KR102310352B1 - Production method of silver particles and carbon nano material composite using Couette-Taylor reactor - Google Patents

Abstract

The present invention comprises: an outer cylinder, an inner cylinder installed along the same axis as the outer cylinder, and a motor for rotationally driving the inner cylinder; In the method for producing a silver particle and carbon nanomaterial composite using a Couette-Taylor reactor including an inlet and an outlet connected to the external cylinder, the carbon nanomaterial is surface-modified to introduce a functional group into the conductive carbon nanomaterial. making; introducing a functional group capable of reacting with a silver salt precursor into the carbon nanomaterial by mixing the surface-modified carbon nanomaterial with an isocyanate-based compound and a pyrimidine-based compound; injecting the carbon nanomaterial into which the functional group is introduced together with a solvent into the inlet of the Couet-Taylor reactor; injecting the silver salt precursor together with a solvent into the inlet at a constant speed while rotating the inner cylinder; Injecting a reducing agent into the inlet at a constant speed, and forming a Kuwet-Taylor flow through the rotational driving of the inner cylinder to form silver particles of a uniform diameter. Thereby, it is possible to obtain the effect that the carbon nanomaterial, the silver precursor, and the reducing agent are synthesized into silver particles having a uniform diameter by the Kuett-Taylor flow.

Description

{Production method of silver particles and carbon nano material composite using Couette-Taylor reactor}

The present invention relates to a method for manufacturing a composite of silver particles and carbon nanomaterials using a Quett-Taylor reactor, and more particularly, to a method for manufacturing a composite of silver particles and carbon nanomaterials, and more particularly, injecting carbon nanomaterials and silver precursors into a Quett-Taylor reactor and uniformly using a Quett-Taylor flow It relates to a method for manufacturing a composite of silver particles and carbon nanomaterials using a Kuett-Taylor reactor for synthesizing silver of one particle size.

In general, conductive carbon nanomaterials such as carbon nanotubes, graphene, and carbon fiber are transparent electrodes, antistatic, electromagnetic wave shielding, energy generation and storage electrode materials, heat dissipation materials, It can be applied to various fields such as polymer composites, metal composites, ceramic composites, and conductive fibers. In order to coat these conductive carbon nanomaterials or to manufacture them in the form of fibers, a coating solution or spinning dope in the form of a dilute solution or high-viscosity paste is required.

In general, in order to prepare a coating solution or paste, a dispersant such as a surfactant, a copolymer polymer, or an ionic liquid is essentially used. Of course, when a functional group is excessively introduced to the surface of the material, dispersion is easy, but a problem of lack of conductivity occurs.

Therefore, when manufacturing a conductive coating solution or paste using a conductive carbon nanomaterial while maintaining conductivity without using a dispersant, it is possible to reduce cost and simplify the process. In addition, since a dispersant is not required, it has the advantage that it can be combined with various binder materials, metals, and metal oxides.

In order to improve the electrical conductivity of such carbon nanomaterials, recently, techniques for introducing metal particles have been reported. Among them, 'Korea Intellectual Property Office Registration Patent No. 10-1410854' introduces a functional group capable of multiple hydrogen bonding to a conductive carbon nanomaterial to form a carbon nanomaterial having a higher order structure by multiple hydrogen bonding between carbon nanomaterials, and the higher order It is a highly conductive material formed by hybridizing a carbon nanomaterial having a higher-order structure and a metal nanomaterial by multiple hydrogen bonding, characterized in that a composite material is formed by simply mixing a carbon nanomaterial having a structure and a metal nanomaterial. However, although this prior art has excellent dispersibility, there is a problem in that the expression of excellent metal properties is rather insignificant because they are individually distributed by the bonding force of the carbon nanomaterial and the metal nanomaterial used as the material.

