JPS63241864A - Electro-chemical cell - Google Patents
Electro-chemical cellInfo
- Publication number
- JPS63241864A JPS63241864A JP62076902A JP7690287A JPS63241864A JP S63241864 A JPS63241864 A JP S63241864A JP 62076902 A JP62076902 A JP 62076902A JP 7690287 A JP7690287 A JP 7690287A JP S63241864 A JPS63241864 A JP S63241864A
- Authority
- JP
- Japan
- Prior art keywords
- electrode
- battery
- negative electrode
- ion
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 3
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 3
- 229910052791 calcium Inorganic materials 0.000 claims abstract 2
- 229910052745 lead Inorganic materials 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 229910052738 indium Inorganic materials 0.000 claims description 3
- -1 AgCd Inorganic materials 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 229910052716 thallium Inorganic materials 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 229910052706 scandium Inorganic materials 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 15
- 229910001416 lithium ion Inorganic materials 0.000 abstract description 7
- 239000013078 crystal Substances 0.000 abstract description 5
- 238000007599 discharging Methods 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 230000010287 polarization Effects 0.000 abstract description 2
- 230000008021 deposition Effects 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 7
- 239000003792 electrolyte Substances 0.000 description 7
- 229910052744 lithium Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 4
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 4
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 241000251730 Chondrichthyes Species 0.000 description 1
- 229910018298 Cu2Mo6S8 Inorganic materials 0.000 description 1
- 102100030393 G-patch domain and KOW motifs-containing protein Human genes 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 1
- 229910001386 lithium phosphate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、リチウムイオン導伝性電解質を用いた電気化
学セル特に電池に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to electrochemical cells, particularly batteries, using lithium ion conductive electrolytes.
従来の技術
近年、リチウムを用いた二次電池の開発が広く行われて
いる。例えば、正極にＴ Ｉ Ｓ２を用い、負極にＬｌ
、電解質としてＬＩＣＩＯ４／プロピレンカーボネイト
を用いたものが提案された。BACKGROUND OF THE INVENTION In recent years, secondary batteries using lithium have been widely developed. For example, use TIS2 for the positive electrode and Ll for the negative electrode.
, one using LICIO4/propylene carbonate as the electrolyte was proposed.
発明が解決しようとする問題点
しかしながらこの電池は充放電を繰り返すと、負極にＬ
ｉの針状結晶が成長し充放電効率が悪く、負極と正極が
短絡しやすく比較的早期に電池容量の低下を起こすとい
う問題を有していた。Problems to be Solved by the Invention However, when this battery is repeatedly charged and discharged, L is generated at the negative electrode.
The problem was that the acicular crystals of i grew, resulting in poor charging and discharging efficiency, and the negative and positive electrodes were easily short-circuited, causing a relatively early reduction in battery capacity.
問題点を解決するための手段
電気化学セルの構成要素でちる電極として、Ｌ ｔｘＭ
、 Ｍｏ６Ｓ８−ｙ（ＭはＮａ 、Ｍｇ 、ＡＩ 、Ｃ
ａ 、Ｓｏ。Means for solving the problemAs a component of an electrochemical cell, L txM is used as an electrode.
, Mo6S8-y (M is Na, Mg, AI, C
a, So.
Ｍｎ、Ｆｅ、Ｃｏ、Ｎｉ、Ｃｕ、Ｚｎ、Ｇａ、Ｓｒ、Ｙ
、Ａｇ、Ｃｄ。Mn, Fe, Co, Ni, Cu, Zn, Ga, Sr, Y
, Ag, Cd.
Ｉｎ、Ｓｎ、Ｂａ、Ｌａ、Ｔｌ、Ｐｂより選ぶ元素、ｏ
＜ｘ＜１３．Ｏ≦ｙ≦０．５．０≦２≦４）で表わされ
る化合物を用いる。Element selected from In, Sn, Ba, La, Tl, Pb, o
<x<13. A compound represented by O≦y≦0.5.0≦2≦4) is used.
