 and No. 2005-23013, they have proposed a stable and transparent conductive ink composition having excellent solubility and good electrical conductivity, the metal content and film thickness thereof. It is easy to control, and the use of these compositions is a method of easily forming a metal pattern even at low temperatures. However, a variety of conductive inks are required to produce high quality specialty products or to meet the special properties required. According to UUmann's Encyclopedia of ind. chem., VcA. A24, 107 7 1326297 (1993), silver is a precious metal, which is not easily oxidized and has good electrical and thermal conductivity and catalytic ability and antibacterial ability, so silver and silver compounds It is widely used in industry, in silver alloys, electroplating, medicine, photo, conductive and electronic products, fiber, detergent, household products, etc. Further, a silver compound can be used as a catalyst for synthesizing an organic compound and a polymer. In particular, silver has recently been used in new areas requiring metal patterns or electrodes, including lead-free conductive/circuits, low-resistance metal lines, PCBs, FPCs, RFID tag antennas, EMI shielding, PDPs, TFT-LCDs, OLEDs, Soft displays and OTFTs. Recently, research on the use of silver in place of aluminum in a reflective film of a reflective or semi-transmissive liquid crystal screen is underway (silver has better reflection and conductivity characteristics), as disclosed in Japanese Laid-Open Patent Publication No. 2002-129259 ( May 9, 2002), Japanese Patent Publication No. 2004-176115 (June 24, 2004) and Japanese Patent Publication No. 2004-231982 (August 19, 2004). However, compounds derived from silver are limited and lack stability and solubility. Further, they have a decomposition temperature of 200 ° C or higher, since the temperature is too high to obtain a metal pattern having good conductivity and their decomposition speed is slow. The inventors of the present invention have continued to study to solve these problems and complete the present invention. The present invention provides a conductive ink composition having excellent stability and solubility, which is easy to form a film and is easily calcined even at a low temperature, so that a uniform and precise film or a pattern having good conductivity can be formed without A special substrate is used, as well as a method of preparing the composition. SUMMARY OF THE INVENTION An object of the present invention is to provide a conductive ink composition comprising a metal complex compound having a specific structure of 1326297 and an additive, and a method of preparing the composition.

Another object of the present invention is to provide a conductive ink composition which is easy to control metal content and film thickness, and a method of preparing the composition. Still another object of the present invention is to provide a conductive ink composition which can be calcined even at a low temperature of 200 ° C or lower, and which is easy to form a uniform and precise film or a micropattern having good conductivity. And a method of preparing the composition. A further object of the present invention is to provide a conductive ink composition which has excellent stability and solubility and which is easy to form a film without considering the use of a special substrate, and a method of preparing the composition. In order to achieve the above object, the inventors of the present invention have invented a conductive ink composition comprising a metal complex compound and an additive which is obtained by at least one metal or metal compound represented by the following Chemical Formula 1. It is obtained by reacting at least one compound represented by the following chemical formula 2, chemical formula 3 or chemical formula 4 with ammonium urinate or ammonium carbonate as a substrate, and a method for preparing the composition:

ΜηΧ Rl household 3 NCONH-R4 R2 R5 (l) (2) ©Θ ηθ© r2-hnoconh-r5 R3 Rg (3) R1 r2-hnocohR;

In Chemical Formula 1, M is a metal or metal alloy; n is an integer from 1 to 10; and 9 1326297 x is a substituent which is absent or is at least one selected from the group consisting of hydrogen, ammonium, oxygen, sulfur, halogen, Cyano, cyanate, carbonate, nitrate, nitrite, sulfate, phosphate, thiocyanate, oleate, percarbonate, tetrafluoroborate, acetoacetate, sulfhydryl, decylamine, alcohol Salts, carboxylates and their derivatives. In Chemical Formula 2 to Chemical Formula 4, R丨, R2, R3, R4, R5 and R6 are each independently selected from hydrogen; substituted or unsubstituted CrCso aliphatic alkyl, cycloaliphatic alkyl, aryl or aromatic An alkyl group; a polymeric compound; a heterocyclic compound; and a derivative thereof; wherein the core and R2 or R4 and R5 may be bonded to each other to form an alkylene ring with or without a hetero atom. Although not intended to limit the present invention, it is preferred that R1 and R4 are Ci_Ci4 aliphatic Hyun> base and Κ·3, 尺4, Κ·5 and 尺6 series are each a mouse or a C 1-C14 aliphatic group. Hyunji. A non-limiting specific example of the compound represented by Chemical Formula 1 is a metal (when η is 1 and X is absent), such as silver, gold, copper, zinc, nickel, Ming, Ji, Turn, Titanium, Hunger, Meng, Iron , 络, 错, 锐, 绍, 鹤, 钌, tin, group, chain, iron, silver, Ilu, marry, wrong, marriage, tin, record, ship, Syria, 钐, 铕, net and stove or the aforementioned Alloys; and metal compounds such as copper oxide, zinc oxide, antimony oxide, sulphide, chlorination, copper carbonate, gasified iron, gasification gold, gasification, gasification, acid, acetonitrile, vanadium , cobalt acetate, tin lactate, manganese oxalate, gold acetate, palladium oxalate, copper 2-ethylhexanoate, iron stearate, nickel formate, ammonium molybdate, zinc citrate, barium acetate, copper cyanide, carbonic acid drill , gasified uranium, hydrogen tetrachloroaurate, titanium tetrabutoxide, zirconium dimethoxide, aluminum isopropoxide, tin tetrafluoroborate, methanol hydrazine, dodecylmercaptoaurate ), indoleacetone or its derivatives. 1326297 Preferably, the metal or metal compound represented by Chemical Formula 1 is silver (Ag) or

a silver compound, wherein n is an integer from 1 to 4 and X is selected from at least one of the group consisting of oxygen, sulfur, pixels, cyano, cyanate, carbonate, sulphate, sulphate, sulfate, phosphoric acid Root, thiocyanate, oleate, peroxylate, tetrafluoroborate, acetoacetate, carboxylate and derivatives thereof. Non-limiting examples of such silver compounds are silver oxide, silver thiocyanate, silver cyanide, silver cyanate, silver carbonate, silver sulphate, silver sulphate, silver sulphate, silver sulphate, silver sulphate, Silver PTFE, silver acetate, silver acetate, silver lactate, silver oxalate and its derivatives. The silver alloy may be formed from at least one metal selected from the group consisting of gold, copper, mud, Ming, Ji, Shi, Ti, Hung, Meng, Iron, Chromium, Wrong, Sharp, Molybdenum, Crane, Strontium, Mine, Group, Chain , iron, watch, Ming, marry, wrong, copper, tin, recorded 'wrong, money, broken, Kun, mining, Peng, pin, stove, town, #5, record and lock, but not limited to this. Non-limiting specific examples of &, R2, R3' R4, R5 and R6 in Chemical Formula 2 to Chemical Formula 4 are hydrogen, mercapto, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, Hexyl, ethylhexyl, heptyl, octyl, isooctyl, decyl, decyl, dodecyl, hexadecyl, octadecyl, docosa, cyclopropyl, cyclodecyl, cyclohexyl, Dilyl, hydroxy, methoxy, decyloxyethyl, methoxypropyl, cyanoethyl, ethoxy, butoxy, hexyloxy, methoxyethoxyethyl, formazan Ethoxyethoxyethyl, hexamethylene imine, chlorin, 0 bottom bit, 11 chen, ethylenediamine, propylenediamine, hexamethylenediamine, triethylenediamine, pyrrole , imidazole, pyridine, carboxymethyl, tridecyl propyl, triethoxy propyl, phenyl, methoxyphenyl, cyanophenyl, phenoxy, tolyl, benzyl, A derivative of the foregoing, such as polyallylamine and a polymeric compound of polyethyleneimine and its derivatives. 11 1326297

Specific examples of the compound represented by the chemical formula 2, which is based on ammonium urinate, are ammonium amide, ethyl ammonium ethinate, isopropyl ammonium isopropyl methoxide, n-butyl ammonium n-butyl carbamate, and isobutyl amide. Isobutylammonium decanoate, tert-butylammonium tert-butylcarbamate, 2-ethylhexylammonium 2-ethylhexylcarbamate, octaammonium octadecylcarboxylate, 2-methoxyethyl 2-methoxyethylammonium carbazate, 2-cyanoethylammonium 2-cyanoethylaminecarboxylate, dibutylammonium dibutylammonium decanoate, di-octadecyl ammonium bis-octadecylcarbamate Dioctadecylammonium dioctadecylcarbamate), methyl decyl ammonium decyl carbazate, hexamethylene imide hexamethylene imide, morpholinium ruthenium ruthenate, ethyl hexyl amide Salt pyridinium, isopropylamino decanoic acid triamethylene glycol, benzyl benzyl ammonium benzyl ammonium, triethoxy propyl propyl methic acid triethoxy propyl propyl ammonium. Specific examples of the ammonium carbonate-based compound represented by Chemical Formula 3 are ammonium carbonate, ethyl ammonium ethyl carbonate, isopropyl ammonium isopropyl carbonate, n-butyl ammonium n-butyl carbonate, and isobutyl carbonate. Butyl ammonium, tert-butylammonium carbonate, 2-ethylhexyl ammonium 2-ethylhexyl carbonate, 2-methoxyethyl ammonium 2-methoxyethyl carbonate, 2-cyanoethyl 2-cyanoethylammonium carbonate, octadecyl ammonium octadecyl carbonate, dibutyl butyl carbonate, dioctadecylammonium dioctadecylcarbonate, methyl hydroxymethyl carbonate Mercaptoammonium, hexamethyleneimine carbonate hexamethyleneimine ammonium, morpholine carbonate morpholinium, benzyl benzyl ammonium carbonate, triethoxy propyl propyl carbonate Ammonium, isopropyl carbonate, triethylene glycol diammonium, and the like. Specific examples of the carbonate-based compound represented by Chemical Formula 4 are ammonium hydrogencarbonate, isopropylammonium hydrogencarbonate, tert-butylammonium hydrogencarbonate, 2-ethylhexylammonium hydrogencarbonate, hydrogencarbonate 2-A Oxyethylammonium, hydrogencarbonate 2-disethyl, dioctadecylammonium 12 1326297 bicarbonate, hydrogen pyridinium bicarbonate, triamethylenediamine hydrogencarbonate and derivatives thereof. The compound to be used as the base represented by the chemical formula 2 to the chemical formula 4, which is represented by ammonium amide or carbonic acid, is not particularly limited. For example, U.S. Patent No. 4,542,214 (September 17, 1985), "/· Jw. Soc., 123, p. 10393 f

(2001) 'Ια«尽 m«z>, 18, p. 71247 (2002), which can be prepared from a primary amine, a secondary amine, a tertiary amine or a mixture thereof and carbon dioxide. Compound. If 〇5 moles of water is used per 1 mole of amine, a compound based on ammonium amide ammonium amide can be obtained; if 1 mole or more of water per 1 mole of amine is used, one can be obtained. Ammonium bicarbonate is a matrix compound. The preparation can be carried out under normal atmospheric pressure or under pressure in the absence of a solvent or in the presence of an alcohol such as methanol, ethanol, isopropanol or butanol; an ethylene glycol such as ethylene glycol or Glycerin; acetates such as ethyl acetate, butyl acetate or carbitol acetate; terpenoids such as diethyl sulfonate, tetrahydrogen oxime or dioxane; Terpenoids, such as methyl ethyl net or C-; genus, such as hexane or heptane; aromatic solvents, such as benzene and toluene; and dentate-substituted solvents, such as dichlorocarbyl, a milk And carbon tetrachloride. Carbon dioxide f is foamed in the gas phase or used in the form of dry ice. Alternatively, the preparation can be carried out in a supercritical state τ. In the present invention, the ammonium amide derivative and the ammonium carbonate-based derivative may be prepared by any other known method as long as the final oxime is the same. In other words, the solvent, reaction temperature, concentration, catalyst and the like of the preparation are not particularly limited. The preparation yield is also not particularly limited. A composite ammonium compound obtained by reacting an amine compound with a triatomic molecule can be used together with carbon dioxide. For example, an adduct can be used with the ammonium compound of the invention 13 1326297, which can be obtained by combining an amine compound (such as propylamine, decylamine and octadecylamine) with nitrogen dioxide. Obtained by the reaction of sulfur dioxide or carbon disulfide, please refer to La « Rong WM, >, 19, p, 1017 (2003) and 19, p. 8168 (2003). Alternatively, a compound of ammonium ammine or ammonium carbonate can be directly prepared by using a triatomic molecule and carbon dioxide during the reaction with the amine. In addition, 'a compound obtained by reacting an amine compound with a boron compound (for example, boric acid and boron acid) may be used, and for example, an ammonium sulfamate may be used. Ammonium compounds, sulfuric acid, hydrogen sulfate, sulfurous acid and mixtures thereof. A compound based on ammonium amide or ammonium carbonate is reacted with a metal or a metal compound to prepare a metal complex compound. For example, at least one metal or metal compound represented by Chemical Formula 1 and at least one compound represented by Chemical Formula 2, Chemical Formula 3 or Chemical Formula 4, which are based on ammonium amide or ammonium carbonate, are under a nitrogen atmosphere. The reaction is carried out under normal atmospheric pressure or under pressure in the absence of a solvent or in the presence of the following solvents: water; alcohols such as methanol, ethyl yeast, isopropanol and butanol; glycols such as ethylene glycol And glycerol; acetates such as ethyl acetate, butyl acetate and diethylene glycol diethyl ether acetate; ethers such as diethyl ether, tetrahydrofuran and dioxane; ketones such as mercaptoethyl ketone and Acetone; hydrocarbons such as hexane and heptane; aromatic solvents such as benzene and toluene; solvents substituted with dentate, such as trimethyl, methylene chloride and tetra-carbonated carbon; or a mixture of the foregoing. Alternatively, a metal complex compound can be obtained by preparing a solution containing a metal or a metal compound represented by Chemical Formula 1 and a small amine compound to react with carbon dioxide. This reaction can also be carried out under normal pressure or under pressure in the absence of solvent or in the presence of 1326297 solvent. However, the preparation method of the metal complex compound is not particularly limited and any known method can be applied as long as the final structure is the same. In other words, the solvent, the reaction temperature, the concentration, the catalyst, and the like are not particularly limited. There are no special restrictions on the production yield.