As another prior art, 'Korean Patent Office Laid-Open Patent Publication No. 10-2009-0117195, a method for manufacturing a carbon nanotube nanocomposite decorated with silver nanoparticles' is introduced. This prior art comprises a first step of making a carbon nanotube dispersion in which a carbon tube is dispersed in an organic solvent; a second step of adhering the silver nanoparticles to the surface of the carbon nanotubes by mixing the carbon nanotube dispersion with a solution containing ions; A third step of applying a centrifugal separation and washing process to the result of the second step; consists of a step of providing. However, in this prior art, a complex of carbon nanotubes is formed by reducing silver ions to silver particles in the presence of carbon nanotubes. It is not easy to apply to a conductive electrode. In addition, since the silver particles are introduced into the functional group of the carbon nanotube, the dispersibility of the composite in the solvent is significantly reduced after the introduction of the silver particles, so there is a problem that a separate dispersing agent must be used.

Accordingly, an object of the present invention is to provide a method for manufacturing a composite of silver particles and carbon nanomaterials using a Couett-Taylor reactor in which a carbon nanomaterial, a silver precursor, and a reducing agent are synthesized into silver particles of a uniform diameter by a Cuett-Taylor flow. will be.

The above object includes: an outer cylinder, an inner cylinder installed along the same axis as the outer cylinder, and a motor for enabling rotational driving of the inner cylinder; In the method for producing a silver particle and carbon nanomaterial composite using a Couette-Taylor reactor including an inlet and an outlet connected to the external cylinder, the carbon nanomaterial is surface-modified to introduce a functional group into the conductive carbon nanomaterial. making; introducing a functional group capable of reacting with a silver salt precursor into the carbon nanomaterial by mixing the surface-modified carbon nanomaterial with an isocyanate-based compound and a pyrimidine-based compound; injecting the carbon nanomaterial into which the functional group is introduced together with a solvent into the inlet of the Couet-Taylor reactor; injecting the silver salt precursor together with a solvent into the inlet at a constant speed while rotating the inner cylinder; Injecting a reducing agent into the inlet at a constant speed, and forming a Kuwet-Taylor flow through rotational driving of the inner cylinder to form silver particles of uniform diameter Kuett-Taylor reactor It is achieved by a method for manufacturing a composite using silver particles and carbon nanomaterials.

Here, after the step of forming the silver particles having a uniform diameter, it is preferable to further include the step of stopping the rotational driving of the inner cylinder to obtain the silver particles and the carbon nanomaterial composite from the outlet.

In addition, the step of surface-modifying the carbon nanomaterial may include: introducing a solution in which the carbon nanomaterial and the oxidizing agent are mixed into a surface treatment reactor under subcritical water or supercritical water conditions; a step of forming a carbon oxide nanomaterial by reacting the carbon nanomaterial with the oxidizing agent, or immersing the carbon nanomaterial in a strong acid and heating and stirring; preparing a diluted solution obtained by diluting the strong acid by adding water or distilled water to the strong acid; It is preferable to include the step of filtering the carbon nanomaterial from the diluent.

According to the above-described configuration of the present invention, it is possible to obtain the effect of synthesizing the carbon nanomaterial, the silver precursor, and the reducing agent into silver particles having a uniform diameter by the Kuet-Taylor flow.

1 is a cross-sectional view of a Kuett-Taylor reactor;
2 is a flowchart of a method for manufacturing a silver particle/carbon nanomaterial composite according to an embodiment of the present invention;
3 and 4 are SEM photographs of silver particle/carbon nanomaterial composites according to Examples and Comparative Examples.

Hereinafter, a method for manufacturing a composite of silver particles and carbon nanomaterials using a Kuet-Taylor reactor according to an embodiment of the present invention will be described in detail with reference to the drawings.