作 用
上記Ｌｉ８Ｍ、 Ｍ ｏ６Ｓ８−アで表わされる化合物
は、Ｍｏ６Ｓ８−７が作る三次元骨格の中をＬ１＋イオ
ンが自由に出入りする。この際結晶格子内におけるＬｉ
＋イオンの移動に必要なエネルギーは非常に小さく、し
たがってＴ極表面でのリチウムイオンの溶解析出反応も
極めて優れたものとなる。このため、リチウムの溶解析
出に際し電極表面におけるリチウムの針状結晶が成長し
にくくなる。以上の作用により上記化合物は、電極とし
ての可逆性が優れ、これを負極として用いた電気化学セ
ル例えば二次電池では、充放電の繰り返しによる容量低
下も非常に小さいものとなる。Function: In the compounds represented by Li8M and Mo6S8-a, L1+ ions freely move in and out of the three-dimensional skeleton formed by Mo6S8-7. At this time, Li in the crystal lattice
The energy required for the movement of + ions is very small, and therefore the dissolution and precipitation reaction of lithium ions on the T-electrode surface is also extremely excellent. This makes it difficult for needle-like crystals of lithium to grow on the electrode surface during dissolution precipitation of lithium. Due to the above effects, the above compound has excellent reversibility as an electrode, and in an electrochemical cell such as a secondary battery using this compound as a negative electrode, the capacity decrease due to repeated charging and discharging is extremely small.
実施例
第１図は本発明の一実施例の電気化学装置の断面図であ
る。１は正極であり二次電池として用いる場合具体的に
は、例えばＴ ｉ ８２ 、 Ｎｂ Ｓ２ 、 Ｍｏ
Ｓ ２ 。Embodiment FIG. 1 is a sectional view of an electrochemical device according to an embodiment of the present invention. 1 is a positive electrode, and when used as a secondary battery, specifically, for example, T i 82 , Nb S2 , Mo
S2.
ＭｎＯ２等の遷移金属の硫化物や硫化物や酸化物、また
は高表面積のカーボン等の電極を用いる。２はリチウム
イオン導電性電解質であり、Ｌｌｒ。An electrode made of sulfide, sulfide or oxide of a transition metal such as MnO2, or carbon with a high surface area is used. 2 is a lithium ion conductive electrolyte, Llr.
Ｌ Ｌ ｒ＋ＡＬ２０３ 、 Ｌ Ｌ ４８１０４−Ｌ
ｌ ３ＰＯ４％（Ｄ固体電解質や、プロピレンカーボ
ネイトに過塩素酸リチウムＬＬＣ１０４（１ｍｏｐ／ｌ
）を溶解させた電解液等が用いられる。３はＬ ｉｘＭ
ｚＭｏ６ ｓ８−アで表わされる負極である。４および
６は集電体であり、ステンレススチール、グラファイト
や貴金属など電気化学的に不活性な物質を用い、それぞ
れ正極及び負極の中にネット状の形で埋め込まれている
。L L r+AL203, L L 48104-L
l 3PO4% (D solid electrolyte, propylene carbonate with lithium perchlorate LLC104 (1 mop/l)
) is used. 3 is LixM
The negative electrode is represented by zMo6 s8-a. Current collectors 4 and 6 are made of electrochemically inactive materials such as stainless steel, graphite, and precious metals, and are embedded in the positive and negative electrodes in the form of a net, respectively.
６は密封ケースである。6 is a sealed case.
以上が単セルの構成であり、出力電圧は約２．８（Ｖ）
程度であり、必要な電圧を得るためには、複数の単セル
を導電性接着剤等、公知の手段で直列に接続すればよい
。The above is the configuration of a single cell, and the output voltage is approximately 2.8 (V)
In order to obtain the necessary voltage, a plurality of single cells may be connected in series using a known means such as a conductive adhesive.
次に化合物Ｌ ＬｘＭ２Ｍｏ６Ｓ８−アの作製方法を説
明する。Next, a method for producing the compound L LxM2Mo6S8-a will be explained.
まず始め、Ｍ２ Ｓ 、ＭＯＳ２ 、 Ｍｏの粉末を所
定量混合、プレス成型した後、石英ガラス管に真空封入
し、これを４００℃で１２時間、次いで１ｏＯｏ℃で２
４時間加熱し、Ｍ、Ｍｏ６Ｓ８−アを作製する。つぎに
上記Ｍ、Ｍｏ６Ｓ８−アとＬｉ板を、プロピレンカーボ
ネイトにＬｉｃｌｏ４（１ｍｏｐ／ｌ）を溶解した電解
液を用い、電解液中で一定電流を流すかあるいはＭ、Ｍ
ｏ６Ｓ８−アとＬｉ板とを電気的に短絡することにより
、Ｍ２Ｍｏ６ｓ８−７中にＬｉ＋をインターカレートシ
、Ｌ ｔ、ＭｚＭｏ６Ｓ８．を作製する。First, a predetermined amount of M2S, MOS2, and Mo powders were mixed and press-molded, then vacuum sealed in a quartz glass tube, heated at 400°C for 12 hours, and then heated at 100°C for 2 hours.
