JP2003137758A - Masking composition for hair cosmetic and hair cosmetic containing the same and method for masking hair cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a formula perfume comprising at least one formula material selected from the group consisting of synthetic and natural materials classified in terms of functional group used in general as raw materials for formula perfumes, to provide a method for producing the formula perfume, and to provide a deodorizing/masking composition for perfume formulation containing the formula perfume. SOLUTION: The masking composition for hair cosmetics is easily obtained by appropriately formulating at specific concentration(s) at least one material selected from the group of materials used in general as those for formula perfumes classified in terms of functional group into 12 categories, i.e., (A) hydrocarbons, (B) alcohols, (C) phenolics, (D) aldehydes and/or acetals, (E) ketones and/or ketals, (F) ethers, (G) synthetic musks, (H) acids, (I) lactones, (J) esters, (K) nitrogen-/sulfur- and/or halogen-containing compounds and (L) natural perfumes.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to (A) hydrocarbons, (B) alcohols, (C) phenols, (D).
Aldehydes and / or acetals, (E) ketones and / or ketals, (F) ethers, (G) synthetic musks, (H) acids, (I) lactones, (J) esters, ( K) nitrogen-containing and / or sulfur-containing and / or halogen-containing compound, and (L) at least one or more perfume selected from the group consisting of natural perfumes,
The present invention relates to a masking composition for hair cosmetics, a hair cosmetic containing the composition, and a method for masking a hair cosmetic.

[0002]

2. Description of the Related Art Blended fragrances are cosmetics (skin care, makeup, hair care, perfume, cologne, body care), hair cosmetics, body cleaning agents, hair cleaning agents, bath agents, laundry detergents / softeners, kitchens. It is used in a variety of fragrance products such as cleaning products for household use, cleaning products for home use, bleach cleaning products, deodorants (human body, environment, base material), fragrances, oral products, and aromatherapy products.

The purpose of perfuming a fragrance product with a mixed fragrance is to impart a fragrance of moderate intensity with a pleasant fragrance. Sometimes requires functionality.

[0004] One of the functions of this blended fragrance is a masking effect on human body odor such as sweat odor, axillary odor, hair odor, and pet odor such as animal odor and animal hair odor. It is the masking effect of the base material used in various fragrance products used. Therefore, the compounded fragrance is required to have a function as a masking agent while giving a pleasant scent. Particularly in hair cosmetics, various processes such as permanent, bleaching, dyeing, conditioning, and hair styling of the hair are performed, so the unpleasant odor of the base used for them, such as surfactant odor, special polymer odor, ammonia odor. , Acid odor, sulfur odor, etc. are remarkable, and it is important to mask them. That is, the masking effect of the fragrance in hair cosmetics plays an important role in the quality of the cosmetics.

By the way, in the preparation of mixed flavors, the volatility is often used as an index. Because the relationship between fragrance and volatility is extremely important, and as a characteristic of the synthetic and natural flavors that are the ingredients of the blended fragrance, it is basically necessary to recognize the volatile level of each blended material before blending. Because it is done. Synthetic fragrances are usually classified into high volatile top notes (A), medium middle notes (B) and low volatile base notes (C). In addition, natural essential oils are also classified into the above (A), (B) and (C), and a note (A) + which is a mixture of a top note and a middle note.
(B), mixed note of middle note and base note (B) + (C), mixed note of top note, middle note and base note (A) + (B) +
It is classified into (C). The volatility of the synthetic and natural flavors used as the blended flavor material can be represented by vapor pressure, but generally, a method of capturing the volatility is adopted. That is, when selecting the material of the mixed flavor mainly composed of sensuality, the mixed flavor is usually assembled based on the above-mentioned top note, middle note, base note and mix note. On the other hand, observing the characteristics of functional groups can also be an effective means for preparing a blended fragrance. As a general property, the compounding material has hydrocarbons (A) which have a high volatility and are stable to alkalis, and alcohols (B) which have various aroma properties and are relatively stable to acids and / or alkalis. , Stable to acids with a unique fragrance, stable to alkalis, especially phenols (C) that are unstable to certain metals, stable to aldehydes and alkalis with various fragrance characteristics Acetals (D), ketones with various scent characteristics and alkali-stable ketals (E), ethers (F) stable to acids, alkalis and oxidants, fragrance base fragrance Synthetic musks (G) that have a tone and show a holding effect,
Acids (H) capable of capturing alkaline unpleasant odor,
Lactones (I) that express heavy sweetness, esters that are diffusible but may decompose to form carboxylic acids and alcohols in aqueous acid or alkaline solution (J), basic odors that have a strong odor It is classified as (L) a natural fragrance in which the above components (A) to (K) are fused together with a synthetic fragrance such as a nitrogen-containing and / or sulfur-containing and / or halogen-containing compound (K).

The relationship between the masking effect and the functional group of the compounding material is extremely important in combination with the physicochemical properties of the target malodor and offensive odor, and the compounding fragrance for masking is prepared based on this characteristic of the functional group. By doing so, it can be finished more effectively. Therefore, it is necessary to recognize what kind of functional group property each of the mixed materials has as a characteristic of the synthetic perfume as a material of the mixed perfume, and to be familiar with the functional group characteristics of the natural material containing the synthetic perfume ingredient. However, synthetic fragrances, which are the raw materials for compounded fragrances, have been empirically conducted to classify them by functional group and obtain an excellent masking composition by appropriately combining them, and were established as a systematic method. It could not be said to be a thing.

[0007]

The object of the present invention is to establish, as a systematic method, to classify materials used as materials for compounded fragrances according to their functional groups and select them appropriately according to their characteristics. It is to provide an excellent masking composition by the method.