As shown in FIG. 1, the Couette-Taylor reactor 10 used to synthesize the silver particle/carbon nanomaterial composite is a device that causes a reaction by forming a vortex flow therein, The outer cylinder 11, the inner cylinder 13 installed along the same axis as the outer cylinder 11, the motor 15 for rotating the inner cylinder 13, the inlet 17 and the outlet connected to the outer cylinder 11 (19). The outer cylinder 11 is in a stationary state, and the inner cylinder 13 is rotated by a motor 15 connected to the inner cylinder 13 to enable the rotational driving of the inner cylinder 13, and the vortex flow by rotational driving this is formed Here, when carbon nanomaterial, silver precursor and reducing agent are injected into the inlet 17, silver particles having a uniform particle size are synthesized in the carbon nanomaterial, and the synthesized silver particle/carbon nanomaterial composite is passed through the outlet 19. can be obtained

When explaining this synthesis process in more detail, first, as shown in FIG. 2, the carbon nanomaterial is surface-modified (S1).

The carbon nanomaterial is surface-modified to introduce a functional group that reacts with the silver precursor to the carbon nanomaterial. The step of surface-modifying the carbon nanomaterial uses a different method depending on the type of the carbon nanomaterial. Here, the carbon nano material is selected from the group consisting of graphene, carbon nano tuber, carbon fiber, carbon black, and mixtures thereof.

For example, in the case of surface modification of graphene, the Hummus method is used. The Hummus method is made by injecting graphene into a vacuum chamber in which a vacuum atmosphere is formed, and injecting oxygen gas thereto. When a vacuum chamber containing oxygen gas is heated to dissociate molecules of oxygen gas into atoms, oxygen atoms and graphene react to form carbon oxide nanomaterials. Thereafter, graphene oxide into which a carboxyl group is introduced is obtained through freeze-drying. That is, graphene oxide surface-modified with a carboxyl group is obtained.

As another method, when surface-modifying carbon fiber, the carbon fiber is immersed in a strong acid and stirred while heating to surface-modify the carbon fiber, and after surface modification, water or distilled water is added to the strong acid to dilute the strong acid to prepare a diluent. do. Thereafter, the carbon fibers are filtered from the diluent through a filter paper to obtain surface-modified carbon fibers. Here, the strong acid is preferably selected from the group consisting of hydrochloric acid (HCl), sulfuric acid (H ₂ SO ₄ ), nitric acid (HNO ₃ ), phosphoric acid (P ₂ O _{3 ), and mixtures thereof.}

A functional group is introduced into the carbon nanomaterial (S2).

In step S1, a functional group capable of reacting with the silver precursor is introduced into the surface-modified carbon nanomaterial. The functional group is introduced into the carbon nanomaterial by dispersing the carbon nanomaterial in a solvent, mixing the isocyanate-based compound, and heating and stirring to introduce the isocyanate group into the carbon nanomaterial. After adding a pyrimidine-based compound to this, a functional group is introduced in such a way that the conjugation reaction proceeds by heating and stirring.

Here, the isocyanate-based compound is ethylene diisocyanate, 1,4-tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate (HDI), 1,12-dodecane diisocyanate, cyclobutane-1,3-diisocyanate, Cyclohexane-1,3-diisocyanate, cyclohexane-1,4-diisocyanate, 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethyl-cyclohexane, 2,4 - Hexahydrotoluene diisocyanate, 2,6-hexahydrotoluene diisocyanate, hexahydro-1,3-phenylene diisocyanate, hexahydro-1,4-phenylene diisocyanate, perhydro-2,4'- Diphenylmethane diisocyanate, perhydro-4,4'-diphenylmethane diisocyanate, 1,3-phenylene diisocyanate, 1,4-phenylene diisocyanate, 1,4-durol diisocyanate (DDI), 4 ,4'-stilbene diisocyanate, 3,3'-dimethyl-4,4'-biphenylene diisocyanate (TODI), toluene 2,4-diisocyanate, toluene 2,6-diisocyanate (TDI), di Phenylmethane-2,4'-diisocyanate (MDI), 2,2'-diphenylmethane diisocyanate (MDI), diphenylmethane-4,4'-diisocyanate (MDI) and naphthylene-1,5- Isocyanate (NDI), 2,2-methylenediphenyl diisocyanate, 5,7-diisocyanatonaphthalene-1,4-dione, isophorone diisocyanate, m-xylene diisocyanate, 3,3-dimethoxy-4, 4-biphenylene diisocyanate, 3,3-dimethoxybenzidine-4,4-diisocyanate, toluene 2,4-diisocyanate poly (propylene glycol) with end groups, toluene 2,4-diisocyanate poly with end groups (ethylene glycol), triphenylmethane triisocyanate, diphenylmethane triisocyanate, butane-1,2,2-triisocyanate, trimethylolpropantoylene didisocyanate trimer, 2,4,4-diphenyl ether triisocyanate, Isocyanurates with multiple hexamethylene diisocyanates, iminooxadiazines with multiple hexamethylene diisocyanates, polymethylene polyphenyl isocyanates It is preferably selected from the group consisting of tallow and mixtures thereof.