The conductive ink composition of the present invention comprises the metal complex compound and an additive. The additive contained in the ink composition of the present invention may be a known compound: a conductor, a metal precursor, an oxidizing agent, a stabilizer, a solvent, a dispersing agent, an adhesive resin, a reducing agent, a surfactant, a wetting agent, a thixotropic Thixotropic agent and leveling agent. The additives are not particularly limited and any known additives may be used within the scope of the object of the present invention. When the additive is used in the present invention, the kind, size or shape of the conductor or the metal precursor is not particularly limited. For the conductor, at least one metal selected from the group consisting of transition metals such as silver, gold, copper, zinc, recorded 'Ming', Shi, Titanium, Tantalum, Meng, Iron, Chromium, Wrong, Sharp , 钿, crane, 钌, tin, group, 铢, iron and 铱; metals, such as Shao, gallium, Xu, indium, tin, recorded, ship and Syria; mineral elements, such as Peng and 铕; fishing elements, such as Jing and 鈇; the aforementioned alloy or the aforementioned alloy oxide. Further, conductive carbon black, graphite, carbon nanotubes, and conductive polymers such as polyacetylene, polypyrrole, polyaniline, polythiophene, and derivatives thereof can also be used. There are also no special restrictions on the metal precursor. In other words, any metal precursor can be used within the scope of the object of the present invention, and conductivity is preferably imparted by heat treatment, oxidation or reduction treatment, IR, UV, electron beam or laser treatment. For example, the metal precursor may be an organometallic compound or a metal salt and is generally represented by Chemical Formula 1, wherein the lanthanide is at least one metal selected from the group consisting of silver, gold, copper, rhodium, nickel, cobalt, 15 1326297 Syria, Ming, Qin, hunger, manganese, iron, chrome, Ming 'sharp, turn, crane, sputum, tin, group, chain, iron, silver, is, gallium, germanium, indium, tin, recorded, wrong, silk , 衫, 铕, 钍 and 钍 or an alloy of the foregoing; η is an integer from 1 to 10; and X is at least one substituent selected from the group consisting of hydrogen, ammonium, oxygen, sulfur, halogen, cyano, cyanate, carbonic acid Root, nitrate, nitrite, sulfate, phosphate, thiocyanate, oleate, perchlorate, tetrafluoroborate, acetoacetate, sulfhydryl, decylamine, alkoxide, carboxylate and their derivatives Things. More precisely, at least one of the following may be used: metal carboxylates such as gold acetate, silver acetate, palladium oxalate, silver 2-ethylhexanoate, copper 2-ethylhexanoate, iron stearate, formic acid Nickel and zinc citrate; metal compounds such as silver silicate, copper cyanide, carbonic acid drill, vaporized platinum, tetrachloroauric acid, titanium tetrabutoxide, dimethoxyzirconium dimethoxide, aluminum isopropoxide, Tin tetrafluoroborate, vanadium oxide, indium tin oxide, bismuth decoxide, cesium acetate, dodecyl hydrazine, and indium acetonate. The conductor or metal precursor can be spherical, linear or planar or a combination thereof. They may be in the form of granules (including nanoparticles), powders, flakes, gels, hybrids, pastes, sols, solutions or combinations thereof. The size or content of the conductor or the metal precursor is not particularly limited as long as they do not adversely affect the characteristics of the ink. Preferably, the conductor or metal precursor has a size of 50 μm or less, more preferably between 1 nm and 25 μm in consideration of the film thickness after calcination. They are preferably not used in excess so that the calcination temperature does not rise excessively or does not adversely affect the coating or pattern formation. In general, they are used in an amount of from 1% by weight to 90% by weight, preferably from 10% by weight to 70% by weight, per 100% by weight of the ink composition. 16 1326297 In the preparation of metal complex compounds, an oxidizing agent can be used as an additive. The oxidizing agent may be an oxidizing gas such as air, oxygen and ozone; a peroxide such as hydrogen peroxide (H202), Na202, K02, NaB03, K2S208, (Nh4)2s2〇8, Na2S208, H2S05, KHS05, ( CH3)3c〇2H and (6) postal; peroxyacid, • such as HC03H, CH3C03H, CF3C03H, C6H5C03H, m-ClC6H5C03H; a commonly known oxidized inorganic acid such as nitric acid, sulfuric acid, FeCl3,

Fe2(S04)3, K3Fe(CN)6, (NH4)2Fe(S04)2, Ce(NH4)4(S04)4, NaI〇4, • KM11O4 and KfrO4; - metal or non-metal compound. The oxidizing agents may be used singly or in combination. Heating, cooling, electrolysis, ultrasonic, microwave treatment, high frequency treatment, plasma treatment, iR treatment*uv treatment can be performed during the preparation period. For example, the stabilizer may comprise at least one amine compound, such as a primary amine 'secondary amine and a tertiary amine; a compound based on the ammonium ammonium carbamate, ammonium carbonate or ammonium hydrogencarbonate; a phosphorus compound such as a phosphine and Phosphite; or sulfur compounds such as mercaptans and sulfides. Specifically, the amine compound may be methylamine, ethylamine, n-propylamine, isopropylamine, n-butylamine, isobutylammonium, isoamylamine, n-hexylamine, 2-ethylhexylamine, n-heptylamine, • n-octylamine. , isooctylamine, decylamine, decylamine, dodecylamine, hexadecylamine, octadecylamine, dodecaamine, cyclopropylamine, cyclopentylamine, cyclohexylamine, allylamine, hydroxylamine, ammonium hydroxide, hydrazine Oxyamine, 2-ethanolamine 'methoxyethylamine, 2-hydroxypropylamine, decyloxypropylamine, cyanoethylamine, ethoxyamine 'n-butoxyamine, 2-hexyloxyamine, decyloxyethoxy B Amine, methoxyethoxyethoxyethylamine, diethylamine, dipropylamine, diethanolamine, hexamethyleneimine, morpholine, piperidine, piperazine, ethylenediamine, propylenediamine, hexane Amine, triamethylenediamine, 2,2-(ethylenedioxy)diethylamine, triethylamine, triethanolamine, pyrrole, imidazole, pyridine, aminoethane acetal (amm〇acetaldehyde di〇lethyl acetal) ), 3_Aminopropyl 17 1326297

Dimethoxy decane, 3-aminopropyl triethoxy decane, aniline, methoxyaniline, aminobenzonitrile, benzylamine, derivatives of the foregoing or, for example, polyallylamine and polyethyleneimine or a polymer compound of its derivatives. A specific example of the ammonium compound is a compound based on amino formic acid, such as ammonium urethane, ethyl ammonium ethane hydride, propyl ammonium isopropyl methoxide, n-butyl ammonium butyl butyl hydride Isobutylammonium formate, tert-butylammonium tert-butylcarbamate, 2-ethylhexylammonium 2-ethylhexylamine decanoate, octaammonium octadecylcarboxylate, 2-methoxyethylamine 2-methoxyethylammonium citrate, 2-cyanoethylammonium 2-cyanoethylaminocarbamate, dibutylammonium dibutylammonium decanoate, di-octadecylamine formic acid-dioctadecylammonium Dioctadecylcarbamate ), methyl mercaptomethyl carbamate, hexamethyleneimine hexamethylene imide, morpholinium morpholine, pyridinium ethylhexylaminocarbamate , isopropylammonium methacrylate, benzyl ammonium benzyl carbazate, triethoxy propyl propyl ammonium triethoxy propyl propyl methacrylate or the foregoing derivatives; Ammonium-based compound 'eg ammonium carbonate, ethyl ammonium ethyl carbonate, isopropyl ammonium isopropyl carbonate, n-butyl ammonium n-butyl carbonate, isobutyl carbon Isobutylammonium, tert-butylammonium carbonate, 2-ethylhexylammonium 2-ethylhexyl carbonate, 2-methoxyethylammonium 2-methoxyethyl carbonate, 2-cyanoethyl 2-cyanoethylammonium carbonate, octadecyl carbonate 18-base, dibutylammonium dibutylammonium carbonate, dioctadecylammonium dioctadecylcarbonate, methyl thiol acid Methyl decyl ammonium, hexamethyleneimine carbonate hexamethyleneimine, morpholine carbonate, benzyl benzyl ammonium carbonate, triethoxy propyl propyl triethoxy oxalate Kesu, isopropyl sulphate, S-Shen Di-B--- and derivatives as described below, and compounds recorded with hydrogencarbonate as 'substrate, such as ammonium bicarbonate, isopropylammonium hydrogencarbonate, dibutyl bromide , 1326297 2-ethylhexylammonium hydrogencarbonate, 2-methoxyethylammonium hydrogencarbonate, 2-cyanoethyl hydrogencarbonate, dioctadecylammonium bicarbonate, pyridinium bicarbonate, carbonic acid Hydrogen triethylene diammonium and the aforementioned derivatives. The phosphorus compound may be represented by the formula R3P or (ROhP, wherein R is C^-Cso alkyl or aryl. Typical examples of such phosphorus compounds are tributylphosphine, triphenylphosphine, triethylphosphine and phosphorous triphosphate Phenyl ester. In addition, the sulfur compound may be butyl mercaptan, n-hexyl mercaptan, diethyl dilute, four

Hydrothiophene and the like. The content of the stabilizer is not limited as long as it does not adversely affect the characteristics of the ink. However, its content is preferably from 0.1% to 90%, more preferably 1% per 100% of the metal or metal compound. Up to 50%, optimally 5% to 30%, in molar ratio. Outside this range, the conductivity of the film may be reduced and storage stability may be degraded. A decrease in storage stability may cause problems in the quality of the film. Further, if the content of the stabilizer is outside the foregoing range, the film obtained by coating the ink composition and calcining may be uneven or inaccurate and may There will be a break. A solvent may be required to control the viscosity of the ink or to promote film formation. For this purpose, water can be used; alcohols such as methanol, ethanol, isopropanol, decyloxypropanol, butanol, ethylhexanol and terpineol; glycols such as ethylene glycol and glycerol Acetate, such as ethyl acetate, butyl acetate, methoxyacetic acid acetate, diethylene glycol ethyl ether acetate, ethyl diethylene glycol ethyl ether acetate; ether, such as methyl fibrin (methylcellosolve), butyl cellosolve, diethyl ether, tetrahydrofuran and dioxane; ketones such as methyl ethyl ketone, propyl dimethyl ketone and 1-methyl-2- °Billow; smog, such as hexagram, gargane, dodecane, paraffin oil and mineral spirit; aromatic solvents such as benzene, toluene and xylene; replaced by halogen Solvents such as trimethyl ketone, digas 1326297 decane and carbon tetrachloride; acetonitrile; dimethyl sulfoxide; or a mixture of the foregoing. Dispersants are used to effectively disperse the conductors in the form of granules or flakes. To achieve this, use EFKA's 4000 series, BYK's Disperbyk series, Avecia's Solsperse series, Degussa's TEGO Dispers series, Elementis' Disperse-AYD series, and Johnson Polymer's JONCRYL series. The adhesive resin may be at least one of: an acrylic resin such as polyacrylic acid and polyacrylic acid vinegar, a cellulose resin such as ethyl cellulose, cellulose vinegar, and nitric acid

Cellulose; aliphatic or copolymer polyester resin; vinyl resin, such as polyvinyl butyral, polyvinyl acetate and polyvinylpyrrolidone; polyamine tree Jia't amine Sa stalk Resin, gland resin; alkyd resin; polyoxyn resin; fluorinated resin; olefin resin, such as polyethylene or polystyrene; thermoplastic resin, such as petroleum and rosin; epoxy resin; unsaturated or vinyl Polyester resin, diallylphthalate resin; discrete resin; oxetane resin; oxazine resin; bismaleimide resin Modified polyoxynene resin, such as polyoxyn epoxide or polyoxyethylene polyester; thermosetting resin such as melamine; uv or electron beam hardened acrylic resin; ethylene-propylene rubber (EPR); styrene _ Butadiene rubber (SBR); or natural polymers such as starch and gelatin. In addition to these organic binders, inorganic binders such as glass resins or glass frit; decane coupling agents such as trimethoxypropyl decane and vinyl triethylene ketone can be used. Or a coupling agent based on titanium, zirconium or imprint. The surfactant may be an anionic surfactant such as sodium lauryl sulfate; a non-anionic surfactant such as nonylphenoxy 20 1326297 polyethoxyethanol or DuPont fsn; cationic interfacial activity Agents such as gasified dodecyl ammonium; or amphoteric surfactants such as guanaurylbetaine and coco betaine 〇 wetting agent or lake wet dispersing agent can be polyethylene Alcohol, Air pr〇duct's Surfynol series or Degussa's TEGO Wet series. In addition, the thixotropic agent or leveling agent can be BYK's BYK series, Degussa's Glide series, EFKA's EFKA 3000 series, and Cognis' DSX series.

A reducing agent may be added to promote calcination. For example, hydrazine; acetic hydrazide; sodium borohydride or potassium borohydride; trisodium citrate; amine compounds such as decyldiethanolamine and dinonylamine borane; metal salts, for example, may be used. Ferrous chloride and ferric sulfate; hydrogen; hydrogen halide; carbon monoxide; road compounds such as citric acid and acetaldehyde; organic compounds such as glucose, ascorbic acid, salicylic acid, tannic acid, pyrogallol and Hydroquinone and the like. Alternatively, the conductive ink composition of the present invention can be obtained by preparing a metal or metal compound represented by Chemical Formula 1 and an excess of an amine compound, recording with an aminocarboxylic acid or carbonic acid. a mixture solution of at least one of the compounds of the matrix; if necessary, a conductor, a metal precursor, a dispersant, an adhesive or an additive; and then reacting the solution with carbon dioxide. The reaction can be carried out under normal pressure or under pressure in the absence of a solvent or in the presence of a solvent. The metal complex compound of the present invention can be represented by the following Chemical Formula 5: MAm (5) A is a compound represented by Chemical Formula 2 to Chemical Formula 4, and 〇.5^nS5.5. The ink composition prepared according to the present invention has excellent stability, and thus various substrates of 21 1326297 can be used and a film or pattern can be easily formed by coating or printing. For example, it can be applied or printed directly onto the following substrates: metal, glass, germanium wafers, ceramics, plastic films such as polyester or polyimide, rubber sheets, fibers, wood and paper. The substrate can be used after washing with water, fat removal or after special pretreatment. The pretreatment method includes electric paddle, ion beam or corona treatment, oxidation or reduction, heating, etching, uv treatment, primer treatment using the above-mentioned adhesive or additive, and the like. Considering the physical properties of the ink 'can be applied by spin coating, roller coating, spray coating, dip coating, leaching coating, blade coating, dispensing, inkjet printing, lithography, Screen printing, transfer printing, flexographic printing, offset printing, stenciling, brushing, stamping, xerographic, lithography, etc. for film preparation or printing. The viscosity of the ink of the present invention is not particularly limited as long as it does not adversely affect the formation or printing of the film. The viscosity is changed depending on the preparation method and the particular type of ink. The viscosity is preferably from 0.1 cps to 1, 〇〇〇, 〇〇〇 centipoise and more preferably from 1 cps to 500,000 PCT. Parking. When the formation of a film or pattern is accomplished by ink jet printing, the viscosity of the ink becomes an important factor. In this case, it is advantageous that the viscosity is from 0.1 cps to 50 cps, preferably from 1 cps to 20 cps, more preferably from 2 cps to 15 φ centipoise. If the viscosity is too small, the conductivity may be insufficient due to insufficient film thickness. Conversely, 'right viscosity is too large' ink may not flow easily. For the formation of a metal or metal oxide pattern, the film or pattern thus obtained can be post-treated by oxidation or reduction, heat treatment, IR, UV, electron beam or laser. Depending on the requirements, the heat treatment can be carried out under an inert gas atmosphere, or with air, nitrogen or carbon monoxide, or a mixture containing hydrogen and air or other 'inert gas. In order to obtain better physical properties of the film, the heat treatment is usually carried out at 8 ° C to 22 500 cc. - For 犋: 仃 is preferably 9 〇 < 3C to 3 〇〇 ° C, more preferably 100 °C to 25〇〇C.