[0008]

In order to solve the above-mentioned problems, the present inventor has selected, based on functional groups, several thousand and several hundreds of materials that are usually used as materials for blended fragrances (A) hydrocarbons,
(B) alcohols, (C) phenols, (D) aldehydes and / or acetals, (E) ketones and / or ketals, (F) ethers, (G) synthetic musks, (H) Acids, (I) lactones, (J) esters, (K) nitrogen-containing and / or sulfur-containing and / or halogen-containing compounds, and (L) natural flavors are classified into 12 types and at least selected from these groups. By appropriately blending one or more, preferably two or more, more preferably three or more, particularly preferably four or more, and most preferably five or more materials, a desired masking composition can be obtained as compared with the conventional one. They have found that they can be easily prepared and completed the present invention.

Furthermore, the masking composition of the present invention is added to a hair cosmetic composition in an appropriate amount together with a surfactant and a solvent, if necessary, so that the content concentration is 1 times the threshold value of the composition or more. The present invention has been completed by finding that an excellent masking effect can be obtained at 10 ⁷ times. That is, the present invention relates to (A) hydrocarbons, (B) alcohols, (C) phenols, (D) aldehydes and / or acetals, (E) ketones and / or ketals, (F) ethers. , (G) synthetic musks, (H) acids, (I) lactones, (J) esters, (K) nitrogen-containing and / or sulfur-containing and / or halogen-containing compounds, (L)
A masking composition comprising at least one or more fragrances selected from the group consisting of natural fragrances.

[0010]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be specifically described below according to its embodiments.

The composition of the present invention comprises the above-mentioned (A) hydrocarbons, (B) alcohols, (C) phenols, (D).
Aldehydes and / or acetals, (E) ketones and / or ketals, (F) ethers, (G) synthetic musks, (H) acids, (I) lactones, (J) esters, ( A large number of synthetic or natural fragrances having different functional groups represented by (K) nitrogen-containing and / or sulfur-containing and / or halogen-containing compound and (L) natural fragrance are prepared, and masking compositions for respective hair cosmetics. Required physical properties, and if necessary a specified fragrance or aroma (for example, citrus, fruity, green, floral, aldehyde, spicy, woody, sweet, mossy, musky, amber, animal, herbal, marine, and mint) Masking compositions that give notes) can be readily prepared.

In the formulation of the masking composition of the present invention, the blending ratio of the functional group component of the synthetic or natural fragrance is
For example, the hydrocarbon component (A) is 0 to 100% by weight,
(B) alcohol component 0 to 100% by weight, (C) phenol component 0 to 100% by weight, (D) aldehyde and / or acetal component 0 to 100% by weight,
(E) 0 to 100 ketones and / or ketals
% By weight, 0 to 100% by weight of (F) ether component,
(G) Synthetic musk component is 0 to 100% by weight, (H) Acid component is 0 to 100% by weight, and (I) Lactone component is 0.
To 100% by weight, (J) ester component 0 to 100% by weight, (K) nitrogen-containing and / or sulfur-containing and / or halogen-containing compound component 0 to 100% by weight, and (L) natural flavor component 0. It is used in the range of 100 wt% to 100 wt%, but usually 5 to 90 wt% of (A) hydrocarbon component, 10 to 90 wt% of (B) alcohol component, and 1 to (C) phenol component. 50% by weight, 5 to 50% by weight of (D) aldehydes and / or acetals, 10 to 80% by weight of (E) ketones and / or ketals, and 1 to 50 of (F) ethers. % By weight, 0.1 to 30% by weight of (G) synthetic musk component, 0.1 to 20 of (H) acid component
% By weight, 0.1 to 30% by weight of (I) lactone component,
The (J) ester component is 10 to 90% by weight, and the (K) nitrogen-containing and / or sulfur-containing and / or halogen-containing compound component is 0.
10 to 10% by weight, (L) natural flavor component is often used in the range of 0 to 70% by weight.

The hydrocarbons (A) used in the present invention are
It is not particularly limited as long as it is a volatile organic compound composed of carbon and hydrogen, and examples thereof include aliphatic hydrocarbons, alicyclic hydrocarbons, terpene hydrocarbons, aromatic hydrocarbons, etc. , Preferably 1,3,5-undecatriene, p-cymene, α-pinene, α-ferrandrene,
β-caryophyllene, β-pinene, Δ-carene, alloocimene, ocimene, dihydromyrcene, dipentene, squalene, sedrene, terpinene, terpinolene, valencene, bisaborene, farnesene, myrcene,
Limonene, longifolene, adamantane, isolongifolene, camphene, guayen, diphenyl,
Diphenylmethane, biphenyl, 3,7-dimethyl-
1,3,6-octatriene, 4-isopropyl-1-
Methyl-2-propenylbenzene, 7-methyl-3-methylene-1,6-octadiene, p-ethylstyrene,
α-p-dimethylstyrene, isoprene, undecatriene, undecane, octadecadiene, octadecane,
Octadecene, octane, octene, cumene, sabinene, cyclohexane, cyclohexene, cyclopentadiene, dicyclopentadiene, styrene, decalin, decane, tetradecane, tetralin, dodecane, tridecane, tridecene, naphthalene, nonane, nonene, norbornane, norbornene, hexadecane, hexane. , Heptadecadiene, heptadecane, heptadecene, heptane, pentadecane are exemplified, and more preferably 1,3,
5-undecatriene, p-cymene, α-pinene, α
-Ferrandrene, β-caryophyllene, β-pinene,
Δ-calene, alloocimene, ocimene, dihydromyrcene, dipentene, squalene, sedrene, terpinene,
Examples include terpinolene, valencene, bisaborene, farnesene, myrcene, limonene, longifolene, adamantane, isolongifolene, and camphene.