In addition, pyrimidine-based compounds include 2-amino-6-methyl-1H-pyrido[2,3-d]pyrimidin-4-one, 2-amino-6-bromopyrido[2,3-d]pyridine -4(3H)-one, 2-amino-4-hydroxy-5-pyrimidinecarobonic acid ethyl ester, 2-amino-6-ethyl-4-hydroxypyrimidine, 2-amino-4-hydroxy It is preferably selected from the group consisting of -6-methyl pyrimidine, 2-amino-5,6-dimethyl-4-hydroxypyrimidine and mixtures thereof.

The carbon nanomaterial into which the functional group is introduced is injected into the Couette-Taylor reactor (S3).

After mixing the carbon nanomaterial into which the functional group is introduced through step S2 with the solvent, it is injected into the outer cylinder 11 through the injection hole 17 formed in the Couet-Tayler reactor 10 . At this time, a metering pump is used to inject the carbon nanomaterial into the outer cylinder 11 at a constant speed and amount.

The silver salt precursor is injected into the inlet and mixed (S4).

The silver salt precursor is injected together with the solvent through the injection hole 17 into the outer cylinder 11 into which the functional group is introduced into the carbon nanomaterial. When injecting the silver salt precursor, as in step S3, it is injected at a constant speed and amount through a metering pump so that it is uniformly mixed with the carbon nanomaterial. At this time, the silver salt precursor is injected while rotationally driving the inner cylinder 13 using the motor 15 . When the inner cylinder 13 is rotated in this way, the vortex is located between the outer cylinder 11 and the inner cylinder 13 . A flow is formed so that the carbon nanomaterial and the silver salt precursor are more uniformly mixed.

Here, the silver salt precursor is silver _{nitride (AgNO 3} ), silver perchlorate (AgClO ₄ ), silver tetrafluoroborate (AgBF ₄ ), silver hexafluorophosphate (AgPF ₆ ), silver acetate (CH ₃ COOAg), silver tree It is preferably selected from the group consisting of fluoromethanesulfonate (AgCF ₃ SO ₃ ), silver sulfate (Ag ₂ SO ₄ ), silver 2,4-pentanedionate (CH ₃ COCH=COCH _{3 Ag) and mixtures thereof.}

A reducing agent is injected to form silver particles of uniform diameter (S5).

By rotating the inner cylinder 13 of the Couet-Taylor reactor 10, a reducing agent is injected into the outer cylinder 11 in a state in which a vortex flow is formed, using a metering pump, into the inlet 17 at a constant speed and amount. When a reducing agent is injected in a state in which the carbon nanomaterial and the silver salt precursor are present, the carbon nanomaterial and the silver salt precursor react to synthesize silver particles in the carbon nanomaterial. At this time, when the rotational speed of the inner cylinder 13 increases, the fluid becomes unstable due to the tendency of the inner fluids to go out in the direction of the outer cylinder 11, and a Taylor vortex is formed above a certain critical speed. Taylor vortices are arranged in a very regular ring shape in the axial direction, and because they rotate in opposite directions, they do not mix in the axial direction, leading to uniform synthesis. That is, when the reducing agent is constantly injected in a state in which the vortex flow is formed, the synthesized silver particles are synthesized to have a uniform diameter by the vortex flow. are synthesized

Here, the reducing agent is sodium hydroxide (NaOH), potassium hydroxide (KOH), ammonium hydroxide (NH ₄ OH), sodium borohydride (NaBH ₄ ), hydrazine (N ₂ H ₄ ), hydriodine (HI), ascorbic acid ( Ascorbic acid), a reducing organic solvent, and a mixture thereof are preferably selected.