To 15 baht. The uniformity of the sentence can be carried out at different temperatures. For example, it can be treated at 80 ° C i8 for 1 to 30 minutes, followed by 1 to 5 ° C to 3 〇 0. (The lower treatment is carried out for 77 to 30 minutes to carry out the heat treatment. The present invention can provide a plurality of conductive ink compositions comprising - a metal complex compound I - by at least - a metal or a metal compound represented by Chemical Formula 1 It is obtained by reacting a compound represented by the formula 3 or the chemical formula 4 with an aminocarboxylic acid or ammonium carbonate as a matrix and an additive. The ink set of the present invention has excellent stability and solubility, and can be easily formed into a film. Even at temperatures below 2 GG ° C or below, it is easy to calcination to form a film or pattern with good electrical conductivity. The ink composition of the present invention can be coated or directly printed on a variety of substrates - including metal, glass, Dream wafers, shouting, plastic films such as (iv) or polyamido, rubber sheets, fibers, wood and paper. Depending on the physical properties of the ink, a variety of film formation or printing methods can be applied, such as spin coating, Roller coating, spray coating, dip coating, leaching coating, knife coating, dispensing, inkjet printing, lithography, screen printing, transfer printing, flexographic printing, offset printing, engraving Printing, stamping, xerographic printing, lithography, etc. The use of the ink composition of the present invention can form a uniform film having excellent electrical conductivity and adhesion. Further, the film is not easily broken. Further, the ink composition of the present invention can be used. EMI shielding materials, conductive adhesives, low-resistance metal wires, PCBs, FPCs, RFID tag antennas, pdps, TFT-LCDS, OLEDs, softness and OTFTs, 1% energy battery, secondary battery or fuel The invention will be further described in detail below with the aid of the embodiments. However, it should be understood that those skilled in the art of the present invention may be in the spirit of the invention after considering the disclosure. Modifications and improvements are made within the scope and scope.

In a 50 ml Schlenk flask equipped with a stirrer, 9.52 g (31.48 mmol) of 2-ethylhexylaminocarbamate 2-ethylhexylammonium (a viscous liquid) was dissolved in a solution containing 10.00 ml of methanol and 3.00 ml of a mixed solution of an aqueous solution. Next, 1.00 g (15.74 mmol) of copper powder (Aldrich, particle size = 1 μm to 5 μm) was added and reacted for 30 minutes under oxygen foaming at room temperature. When the reaction proceeded, the reaction mixture became a dark brown paste. And finally turned into a blue, clear solution. The solvent was removed from the reaction solution in vacuo to obtain 7.15 g of a blue copper complex compound. The copper content was confirmed to be 11.28% by weight by thermogravimetric analysis (TGA). 5.00 g of copper flakes (TSC-20F ' Chang Sung), 0.20 g of polyvinyl condensate dissolved in 1.80 g of butylcarbitol were added to the 3.00 g copper complex compound. BS-18, Wacker) · (an adhesive). After 10 minutes of scramble, the mixture was transferred to a three-roll mil drais Mannheim five times to obtain a conductive ink composition having a viscosity of 72,600 centipoise. The metal content was confirmed by thermogravimetric analysis to be 53.33 wt% (refer to Fig. 1). The ink composition was applied to a PET film using a 325 mesh patterned screen printer under a nitrogen atmosphere to obtain a uniform and precise film 'calcined at the temperature of Table 1 to Obtain the pattern of Figure 2. The conductivity (planar resistivity) and adhesion of the film are shown in Table 1 of 24 1326297. Example 2

In a 50 ml Schlenk flask equipped with a stirrer, 6.99 g (3 1.48 mmol) of 3-methoxypropylammonium 3-methoxypropylammonium (a viscous liquid) was dissolved in one. A 2.00 g mixed solution containing 5.00 ml of sterol and 50% by weight of an aqueous hydrogen peroxide (H 2 〇 2) solution. Next, 1.00 g (15.74 mmol) of metallic copper was added and reacted at room temperature for 2 hours. As the reaction proceeded, the reaction mixture turned into a dark brown slurry and eventually turned into a blue, clear solution. The solvent was removed from the reaction solution in vacuo to obtain 5.58 g of a blue copper complex compound. The copper content was confirmed by thermogravimetric analysis (TGA) to be 16.26% by weight. 1.00 g of the copper complex compound was dissolved by adding 1.00 g of sterol. Next, by using a 1:1 (mole ratio) of 2-ethylhexylamino phthalic acid 2-ethylhexyl ammonium and 2-methoxyethyl carbamic acid 2-methoxyethyl ammonium The mixture was reacted with silver oxide (silver content = 22.00% by weight) to obtain 8.00 g of the complex compound to obtain a clear ink composition having a viscosity of 50.7 centipoise. The ink composition was applied under a nitrogen atmosphere to obtain a uniform and precise film, and the film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 3 In a 50 ml Schlenk flask equipped with a stirrer, 7.53 g (41.88 mmol) of isopropylammonium isopropyl amide was dissolved in a solution containing 20.00 ml of methanol and 50% by weight. 1.89 g of a mixed solution of an aqueous hydrogen peroxide (H202) solution. Next, 1.00 g (6.98 mmol) of copper (I) oxide was added and reacted at room temperature for 2 hours. As the reaction proceeded, the reaction mixture turned into a dark brown slurry and eventually became 25 1326297

A blue, transparent solution. The solvent was removed from the reaction solution in vacuo to obtain 6.28 g of a blue copper complex compound. The copper content was confirmed by thermogravimetric analysis (TGA) to be 14.17% by weight. 3.00 g of the copper complex compound was added to 2.80 g of a transparent butyl-solvent containing 4.00 g of silver flakes (EA0295, Chemet) and 0.20 g of polyvinyl butyral (Wacker) (-adhesive). After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain a conductive ink composition having a viscosity of 350.4 centipoise. The ink composition was applied under a nitrogen atmosphere to obtain a uniform and precise film, and the film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 4 In a 50 ml Schlenk flask equipped with a stirrer, 6.79 g (41.88 mmol) of isopropylammonium isopropylcarbamate was dissolved in a solution containing 20.00 ml of methanol and 50% by weight. 1.89 g of the mixed solution of the aqueous hydrogen peroxide solution. Next, 1.00 g (6.98 mmol) of copper (I) oxide was added and reacted at room temperature for 2 hours. As the reaction proceeded, the reaction mixture turned into a dark brown slurry and eventually turned into a blue, clear solution. The solvent was removed from the reaction solution in vacuo to obtain 6.35 g of a blue copper complex compound. The copper content was confirmed to be 14.61% by weight by thermogravimetric analysis (TGA). 2.00 g of the copper complex compound was added to a solution in which 1.00 g of methanol and 1.00 g of 2-ethylhexylamine were dissolved in 6.00 g of silver acetate. After stirring for 10 minutes, a clear ink composition having a viscosity of 26.7 centipoise was obtained. The ink composition was applied under a nitrogen atmosphere to obtain a uniform and precise film, and the film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. 26 1326297 Example 5 In a 50 ml Sch丨enk flask equipped with a stirrer, u% g (38.22 mmol) of 2-ethylhexylaminocarbamic acid 2-ethylhexyl (__ viscous liquid) • Dissolved in 5 ml of acetonitrile and lo.oo in methanol. Next, i 00 g (1529 " millimolar) powder (Aldrich, particle size = ι mesh or smaller) was added and reacted at room temperature for 10 hours. As the reaction proceeded, the reaction mixture turned into a grayish purple material and eventually turned into a colorless, clear solution. The solvent was removed from the reaction solution in vacuo to give a solution of 1.87 g of a white compound. The content of the confirmed content by thermogravimetric analysis (TGA) was 14.78% by weight. Add 2 g of zinc complex compound to 2.80 g of clear methyl fibrin, which is dissolved in 5 g of silver flakes (cheme〇 and 0.20 g of polyvinyl butyral (Wacker) (-adhesive) β After stirring for 1 minute, the solution was transferred to a three-roll mill for five times to obtain a conductive ink composition having a viscosity of i 26 G centipoise. The ink composition was applied under a nitrogen atmosphere to obtain a uniformity. And the film of the fine ball was fired at the temperature of Table i. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. % Example 6 - equipped with - agitator In a 50 ml Schlenk flask, 6 63 g (36 84 mmol) of isopropyl ammonium isopropyl carbonate was dissolved in 7 (9) ml of a 14% by weight aqueous solution, followed by 'addition 〖. (9) g (12 28 mM zinc oxide (π) and reacted at room temperature for 2 hours. As the reaction proceeds, the reaction mixture becomes a white slurry and eventually becomes a colorless, transparent solution. The solvent is added to the reaction solution in vacuo. Removed to obtain 5,52 grams of white zinc complex compound. Thermogravimetric analysis (TGA) The zinc content is 15.2 Gg %. L (8) g of zinc complex compound 27 1326297 is added to a solution by reacting isopropyl ammonium isopropyl carbonate with silver oxide (silver content = 36.45% by weight) The obtained 7.00 g of the silver complex compound was dissolved in 2.00 g of methanol. After stirring for 10 minutes, a clear ink composition having a viscosity of 27.4 cps was obtained. The ink composition was applied under a nitrogen atmosphere to obtain To a uniform and precise film, the film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 7

In a 50 ml Schlenk flask equipped with a stirrer, 1.00 g (7·71 mmol) of hydrated nickel chloride (11)-6 was dissolved in a 5.00 ml aqueous solution. Next, a solution was added in which 5.83 g (19.27 mmol) of 2-ethylhexylamine decanoic acid 2-ethylhexyl ammonium (a viscous liquid) was dissolved in 10.00 ml of benzene and reacted at room temperature. The solution was vigorously and vigorously stirred for 2 hours during the reaction. As the reaction proceeded, the reaction mixture turned into a green slurry and eventually turned white. The colorless, transparent aqueous phase is separated from the green, transparent organic phase. The solvent was removed from the organic phase in vacuo to give 4.73 g of emerald green nickel complex compound. The nickel content was confirmed to be 14.51% by weight by thermogravimetric analysis (TGA). 1.00 g of the nickel complex compound was added to a solution obtained by reacting 2-ethylhexyl ammonium 2-ethylhexyl ammonium with silver oxide (silver content = 22.00% by weight). The gram silver complex compound was dissolved in 3.00 g of sterol. After stirring for 10 minutes, a clear ink composition having a viscosity of 127.2 centipoise was obtained. The ink composition was applied under a nitrogen atmosphere to obtain a uniform and precise film, and the film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 8 28 1326297

In a 50 ml Schlenk flask equipped with a stirrer, 1.00 g (7.70 mmol) of hydrated cobalt (ruthenium)-6 was dissolved in a 5.00 ml aqueous solution. Next, a solution was added in which 5.82 g (19.25 mmol) of 2-ethylhexylaminocarbamate 2-ethylhexylammonium (a viscous liquid) was dissolved in 10.00 ml of toluene and reacted at room temperature for 2 hours. The solution was vigorously stirred during the reaction. As the reaction proceeded, the reaction mixture turned into a red slurry and eventually turned purple. The colorless, transparent aqueous phase is separated from the purple, transparent organic phase. The solvent was removed from the organic phase in vacuo to give 5.36 g of a purple cobalt complex compound. The cobalt content was confirmed by thermogravimetric analysis (TGA) to be 14.51% by weight. 1.00 g of the cobalt complex compound was added to a solution obtained by reacting 2-ethylhexyl ammonium 2-ethylhexyl ammonium with silver oxide (silver content = 22.00% by weight). The gram silver complex compound was dissolved in 3.00 g of sterol. After stirring for 10 minutes, a clear ink composition having a viscosity of 347.2 centipoise was obtained. The ink composition was applied under a nitrogen atmosphere to obtain a uniform and precise film, and the film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 9 In a 50 ml Schlenk flask equipped with a stirrer, 2.62 g (16.18 mmol) of isopropylammonium isopropylcarbamate was dissolved in 5.00 ml of methanol. Next, 1.00 g (0.81 mmol) of hydrated ammonium molybdate (VI)-4 ((NH4)6Mo7 0 24-4 H20) was added and reacted at room temperature for 10 hours. As the reaction proceeded, the reaction mixture turned into a green paste and eventually turned into a colorless, clear solution. The solvent was removed from the reaction solution in vacuo to obtain 3.02 g of a white molybdenum compound. The molybdenum content was confirmed to be 16 to 62% by weight by thermogravimetric analysis (TGA). 2.00 g of a molybdenum complex 29 1326297 was added to 2.80 g of a transparent butyl cellosolve solution, which was dissolved in 5.00 g of silver flakes and 0.20 g of polyvinyl butyral (an adhesive). After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain a conductive ink composition having a viscosity of 940.8 cps. The ink composition was applied under a nitrogen atmosphere to obtain a uniform and precise film, and the film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 10

In a 50 ml Schlenk flask equipped with a stirrer, 8.92 g (55.5 mmol) of isopropylammonium isopropylcarbamate was dissolved in 5.00 ml of methanol. Next, 1.00 g (5.50 mmol) of vanadium oxide (V) was added and reacted at room temperature for 10 hours. As the reaction proceeded, the reaction mixture turned into a yellow slurry and eventually turned into a colorless, clear solution. The solvent was removed from the reaction solution in vacuo to obtain 9.35 g of a white vanadium complex compound. The vanadium content was confirmed by thermogravimetric analysis (TGA) to be 12.37% by weight. 2.00 g of the vanadium complex compound was added to 2.80 g of a transparent butyl-solvent, which was dissolved in 5.00 g of silver flakes and 0.20 g of polyvinyl butyral (an adhesive). After stirring for 1 minute, the solution was transferred to a three-roll mill for five times to obtain a conductive ink composition having a viscosity of 1,540 ° centipoise. The ink composition was applied under a nitrogen atmosphere to obtain a uniform and precise film, and the film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 11 In a 50 ml Schlenk flask equipped with a stirrer, 7.65 g (25.31 mmol) of ethylhexylamine decanoic acid ethylhexylammonium (a viscous liquid) was dissolved in 5.00 ml of acetic acid. In the ester. Next, add 1.00 g (2.53 mmol) of cerium (III) nitrate 30 1326297

And reacted at room temperature for 2 hours. As the reaction proceeded, the reaction mixture turned into a white slurry and eventually turned into a colorless, clear solution. The solvent was removed from the reaction solution in vacuo to obtain 5.16 g of a white silk compound. The cerium content was confirmed to be 11.35 wt% by thermogravimetric analysis (TGA). 2.00 g of the ruthenium complex compound was added to 2.80 g of a transparent butyl-solvent containing 5.00 g of silver flakes and 0.20 of polyvinyl butyral (an adhesive). After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain a conductive ink composition having a viscosity of 1,620 cps. The ink composition was applied under a nitrogen atmosphere to obtain a uniform and precise film, and the film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 12 In a 50 ml Schlenk flask equipped with a stirrer, 1.00 g (5.64 mmol) of palladium(II) chloride was dissolved in a 5.00 ml aqueous solution. Next, a solution was added in which 1.71 g (16.92 mmol) of 2-ethylhexylamine decanoic acid 2-ethylhexyl ammonium (a viscous liquid) was dissolved in 5.00 ml of ethyl acetate at room temperature. The reaction was carried out for 2 hours at % and the solution was vigorously stirred during the reaction. As the reaction proceeded, the reaction mixture turned into a red paste and eventually became colorless. The colorless, transparent aqueous phase is separated from the colorless, transparent organic phase. The solvent was removed from the organic phase in vacuo to yield 2.22 g of a yellow, transparent palladium complex compound. The palladium content was confirmed to be 10.80% by weight by thermogravimetric analysis (TGA). 2.00 g of a palladium complex compound was added to 0.50 g of sterol. After stirring for 10 minutes, a clear ink composition having a viscosity of 25.6 centipoise was obtained. The ink composition was applied under a nitrogen atmosphere to obtain a uniform and precise film, and the film was calcined at the temperature of Table 1. The conductivity of the film 31 1326297 (planar resistance) and adhesion are shown in Table 1. Example 13