The alcohol (B) used in the present invention is not particularly limited as long as it is a volatile organic compound having a hydroxyl group, and aliphatic alcohols, alicyclic alcohols, terpene alcohols, aromas are used. Examples thereof include group alcohols, preferably 10-undecenol, 1-
Octene-3-ol, 2,6-nonadienol, 2-
tert-butylcyclohexanol, 2-ethylhexanol, 2-heptanol, 3,5,5-trimethylhexanol, 3-octanol, 3-phenylpropyl alcohol, L-menthol, n-decyl alcohol, p, α-dimethylbenzyl alcohol , P-ter
t-butylcyclohexanol, p-methyldimethylbenzylcarbinol, α, 3,3-trimethyl-2-norbornanemethanol, α-n-amylcinnamic alcohol, α-phenalkyl alcohol, β-phenylethyl alcohol, anis alcohol , Ambercore, ambrinol, isononyl alcohol, isophytol, isopulegol, isoborneol, ethyl linalool, octanol, carveol, geraniol, santalol, cis-3-hexen-1-ol, cis-
6-nonenol, citronellol, dihydro-α-terpineol, dihydrocitronellol, dihydromyrcenol, dihydrolinalool, dimethylphenylethylcarbinol, dimethylbenzylcarbinol, cinnamic alcohol, styralyl alcohol, cedrol, terpineol, terpinene-4- All, timbelol, tetrahydrogeraniol, tetrahydromyrcenol, tetrahydromugol, tetrahydrolinolol, nerol, nerolidol, nonanol, nonyl alcohol, nopol, hydrotropyl alcohol, bacdanol, patchouli alcohol, farnesol, phytol, phenylethylmethylethylcarbi Noor,
Phenoxyethyl alcohol, furfuryl alcohol,
Vetiverol, perilla alcohol, benzyl alcohol, mayol, myrcenol, myrtenol, lavandulol, linalool, 1- (2,2,6-trimethylcyclohexanyl) -hexan-3-ol, 1,1
-Dimethyl-3-phenylpropanol, 1-decanol, 1-dodecanol, 1-nonen-3-ol, 1-
Heptanol, 1-penten-3-ol, 2,2-dimethyl-3-phenylpropanol, 2,4-dimethyl-3-cyclohexene-1-methanol, 2,4-dimethylbenzyl alcohol, 2,4-hexadienol ,
2,5,5-Trimethyloctahydro-2-naphthol, 2,6-dimethylheptan-2-ol, 2-isobutyl-4-hydroxy-4-methyltetrahydropyran, 2-undecanol, 2-octanol, 2-
Nonanol, 2-phenylpropyl alcohol, 2-methyl-3-buten-2-ol, 2-methyl-4-
(2,2,3-Trimethyl-3-cyclopentenyl)-
2-butenol, 2-methyl-4- (2,2,3-trimethyl-3-cyclopentenyl) -butanol, 2-methyloctanol, 2-methyldecanol, 2-methoxy-2-phenylethyl alcohol, 3, 3-dimethyl-Δ2, β-norbornane-2-ethanol, 3,4
5,6,6-pentamethyl-2-heptanol, 3,6
-Dimethyloct-3-ol, 3,7-dimethyl-1
-Octanol, 3,7-dimethyl-7-methoxyoct-2-ol, 3-tunanol, 3-dodecanol,
3-heptanol, 3-methyl-1-phenyl-3-pentanol, 3-methyl-2-buten-1-ol, 3
-Methyl-5- (2,2,3-trimethyl-3-cyclopentenyl) -pentan-2-ol, 3-methyl-5
-Phenylpentanol, 3-methylpentanol, 4
-Isopropylcyclohexanol, 4-tunanol,
4-methyl-3-decen-5-ol, 5-methyl-2
-Phenyl-2-hexanol, 6,8-dimethyl-2
-Nonanol, 9-decenol, 9-decen-1-ol, E.I. G. Monobutyl ether, sec-undecyl alcohol, sec-octyl alcohol, sec
-Nonyl alcohol, α, α, p-trimethylphenylethyl alcohol, α, α-dimethylphenylethyl alcohol, α-isobutylphenylethyl alcohol,
α-bisabolol, α-propylphenylethyl alcohol, β, γ-hexenol, β-caryophyllene alcohol, γ-4-dimethyl-3-cyclohexene-1-
Propanol, aloosimenol, ambestol, isocamphyl cyclohexanol, isocyclogeraniol, isodihydrolavandulol, isobutylbenzylcarbinol, undecanol, ethylene glycol, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monopropyl ether Ether, ethylene glycol monomethyl ether, osimenol, camel DH, cumin alcohol, geranyl linalool, sabinene hydrate,
Diethylene glycol, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol monopropyl ether, diethylene glycol monomethyl ether, cyclohexylethyl alcohol, cyclomethylene citronellol, cis-4-hexen-1-ol, cis-p-isopropylcyclohexylmethanol, dihydrocarbeol,
Dipropylene glycol, dipropylene glycol monoethyl ether, dipropylene glycol monobutyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monomethyl ether, dimethyl octanol, dimethyl vinyl carbinol, sclareol, decahydro-β-naphthol, tetrahydroalloocime Nord, trans-2-octanol,
Trans-2-hexenol, trans-3-hexen-1-ol, neopentyl glycol, hydrocinnamic alcohol, vanillyl alcohol, pinocarbeol, butane-1,3-diol, butane-1,3-
Diol monoethyl ether, butane-1,3-diol monobutyl ether, butane-1,3-diol monopropyl ether, butane-1,3-diol monomethyl ether, butane-2,3-diol, butane-2,
3-diol monoethyl ether, butane-2,3-diol monobutyl ether, butane-2,3-diol monopropyl ether, butane-2,3-diol monomethyl ether, butylene glycol, propylene glycol, propylene glycol monoethyl ether, Propylene glycol monobutyl ether, propylene glycol monopropyl ether, propylene glycol monomethyl ether, hexamethylene glycol, hexylene glycol, pentamethylene glycol, muguet alcohol, methyl β-phenylethyl alcohol and methyl sundeflor are exemplified, and more preferably 10-
Undecenol, 1-octen-3-ol, 2,6-
Nonadienol, 2-tert-butylcyclohexanol, 2-ethylhexanol, 2-heptanol,
3,5,5-Trimethylhexanol, 3-octanol, 3-phenylpropyl alcohol, L-menthol, n-decyl alcohol, p, α-dimethylbenzyl alcohol, p-tert-butylcyclohexanol, p-methyldimethylbenzylcarbi Nord, α,
3,3-trimethyl-2-norbornanemethanol, α
-N-amyl cinnamic alcohol, α-phenalkyl alcohol, β-phenylethyl alcohol, anis alcohol, amber core, ambrinol, isononyl alcohol, isophitol, isopulegol, isoborneol, ethyl linalool, octanol, carveol, geraniol, Santalol, cis-3-hexen-1-ol, cis-6-nonenol, citronellol, dihydro-α-terpineol, dihydrocitronellol, dihydromyrcenol, dihydrolinalool, dimethylphenylethylcarbinol, dimethylbenzylcarbinol, syn Namic alcohol, styralyl alcohol, cedrol, terpineol, terpinen-4-ol, timbelol, tetrahydrogeraniol, tetrahydro Lucenol, tetrahydromugol, tetrahydrolinalol, nerol, nerolidol, nonanol, nonyl alcohol, nopol, hydrotropyl alcohol, bacdanol, patchouli alcohol, farnesol, phytol, phenylethylmethylethylcarbinol, phenoxyethyl alcohol, furfuryl alcohol, Examples include vetiverol, perilla alcohol, benzyl alcohol, mayol, myrcenol, myrtenol, lavandulol, and linalool.