Heat for 4 hours to produce M, Mo6S8-a. Next, the above M, Mo6S8-A and the Li plate are subjected to an electrolytic solution in which Licro4 (1 mop/l) is dissolved in propylene carbonate, and a constant current is passed through the electrolytic solution or M, M
By electrically short-circuiting o6S8-A and the Li plate, Li+ is intercalated into M2Mo6s8-7, L t, MzMo6S8. Create.
以下、上記可逆性リチウム電極を二次電池の負極に適用
した例を説明する。Hereinafter, an example in which the above reversible lithium electrode is applied to a negative electrode of a secondary battery will be described.
〔実施例１〕
正極としては、Ｔ目〜 （２００■）の直径１０鵡の円
盤を用いた。負極としてＬ ｔ ６Ｃｕ ２Ｍｏ６Ｓ８
（２ｏｏｍｑ）の直径１０ｍの円盤を用い、電解質には
プロピレンカーボネイトにＬｉＣＬｉＣｌ０４（１／ｌ
）を溶解したものを用い、電池Ａを作製した。比較例と
して負極に金属リチウム（２ｏＯη）の直径１０ｒＥ！
Ｒの円盤を用いた以外は電池Ａと同一構成のものを電池
Ｂとする。[Example 1] As a positive electrode, a disk with a diameter of 10 mm and T-th (200 square meters) was used. L t 6Cu 2Mo6S8 as negative electrode
A disk with a diameter of 10 m (2oomq) was used, and the electrolyte was propylene carbonate and LiCLiCl04 (1/l
) was used to prepare battery A. As a comparative example, metal lithium (2oOη) with a diameter of 10rE was used as the negative electrode.
Battery B has the same configuration as battery A except that R disks are used.
第２図は、上記電池を１ ｍＡ／ｃｒＩｉの電流密度で
１時間の充放電サイクルを繰り返し行った時の各サイク
ルにおける放電終了時の閉路電圧を示したものであり、
横軸は充放電のサイクル数を示している。この図を見る
と分かるように、電池Ａは比較例の電池Ｂに較び充放電
サイクルを行った時の容量低下が著しく少なくなってい
る。FIG. 2 shows the closed circuit voltage at the end of discharge in each cycle when the battery was repeatedly charged and discharged for 1 hour at a current density of 1 mA/crIi,
The horizontal axis indicates the number of charge/discharge cycles. As can be seen from this figure, battery A exhibits significantly less capacity loss during charge/discharge cycles than battery B of the comparative example.
〔実施例２〕
次に上記可逆性リチウム電極となる化合物を二次電池の
正極および負極の双方に用いた実施例を示す。電解質に
はＬ１４３１０４−Ｌｉ３ＰＯ４（２００■）を用いた
。正極および負極として、Ｌｔ２Ｃｕ４Ｍｏ６Ｓ８（２
００＋１９）と前記固体電解質（３ｏｏｒＩｌｉ）との
混合物を用いた。上記材料を正極、電解質、負極の順で
３ ｔｏｎ／ｃＪのプレス圧で一体成型し、第１図に示
す構成の直径１０＋ｍのセルを作製した。このセルに対
して予め１ｏＯμＡ／ｃａの電流密度で充電を行い、上
記化合物Ｌ１２Ｃｕ４Ｍ０６Ｓ８が、正極ではＣｕ４Ｍ
ｏ６Ｓ８に、また負極ではＬ１４Ｃｕ４ＭＯ６Ｓ８にな
るようにし、電池Ｃを作製した。比較例として正極をＴ
ｉ５２（２００■）と前記固体電解質（３００■）の混
合物または負極を金属Ｌｉ（２００■）直径１ｏ■の円
盤で置き換えたものを電池りとする。[Example 2] Next, an example will be shown in which the compound serving as the reversible lithium electrode was used for both the positive electrode and the negative electrode of a secondary battery. L143104-Li3PO4 (200μ) was used as the electrolyte. Lt2Cu4Mo6S8 (2
A mixture of 00+19) and the solid electrolyte (3oorIli) was used. The above materials were integrally molded into a positive electrode, an electrolyte, and a negative electrode in this order at a press pressure of 3 ton/cJ to produce a cell having a diameter of 10+ m and having the configuration shown in FIG. 1. This cell was charged in advance at a current density of 1oOμA/ca, and the above compound L12Cu4M06S8 was charged to Cu4M at the positive electrode.
o6S8, and the negative electrode was L14Cu4MO6S8 to produce a battery C. As a comparative example, the positive electrode was
A battery is made of a mixture of i52 (200 sq.) and the solid electrolyte (300 sq.) or a battery in which the negative electrode is replaced with a disk of metal Li (200 sq.) having a diameter of 10 sq.