In a 50 ml Schlenk flask equipped with a stirrer, 2.00 obtained by reacting 2-ethylhexylamino phthalic acid 2-ethylhexyl ammonium with silver oxide (silver content = 22.00% by weight) The gram silver complex compound was dissolved in 10.00 ml of ethyl acetate. Next, a solution containing 1.71 g (16.92 mmol) of 2-ethylhexylammonium, 1.38 g (4.08 mmol) of hydrogen chloroaurate was added and reacted at room temperature for 1 hour and stirred during the reaction. Solution. As the reaction proceeded, a white precipitate formed and a yellow, clear solution was obtained. The solvent was removed from the supernatant in vacuo to give 3.56 g of a yellow gold compound. The gold content was confirmed by thermogravimetric analysis (TGA) to be 31.26% by weight. Adding 3.30 g of the gold complex compound to a solution which is obtained by reacting isopropylammonium isopropyl carbonate with silver oxide (silver content = 36.45% by weight) to obtain 2.70 g of silver The compound was dissolved in 2.50 g of methanol and 1.50 g of 2-ethylhexylamine. After stirring for 10 minutes, a clear ink composition having a viscosity of 97.4 centipoise was obtained. The ink composition was applied under a nitrogen atmosphere to obtain a uniform and precise film, and the film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film φ are shown in Table 1. Example 14 1.50 g of the 2-ethylhexylammonium palladium complex compound obtained in Example 12 was added to a solution by using ammonium 2-ethylhexylcarbamate and silver oxide (silver) Content = 22.00% by weight) 6.20 g of the silver complex compound obtained by the reaction was dissolved in 2.30 g of methanol. After stirring for 10 minutes, a clear ink composition having a viscosity of 83.2 centipoise was obtained. The ink composition was applied under a nitrogen atmosphere to obtain a uniform and precise film of 32 1326297, which was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 15

33.7 g (141.9 mmol) of 2-ethylhexylamino-2-ethylhexyl ammonium and 2-methoxyethylaminocarbamate 2-methoxyethylammonium (Mo Erbi = 4: The viscous liquid mixture of 6) was placed in a 250 ml Schlen flask equipped with a stirrer. Next, 10.0 g (43.1 mmol) of silver oxide was added, and the mixture was reacted at room temperature for 2 hours and the solution was stirred during the reaction. A black paste was initially obtained, but as the complex formed, the color gradually faded. Finally, 43.7 g of a liquid yellow, clear silver complex compound having a viscosity of 0.31 Pa·s was obtained. The silver content was confirmed by thermogravimetric analysis (TGA) to be 22.0% by weight. 40.9 g of the silver complex compound was added to 12.9 g of a transparent butyl diethylene glycol diethyl ether solution, which was dissolved in 41.2 g of silver flakes (EA0295, Chemet) and 5.0 g of polyacetone condensed (BS-18, Wacker). ) (-adhesive). After stirring for 10 minutes, the solution was transferred to a three-roll mill (Drais Mannheim) five times. As shown in Fig. 3, a conductive ink composition having a silver content of 50.2 wt./? and a viscosity of 3.94 Pa·s was obtained. The ink composition was applied to PET using a screen printer (see Figure 4). The resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 16 40.0 g of a silver complex compound prepared in the same manner as in Example 15 was used, and 41.2 g of silver powder (SNG-PSN-100-99, SONALOHYY, average particle size = 150 nm) was used instead of 41.2. A silver foil was prepared in the same manner as in Example 15 by the method of 33 1326297, an ink composition having a viscosity of 5.74 Pa.s. The ink composition was applied in the same manner as in Example 15 and the resulting uniform and precise film was calcined. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 17 Using the same method as in Example 15 except that 40.0 g of the silver complex compound obtained in the same manner as in Example 15 and 41.2 g of copper flakes (TSC_20F, chang Sung) were used instead of 41.2 g of the silver flakes. An ink composition having a viscosity of 14813 Pa·s was obtained. The ink composition was applied in the same manner as in Example 15 and the uniform and precise film of the article was calcined. The conductivity (planar resistance) and adhesion of the film are as shown in Table 1. Example 18 Using 40.0 g of the silver complex compound prepared in the same manner as in Example 15 and using 41.2 g of copper powder (Aldrich, average particle size = 3 μm) instead of 41.2 g of silver flakes, and Example 15 were used. In the same manner, an ink composition having a viscosity of 14 55 Pa.s. was obtained. The ink composition was applied in the same manner as in Example 15 and the resulting uniform and precise film was fired. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 19 Using a ruthenium complex compound prepared in the same manner as in Example 15 and using 41.2 g of nickel powder (Aldrich, average particle size = 3 μm) in place of 41 2 g of silver flakes ' with Example 15 In the same manner, an ink composition having a viscosity of u 74 Pascal was obtained. The ink composition was applied in the same manner as in Example 15 and the resulting uniform and precise film was calcined. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 20

40.0 g of the silver complex compound prepared in the same manner as in Example 15 and 41.2 g of a 30% by weight silver-coated copper powder (SNG-SN100-30, SOLNANOGY, average particle size = 100 奈) were used. In the same manner as in Example 15, an ink composition having a viscosity of 10.65 Pa·s was produced in place of 41.2 g of silver flakes. The ink composition was applied in the same manner as in Example 15 and the resulting uniform and precise film was calcined. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 21 40.0 g of a silver complex compound and 41.2 g of a silver flake prepared in the same manner as in Example 15 were added to a clear mixed solution in which 2.0 g of ethyl cellulose (Aldrich) was adhered. The agent is dissolved in 6.8 g of methyl fibrin and 5_0 g of benzoguanamine. After stirring for 10 minutes, 5.0 g of carbon powder (Vulcan-XC72, Cabot) was further added. After stirring for 5 minutes, the solution was transferred to a three-roll mill for seven times to obtain an ink composition having a viscosity of 3.75 Pa.s. The ink composition was applied in the same manner as in Example 15 and the resulting uniform and precise film was calcined. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 22 An ink composition having a viscosity of 2.64 Pa·s was obtained in the same manner as in Example 21 except that 5.0 g of graphite powder (CGF-t2N5, Alfaproducts) was used instead of 5 g of the powder. The ink composition was applied in the same manner as in Example 15 and the resulting uniform and precise film was calcined. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. 35 1326297 Example 23 An ink composition having a viscosity of 4.32 Pa·s was obtained in the same manner as in Example 21 except that 5.0 g of nickel powder (Aldrich, average particle size = 3 μm) was used instead of 5.0 g of carbon powder. The ink composition was applied in the same manner as in Example 15 and the resulting uniform and precise film was calcined. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 24

An ink composition having a viscosity of 4.54 Pa·s was obtained in the same manner as in Example 21 except that 5.0 g of copper powder (Aldrich, average particle size = 3 μm) was used instead of 5.0 g of the carbon powder. The ink composition was applied in the same manner as in Example 15 and the resulting uniform and precise film was calcined. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 25 1

40.0 g of a silver complex compound, 20.6 g of a silver flake (EA0295, Chenet) and 20.6 g of a silver powder (SNG-PSN-100-99, SOLNANOGY, average particle size = 2) obtained in the same manner as in Example 15 were added. 150 nm) to a clear mixed solution in which 3.0 g of polyvinyl butyral (BS-18, Wacker) (-adhesive) was dissolved in 15.8 g of butyl cellosolve. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 3.56 Pa·s. The ink composition was applied in the same manner as in Example 15 and the resulting uniform and precise film was calcined. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 26 36 1326297

40.0 g of silver complex compound, 20.6 g of steel flakes (TSC-20F, Chang Sung) and 20.6 g of copper powder (Aldrich 'average particle size = 3 μm) prepared in the same manner as in Example I5 were added to one. In the transparent mixed solution, 3.0 g of polyvinyl butyral (BS-18, Wacker) (-adhesive) was dissolved in 15.8 g of butyl cellosolve. After stirring for 1 minute, the solution was transferred to a three-roll mill five times to obtain an ink composition having a viscosity of 227.87 Pa.s. The ink composition was applied in the same manner as in Example 15 and the resulting uniform and precise film was calcined. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 27 40.0 g of a silver complex compound, 20.6 g of a silver flake (EA0295, Chemet) and 20.6 g of a steel flake (TSC-20F, Chang Sung) prepared in the same manner as in Example 15 were added to a transparent mixture. In the solution, 3.0 g of polyvinyl butyral (BS-18, Wacker) (-adhesive) was dissolved in 15.8 g of butyl cellosolve. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 4.15 Pa.s. The ink composition was applied in the same manner as in Example 15 and the resulting uniform and precise film was calcined. The conductivity (flat resistance) and adhesion of the film are shown in Table 1. Example 28 40.0 g of a silver complex compound, 41.2 g of a silver flake (EA0295, Chemet) prepared in the same manner as in Example 15 was added to a solution in which 1.2 g of diisopentaerythritol was used. Dipentaerythritol hexacrylate (-monomer), 3.5 g EB657 (UCB, molecular weight = 1500) (- oligomer), 0.1 g 819 (Ciba Specialty Chemicals) and 0.2 g 1173 (Ciba Specialty 37 1326297

Chemicals) (photoinitiator) and 0.5 g of Solsperse 20000 (Aercia) (-dispersion) were dissolved in 13.8 g of ethylcellulose. After stirring for 1 minute, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 10.67 Pa.s. The ink composition was applied to a glass plate and cured by UV at 600 mJ/cm 2 to obtain a film. The resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 29

40.0 g of the silver complex compound prepared in the same manner as in Example 15 and 41.2 g of a silver flake (EA0295, Chemet) were added to a solution in which 4.5 g of unsaturated polyacetate (Polycoat, Aekyung Chemical) was added. 0.5 g of benzoyl peroxide and 0.5 g of EFKA 4510 (EFKA) (-dispersant) were dissolved in 3.0 g of 2-pyrrolidone and 10.3 g of ethylcellulose. After stirring for 1 minute, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 3.17 Pa.s. The ink composition was applied to a glass plate and cured by UV at 600 mJ/cm 2 to obtain a film. The resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 30 40.0 g of a silver complex compound and 41.2 g of a silver flake (EA0295, Chemet) prepared in the same manner as in Example 15 were added to a solution in which 2.0 g of ruthenium resin (resol) was added. (TD-2207, Kangnam Chemical) was dissolved in 16.8 grams of ethylcellulose. After stirring for 1 minute, the solution was transferred to a three-wheel mill five times to obtain an ink composition having a viscosity of 3.05 Pa.s. The ink composition was applied to a glass plate and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film of 38 1326297 are shown in Table 1. Example 31

40.0 g of silver flakes (EA0295, Chemet) was added to a clear solution in which 1.0 g of polyvinyl butyral (BS-18, Wacker) was dissolved in 9.0 g of butyl diethylene glycol diethyl ether. The paste was prepared by stirring the solution for 10 minutes. A 50-_0 gram liquid silver complex compound prepared in the same manner as in Example 15 was added. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 3.88 Pa.s. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 32 40.0 g of a silver complex compound and 41.2 g of a silver flake prepared in the same manner as in Example 15 were added to a clear solution, wherein 5.0 g of polyvinyl butyral (BS-18, Wacker) was added. (-Adhesive) and 1.0 g of EFKA4330 (EFKA) (-dispersant) were dissolved in 12.8 g of propyl methoxyacetate. After stirring for 10 minutes, the # solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 1.18 Pa·s. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 33 40.0 g of a silver complex compound and 41.2 g of a silver flake (EA0295, Chemet) prepared in the same manner as in Example 15 were added to a solution in which 5.0 g of polyvinyl butyral (BS) was added. -18, Wacker) (-adhesive) was dissolved in 13.8 g of tetrahydro 39 1326297 furan. After stirring for a few minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 1.45 Pa·s. The ink composition was coated on a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (flat resistance) and adhesion of the film are shown in Table 1. Example 34 40.0 g of a silver complex compound prepared in the same manner as in Example 15 and 41.2 g of a silver flake (EA0295, Chemet) were added to a clear solution, wherein 5.0 g of propylene (HPD671, Johnson Polymer) was added. (--Adhesive) is dissolved in 13.8 g of polyvinyl butyral. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 0.75 Pa.s. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 35 40.0 g of a silver complex compound and 51.2 g of a silver flake (EA0295, Chemet) prepared in the same manner as in Example 15 were added to a solution in which 3.0 g of polyvinyl butyral (BS) was added. -18, Wacker) (-adhesive) was dissolved in 5.8 g of butyl diethylene glycol ether. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 4.35 Pa.s. The ink composition was coated on a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 36 35.0 g of a silver complex compound and 58.3 g of a silver flake (EA0295, Chemet) prepared in the same manner as in Example 15 were added to a solution in which 1326297 3.0 g of polyvinyl butyraldehyde was added. (BS-18, Wacker) (-adhesive) was dissolved in 3.7 g of butyl diethylene glycol ether. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 6.24 Pa.s. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 37

In a 250 ml Schlenk flask equipped with a stirrer, 31.00 g (163.4 mmol) molar ratio of 7:3 isopropylammonium isopropylammonium and 2-methoxyethyl A mixture of 2-methoxyethylammonium carbamate was dissolved in a mixed solution of 40.0 g of methanol and 20.5 g (158·6 mmol) of 2-ethylhexylamine. Next, 10.0 g (43,1 mmol) of silver oxide was added, and the mixture was reacted at room temperature for 4 hours and the solution was stirred during the reaction. A black slurry was initially obtained, but as the complex formed, the color gradually faded. Finally, a colorless, clear solution is obtained. Methanol and unreacted materials were removed from the reaction solution to obtain 61.4 g of a colorless, transparent silver complex solution. The silver content was confirmed by thermogravimetric analysis (TGA) to be 15.1% by weight. 5.0 g of polyvinyl butyral (BS-18, Wacker) (-adhesive) was dissolved in 55.0 g of the silver complex compound. Next, 40.0 g of silver flakes (EA0295, Chemet) was added to obtain an ink composition having a viscosity of 1 · 12 Pa.s. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 38 In a 250 ml Schlenk flask equipped with a stirrer, 39.1 g (365.5 mmol) of ethylamine hydrogencarbonate was dissolved in a mixture of 10.0 g of methanol and 10.0 g of 1326297 of methyl fibrin. In solution. Next, 100 g (431 mmol) of silver oxide was added and reacted at room temperature for 2 hours and the solution was stirred during the reaction. A black slurry was obtained at the beginning, but when the complex was formed, the color gradually faded. Finally, a colorless, clear solution is obtained. The decyl alcohol and unreacted materials were removed from the reaction solution to obtain 55.1 g of a colorless, transparent silver complex solution. The silver content was confirmed to be 16.9% by weight by thermogravimetric analysis (TGA). 5.0 g of a polyvinyl alcohol (Bug, Wacker) (-adhesive) was dissolved in 50,0 g of the silver complex compound. Next, 4 〇 gram silver flakes (EA 〇 295, Chemet) were added. After stirring for 1 minute, the solution was transferred to a three-roll mill for five times, and β was obtained to obtain an ink composition having a viscosity of 0.32 Pa·s. The ink composition was applied to a PET film and expressed on the surface. The resulting film was calcined at a temperature. The conductivity (flat resistance) and adhesion of the film are shown in Table 1. Example 39 In a 250 ml Schlenk flask equipped with a stirrer, 50.0 g (258.0 mmol) of 2-methoxyethylaminocarbamic acid 2-methoxyethyl group was dissolved in 8 Torr. In grams of methanol. Next, 2 Å. gram (86 2 mmol) of silver oxide was added, and the reaction was carried out at room temperature for 2 hours and the solution was stirred during the reaction. A black paste was initially obtained, but as the complex formed, the color gradually faded away. Finally, a colorless, transparent bath is available. Methanol and unreacted materials were removed from the reaction solution to obtain 59 2 g of a yellow, transparent silver complex compound. The content of silver was confirmed by thermogravimetric analysis (TGA) to be 31.4 wt./p. Add 40.0 g of silver complex compound and silver silver flakes (EA〇295, chemet) to a transparent bath. Vinyl butyral (BS-18, 42 1326297