The (C) phenols used in the present invention are not particularly limited as long as they are phenolic compounds and their derivatives and organic compounds having a scent. For example, monovalent, divalent, trivalent Examples thereof include phenolic compounds, polyphenols, and ether derivatives of these compounds, preferably p-cresol, isoeugenol, estragal, eugenol, hinokitiol, benzylisoeugenol, benzyleugenol, methylisoeugenol, methyleugenol, Yarayara, 2,6-dimethoxyphenol, 4-ethylguaiacol, 4-methylguaiacol, 5-propenylguaetol, β-naphthol isobutyl ether, p
-Allylphenol, p-ethylphenol, isosaflor, ethylisoeugenol, catechol dimethyl ether, carvacrol, guaiacol, cresol, safrole, dihydroeugenol, thymol, chabicol, hydroquinone dimethyl ether, banitrope, bromelia, methoxybenzene, resorcinol dimethyl ether, shogaol Is exemplified.

The (D) aldehydes or acetals used in the present invention are not particularly limited as long as they are volatile organic compounds having an aldehyde group or an acetal group in the molecule, and aliphatic aldehydes, acetals, terpenes Examples include aldehydes and acetals, aromatic aldehydes and acetals, preferably 10-undecenal,
2,4-Dimethyl-4,4a, 5,9b-tetrahydroindeno [1,2d] -1,3-dioxin, 2,4-
Decadienal, 2,6-nonadienal, 2-butyl-4,4,6-trimethyl-1,3-dioxane, 2-
Hexyl-5-methyl-1,3-dioxolane, 2-methylundecanal, 2-methylundecanal dimethylacetal, 3-ethyl-2,4-dioxaspiro [5.5] undec-8-ene, 3-ethyl- 8
(9), 11-Dimethyl-2,4-dioxaspiro [5.5] undec-8-ene, 3-propylbicyclo [2.2.1] -hept-5-ene-2-carboxaldehyde, 4-isopropyl -5,5-dimethyl-1,
3-dioxane, 4-heptenal, 5-methyl-5-
Propyl-2- (1-methylbutyl) -1,3-dioxane, o-methoxycinnamic aldehyde, o-methoxybenzaldehyde, p-tolylaldehyde, α-n
-Hexyl cinnamic aldehyde, α-amyl cinnamic aldehyde, acetaldehyde, acetaldehyde ethyl linalyl acetal, acetaldehyde diethyl acetal, anisaldehyde, aldehyde C-1
0, aldehyde C-11, aldehyde C-12, aldehyde C-6, aldehyde C-6 DEA, aldehyde C-6 DMA, aldehyde C-6 PG acetal, aldehyde C-8, aldehyde C-8
DEA, aldehyde C-8 DMA, aldehyde C
-9, aldehyde C-9 DEA, aldehyde C-
9 DMA, isocyclocitral, ethyl vanillin,
Cantoxal, cucumber aldehyde, cumin aldehyde, geranial, cyclamenaldehyde, cis-6-nonenal, citral, citronellal, citronellyloxyacetaldehyde, sinensal, dupicard, trans-2-hexenal, trans-
2-hexenal diethyl acetal, tripral,
Neral, hydrotropaldehyde, vanillin, hydroxycitronellal, phenylacetaldehyde, phenylacetaldehyde P. G. Acetal, phenylacetaldehyde dimethyl acetal, furfural,
Florazone, Heliotropin, Helional, Perillaaldehyde, Bergamar, Bertoacetal, Bernaldehyde, Benzaldehyde, Homomylacaldehyde, Mylacaldehyde, Melonal, Lillard,
Liliar, 2,4,6-triisopropyl-1,3,3
5-trioxane, 2,4-undecadienal, 2,
4-octadienal, 2,4-dioxa-3-methyl-7,10-methanospiro [5.5] -undecane,
2,4-dodecadienal, 2,4-nonadienal,
2,4-hexadienal, 2,4-heptadienal, 2,5,6-trimethyl-4-heptenal, 2,
6,10-trimethyl-5,9-undecadienal,
2-Methyl-3- (4-methylphenyl) -propanal, 2-methyl-4- (2,6,6-trimethyl-2-
Cyclohexenyl) -3-butenal, 2-methylbutanal, 3-phenylpropionic aldehyde, 3-
Phenylpropionic aldehyde dimethyl acetal, 3-methyl-5-phenylvaleraldehyde, 4-
(2,2,6-trimethyl-2 (1) -cyclohexene) -2-methylbutanal, 4- (4-methyl-3-)
Cyclohex-1-ylidene) -pentanal, 4-methyl-2-phenyl-2-pentenal, 5- (hydroxymethyl) -2-furfural, 5,9-dimethyl-
4,9-decadienal, 5-methylfurfural, n
-Valeraldehyde, p-tert-butylhydrocinnamic aldehyde, p-isobutyl-α-methylhydrocinnamic aldehyde, p-isopropylhydrotroparaldehyde, p-methylhydrotroperaldehyde, p-methylphenylacetaldehyde, p- Methylphenoxyacetaldehyde, p-methoxybenzaldehyde, α-n-amylcinnamic aldehyde diethyl acetal, α-amylcinnamic aldehyde dimethyl acetal, α-camphorenaldehyde,