In some cases, in the step of forming silver particles, copper chloride (CuCl ₂ ), a citrate compound, an imidazole compound, a conductive polymer, a polyacrylate derivative, and a mixture thereof selected from the group consisting of It is also possible to carry out a synthesis reaction by adding them together.

A silver particle/carbon nanomaterial composite is obtained (S6).

When the synthesis of the silver particles is completed, the rotational driving of the inner cylinder 13 is stopped to obtain the silver particle/carbon nanomaterial composite from the outlet 19 . In the silver particle/carbon nanomaterial composite obtained through these steps, silver particles are uniformly synthesized on the surface of the carbon nanomaterial.

Hereinafter, embodiments of the present invention will be described in more detail.

<Example 1>

As a first embodiment of the present invention, a functional group capable of interacting with silver ions or silver particles is introduced into graphene, and the functional group-introduced graphene and silver particle precursor are injected into the Couette-Taylor reactor to apply shear stress to the solution. It relates to a manufacturing method for inducing the synthesis of silver particles in a uniformly dispersed state of particles by adding them.

First, 10 g of graphite is prepared as graphite oxide by the Hummus method, and then it is peeled off in an aqueous solution to prepare graphene oxide. Graphene oxide powder into which a carboxyl group (-COOH) was introduced was prepared by freeze-drying graphene oxide. After dispersing graphene oxide into which a carboxyl group is introduced at 100 mg/L in a dimethylformamide solvent, toluene diisocyanate is mixed and reacted in a manner of stirring at 100° C. for 12 hours to form an isocyanate group. introduce

Thereafter, 2-amino-4-hydroxy-6-methyl-pyrimidine was mixed with graphene oxide into which an isocyanate group was introduced, and the mixture was stirred at 100° C. for 20 hours to bond. In such a way that the reaction proceeds, 2-ureido-4[1H]pyrimidinone having a quadruple hydrogen bond (2-Ureido-4[1H]ptrimidone) is introduced.

The functional group-introduced graphene oxide is dispersed in a dimethylformamide solvent at 2 g/L, and this is injected into the Couette-Taylor reactor using a metering pump. Here, a solution of silver nitride (AgNO ₃ ) dissolved in dimethylformamide at 0.05 mol/L was injected into the reactor over 5 minutes using a metering pump. Then, 0.1 mol/L of a hydrazine reducing agent solution was injected with a metering pump over 10 minutes and stirred at room temperature for 1 hour to prepare a composite material in which graphene and silver particles were complexed. In this way, when using the Quett-Taylor reactor, it is possible to obtain more uniform silver particles than the reaction using a general stirrer.

<Example 2>

In the second embodiment of the present invention, carbon fiber was used as a carbon nano material.

First, 10 g of carbon fiber is prepared. 10 g of the prepared carbon fiber was added to 200 ml of a sulfuric acid: nitric acid mixture having a volume ratio of 7:3, heated to 80° C., stirred for 24 hours, and then cooled to room temperature. Then, add 800 ml distilled water to dilute the mixture. After removing the acid solution remaining on the carbon fiber through filtration 4 or more times using filter paper, the diluted mixed solution is dried to prepare a carbon fiber having a carboxyl group (-COOH) introduced therein.

After dispersing the carbon fiber introduced with the carboxyl group at 100 mg/L in a dimethylformamide solvent, toluene diisocyanate is mixed and reacted by stirring at 100° C. for 12 hours to introduce an isocyanate group. Then, 2-amino-4-hydroxy-6-methyl pyrimidine is mixed with the carbon fiber into which the isocyanate group is introduced and stirred at 100° C. for 20 hours to proceed with the conjugation reaction. Figure-4 [1H]pyrimidinone (2-Ureido-4[1H]ptrimidone) is introduced.