WaCker) ("adhesive") was dissolved in 10.0 g of methyl fibrin and 5.0 g of 2-ethylhexylamine. After mixing for 1 G minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a degree of M4 Pa·s. The ink composition was coated on an 'ET film and the resulting film was calcined at a temperature of the surface. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 40 In a 250 ml Schlenk flask with a stirrer, 57.8 g of β (240.8 mmol) 3-methoxypropyl carbonate 3-methoxypropyl was dissolved in 80.0 g of methanol. Next, 2 〇.0 g (86.2 mmol) of silver oxide was added and reacted at room temperature for 2 hours and the solution was stirred during the reaction. A black paste was initially obtained, but when the δ error was formed, the color gradually looked away. Finally, a colorless, clear solution was obtained. The methanol and unreacted materials were removed from the reaction solution to obtain 67 8 g of a liquid yellow, clear silver complex compound. The silver content was confirmed by thermogravimetric analysis (TGA) to be 27.4% by weight. Add 40.0 grams of silver complex compound to 40. 0 grams of silver flakes (EA0295, Chemet) % to a clear solution, which will be 5.0 grams of polyvinyl butyral (BS-18, Wacker) (an adhesive) Dissolved in 10.0 g of methyl solvolysis and 5.0 g of 2-ethylhexylamine. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 1.79 Pa.s. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 41 In a 250 ml Schlenk flask equipped with a stirrer, 65.6 g of 43 1326297 (258.0 mmol) of dimethoxyethylaminoformate dimethoxyethylammonium was dissolved in 8 g. In methanol. Next, 20.0 g (86.2 mmol) of silver oxide was added and reacted at room temperature for 2 hours and the solution was stirred during the reaction. A black paste was initially obtained, but when the complex was formed, the color gradually faded and finally a colorless, clear solution was obtained. The decyl alcohol and unreacted materials were removed from the reaction solution to obtain 80.4 g of a liquid yellow, transparent silver complex compound. The silver content was confirmed by thermogravimetric analysis (TGA) to be 23·1 by weight of 0/〇.

Add 40.0 grams of silver complex compound and 40.0 grams of silver flakes (EA0295, Chemet) to a clear solution, in which 5 grams of polyvinyl butyral (BS-18, Wacker) (an adhesive) is dissolved. In 10.0 g of butyl diethylene glycol ether and 5.0 g of 2-ethylhexylamine. After 10 minutes of mixing, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 3.02 Pa.s. The ink composition was applied to a pET film and the resulting film was calcined at a temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 42

In a 25 liter Schlenk flask equipped with a stirrer, 34.8 g (215. Torr) of isopropylammonium isopropylamide was dissolved in 40.0 g of methanol and 40.0 g of methyl 'fibril. in. Next, 2 G.0 g (86.2 mmol) of silver oxide was added, and the reaction was carried out for 2 hours while stirring, and the solution was stirred during the reaction. A color paste was initially obtained, but as the complex formed, the color gradually faded. Finally, a f-color clear solution is obtained. Methanol and unreacted materials were removed from the reaction solution to obtain a solution of 92. 益 益 、, color, transparent silver complex. The silver content was confirmed by thermogravimetric analysis (TGA) to be 20.2% by weight. 44 1326297 5.0 g of polyvinyl butyral (BS-18, Wacker) (-adhesive) was dissolved in 50.0 g of a silver complex solution. Next, 2-ethylhexylamine and 40.0 g of silver flakes (EA0295, Chemet) were added. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 0.89 Pa·s. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 43

40.0 g of a silver complex solution prepared in the same manner as in Example 38 and 40.0 g of a silver flake (EA0295, Chemet) were added to a solution in which 5.0 g of propylene (HPD62, Johnson Polymer) (- Adhesive) and 0.5 g of coconut betaine (a surfactant) were dissolved in 14.5 g of water. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 0.18 Pa·s. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 44 40.0 g of a silver complex solution, 41.2 g of a silver flake (EA0295, Chemet) and 1.0 g of tetrabutoxytitanium (a metal precursor) prepared in the same manner as in Example 15 were added to a transparent In the solution, 5.0 g of polyvinyl condensate (BS-18, Wacker) (-adhesive) was dissolved in 12-8 g of butyl diethylene glycol diethyl ether. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 4.74 Pa.s. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 45

40.0 g of silver complex solution, 41.2 g of silver flakes (EA0295, Chemet) and 1.0 g of lanthanum acetate (a metal precursor) prepared in the same manner as in Example 15 were added to a transparent solution, wherein 5.0 g of polyvinyl butyral (BS-18, Wacker) (-adhesive) was dissolved in 12.8 g of butyl diethylene glycol diethyl ether. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 2.26 Pa.s. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 46 50.0 g of a silver complex solution, 30.0 g of a silver flake (EA0295, Chemet) and 1.0 g of vanadium oxide were added in the same manner as in Example 39 to 14.0 g of butyl diethylene glycol diethyl ether. It was dissolved in 5.0 g of polyvinyl butyral (BS-18, Wacker) (an adhesive). After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of M0 Pa.s. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 47 20.0 g of a silver complex solution prepared in the same manner as in Example 15, 10.5 g of silver 2-hexanoic acid ester used in Comparative Example 2, and 41.2 g of a silver flake (EA0295, Chemet) were added thereto. In the clear solution, 5.0 g of polyvinyl butyric acid (BS-18, Wacker) (-adhesive) was dissolved in 23.3 g of butyl diethylene glycol diethyl ether. 46 1326297 After stirring for ίο minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 3.98 Pa.s. The ink composition was applied to a PET film and the resulting film was satted at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 48

60.0 g of the silver complex solution prepared in the same manner as in Example 15 and 31.5 g of silver 2-hexanoate used in Comparative Example 2 to 4.0 g of 2-ethylhexylamine and 4.5 g of butyl were added. A mixed solution of diethylene glycol ether. After stirring for 10 minutes, an ink composition having a viscosity of 0.06 Pa.s. was obtained. The ink composition was applied to a PET film and the resulting film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 49 70.0 g of a silver flake (EA0295, Chemet) was added to a solution of 30.0 g of a liquid silver complex compound prepared in the same manner as in Example 39. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a viscosity of 1.06 Pa·s. The ink composition was screen printed on a PET film and heat-treated at 100 ° C for 5 minutes, followed by heat treatment at 130 ° C for 10 minutes. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 50 In a 500 ml Schlenk flask equipped with a stirrer, 84.9 g (0.5 mol) of silver nitrate was dissolved in 100 ml of an aqueous solution. Next, a solution as a protective colloid was added, in which 20.0 g of Solsperse 28000 (Aviacia) was dissolved in ethyl acetate. After stirring for 10 minutes, 149.8 g of diethylethanolamine was added to the solution 47 1326297

In the liquid. After a 5 hour stirring reaction, the colorless, transparent aqueous phase was separated from the dark brown organic phase. A dark brown silver colloid solution is obtained by extracting the organic phase. Ethyl acetate was removed from this solution to obtain 32.5 g of brown silver nanoparticles having an average particle size of 10 nm. 30.0 g of the nanoparticle was redispersed in 20.0 ethyl acetate and 50.0 g of a silver compound compound obtained in the same manner as in Example 25 was added. After stirring for 10 minutes, an ink composition having a viscosity of 0.03 Pa·s was obtained. The ink composition was coated on a polyimide film and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 51 In a 250 ml Schlenk flask equipped with a stirrer, 32. 5 g (107.5 mmol) of 2-ethylhexylaminocarbamate 2-ethylhexyl ammonium (a viscous liquid) was dissolved in 100.0. In milliliters of sterols. Next, 10.0 g (43.1 mmol) of silver oxide was added and the reaction was carried out at room temperature. As the reaction proceeded, the reaction mixture turned into a black slurry and eventually turned into a colorless, clear solution. The solvent was removed from the reaction solution in vacuo to obtain 42.0 g of a white silver compound. 5.3 g of 2-φ ethylhexylamine (a stabilizer) and 8.47 g of methanol (a solvent) were added to 20.0 g of the silver compound to obtain an ink composition having a viscosity of 5.7 cps. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 52 In a 250 ml Schlenk flask equipped with a stirrer, 8.2 g (86 mmol) of ammonium carbonate and 15.0 g (250 mmol) of 48 1326297 isopropylamine dissolved in 100 ml of methanol were mixed. Next, 10.0 g (43 μm) of silver oxide was added and the reaction was carried out at room temperature. As the reaction proceeded, the reaction mixture turned into a black slurry and eventually turned into a colorless, clear solution. The solvent was removed from the solution in vacuo to obtain 28.4 g of a white silver complex compound. 53 g of 2-ethylhexylamine (a stabilizer) 47 g of methanol (a granule) was added to 20.0 g of the silver complex compound to obtain an ink composition having a viscosity of 3.8 cps. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of the watch. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 53 Using 37.2 g of 2-ethylhexyl carbonic acid 2·ethylhexyl-substituted 2-ethylhexylaminocarbamic acid 2-ethylhexyl' to obtain a __ viscosity of 56 PCT. A transparent silver ink composition. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of the watch. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 54: A viscosity of 2 was obtained in the same manner as in Example 51 except that 48.6 g of 2-ethylhexyl carbonate 2-ethylhexylm was used instead of 2-ethylhexylaminocarbamate 2-ethylhexyl. Transparent silver ink composition at centipoise. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table i. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 55 Substituting 32.0 g of n-butylammonium n-butylammonium chloride for 2-ethylhexylaminocarbamic acid 2-ethylhexylammonium and replacing silver oxide with 12. g of silver carbonate, the same as in Example 5 1326297 A clear silver ink composition having a viscosity of 8.5 centipoise was prepared. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 56 A viscosity of 4 3 cps was obtained in the same manner as in Example 51, using 28.2 g of cyclohexyl ammonium cyclohexylammonium in place of 2-ethylhexyl ammonium 2-ethylhexylaminocarbamate. Transparent silver ink composition. Coating the ink composition and calcining at the temperature of Table i

The resulting uniform and precise film. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 57 Using a solution of 31.2 g of benzylammonium benzyl ammonium methoxide in place of 2-ethylhexylammonium 2-ethylhexylaminocarbamate, a viscosity of 5 3 cps was obtained in the same manner as in Example 51. Transparent silver ink composition. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of the watch. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 58 A viscosity was obtained in the same manner as in Example 51 except that 30.8 g of 2-methoxyethyl hydrogencarbonate 2-methoxyethylammonium was substituted for 2-ethylhexylaminocarbamic acid 2-ethylhexyl. A transparent silver ink composition of 2.8 centipoise. The ink composition was applied and the resulting uniform and precise film was fired at the temperature of Table 1 and X. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 59 Using 18.8 g of isopropyl isopropyl hydrogencarbonate (tetra) 25 g of octyl hydrogencarbonate, 50 1326297 generation of 2·ethylhexylaminocarbamic acid 2·ethylhexyl was used to achieve the same as the implementation of w 5 . A transparent silver ink composition having a viscosity of 2.8 centipoise was obtained by the method. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (flat resistance) and adhesion of the film are shown in Table 1. Example 60 Using 19.7 g of 2-ethylhexylaminocarbamic acid 2-ethylhexylammonium and 12 7 g of 2·methoxyethylaminocarbamic acid 2·methoxyethyl-substituted 2-ethylhexylamino group ? A clear silver ink composition having a viscosity of 22 6 centipoise was prepared in the same manner as in Example 51, and the ink composition was coated and calcined at a temperature of the surface to obtain a uniform Precise membrane. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 61 1.2 g of ammonium carbonate (a stabilizer and 25.0 g of propyl methoxyacetate (a solvent) was added to 20.0 g of the silver complex compound prepared in the same manner as in Example 55 to prepare a A transparent silver ink composition having a viscosity of 36 centipoise. The ink composition is coated and the resulting uniform and precise film is calcined at a temperature of the surface. The conductivity (planar resistance) and adhesion of the film are as follows. Table 1. Example 62 Add 1.2 grams of 2,2-ethylenedioxydiethylamine (2,2_ethy丨enedi〇xybisethy) (a stabilizer), 0.05 grams of EFKA 365〇 (EFKA) and 25 〇 The propyl methoxyacetate (a solvent) was added to a 2 gram silver complex compound prepared in the same manner as in Example 55 to prepare a transparent silver ink composition having a viscosity of 3.2 centipoise. The film was coated with the ink composition and the resulting film was obtained at the temperature T of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 63 Add 0.2 g Tripropylamine (a stabilizer), 〇〇3 g ΒγΚ 373 (Βγκ) and gamma methoxypropanol Solvent) to 12.0 g of a silver complex compound prepared in the same manner as in Example 58 to prepare a transparent silver ink having a viscosity of 33 cps, and coating the ink composition. The resulting film was calcined at the temperature of Table i. The conductivity (planar resistance) and adhesion of the film are shown in Table i. Example 64 Add 0.2 g of diisopropylamine (a stabilizer) 0.03 g of BYK 373 (BYK) and 2 gram of 1-methoxypropanol (a solvent) to 12.0 g of a silver complex compound prepared in the same manner as in Example 58 to prepare a A transparent silver ink composition having a viscosity of 42 centipoise. The ink composition is coated and the resulting uniform and precise film is calcined at a temperature of the surface. The conductivity (planar resistance) and adhesion of the film are as follows. Table i shows.