α-methyl cinnamic aldehyde, β-methyl hydrocinnamic aldehyde, γ-n-hexyl cinnamic aldehyde, acetaldehyde ethyl isoeugenyl acetal, acetaldehyde ethyl cis-3-hexenyl acetal, acetaldehyde ethyl phenyl ethyl acetal, acetaldehyde ethyl hexyl acetal, Acetaldehyde citronellyl ethyl acetal, acetaldehyde citronellyl methyl acetal,
Acetaldehyde phenylethyl n-propyl acetal, aldehyde C-13, aldehyde C-14, aldehyde C-5, aldehyde C-7, aldehyde C
-7 DEA, aldehyde C-7 DMA, isovaleraldehyde, octahydro-4,7-methano-1H
-Indenecarboxaldehyde, caryophyllene aldehyde, geranyloxyacetaldehyde, safranal, salicylaldehyde, cyclocitral, cis-3
-Hexenal, cis-3-hexenal diethyl acetal, cis-4-decenal, citral PG acetal, citral diethyl acetal, citral dimethyl acetal, citronellal EG acetal, dihydroindenyl-2,4-dioxane, dimethyl octanal, Cynamic aldehyde, decanal diethyl acetal, decanal dimethyl acetal, tetrahydrocitral, dodecanal dimethyl acetal, trans-2-undecenal, trans-2-decene-
1-are, trans-2-dodecenal, trans-
2-tridecenal, trans-2-nonenal, trans-2-heptenal, trans-2-pentenal, trans-4-decenal, trimethylundecenal, trimethyldecadienal, hydrotroperaldehyde E. G. Acetal, hydrotropalaldehyde dimethyl acetal, vanillin P.I. G. Acetal, paraaldehyde, hydroxycitronellal diethyl acetal, phenylacetaldehyde 2,3-butylene glycol acetal, phenylacetaldehyde 2,4
-Dihydroxy-4-methylpentane acetal, phenylacetaldehyde diisobutyl acetal, phenoxyacetaldehyde, furfuryl acrolein, heptanal E.I. G. Acetal, heliotropin diethyl acetal, heliotropin dimethyl acetal, benzaldehyde PG acetal, benzaldehyde glyceryl acetal, benzaldehyde diethyl acetal, benzaldehyde dimethyl acetal, formaldehyde cyclododecylethyl acetal, methyl decanal, methylnonyl acetaldehyde dimethyl acetal, methyl vanillin, methoxydicyclo Pentadienecarboxaldehyde and methoxycitronellal are exemplified, and more preferably 10-undecenal, 2,4-dimethyl-4,4a, 5,9b-tetrahydroindeno [1,2d] -1,3-dioxin, 2, 4-decadienal, 2,6-nonadienal, 2-butyl-4,
4,6-Trimethyl-1,3-dioxane, 2-hexyl-5-methyl-1,3-dioxolane, 2-methylundecanal, 2-methylundecanal dimethyl acetal, 3-ethyl-2,4-dioxaspiro [ 5.
5] Undeca-8-ene, 3-ethyl-8 (9), 11
-Dimethyl-2,4-dioxaspiro [5.5] undec-8-ene, 3-propylbicyclo [2.2.1]-
Hepta-5-ene-2-carboxaldehyde, 4-isopropyl-5,5-dimethyl-1,3-dioxane,
4-heptenal, 5-methyl-5-propyl-2-
(1-methylbutyl) -1,3-dioxane, o-methoxycinnamic aldehyde, o-methoxybenzaldehyde, p-tolylaldehyde, α-n-hexylcinnamic aldehyde, α-amylcinnamic aldehyde, acetaldehyde, acetaldehyde ethyllinalyl Acetal, acetaldehyde diethyl acetal,
Anisaldehyde, aldehyde C-10, aldehyde C-11, aldehyde C-12, aldehyde C-
6, aldehyde C-6 DEA, aldehyde C-6
DMA, aldehyde C-6 PG acetal, aldehyde C-8, aldehyde C-8 DEA, aldehyde C-8 DMA, aldehyde C-9, aldehyde C-9 DEA, aldehyde C-9 DMA, isocyclocitral, ethyl vanillin, cantoxal. ,
Cucumber aldehyde, cumin aldehyde, geranial, cyclamen aldehyde, cis-6-nonenal, citral, citronellal, citronellyl oxyacetaldehyde, sinensal, dupicar, trans-2-hexenal, trans-2-hexenal diethyl acetal, tripral, neral, hydro Tropaaldehyde, vanillin, hydroxycitronellal, phenylacetaldehyde, phenylacetaldehyde P.I. G. Examples include acetal, phenylacetaldehyde dimethyl acetal, furfural, floralozone, heliotropin, helional, perilaldehyde, bergamar, bert acetal, bernaldehyde, benzaldehyde, homomylacaldehyde, miracaldehyde, melonal, lyral, and lilial.