The carbon fiber introduced with the functional group is dispersed in a dimethylformamide solvent at 2 g/L, and this is injected into the Couette-Taylor reactor using a metering pump. Here, a solution of silver nitride (AgNO ₃ ) dissolved in dimethylformamide at 0.05 mol/L was injected into the reactor over 5 minutes using a metering pump. Then, a 0.1 mol/L hydrazine reducing agent solution was injected with a metering pump over 10 minutes and stirred at room temperature for 1 hour to prepare a composite material in which carbon fibers and silver particles were composited. In this way, when using the Quett-Taylor reactor, it is possible to obtain silver particles having a uniform size than the reaction using a general stirrer.

<Comparative Example 1>

As a first comparative example of the present invention, a composite of carbon nanomaterials and silver particles is prepared by using a general stirrer in a general glass reactor without using a Quett-Taylor reactor.

Prepare a graphene oxide dispersion into which a functional group is introduced in the same manner as in Example 1, prepare a silver salt reaction solution with 0.05 mol/L of silver nitride in dimethylformamide, and mix it with the graphene oxide dispersion, and then use a magnetic stirrer rod ( While stirring with a magnetic bar) and a stirrer, hydrazine was added thereto as a reducing agent, and a graphene oxide/silver particle composite was prepared by stirring at room temperature for 1 hour.

<Comparative Example 2>

As a second comparative example of the present invention, using a mixed acid consisting of sulfuric acid/nitric acid, only carboxyl groups were introduced into carbon fibers, added to a silver salt mixture of 0.05 mol/L at a concentration of 2 g/L, and hydrazine was added as a reducing agent at 100° C. A carbon fiber/silver particle composite was prepared by stirring through a magnetic stirrer rod and a stirrer for 1 hour.

3 is an SEM photograph showing the graphene/silver particle composite synthesized from Example 1 and Comparative Example 1, and FIG. 3a is the graphene/silver particle composite of Comparative Example 1, in which silver particles are not uniform and are not dispersed but agglomerated. can confirm that there is In contrast, FIG. 3b shows that the graphene/silver particle composite synthesized using Quett-Taylor has uniform silver particles and does not agglomerate with each other and maintains a certain interval.

4 is an SEM photograph showing the carbon fiber/silver particle composite synthesized from Example 2 and Comparative Example 2, and FIG. 4a is the carbon fiber/silver particle composite of Comparative Example 2, confirming that the silver particles are not formed with a constant diameter. can In contrast, in FIG. 4b , it can be seen that the silver particles are formed very uniformly with the carbon fiber/silver particle composite synthesized using Quett-Taylor.

Conventionally, synthesis was performed using a general stirrer and a synthesis method to form silver particles. However, when the conventional method is used, the diameters of the silver particles are not uniformly formed and there is a problem in that they are agglomerated. However, in the present invention, since silver particles are synthesized using a vortex flow using the Kuett-Taylor reactor 10, the silver particles are formed to have a very uniform diameter, and are formed to maintain a certain interval without agglomeration. can be checked

10: Couet-Taylor Reactor
11: Outer cylinder
13: inner cylinder
15: motor
17: inlet
19: outlet