Example 65 0. 2 g of 3-methoxypropylamine (a stabilizer), 3 g of teGO Wet 505 (Degussa) and 20.0 g of ethanol (a solvent) were added to the same method as in Example 53. In the 12 gram silver complex compound, a transparent silver ink composition having a viscosity of 42 cps was prepared. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 66 52 1326297 3,4 g of 2-ethylhexylamine (a stabilizer), 0.03 g of TEGO Wet 505 (Degussa) and 20.0 g of ethanol (a solvent) were added to prepare in the same manner as in Example 53. A 12.0 gram silver complex compound was prepared to prepare a transparent silver ink composition having a viscosity of 4.4 centipoise. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 67

3.4 g of 2-ethylhexylamine (a stabilizer), 0.03 g of TEGO Wet 505 (Degussa) and 20.0 g of 1-propanol (a solvent) were added to 12.0 g of silver obtained in the same manner as in Example 53 In the complex compound, a transparent silver ink composition having a viscosity of 4.6 centipoise was prepared. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 68 3.4 g of 2-ethylhexylamine (a stabilizer), 0.02 g of Rilanit HT-Extra (Cognis) and 12.7 g of a methylcellulose-soluble fiber (a solvent) were added to prepare in the same manner as in Example 53. A 12.0 gram silver complex compound was obtained to prepare a transparent silver ink composition having a viscosity of 4.1 centipoise. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 69 3.4 g of 2-ethylhexylamine (a stabilizer), 0.03 g of EFKA 3835 (EFKA), and 12.7 g of ethyl acetate (a solvent) were added to give a ratio of 53 1326297 in the same manner as in Example 53. In 20.0 g of the silver complex compound, a transparent silver ink composition having a viscosity of 65 cps was prepared to be coated with the ink composition and calcined at the temperature of Table i to obtain a uniform and precise ^ The conductivity (plane resistance) and adhesion of the film are as follows! Shown. Example 70 3.4 g of 2-ethylhexylamine (a stabilizer), 〇.〇5 g of EFKA 3777 (efka) and 12.7 g of toluene (one solvent) were added to the same method as in Example 53 In the case of a ruthenium silver complex compound, a transparent silver ink composition having a viscosity of 6 3 centipoise is prepared. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of the watch. The conductivity (planar resistance) and adhesion of the film are shown in Table 。. Example 71 3.4 g of 2-ethylhexylamine (a stabilizer), 3 g of GHde 41 〇 (Degussa) and 12,7 g of 2-propanol and ethyl diethylene glycol B in a weight ratio of 2:1 were added. A mixture of hydrazine acetate (a solvent) was added to a 2 gram silver complex compound prepared in the same manner as in Example 53 to prepare a transparent silver ink composition having a viscosity of 6.2 centipoise. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of the watch. The conductivity (planar resistance) and adhesion of the film are shown in Table 。. Example 72 3.4 g of 2-ethylhexylamine (a stabilizer), 3 g of DSX 1514 (c〇gnis) and 12.7 g of nn-dimethylformamide in a weight ratio of 3:1:1 were added, a mixture of N,N dimethyl hydrazine and methanol (a solvent) to a 20-0 gram silver complex compound prepared in the same manner as in Example 5; 3 to prepare a viscosity of 8 cps. Transparent silver ink composition. The ink composition was applied and the resulting 54^26297 uniform and fine mask was calcined at a temperature of the surface. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 73 Adding 3.4 g of 2-ethylhexylamine (a stabilizer), keke efka4i(e) (efkA) and 12.7 g of a weight ratio of 4:1 [·methyl 2 oxazeone and 2 butanol The mixture of (a solvent) was complexed with 20.0 g of silver prepared by the method of _53 (d). A transparent silver ink composition having a degree of preparation of 67 centipoise. The film of the ink/water composition is applied and the temperature of the wire is applied to the film of the (four) domain. The conductivity (planar resistance) and adhesion of the film are shown in Table 。. Example 74 Adding 3.4 g of 2-ethylhexylamine (a stabilizer), 〇.〇5 g of Surfynol 465 (Air oduct) and I2·7 g of water polyethylene glycol (pEG) in a weight ratio of 2:1:1 a mixture of 2 hydrazine and decyl alcohol (-solvent) to a 2 gram silver complex compound prepared in the same manner as in Example 53 to prepare a transparent silver having a viscosity of 8 9 centipoise Ink composition. Applying the ink nucleus at the temperature of the mash and the uniformity of the film obtained. The conductivity (planar resistance) and adhesion of the film are shown in Table i. Example 75 In a 250 ml Schlenk flask equipped with a stirrer, 26 g (0.20 mol) of 2-ethylhexylamine and 15 g (0.20 mol) of n-butylamine were dissolved in 1 g of methanol. After the stirring, 9.3 g (0.04 mol) of silver oxide was added, and the reaction was carried out at room temperature while the carbon dioxide gas slowly became a bubble. As the reaction proceeds, the reaction mixture becomes a black slurry and eventually becomes a colorless 'transparent solution. The solvent was filtered through a 45 micron filter to obtain a liquid clean, transparent silver complex compound 55 1326297. 3.5 g of 2-ethylhexylamine and 0.05 g of EFKA 3650 (EFKA) were added to 20.0 g of the silver complex compound to obtain a transparent silver ink composition having a viscosity of 15.4 cps. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 76

26 g (0.20 mol) of 2-ethylhexylamine, 15 g (0.20 mol) of n-butylamine and 0.24 g of dodecylamine were added to a 250 ml pressurized vessel equipped with a stirrer. Next, 0.03 g of Rilanit HT-Extra (Cognis) and 10.0 g of decyl alcohol were added and the mixed solution was dissolved by stirring. 9.3 g (0.04 mol) of silver oxide was added and reacted while slowly injecting carbon dioxide gas to obtain a transparent silver ink composition having a viscosity of 135.0 cps. The ink composition was applied and satisfactorily obtained at a temperature of Table 1 to obtain a uniform and precise film. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 77 A transparent silver ink composition having a viscosity of 2,300 cps was prepared by adding 4.8 g of ethyl cellulose to 20.0 g of a silver complex compound of f obtained in the same manner as in Example 60. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 78 To prepare a viscous 56 by adding 2.0 g of 2-ethylhexylamino phthalic acid 2-ethylhexyl ammonium to 20.0 g of a silver complex compound prepared in the same manner as in Example 60. 1326297 A transparent silver ink composition having a degree of 19.2 centipoise. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 79

Prepared by the same method as in Example 60 by adding 3.4 g of 2-ethylhexylamine (a stabilizer), 0.8 g of polyvinyl butyral (BL-18, Wacker) and 4.0 g of butyl cellosolve. A 20.0 gram silver complex compound was prepared to prepare a transparent silver ink composition having a viscosity of 8,000 centipoise. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 80 Using 20.1 g of isopropylammonium isopropyl carbonate in place of 2-ethylhexylamine decanoic acid 2-ethylhexylammonium, 3.4 g of 2-ethylhexylamine (as a stabilizer) and 12.7 g of water and 0.03 A transparent silver ink composition having a viscosity of 3.5 centipoise was prepared in the same manner as in Example 51 except that ketobetaine was substituted for decyl alcohol (as a solvent). The ink composition was applied and % of the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (flat resistance) and adhesion of the film are shown in Table 1. Example 81 20.1 g of isopropylammonium isopropyl carbonate and 13.0 g of water were added to a 250 ml Schlenk flask equipped with a stirrer in a 250 ml. After stirring, 10.0 g (43.1 mmol) of silver oxide was added and the reaction was carried out at room temperature to prepare an aqueous solution of a silver complex compound. 3.4 g of 2-ethylhexylamine (a stabilizer) and 0.03 g of coconut betaine were added to 43.1 g of the liquid silver complex compound to obtain a transparent silver ink composition having a viscosity of 57 1326297 of 3.5 cps. The ink composition was applied and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 82

A transparent silver ink composition having a viscosity of 3.8 cps prepared in Example 52 was filled in a polyethylene container. A pattern was formed on a PET film, a melamine film, and a glass plate using a flat printing machine equipped with a piezoelectric inkjet print head F083000 (Epson). The patterned sample was heat-treated at 80 ° C for 5 minutes, followed by heat treatment at 130 ° C for 10 minutes. Example 83 A transparent silver ink composition having a viscosity of 2,300 cps prepared in Example 76 was patterned on a PET film using a screen printing machine having a 320 mesh pattern. The patterned sample was heat treated at 80 ° C for 3 minutes and then heat treated at 130 ° C for 10 minutes (see Figure 7). Example 84 A transparent f silver ink composition having a viscosity of 19.2 centipoise prepared in Example 77 was formed on a PET film by a flexographic printing machine, and the PET film was pretreated with polyvinyl butyral resin. of. The patterned sample was heat-treated at 80 ° C for 2 minutes, heat-treated at 100 ° C for 3 minutes, and then heat-treated at 130 ° C for 10 minutes (see Fig. 8). Example 85 In a 1,000 ml Schlenk flask equipped with a stirrer, 90.22 g (556.16 mmol) of isopropylammonium isopropylcarbamate was dissolved in 400 ml of decyl alcohol. 58 1326297

Next, 63.06 g (927.08 mmol) of a 50% by weight aqueous hydrogen peroxide solution was slowly added to obtain a colorless, transparent solution. The reaction was carried out at room temperature, while silver powder (SNGPSN-100-99, SOLNANOGY, average particle size = 100 nm) was slowly added until it was no longer dissolved. As the reaction proceeded, the reaction solution turned into a gray paste and eventually turned into a colorless, clear solution. The amount of silver consumed was 20.00 grams (185_41 millimoles). The reaction solution was filtered through a 0.45 μm membrane filter and the solvent was removed in vacuo to obtain 54.70 g of a white silver compound. The silver content was confirmed by thermogravimetric analysis (TGA) to be 36.50% by weight. 5-30 g of 2-ethylhexylamine (a stabilizer) and 12.49 g of methanol (a solvent) were added to 20.00 g of the silver complex compound to obtain a transparent silver ink composition having a viscosity of 3.3 cps. The silver content of the ink composition was confirmed by thermogravimetric analysis (TGA) to be 19.47% by weight (see Fig. 9). The ink composition was applied to a PET film and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 86 40.00 g of a clear silver ink composition prepared in Example 85 and 41.00 g of a silver flake (EA0295, Chemet) were added to a clear solution, wherein 5.00 g of polyvinyl butyral (BS-18, Wacker) (-adhesive) was dissolved in 14.00 g of butyl diethylene glycol ether. After stirring for 10 minutes, the solution was transferred to a three-roll mill (Drais Mannheim) five times to obtain a conductive ink composition having a silver content of 49.64% by weight and a viscosity of 2,500 centipoise. The ink composition was applied to a PET film and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. 59 1326297 Example 87 40.00 g of a clear silver ink composition obtained in Example 85 was added to a mixed solution of 22.60 g of silver acetate to 5.00 g of isopropylamine and 32.40 g of butyl diethylene glycol diethyl ether. Thereafter, a transparent silver ink composition having a viscosity of 11.5 centipoise is obtained. The ink composition was applied to a PET film and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1.

Example 88

A colorless, clear solution was obtained in the same manner as in Example 85, using 67.36 g ( 556.16 mmol) of isopropyl ammonium hydrogencarbonate in place of isopropyl ammonium isopropylamine. The amount of silver consumed was 12.80 grams (118.66 millimoles). The reaction solution was filtered through a 0.45 μm membrane filter and the solvent was removed in vacuo to obtain 33.62 g of a white silver complex compound. The silver content was confirmed by thermogravimetric analysis (TGA) to be 37.50% by weight. 5.30 g of 2-ethylhexylamine (a stabilizer) and 8.47 g of decyl alcohol (a solvent) were added to 20.00 g of the silver complex compound to obtain a transparent silver ink composition having a viscosity of 3.5 cps. The ink composition was applied to a PET film and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 89 The same procedure as in Example 85 was carried out using 50.12 g (278.08 mmol) of isopropylammonium isopropyl carbonate in place of isopropylammonium isopropylaminocarbamate and replacing the decyl alcohol with an equivalent amount of water. Get a colorless, transparent solution. The amount of silver consumed was 3.60 grams (33.37 millimoles). The reaction solution was filtered through a 0.45 μm membrane filter and the solvent 60 1326297 was removed in vacuo to obtain 11.31 g of a white silver complex compound. The silver content was confirmed by thermogravimetric analysis (TGA) to be 31.50% by weight. 2.65 g of 2-ethylhexylamine (a stabilizer) and 4.24 g of methanol (a solvent) were added to 10.00 g of the silver complex compound to obtain a transparent silver ink composition having a viscosity of 3.6 cps. The ink composition was applied to a PET film and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 90

A solution was prepared in the same manner as in Example 85 except that 108.20 g (556.16 mmol) of 2-decyloxyethylaminocarbamate 2-methoxyethylammonium chloride was substituted for isopropylammonium isopropylaminocarbamate. Yellow, clear solution. The amount of silver consumed was 11.20 grams (103.83 millimoles). The reaction solution was filtered through a 0.45 μm membrane filter and the solvent was removed in vacuo to obtain 35.40 g of a liquid brown silver complex compound. The silver content was confirmed by thermogravimetric analysis (TGA) to be 31.42% by weight. 8.48 g of silver flakes, 8.48 g of silver powder and a clear solution (in which 1.50 g of polyvinyl butyral (an adhesive) was dissolved in 11τ of 54 g of butylcellulose) were added to 20.00 g of the silver complex compound. After stirring for 10 minutes, the solution was transferred to a three-roll mill (Drais Mannheim) five times to obtain a conductive ink composition having a silver content of 46.49% by weight and a viscosity of 1,120 centipoise. The ink composition was applied to a PET film and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (flat resistance) and adhesion of the film are shown in Table 1. Example 91 20.00 g of silver complex compound, 16.96 g of silver flakes and 1.00 g of cerium acetate (a metal precursor) obtained in Example 90 were added to a clear solution, wherein 61 1326297 1.50 g was charged. Vinyl butyral (an adhesive) was dissolved in 10.54 g of butylcellulose. After stirring for 10 minutes, the solution was transferred to a three-roll mill (Drais Mannheim) five times to obtain a conductive ink composition having a viscosity of 1,560 centipoise. The ink composition was applied to a PET film and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 92

A colorless, clear solution was obtained in the same manner as in Example 85, using 43.42 g ( 556.16 mmol) of ammonium amide. The amount of silver consumed was 8.80 grams (81.58 millimoles). The reaction solution was filtered through a 0.45 μm membrane filter and the solvent was removed in vacuo to obtain 20.80 g of a liquid white silver complex compound. The silver content was confirmed by thermogravimetric analysis (TGA) to be 42.00% by weight. Add 1.20 g of ammonium carbonate (a stabilizer), 0.05 g of EFKA 3650 (EFKA) and 25.00 g of propyl methoxyacetate (a solvent) to 20.00 g of the silver complex compound to obtain a transparency of 3.5 cps. Silver ink composition. The ink composition was applied to a PET film and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 93 In a 〇〇〇 ml flask equipped with a stirrer, 66.02 g (370.77 mmol) of a mixture of isopropylamine and boric acid having a molar ratio of 2:1 was dissolved in 400 ml of sterol. in. Add 30.07 g (185.39 mmol) of isopropylammonium isopropyl citrate and slowly add 63.06 g (927.08 mmol) of a 50% by weight aqueous solution of hydrogen peroxide to obtain a colorless, transparent Solution. Then, the reaction is carried out at room temperature and the same as 62 1326297

Slowly add metallic silver until it no longer dissolves. As the reaction proceeded, the reaction solution turned into a gray paste and eventually turned into a colorless, transparent solution. The amount of silver consumed was 9.10 grams (84.36 millimoles). The reaction solution was filtered through a 0.45 μm membrane filter and the solvent was removed in vacuo to obtain 29.72 g of a white silver compound. The silver content was confirmed by thermogravimetric analysis (TGA) to be 30.3 1% by weight. 0.20 g of tripropylamine (a stabilizer), 0.03 g of BYK 373 (BYK) and 20.00 g of 1-methoxypropanol (a solvent) were added to 12.00 g of the silver complex compound to obtain a viscosity of 3.6 cps. Transparent silver ink composition. The ink composition was coated on a quinone film and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 94 In a 〇〇〇 ml flask equipped with a stirrer, 90.22 g (556.16 mmol) of isopropylammonium isopropylcarbamate was dissolved in 400 ml of methanol. The reaction mixture was cooled to -40 ° C using an ice bath and an ozone bubble (6.21 g/hr) was produced using an ozone generator (Ozone Generator-LAB 2, Ozone Tech).