The (E) ketone or ketal used in the present invention is not particularly limited as long as it is a volatile organic compound having a ketone group or a ketal group in the molecule, and an aliphatic ketone, a ketal or a terpene. System ketones and ketals,
Aromatic ketones and ketals are exemplified, and preferably 2
-Sec-butylcyclohexanone, 2-acetyl-
3,3-dimethylnorbornane, 2-acetyl-5-methylfuran, 2-acetylfuran, 2-butyl-1,4
-Dioxaspiro [4,4] nonane, 2-hexylcyclopentanone, 3-hydroxy-4,5-dimethyl-2
-(5H) -furanone, 5-ethyl-3-hydroxy-4-methyl-2 [5H] -furanone, 6-methyl-
3,5-heptadien-2-one, d-pulegone, L-
Carvone, o-tert-butylcyclohexanone, p
-Tert-butylcyclohexanone, p-methylacetophenone, p-methoxyacetophenone, α-dynascon, α-phencon, β-methylnaphthylketone,
Acetyl Cedrene, Acetophenone, Anisylacetone, Allyl α-ionone, Ionone, Iso E Super, Isojasmon, Isodamascon, Isolongiforanone, Iron, Ethylisoamylketone, Ethylmaltol, Kashmeran, Calone, Camphor, Coabon, Cycloten, Cis-jasmone, dihydrocarvone, dihydrojasmone, dibenzyl ketone, cedrenone, sotron, damascon, damascenone, trimofix O, nootkatone, furaneol, plicaton,
Florex, Bertfix, Verbenone, Benzophenone, Maltol, Methylionone, Methylcyclopentenolone, Methylheptenone, Mentone, Raspberry Ketone, 1- (4-Methoxyphenyl) -1-penten-3-one, 1- (p-Menten-6 -Ill) -1-
Propanone, 1-acetyl-3,3-dimethyl-1-cyclohexene, 2- (1-cyclohexen-1-yl)
Cyclohexanone, 2,2,5,5-tetramethyl-4
-Isopropyl-1,3-dioxane, 2,2,5-trimethyl-5-pentylcyclopentanone, 2,3,5
-Trimethylcyclohexen-4-yl-1-methyl ketone, 2,3-hexadione, 2,3-heptanedione, 2,3-pentadione, 2,4-di-tert-butylcyclohexanone, 2,5,5-trimethyl- 2-
Phenyl-1,3-dioxane, 2,6,10-trimethyl-1-acetyl-2,5,9-cyclododecatriene, 2,6,6, -trimethyl-2-cyclohexene-
1,4-dione, 2-n-butylidene-3,5,5
(3,3,5) -Trimethylcyclohexanone, 2-n
-Heptylcycloheptanone, 2'-acetonaphthone,
2-undecanone, 2-octanone, 2-cyclopentylcyclopentanone, 2-tridecanone, 2-nonanone, 2-hydroxy-6-isopropyl-3-methyl-2-cyclohexenone, 2-butanone, 2-heptanone, 2- Heptyl cyclopentanone, 2-pentanone,
2-pentyl-2-cyclopentenone, 2-pentylcyclopentanone, 3,3-dimethylcyclohexyl methyl ketone, 3,4-dimethyl-1,2-cyclopentadione, 3,4-hexadione, 3,5- Dimethyl-1,
2-cyclopentadione, 3-acetyl-2,5-dimethylfuran, 3-octanone, 3-nonanone, 3-hydroxymethyl-2-nonanone, 3-hexanone, 3-heptanone, 3-hepten-2-one, 3-methyl-4-
Phenyl-3-buten-2-one, 3-methyl-5-
(2,2,3-Trimethyl-3-cyclopentenyl)-
3-Penten-2-one, 3-methyl-5-propyl-
2-cyclohexenone, 4- (4-hydroxy-3-
Methoxyphenyl) -2-butanone, 4- (4-methoxyphenyl) -3-buten-2-one, 4 (5) -acetyl-7,7,9 (7,9,9) -trimethylbicyclo [4. 3.0] Nona-1-ene, 4,7-dihydro-2
-(3-pentanyl) -1,3-dioxepin, 4,7
-Dihydro-2-isoamyl-2-methyl-1,3-dioxepin, 4-tert-amylcyclohexanone,
4-oxoisophorone, 4-cyclohexenyl-4-methyl-2-pentanone, 4-heptanone, 4-methyl-
3-penten-2-one, 4-methyl-4-phenyl-
2-pentanone, 4-methylene-3,5,6,6-tetramethyl-2-heptanone, 5-cyclohexadecene-
1-one, 5-hydroxy-4-octanone, 5-phenyl-5-methyl-3-hexanone, 5-methyl-
2,3-hexadione, 7-methyl-3,5-dihydro-2H-benzodioxepin-3-one, p-hydroxyphenylbutanone, p-methoxyphenylacetone, α-methylanisalacetone, acetylisovaleryl , Acetylcaryophyllene, acetyldimethyltetrahydrobenzindane, acetoin, acetoketal,
Acetophenone neopentyl glycol acetal, acetone, atrinone, anisylideneacetone, amylcyclopentanone, ethyl acetoacetate E. G. Ketal, ethyl acetoacetate propylene glycol acetal, oxocedrane, krypton, geranylacetone, diacetyl, diacetone alcohol, diosphenol, cyclohexanone, cyclohexenone, cyclopentanone, cis-2-acetonyl-4-methyltetrahydropyran, dimethyloctenone, Gingerol, cedranone, vitalide, piperitenone, piperiteton,
Piperonylacetone, farnesylacetone, pseudoionone, butylideneacetone, furfuralacetone, propiophenone, heliotropylacetone, verdoxane, benzylideneacetone, homofuraneol,
Mesityl oxide, methyl α-furyl ketone, methyl isopropyl ketone, methyl yritone, methyl cedrilone, methyltetrahydrofuranone are exemplified, and more preferably 2-sec-butylcyclohexanone, 2-acetyl-3,3-dimethylnorbornane, 2-acetyl. −
5-methylfuran, 2-acetylfuran, 2-butyl-
1,4-Dioxaspiro [4,4] nonane, 2-hexylcyclopentanone, 3-hydroxy-4,5-dimethyl-2- (5H) -furanone, 5-ethyl-3-hydroxy-4-methyl-2 [5H] -furanone, 6-methyl-3,5-heptadien-2-one, d-pulegone,
L-carvone, o-tert-butylcyclohexanone, p-tert-butylcyclohexanone, p-methylacetophenone, p-methoxyacetophenone, α-
Dynascon, α-phencon, β-methylnaphthyl ketone, acetylcedrene, acetophenone, anisylacetone, allyl α-ionone, ionone, iso E super, isojasmon, isodamascon, isolongiforanone, iron, ethyl isoamyl ketone, ethyl Maltol, cashmellan, calone, camphor, coabon, cyclotene, cis-jasmone, dihydrocarvone, dihydrojasmone, dibenzylketone, cedrenone, sotron, damascon, damascenone, trimofix O, nootkaton, furaneol, pricatone,
Examples include Florex, Bertfix, Verbenone, Benzophenone, Maltol, Methylionone, Methylcyclopentenolone, Methylheptenone, Mentone and Raspberry Ketone.