Claims (9)

an outer cylinder, an inner cylinder installed along the same axis as the outer cylinder, and a motor for rotationally driving the inner cylinder; In the method for producing a composite of silver particles and carbon nanomaterials using a Kuet-Taylor reactor including an inlet and an outlet connected to the external cylinder,
surface-modifying the carbon nanomaterial to introduce a functional group into the conductive carbon nanomaterial;
introducing a functional group capable of reacting with a silver salt precursor into the carbon nanomaterial by mixing the surface-modified carbon nanomaterial with an isocyanate-based compound and a pyrimidine-based compound;
injecting the carbon nanomaterial into which the functional group is introduced together with a solvent into the inlet of the Couet-Taylor reactor;
injecting the silver salt precursor together with a solvent into the injection hole at a constant speed while rotating the inner cylinder;
Injecting a reducing agent into the inlet at a constant speed, and forming a Kuwet-Taylor flow through rotational driving of the inner cylinder to form silver particles of a uniform diameter Kuett-Taylor reactor A method for manufacturing a composite using silver particles and carbon nanomaterials. The method of claim 1,
After the step of forming the silver particles of the uniform diameter,
The method for producing a silver particle and carbon nanomaterial composite using a Kuet-Tayler reactor, characterized in that it further comprises the step of stopping the rotational driving of the inner cylinder to obtain the silver particle and carbon nanomaterial composite from the outlet. The method of claim 1,
The step of surface-modifying the carbon nanomaterial,
introducing a solution in which the carbon nanomaterial and the oxidizing agent are mixed into a surface treatment reactor under subcritical water or supercritical water conditions;
A method for manufacturing a composite of silver particles and carbon nanomaterials using a Couette-Tayler reactor, characterized in that it comprises the step of forming a carbon oxide nanomaterial by reacting the carbon nanomaterial with the oxidizing agent. The method of claim 1,
The step of surface-modifying the carbon nanomaterial,
heating and stirring the carbon nanomaterial by immersing it in a strong acid;
preparing a diluted solution obtained by diluting the strong acid by adding water or distilled water to the strong acid;
A method for producing a composite of silver particles and carbon nanomaterials using a Kuet-Tayler reactor, comprising the step of filtering the carbon nanomaterial from the diluent. 5. The method of claim 4,
The strong acid is hydrochloric acid (HCl), sulfuric acid (H ₂ SO ₄ ), nitric acid (HNO ₃ ), phosphoric acid (P ₂ O ₃ ), characterized in that selected from the group consisting of, and mixtures thereof - Silver particles using a Taylor reactor and carbon nanomaterial composite manufacturing method. The method of claim 1,
The carbon nanomaterial is
Graphene, carbon nanotube (Carbon nano tuber), carbon fiber (Carbon fiber), carbon black (Carbon black), characterized in that selected from the group consisting of mixtures thereof - silver particles using a Taylor reactor and Carbon nanomaterial composite manufacturing method. The method of claim 1,
In the step of forming the silver particles of the uniform diameter,
Copper chloride (CuCl ₂ ), a citrate compound (Citrate compound), an imidazole compound (Imidazole compound), a conductive polymer, polyacrylic acid derivatives, and a mixture thereof, characterized in that the addition selected from the group consisting of a kuett-Taylor reactor A method for manufacturing a composite of silver particles and carbon nanomaterials using The method of claim 1,
The silver salt precursor is
Silver nitride (AgNO ₃ ), silver perchlorate (AgClO ₄ ), silver tetrafluoroborate (AgBF ₄ ), silver hexafluorophosphate (AgPF ₆ ), silver acetate (CH ₃ COOAg), silver trifluoromethanesulfonate (AgCF ₃ SO ₃ ), silver sulfate (Ag ₂ SO ₄ ), silver 2,4-pentanedionate (CH ₃ COCH=COCH ₃ Ag), and a mixture thereof, characterized in that selected from the group consisting of Kuett-Tayler reactor A method for manufacturing a composite of silver particles and carbon nanomaterials using The method of claim 1,
The reducing agent,
Sodium hydroxide (NaOH), potassium hydroxide (KOH), ammonium hydroxide (NH ₄ OH), sodium borohydride (NaBH ₄ ), hydrazine (N ₂ H ₄ ), hydriodine (HI), ascorbic acid (Ascorbic acid), A method for producing a composite of silver particles and carbon nanomaterials using a Kuet-Tayler reactor, characterized in that it is selected from the group consisting of a reducing organic solvent and a mixture thereof.

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