% Next, the reaction was carried out at room temperature while metal silver was slowly added until it was no longer dissolved. As the reaction proceeded, the reaction solution turned into a gray paste and eventually became a colorless, transparent solution. The amount of silver consumed was 5.20 grams (48.21 millimoles). The reaction solution was filtered through a 0.45 μm membrane filter and the solvent was removed under vacuum to obtain 14.68 g of a white silver compound. The silver content was confirmed by thermogravimetric analysis (TGA) to be 35.00% by weight. 2.65 g of 2-ethylhexylamine (a stabilizer) and 4.24 g of methanol (a solvent) were added to 10.00 g of the silver complex compound to obtain a transparent silver ink composition having a viscosity of 3.7 cps. The ink composition was coated on a PET 63 1326297 film and the resulting uniform and fine film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 95 In a 〇〇〇 ml flask equipped with a stirrer, 90.22 g (556.16 mmol) of isopropylamino decanoic acid isopropyl was dissolved in 400 liters of methanol. The reaction mixture was cooled to -40 ° C using an ice bath and a bubble of ozone (6 2 g/hr) was produced using an ozone generator (〇z〇ne Generator-LAB 2, Ozone Tech). Next, the reaction was carried out while using a silver foil as an electrode to supply alternating current (8 volts, 60 Hz) to the solution until the silver electrode was no longer dissolved. As the reaction proceeds, the reaction solution turns into a gray paste and eventually becomes a colorless, transparent solution. The amount of silver consumed was 12.20 grams (113.10 millimoles). The reaction solution was filtered through a membrane filter of 45 μm and the solvent was removed in vacuo to obtain 3416 g of a white silver complex compound. The mass of the silver was confirmed by thermogravimetric analysis (TGA) to be 35 〇 weight 0/ Hey. Add 0.20 g of monoisopropylamine (a stabilizer), 3 g of Βγκ 373 (BYK) and 20.00 g of 1-methoxypropanol (a solvent) to 12 g of the silver complex compound to A clear silver ink composition having a viscosity of 3.8 centipoise was obtained. The ink composition was coated with a film of PET film _L and fired at the temperature of the watch to obtain a film of the obtained smear and fine disk. The conductivity (planar resistance) and adhesion of the film are shown in Table i. Example 96 In a 1,000 ml flask equipped with a stirrer, 90 22 g (556 16 mmol) of isopropylamino isopropyl isopropyl and 1 (9) t were added. 1465 (Ak Product) is dissolved in _ liter of methanol. The reaction mixture was cooled to -40 C using an ice bath and a bubble of ozone was produced. Next, the reaction is carried out while using a silver knot 64 1326297

The electrode was supplied with alternating current (80 volts, 60 Hz) to the solution until the silver electrode was no longer dissolved. As the reaction proceeded, the reaction solution turned into a gray paste and eventually became a colorless, transparent solution. The amount of silver consumed was 9.40 grams (87.14 millimoles). The reaction solution was filtered through a 0.45 μm membrane filter and the solvent was removed in vacuo to give 27.73 g of a white silver compound. The silver content was confirmed by thermogravimetric analysis (TGA) to be 33.80% by weight. 0.20 g of 3-methoxypropylamine (a stabilizer), 0.03 g of TEGO Wet 505 (Degussa) and 20.00 g of ethanol (one solvent) were added to 12.00 g of the silver complex compound to obtain a viscosity of 3.3 cps. Transparent silver ink composition. The ink composition was applied to a PET film and the resulting uniform and precise film was calcined at the temperature of Table 1. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. Example 97 A conductive ink having a viscosity of 2,500 cps prepared in Example 86 was patterned on a PET film using a screen printing machine having a 320 mesh pattern. The patterned sample was heat treated at 1 ° C for 3 minutes and then heat treated at 130 ° C for 10 minutes (see Figure 10). Comparative Example 1 50.2 g of silver flakes (EA0295, Chemet) was added to a clear solution in which 5.0 g of polyvinyl butyral (BS-18, Wacker) (-adhesive) was dissolved in 44.8 g of butyl di In diol ether. After stirring for 10 minutes, the solution was transferred to a three-roll mill for five times to obtain an ink composition having a silver content of 50.2% by weight and a viscosity of 3.21 Pa·s. The ink composition was applied in the same manner as in Example 15 and the resulting film was calcined at the temperature of Table 1. The conductivity of the film (planar resistance) 65 # danger is as shown in Table i. The conductivity and adhesion were inferior to those of Example K and cracks were observed. Comparative Example 2 Add 21.0 g of silver 2-hexanoic acid and 41 2 g of silver flakes (ea 295, chemet) in the liquid-cold liquid, which is a 5 G gram of polyvinyl condensate (10) ruthenium agent ) / combined with 32.8 grams of butyl diethylene glycol. After mixing for 1 minute, The solution was transferred to a three-roll mill five times, and the silver content was 50.2 weight. An ink composition having a viscosity of 3.57 Pa.s. The resulting film was overcoated with the ink Jc, .a σ in the same manner as in Example 15. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. The conductivity and adhesion were significantly lower than those of Example 15. Comparative Example 3 In the same manner as in Example 15, a liquid silver complex compound having a silver content of Μ% by weight and a viscosity of Pa & This was coated and calcined in the same manner as in Example 锻. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. The film was thin and the conductivity was inferior to that of Example 15. The uniformity of the film is also less than good. Comparative Example 4 A person was added 13'8 g of methanol ("solvent" to 20% gram silver obtained in Example 51. The compound was used without using diethylhexylamine (a stabilizer) to obtain a transparent silver ink composition having a viscosity of / centipoise. The composition was applied in the same manner as in Example 51 and the resulting film was calcined. The conductivity (planar resistance) and adhesion of the film are shown in Table 1. The conductivity and adhesion were inferior to those of Example 51 and cracks were observed in 1326297. Comparative Example 5 A transparent silver ink composition having a viscosity of 56 cps was prepared by using 5.0 g of silver hexanoate and adding 53 g of 2-ethylhexylamine (a stabilizer) and 5.54 g of methanol (a solvent). The ink composition was applied in the same manner as in Example 51 and the obtained film was calcined. The conductivity (planar resistance) and adhesion of the film are shown in Table i. guide

The electrical and adhesive lines were significantly worse than those of Example 51. Table 1: Physical properties of the films obtained in the examples and comparative examples Calcination temperature (° C.) Conductivity (Ω/) Adhesion Example 1 150 0.472 〇 Example 2 150 0.089 〇 Example 3 150 0.210 0 Example 4 180 0.924 △ Example 5 200 0.528 0 Example 6 150 0,162 〇 Example 7 180 0.956 0 Example 8 180 0.742 〇 Example 9 200 0.174 〇 Example 10 200 0.152 0 Example 11 200 0.193 0 Example 12 180 1.831 0 Example 13 150 0.470 〇 Example 14 150 0.098 〇67 1326297

Example 15 130 0.115 〇Example 16 130 0.477 0 Example 17 130 0.320 〇Example 18 130 0.779 0 Example 19 130 0.954 〇Example 20 130 0.789 〇Example 21 130 0.368 〇Example 22 130 0.377 〇Example 23 130 0.340 0 Example 24 130 0.865 Δ Example 25 130 0.405 0 Example 26 130 0.724 Δ Example 27 130 0.534 〇 Example 28 250 0.120 0 Example 29 250 0.456 〇 Example 30 250 0.389 〇 Example 31 130 0.128 〇Example 32 130 0.456 0 Example 33 130 0.132 0 Example 34 130 0.497 〇Example 35 130 0.048 0 Example 36 130 0.024 〇Example 37 130 0.241 0 68 1326297

Example 38 100 0.133 Δ Example 39 130 0.537 〇 Example 40 130 0.134 〇 Example 41 150 0.346 0 Example 42 130 0.351 〇 Example 43 130 0.545 Δ Example 44 130 0.349 0 Example 45 130 0.641 〇Example 46 130 0.389 0 Example 47 130 0.237 0 Example 48 130 0.596 0 Example 49 130 0.014 〇 Example 50 200 0.458 0 Example 51 130 0.22 0 Example 52 130 0.30 〇 Example 53 130 0.25 〇 Example 54 130 0.25 〇 Example 55 130 0.48 Δ Example 56 120 0.58 Δ Example 57 130 0.44 Δ Example 58 130 0.38 0 Example 59 250 0.37 0 Example 60 130 0.29 0 69 1326297 Example 61 250 0.50 0 Example 62 250 0.56 0 Example 63 100 0.25 Δ Example 64 100 0.28 Δ Example 65 120 0.41 Δ Example 66 130 0.38 Δ Example 67 130 0.35 0 Example 68 130 0.45 0 Example 69 130 0.35 Δ Example 70 250 0.51 Δ Example 71 130 0.55 0 Example 72 130 0.58 Δ Example 73 250 0.90 0 Example 74 130 1.00 Δ Example 75 130 0.24 Δ Example 76 130 0.39 0 Example 77 130 0.51 0 Example 78 130 0.32 实施 Example 79 130 0.42 0 Example 80 130 0.65 Δ Example 81 130 0.61 Δ Example 82 130 0.38 0 Example 83 250 0.32 〇

70 1326297

EXAMPLES '84 130 0.58 〇Example 85 130 0.25 〇Example 86 130 0.11 〇Example 87 130 0.35 0 Example 8 8 130 0.28 0 Example 89 150 0.71 Δ Example 90 150 0.23 0 Example 91 130 0.64 0 Example 92 130 0.45 〇 Example 93 200 0.53 〇 Example 94 130 0.28 0 Example 95 130 0.33 〇 Example 96 100 0.31 〇 Example 97 130 0.12 0 Comparative Example 1 130 1.106 Δ Comparative Example 2 130 3.425 X Comparative Example 3 130 0.455 Δ Comparative Example 4 130 0.35 Δ Comparative Example 5 130 5000 X (1) Adhesion test: evaluated by attaching and peeling Scotch tape (3M) to the printed surface of the film. 0: The surface of the film was not peeled off. △: Part of the film surface peeled off. 71 1326297 x: Most of the film surface peeled off. (2) Conductivity test: The plane resistance was measured for a square specimen of 1 cm x 1 cm using CMT-SR1000N (AIT). Industrial application

The present invention is directed to a plurality of electrically conductive ink compositions comprising a metal complex compound of a particular structure and an additive' and a method of making such compositions. The ink composition of the present invention has excellent stability and solubility, is easy to form a film, and is easily calcined even at a low temperature of 200 ° C or lower to form a film or pattern having good electrical conductivity. The composition can be applied or printed directly onto a variety of substrates, including metal, glass, tantalum wafers, ceramics, plastic films such as polyester or polyimide, rubber sheets, fibers, wood, paper, and the like. The composition of the present invention allows the film to be uniformly formed and provides a film of good electrical conductivity and adhesion. In addition, the film has an excellent quality and no cracks. The ink composition of the invention can be widely used for EMI shielding materials, conductive adhesives, low-resistance metal wires, PCBs, FPCs, antennas for RFID tags, solar cells of pdps, TFT-LCDS, OLEDs, flexible displays and OTFTs, and secondary Battery or fuel cell, cell and electrode or wiring. It will be appreciated that those skilled in the art will be able to modify or design other embodiments to achieve the same objectives as the present invention. It is to be understood by those skilled in the art that the same embodiments are not to be construed as a BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a thermogravimetric analysis chart 72 1326297 (thermaogram, TGA) of the metal ink composition of Example 1, and Fig. 2 is a metal ink composition screen using the embodiment 1. The pattern printed on the PET film; the third figure shows the TGA of the conductive ink composition of Example 15, and the fourth figure shows the pattern printed on the PET film using the ink composition of Example 15, Figure 5 is a graph showing the TGA of the ink composition of Example 52;

Fig. 6 is a view showing ink jet printing using the ink composition of Example 82; Fig. 7 is a view showing a pattern printed on the PET film using the ink composition of Example 83, and Fig. 8 is a view A pattern of flexographic printing using the ink composition of Example 84; Fig. 9 is a TGA of the ink composition of Example 85; and Fig. 10 is a screen printing using the ink composition of Example 97. The pattern on the PET film. [Main component symbol description]

73

Claims (1)