The (F) ethers used in the present invention are
There is no particular limitation as long as it is a volatile organic compound having an ether group in the molecule, and examples thereof include aliphatic ethers, terpene ethers, aromatic ethers, etc., preferably 1,4-cineole, 1,8- Cineol, p-cresyl methyl ether, β-caryophyllene oxide,
β-naphthyl isobutyl ether, β-naphthyl ethyl ether, β-naphthyl methyl ether, anethole,
Ambroxane, isoamyl phenyl ethyl ether,
Isobornyl methyl ether, glycalva, cyclan bar, diphenyl oxide, sedlum bar, cedryl methyl ether, theaspiran, nerol oxide,
Phenylethyl methyl ether, Madrox, Linalool oxide, Limetol, Rubofix, Ruboflor, Rose oxide, Rosefuran, 13-
Oxabicyclo [10.3.0] pentadecane, 1-methylcyclododecylmethyl ether, 2,2,6-trimethyl-6-vinyltetrahydropyran, 2,2-dimethyl-5- (1-methyl-1-propenyl) -Tetrahydrofuran, 2-ethylidene-6-isopropoxybicyclo [2.2.1] heptane, 2-oxaspiro [4.
7] Dodecane, 2-butyl-4,6-dimethyldihydropyran, 2-methyl-2-butenylphenylethyl ether, 3,3,5-trimethylcyclohexylethyl ether, 3-oxabicyclo [10.3.0]. -Pentadec-6-ene, 4-allylanisole, 5-isopropenyl-2-methyl-2-vinyltetrahydrofuran,
8,9-epoxy cedrene, n-decyl vinyl ether, tert-butyl hydroquinone dimethyl ether, α-cedrene epoxide, α-terpinyl methyl ether, allyl phenyl ethyl ether, isoamyl benzyl ether, isolongifolene epoxide, ethyl o- Methoxybenzyl ether, ocimene epoxide, geranyl ethyl ether, cyclodecenyl methyl ether, cyclohexyl ethyl ether, cyclohexyl phenyl ethyl ether, citroxide,
Citronellyl ethyl ether, dibenzyl ether, juniparome, cedrol methyl ether, decyl methyl ether, tricyclodecenyl methyl ether, trimethylcyclododecatriene epoxide, methylphenylethyl ether, methylhexyl ether, methylbenzyl ether, limonene oxide, 1 , 2-dimethoxybenzene, 1,3-dimethoxybenzene, 1,4
-Dimethoxy-2-tert-butylbenzene, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, ethylene glycol dipropyl ether, ethylene glycol dimethyl ether, diethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, diethylene glycol dipropyl ether, diethylene glycol dimethyl ether, dimethyl ether , Tetrahydrofuran,
Propylene glycol diethyl ether and propylene glycol dimethyl ether are exemplified, and more preferably 1,4-cineole, 1,8-cineole, p-cresyl methyl ether, β-caryophyllene oxide and β.
-Naphthyl isobutyl ether, β-naphthyl ethyl ether, β-naphthyl methyl ether, anethole, ambroxane, isoamyl phenyl ethyl ether, isobornyl methyl ether, glycalva, cyclumber, diphenyl oxide, cedramber, cedolyl methyl ether, theaspiran, Examples thereof include nerol oxide, phenylethyl methyl ether, madrox, linalool oxide, rimitol, rubofix, ruvoflor, rose oxide and rose furan.