これらの電池を１０ｏμＡ／ｃａの電流密度で１時間の
充放電サイクルを行った時の、放電直後の電池電圧とサ
イクル数との関係を示したものが第３図である。この図
を見ると分かるように、本実施例の電池は比較例に較べ
、サイクル数の増化に伴う電池電圧の低下のきわめて小
さいサイクル寿命に優れた電池容量の著しく大きいもの
であるといえる。FIG. 3 shows the relationship between the battery voltage immediately after discharge and the number of cycles when these batteries were charged and discharged for 1 hour at a current density of 10 μA/ca. As can be seen from this figure, the battery of the present example can be said to have an excellent cycle life and a significantly larger battery capacity, with a very small drop in battery voltage as the number of cycles increases, compared to the comparative example.
〔実施例３〕
実施例１では負極としてＬｌ、Ｃｕ２Ｍｏ６Ｓ８を用い
た電池Ａを作製した。そこで本実施例３では社記化合物
中ＣｕをＡＩに置き換えた化合物Ｌｉ６Ａ１２Ｍ０６Ｓ
８を負極材料として用い、それ以外は電池Ａと同一構成
のものを作製、これを電池Ｅとする。[Example 3] In Example 1, a battery A was produced using Ll and Cu2Mo6S8 as the negative electrode. Therefore, in this Example 3, a compound Li6A12M06S in which Cu in the listed compound was replaced with AI was used.
A battery E was prepared using No. 8 as the negative electrode material, but otherwise having the same configuration as the battery A.
この電池Ｅに対し実施例１と同様１ｍＡ／ｃｒＡの電流
密度で１時間の充放電サイクルを行った。第２図を見る
と分かるように、１ｏ００サイクル目における初期電圧
からの電圧降下量は電池Ａではｏ、５（Ｖ）であったが
、電池Ｅにおいてもほぼ同様０．３１（Ｖ）であった。This battery E was subjected to a charge/discharge cycle for 1 hour at a current density of 1 mA/crA in the same manner as in Example 1. As can be seen from Figure 2, the voltage drop from the initial voltage at the 1000th cycle was o, 5 (V) for battery A, but it was almost the same for battery E, 0.31 (V). Ta.
つまシ、電池Ａと同様電池Ｅも優れた特性を示すと言え
る。It can be said that, like Battery A, Battery E also exhibits excellent characteristics.
以下、実施例４−８において、Ｌ ｔ６Ｍ２Ｍｏ６Ｓ８
で表わされる化合物のＭとして、Ｚｎ、Ｃｄ、Ｉｎ。Hereinafter, in Example 4-8, L t6M2Mo6S8
M of the compound represented by Zn, Cd, In.
Ｓｎ、Ｐｂを負極とする電池を作製、実施例３と同−余
件で１０００サイクル目における電圧降下量を測定した
。その結果を表１に示す。これを見ると分かるように、
各実施例の電池は電池Ａと同じくサイクル特性に優れた
ものであると言える。A battery using Sn and Pb as the negative electrode was prepared, and the voltage drop at the 1000th cycle was measured in the same manner as in Example 3. The results are shown in Table 1. As you can see,
It can be said that the batteries of each example have excellent cycle characteristics like battery A.
表 １
なお上記実施例ではＬ ｉ ｚ Ｍｚ Ｍｏ６８Ｂで表
わされる化合物において、ＭがＣｕ、Ａｌ、Ｚｎ、Ｃｄ
、Ｉｎ。Table 1 In the above example, in the compound represented by L i z Mz Mo68B, M is Cu, Al, Zn, Cd
, In.
Ｓｎ、Ｐｂを用いた例を示した。しかし、Ｌｉイオンが
ＭＯＳ ８Ｂ−アのつくる３次元骨格中を移動すること
により上記化合物は全て、可逆的にリチウムがインター
カレートするため、上記化合物中のＣｕが、特許請求の
範囲第１項に記載したＭ中の他の元素であっても、同様
に機能することは言うまでもない。An example using Sn and Pb was shown. However, in all of the above compounds, lithium intercalates reversibly as Li ions move through the three-dimensional skeleton created by MOS 8B-A, so Cu in the above compounds is It goes without saying that other elements in M described in 1 can function in the same manner.
発明の効果
以上のように、本発明の電気化学装置は、放電分極が小
さく、長寿命の二次電池等の電気化学装置の実現を可能
にするものである。Effects of the Invention As described above, the electrochemical device of the present invention makes it possible to realize an electrochemical device such as a secondary battery with small discharge polarization and long life.