1326297 ,, 丨公' '第09510分4丨3 Patent Application Replacement of Chinese Patent Application (March 99) X. Patent Application Range: 1. A conductive ink composition comprising a metal complex a compound and an additive, wherein the metal complex compound is represented by at least one metal or metal compound represented by the following Chemical Formula 1 and at least one amino acid represented by the following Chemical Formula 2, Chemical Formula 3. or Chemical Formula 4 Obtained by ammonium or ammonium carbonate as a matrix compound: ΜηΧ (1) Μ is a metal or metal alloy; η is an integer from 1 to 10; and X is a substituent which is absent or at least one selected from the group consisting of hydrogen, ammonium, oxygen, sulfur, halogen, cyano, cyanate, Carbonate, nitrate, nitrite, sulfate, phosphate, thiocyanate, oleate, peroxyacid, tetrafluoroborate, acetoacetate, sulfhydryl, decylamine, alkoxide, carboxylate and derivatives thereof And R1 9θ© , r3 nconh-r4 (2) (3) (4) R2 R5 ^ ©θ^ββ R2-HNOCONH-R5 R3 Re r2-hnocoh R3 In Chemical Formula 2 to Chemical Formula 4, R丨, R 2 , R 3 , R 4 , R 5 and R 6 are each independently selected from hydrogen; substituted or unsubstituted Ci-C 3 G aliphatic alkyl, cycloaliphatic alkyl, aryl or aralkyl; polymeric compound; heterocyclic ring a compound, and a derivative thereof; wherein, 1 and R2 or R4 and R5 may be bonded to each other to form an alkylene ring having or without a hetero atom; and the strip 74 ^^6297 is not all Β · ι to I are all hydrogen. 2. The conductive ink composition according to claim 4, wherein the metal complex compound is represented by the chemical formula 5: m (5) A is a red-human-represented compound represented by Chemical Formula 4 in Chemical Formula 2 And 0.7SmS5.5. As for the conductive ink of the request item 1 household, and the makeup is good, and. And the metal or metal compound represented by the chemical formula 1 is selected from at least one of the group consisting of silver, gold, steel, rhodium, nickel, cobalt, palladium, platinum, titanium, vanadium, manganese, iron, chromium , zirconium, hafnium, molybdenum, tungsten, nail, cadmium, button, bismuth, hungry, antimony, aluminum 'gallium, indium, tin, antimony, lead, antimony, bismuth, antimony, bismuth, antimony, copper oxide, zinc oxide, Vanadium oxide, nickel sulfide, palladium chloride 'copper carbonate, ferric chloride, gasification gold, vaporized nickel, cobalt vapor, barium nitrate, vanadyl acetone, cobalt acetate, tin lactate, manganese oxalate, gold acetate, oxalic acid Palladium, copper 2-ethylhexanoate, iron stearate, nickel formate, molybdate, zinc citrate, acetic acid, copper cyanide, carbonic acid, gasified platinum, hydrogen tetrachloroaurate, Titanium tetrabutoxide, dimethoxy chloroformate, aluminum isopropoxide, tin tetrafluorophosphate, hydrazine, dodecylmercaptoaurate, and acetonitrile. 4. The conductive ink composition according to claim 1, wherein the metal or metal compound represented by Chemical Formula 1 is silver (Ag), a silver compound or a silver alloy; η is an integer of 1 to 4; Select from at least one of the following groups: oxygen, sulfur, halogen, cyano, cyanate, carbonate, nitrate, nitrite, sulfate, phosphate, thiocyanate, oleate, perchlorate, tetrafluoro Borate, acetophenone, root, carboxylate and derivatives thereof. 75 1326297 5. The conductive ink composition of claim 4, wherein the silver compound is selected from at least one of the group consisting of silver oxide, silver thiocyanate, silver cyanide, silver cyanate, silver carbonate, silver nitrate , silver nitrite, silver sulfate, silver phosphate, silver peroxyacid, silver borofluoride, silver acetonitrile, silver acetate, silver lactic acid, silver oxalate and the foregoing derivatives; and the silver alloy system contains at least one selected Alloys from the following group of metals: gold, copper, mud, diamond, Ji, Shi, Titanium, Niobium, Manganese, Iron, Ming, Wrong, Sharp, Crane, Nail, Tin, Group, Chain, Hungry, 铱, Ming, recorded, 锗, indium, tin, recorded, wrong, Syrian, Shixi, 珅, mercury, Peng, 铕, I soil, magnesium, calcium, strontium and strontium. 6. The conductive ink composition according to claim 1, wherein each of the substituents 丨, R2, R3, R4, R5 and R6 are independently selected from the group consisting of hydrogen, methyl, ethyl, propyl, Isopropyl, butyl, isobutyl, pentyl, hexyl, ethylhexyl, heptyl, octyl, isooctyl, decyl, decyl, dodecyl, hexadecyl, octadecyl, di Dodecyl, cyclopropyl, cyclopentyl, cyclohexyl, allyl, hydroxy, decyloxy, methoxyethyl, methoxypropyl, cyanoethyl, ethoxy, butoxy, hexyl Oxyl, decyloxyethoxyethyl, methoxyethoxyethoxyethyl, hexamethyleneimine, morpholine, piperidine, piperazine, ethylenediamine, propylenediamine, hexane Amine, triethylenediamine, pyrrole, imidazole, pyridine, carboxymethyl, trimethoxysulfonylpropyl, triethoxyphosphonium propyl, phenyl, methoxyphenyl, cyanophenyl, phenoxy, Tolyl' phenyl fluorenyl, polyallylamine, and polyethyleneamine; the conditions are not all of R, and R3 is hydrogen. 7. The conductive ink composition according to claim 1, wherein the compound based on ammonium ammonium citrate is selected from at least one of the group consisting of ethylamine sulfonate 76 1326297 ammonium, isopropylamine Isopropylammonium formate, n-butylammonium n-butylammonate, isobutylammonium isobutylamine decanoate, tert-butylammonium tributylammoniumcarboxylate, 2-ethylhexylamine 2-ethylhexylaminocarbamate , octadecyl decanoic acid 18-record, 2-methoxyethyl carbamic acid 2-methoxyethyl ammonium, 2-cyanoethyl carbamic acid 2-cyanoethyl ammonium, dibutylamino carboxylic acid Dibutyladecylammonium dioctadecylcarbamate, methyl mercaptocarbamic acid decyl decyl ammonium, hexamethylene sulfoxide hexamethylene sulfoxide Morpholinamide morpholinium decanoate, pyridinium ethylhexylaminocarbamate, triamethylene methionine isopropylaminocarbamate, benzyl ammonium benzyl carbazate, and triethoxy propyl propyl Amino ruthenium decyl ammonium amide; and the ammonium carbonate-based compound is selected from at least one of the group consisting of ethyl ammonium ethyl carbonate and different Isopropyl propyl carbonate, n-butyl butyl butyl carbonate, isobutyl ammonium isobutyl hydride, tert-butyl ammonium tert-butyl carbonate, 2-ethylhexylammonium 2-ethylhexyl carbonate, 2-methoxyethylammonium 2-methoxyethylammonium, 2-cyanoethyl carbonate 2-cyanoethyl carbonate, octadecyl carbonate 18-base, dibutyl carbonate dibutyl, two Dioctadecylammonium dioctadecylcarbonate, methyl decyl ammonium decyl sulfonate, hexamethylene imide ammonium hexamethylene imide, morpholinium carbonate morpholine, benzene Benzoyl ammonium carbonate, triethoxy propyl propyl triethoxy propyl propyl ammonium, isopropyl ethylene diamethylene diammonium, hydrogen isopropyl ammonium carbonate, hydrogen carbonate third butyl ammonium, carbonic acid 2-ethylhexylammonium hydrogenate, 2-methoxyethylammonium hydrogencarbonate, 2-cyanoethyl carbonate hydrogencarbonate, dioctadecylammonium bicarbonate, hydrogencarbonate pyridine, hydrogencarbonate Ethylene diammonium and the aforementioned derivatives. 77 1326297 8. The conductive ink composition according to claim 1, wherein the additive is selected from at least one of the group consisting of a conductor, a metal precursor, an oxidizing agent, a stabilizer, a solvent, a dispersing agent, an adhesive resin, and a reduction. Agents, surfactants, wetting agents, thixotropic agents, and leveling agents. 9. The conductive ink composition of claim 8, wherein the conductive system is selected from at least one of the group consisting of at least one metal selected from the group consisting of silver, gold, copper, zinc, recorded, Drill, Ji, Shaft, Titanium, Hunger, Meng, Iron, Chromium, Wrong, Sharp, Tantalum, Tungsten, Tantalum, Braid, Group, Chain, Iron, Watch, Ming, Gallium, Germanium, Indium, Tin, Record, Wrong, Syrian, Peng, 铕, milk and 钍, the aforementioned alloy or alloy oxide, conductive carbon black, graphite, carbon nanotubes and conductive polymers. 10. The conductive ink composition according to claim 8, wherein the metal precursor is at least one metal compound represented by the following Chemical Formula 1: ΜηΧ (1) Μ is at least one metal selected from the group consisting of silver , gold, copper, zinc, nickel, cobalt, Ji, turn, Qin, Syria, Meng, iron, collateral, wrong, sharp, 锢, tungsten, 钌, money, group, chain, iron, silver, Ming, marry, wrong , indium, tin, ruthenium, smect, smear, smear, samarium, ytterbium and ytterbium or alloys of the foregoing; η is an integer from 1 to 10; and X is at least one substituent selected from the group consisting of hydrogen, ammonium, oxygen , sulfur, halogen, cyano, cyanate, carbonate, nitrate, nitrite, sulfate, phosphate, thiocyanate, oleate, perchlorate, tetrafluoroborate, acetoacetate, sulfhydryl, Indoleamines, alkoxides, carboxylates and derivatives thereof. The conductive ink composition according to claim 10, wherein the metal precursor is selected from at least one of the group consisting of gold acetate, silver acetate, palladium oxalate, 2-ethyl 78 1326297-based silver citrate, Copper 2-ethylhexanoate, iron stearate, nickel formate, zinc citrate, silver acetate, copper cyanide, cobalt carbonate, platinum gasification, tetra-gas gold acid, titanium tetrabutoxide, dichloride Methoxyquinone, aluminum isopropoxide, tin tetrafluoroborate, vanadium oxide, indium tin oxide, methanol button, barium acetate, dodecylphosphonate, and indium acetonate. The conductive ink composition according to claim 8, wherein the ink composition contains 1% by weight to 90% by weight of the conductor, the metal precursor or a mixture thereof per 1% by weight of the ink composition. 13. The conductive ink composition according to claim 8, wherein the guide vessel or the metal precursor is in a form selected from the group consisting of granules, powders, flakes, gels, hybrids, pastes. Form, sol, solution and combinations thereof. 14. The conductive ink composition of claim 8, wherein the guide or the metal precursor is a sphere, a straight line or a plane or a combination thereof. 15. The electroconductive ink composition according to claim 8, wherein the oxidizing agent is selected from at least one of the group consisting of an oxidizing gas, a peroxide, a peroxyacid, an oxidizing inorganic acid, and an oxidizing property. Metal compounds and oxidized non-metal compounds. 16. The conductive ink composition of claim 15, wherein the oxidizing agent is selected from at least one of the group consisting of: air, oxygen, ozone, hydrogen peroxide (h2〇2), Na202, k〇2 NaB〇3, K2S208, (NH4)2S2〇8, Na2S208, H2S05, khso5, (ch3)3co2h, (c6h5co2)2 'HC03H, CH3C03H, CF3C〇3H, C6H5C03H, m-ClC6H5C03H, nitric acid, sulfuric acid, I2, FeCl3 Fe(N〇3)3. Fe2(S04)3' K3Fe(CN)6. (NH4)2Fe(S04)2' Ce(NH4)4(s〇4)4, NaI04, KMn04 and K2Cr〇4. The conductive ink composition of claim 8, wherein the stabilizer is selected from at least one of the group consisting of: an amine compound, an ammonium compound, a phosphorus compound, a sulfur compound, and a mixture thereof. 18. The conductive ink composition of claim 17, wherein the amine compound is selected from at least one of the group consisting of a primary amine, a secondary amine, and a tertiary amine. 19. The conductive ink composition of claim 18, wherein the amine compound is selected from at least one of the group consisting of methylamine, ethylamine, n-propylamine, isopropylamine, n-butylamine, isobutylammonium, Isopentanamine, n-hexylamine, 2-ethylhexylamine, n-heptylamine, n-octylamine, isooctylamine, decylamine, decylamine, dodecylamine, hexadecylamine, octadecylamine, dodecaamine, cyclopropylamine, Cyclopentylamine, cyclohexylamine, allylamine, hydroxylamine, ammonium hydroxide, methoxyamine, 2-ethanolamine, methoxyethylamine, 2-hydroxypropylamine, methoxypropylamine, cyanoethylamine, ethoxyamine , n-butoxyamine, 2-hexyloxyamine, methoxyethoxyethylamine, decyloxyethoxyethoxyethylamine, diethylamine, dipropylamine, diethanolamine, hexamethyleneimine, 】, 底琳, 派, ethylenediamine, propylenediamine, hexamethylenediamine, triethylenediamine, 2,2-(ethylenedioxy)diethylamine, triethylamine, triethanolamine, pyrrole , imidazole, pyridine, aminoacetaldehyde dimethyl acetal, 3-aminopropyltrimethoxydecane, 3-aminopropyltriethoxydecane, aniline, methoxyaniline, amine Carbonitrile benzene, benzene Yue, polyallylamine, polyethyleneimine, and derivatives of the foregoing. 20. The conductive ink composition of claim 17, wherein the phosphorus compound is selected from at least one of the group consisting of phosphines and phosphites. The conductive ink composition according to claim 8, wherein the adhesive resin is selected from at least one of the group consisting of acrylic resin, cellulose resin, polyester resin, polyamide resin, and polyether resin. , vinyl resin, polyurethane resin, urea 80 1326297 resin, alkyd resin, polyoxyn resin, fluorinated resin, olefin resin, petroleum resin, rosin resin, epoxy resin, unsaturated polyester resin, ethylene Base polyester resin, diallylphthalate resin, phenol resin, oxetane resin, oxazine resin, bismaleimide resin, Modified polyoxynized resin, melamine resin, acrylic resin, rubber, natural polymer, glass resin and glass frit. The conductive ink composition according to claim 8, wherein the reducing agent is at least one selected from the group consisting of a reducing amine compound, a metal salt, and an organic compound. 23. The conductive ink composition of claim 22, wherein the reducing amine compound is selected from at least one of the group consisting of hydrazine, acetate hydrazide, sodium borohydride or potassium borohydride , trisodium citrate, methyl diethanolamine, and dimethylamine borane; and the organic compound is selected from at least one of the group consisting of hydrogen, hydrogen iodide, carbon monoxide, formaldehyde, acetaldehyde, glucose, ascorbic acid , salicylic acid, tannic acid, pyrogallol and chlorinated. 24. The conductive ink composition according to claim 8, wherein the solvent is selected from at least one of the group consisting of water, alcohols, glycols, acetates, ethers, and brews, Aromatic solvents and toothed hydrocarbons. 25. The conductive ink composition of claim 24, wherein the solvent is selected from the group consisting of: at least one of: water, methanol, ethanol, isopropanol, 1-methoxypropanol, butanol , ethylhexanol, terpineol, ethylene glycol, glycerol, ethyl acetate, 81 V / 1326297, Butyl acetate, methoxypropyl acetate, carbit〇l acetate, ethylcarbitol acetate, methylcellosolve, butyl soluble fiber Sword (butylcellosolve), diethyl ether, tetrahydrofuran, dioxane, methyl ethyl ketone, acetone, dimethylamylamine, 1-methyl-2- 0 洛洛烧钢, 烧烧, 庚烧,十二烧, 石堪油, mineral spirit, benzene, toluene, xylene, tri-gas methane, di-halogen methane, tetra-carbonized carbon, acetonitrile and Dimethyl sulfoxide. 26. The conductive ink composition according to claim 1, which is obtained by at least one selected from the group consisting of heating, cooling, electrolysis, ultrasonic, microwave treatment, high frequency treatment, plasma Processing, IR processing, and UV processing. 27. The conductive ink composition according to any one of claims 1 to 26, wherein at least one selected from the group consisting of the following is prepared by preparing at least one compound represented by Chemical Formula 2, Chemical Formula 3 or Chemical Formula 4 The components are prepared by combining carbon dioxide with an amine compound. Nitric oxide, sulfur dioxide, carbon dioxide, acid, and boron acid. 28. A method of preparing a metal-containing film, comprising the steps of: coating a conductive ink composition according to any one of claims 27 to 27, and subjecting it to oxidation, reduction, heat treatment, 111 treatment, UV treatment 'Electron beam processing or laser processing. 29. A method of preparing a metal-containing film according to claim 28, wherein the oxime is formed by coating on a ruthenium. 3. The method of preparing a metal-containing film according to claim 29, wherein the substrate is selected from the group consisting of: metal, glass, germanium wafer, ceramic, polyester, 82 1326297. Imine, rubber sheet, fiber, wood and paper. 31. A method of making a metal-containing film according to claim 29, wherein the substrate is pretreated prior to use. 32. The method of preparing a metal-containing film according to claim 31, wherein the pretreatment is performed by at least one selected from the group consisting of: plasma treatment, ion beam treatment, corona treatment, oxidation, or Reduction, heating, etching, UV treatment, and primer treatment. 33. A method of preparing a metal-containing film according to claim 28 or 32, wherein the heat treatment is carried out under air, nitrogen, argon, carbon monoxide, hydrogen or a mixture thereof. The method of producing a metal-containing film according to claim 28, wherein the heat treatment is carried out at a temperature ranging from 80 °C to 300 °C. 35. The method of preparing a metal-containing film according to claim 28, wherein the heat treatment is performed at 80 ° C to 150 ° C for 1 minute to 30 minutes, followed by treatment at 150 ° C to 300 ° C for 1 minute. It takes 30 minutes to proceed. 36. The method of preparing a metal-containing film according to claim 28, wherein the method is performed by spin coating, roller coating, spray coating, dip coating, leaching coating or doctor blade coating. Coating. 37. A method of preparing a metal-containing film according to claim 28, wherein by dispensing, ink jet printing, lithography, screen printing, transfer printing, flexographic printing, offset printing, stereotyping This coating is carried out by printing, stamping, xerographic or lithographic printing. 38. The method of preparing a metal-containing film according to claim 28, wherein the coating is performed by dissolving the conductive ink composition in at least one solvent selected from the group consisting of 83 1326297 39. : water, alcohols, glycols, acetates, ethers, anthraquinones, aliphatic hydrocarbons, aromatic hydrocarbons, and halogenated hydrocarbons. The method of preparing a metal-containing film according to claim 38, wherein the solvent is selected from at least one of the group consisting of water, methanol, ethanol, isopropanol, decyloxypropanol, butanol, Ethylhexanol, terpineol, ethylene glycol, glycerin, ethyl acetate, butyl acetate, methoxypropyl acetate, diethylene glycol diethyl ether acetate, ethyl diethylene glycol diethyl ether acetate, methyl Solvent, butyl cellosolve, diethyl ether, tetrahydrofuran, dioxane, methyl ethyl ketone, acetone, dimethyl decylamine, 1-methyl-2-pyrrolidone, hexane, heptane, Dodecane, paraffin oil, mineral spirits, benzene, toluene, xylene, tri-gas methane, dichloromethane, tetra-carbonized carbon, acetonitrile and dimethyl sulfoxide. 84