第１図は本発明の電気化学装置の断面図、第２図−鼻会
１蕃丈母および第３図はその特性図である。
１・・・・・・正極、２・・・・・・電解質、３・・・
・・・負極、４・・・・・・正極集電体、６・・・・・
・負極集電体、ｅ・・・・・・密封ケース。
代理人の氏名 弁理士 中 尾 敏 男 ほか１名第１
図
Ａ−芙ｊ！例 ＬｉｓＣｕｚＭｏｂＳａナイクＡ／ｌｋ
（回）
ｃ ・−ｘｉ例 ＣＬＬ４Ｍｏ６Ｓｓ／ＬｔａＣｕｒｔ
Ｍｏ６Ｓ；ＩｔＯ−Ｃ鮫例 Ｔｉ５２／Ｌｔ
第 ３ 図
サイクＬ歓 （ｒＢ）FIG. 1 is a sectional view of the electrochemical device of the present invention, FIG. 2 is a sectional view of the electrochemical device, FIG. 2 is a characteristic diagram thereof, and FIG. 1... Positive electrode, 2... Electrolyte, 3...
...Negative electrode, 4...Positive electrode current collector, 6...
・Negative electrode current collector, e... Sealed case. Name of agent: Patent attorney Toshio Nakao and 1 other person No. 1
Figure A-Fuj! Example LisCuzMobSa Naik A/lk
(times) c ・-xi example CLL4Mo6Ss/LtaCurt
Mo6S; ItO-C shark example Ti52/Lt Figure 3 Cycle L Huan (rB)
Claims (2)
ａ、Ｍｇ、Ａｌ、Ｃａ、Ｓｃ、Ｍｎ、Ｆｅ、Ｃｏ、Ｎｉ
、Ｃｕ、Ｚｎ、Ｇａ、Ｓｒ、Ｙ、ＡｇＣｄ、Ｉｎ、Ｓｎ
、Ｂａ、Ｌａ、Ｔｌ、Ｐｂより選ぶ元素、０＜ｘ＜１３
、０≦ｙ≦０．５、０≦ｚ≦４）で表わされる化合物よ
りなる電極を構成要素とする電気化学セル。(1) Li_xM_zMo_6S_8_-_y (M is N
a, Mg, Al, Ca, Sc, Mn, Fe, Co, Ni
, Cu, Zn, Ga, Sr, Y, AgCd, In, Sn
, an element selected from Ba, La, Tl, Pb, 0<x<13
, 0≦y≦0.5, 0≦z≦4).
ことを特徴とする特許請求の範囲第１項記載の電気化学
セル。(2) The electrochemical cell according to claim 1, wherein the electrode is used as at least one of a positive electrode and a negative electrode.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62076902A JPH0821381B2 (en) | 1987-03-30 | 1987-03-30 | Electrochemical cell |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62076902A JPH0821381B2 (en) | 1987-03-30 | 1987-03-30 | Electrochemical cell |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63241864A true JPS63241864A (en) | 1988-10-07 |
| JPH0821381B2 JPH0821381B2 (en) | 1996-03-04 |
Family
ID=13618594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62076902A Expired - Fee Related JPH0821381B2 (en) | 1987-03-30 | 1987-03-30 | Electrochemical cell |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0821381B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105247715A (en) * | 2013-07-30 | 2016-01-13 | 株式会社Lg化学 | Negative electrode material for lithium ion secondary battery |
| JP2017041434A (en) * | 2015-06-05 | 2017-02-23 | ローベルト ボツシユ ゲゼルシヤフト ミツト ベシユレンクテル ハフツングＲｏｂｅｒｔ Ｂｏｓｃｈ Ｇｍｂｈ | Cathode material for lithium sulfur cell |
-
1987
- 1987-03-30 JP JP62076902A patent/JPH0821381B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105247715A (en) * | 2013-07-30 | 2016-01-13 | 株式会社Lg化学 | Negative electrode material for lithium ion secondary battery |
| JP2016518012A (en) * | 2013-07-30 | 2016-06-20 | エルジー・ケム・リミテッド | Positive electrode mixture for secondary battery containing irreversible additive |
| US10218002B2 (en) | 2013-07-30 | 2019-02-26 | Lg Chem, Ltd. | Positive electrode mix for secondary batteries including irreversible additive |
| JP2017041434A (en) * | 2015-06-05 | 2017-02-23 | ローベルト ボツシユ ゲゼルシヤフト ミツト ベシユレンクテル ハフツングＲｏｂｅｒｔ Ｂｏｓｃｈ Ｇｍｂｈ | Cathode material for lithium sulfur cell |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0821381B2 (en) | 1996-03-04 |
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