The synthetic musk (G) used in the present invention is not particularly limited as long as it is an organic compound having a musk aroma or a musk-like aroma, and 10-oxahexadecanolide and 11-oxahexadecanolide. De, 12-oxahexadecanolide, ambretlide, ambreton, ezaltolide, egizalton, galaxolide, cyclohexadecanolide, cyclopentadecanolide, cyclopentadecane, civetone, cerbolide, celestrid, tonalide, phantolide, pentalide. , Formylethyltetramethyltetralin, musktibeten, muskone, mosken, musk ambrette, bersalide and the like.

The (H) acid used in the present invention is not particularly limited as long as it is an organic compound having a carboxyl group in the molecule, and it is phenylacetic acid, 2-ethylbutyric acid, 2-ethylhexanoic acid. Ic acid, 2-decenoic acid, 2-hexenoic acid, 2-methyl-2-pentenoic acid, 2-methylbutyric acid, 2-methylheptanoic acid, 4-pentenoic acid, 4-methylpentanoic acid, acetic acid, isovaleric acid, isobutyric acid, undecanoic acid, undecylenic acid, octanoic acid, oleic acid, geraniic acid, synthetic acid, stearic Acid, Tigriqua Dod, Decanoic Acid, Dodecanoic Acid, Tridecanoic Acid, Nonanoic Acid, Valeric Acid, Hydrocinnamic Acid, Pyrvic Acid, Butyric Acid, Propionic Acid, Hexanoic Acid, Hepta Noic Acid, Mystic Acid, Lactic Acid, Linoleic Acid, Linolenic Acid, Lebric Acid, Oxalic Acid, Glutaric Acid, Citric Acid,
Examples thereof include succinic acid, tartaric acid, terephthalic acid, vanillic acid, valine, phytic acid, fumaric acid, benzoic acid, malic acid, maleic acid, and malonic acid.

The (I) lactone used in the present invention is
There is no particular limitation as long as it is a volatile organic compound having a lactone group in the molecule, and examples thereof include aliphatic lactones, terpene lactones, aromatic lactones, and the like, preferably 6-methylcoumarin, α-angelicalactone, γ-
n-butyrolactone, γ-undecalactone, γ-octalactone, γ-decalactone, γ-nonalactone, γ
-Valerolactone, γ-hexalactone, γ-heptalactone, δ-2-decenolactone, δ-undecalactone, δ-octalactone, δ-decalactone, δ-tetradecalactone, δ-dodecalactone, δ-trideca Lactone, δ-nonalactone, δ-hexalactone, ε-
Decalactone, ε-dodecalactone, aldehyde C-
14 (peach), aldehyde C-18 (coconut), whiskey lactone, coumarin, dihydrojasmon lactone, jasmine lactone, jasmolactone, methyl γ-decalactone, menthalactone, 4,
6,6 (4,4,6) -trimethyltetrahydropyran-2-one, 7-decene-1,4-lactone, octahydrocoumarin, dihydrocoumarin, dodecalactone,
Examples include 3-n-butylidenephthalide, 3-n-butylphthalide, 3-propylidenephthalide, and 3-propylphthalide.

The (J) esters used in the present invention are
If it is a volatile organic compound having an ester group in the molecule
There is no particular limitation, and aliphatic ester, terpene
Examples include systemic esters and aromatic esters, preferably
Is 1-ethynylcyclohexyl acetate, 1-octe
N-3-yl acetate, 2-ethylhexyl acetate
2-phenoxyethyl isobutyrate, 2-pheno
Xyethylpropionate, 3,5,5-trimethyl
Xyl acetate, 3,7-dimethyloctanyl acete
, 3-phenylpropyl acetate, 9-decene-
1-yl acetate, L-menthyl acetate, L-me
N-ethylpropionate, o-tert-butylcyclohexyl
Xyl acetate, p-tert-butylcyclohexyl
Luacetate, p-cresyl acetate, p-cresyl
Isobutyrate, p-cresyl phenylacetate, a
Cetylisoeugenol, acetyleugenol, ani
Syl acetate, afermato, amyl acetate,
Amilcaprylate, Amilcaproate, Amyrsari
Sylate, amyl valerate, amyl butyrate, ami
Ruformate, allyl 2-ethylbutyrate, allyla
Mill glycolate, allyl isovalerate, allyl oc
Tanoate, allyl caprylate, allyl caproe
Allyl cyclohexyl acetate, allyl cyclohexyl
Xyloxyacetate, allyl cyclohexyl butyr
, Allylcyclohexyl propionate, allyl
Namate, allyl phenoxyacetate, allyl butyrate
Rate, allyl propionate, allyl heptanoe
Tol, allyl benzoate, aldehyde C-16 (str
Lover), aldehyde C-19 (pineapple),
Aldehyde C-20 (raspberry), isoamyl ace
Tate, isoamyl angelate, isoamyl isovale
Rate, isoamyl isobutyrate, isoamyl unde
Silenate, isoamyl octanoate, isoamylsa
Lysylate, isoamyl cinnamate, isoamyl deca
Noate, isoamyldecanoate, isoamyl butyrate
Rate, isoamyl propionate, isoamyl hexa
Noate, Isoamylheptin carbonate, Isoami
Rubenzoate, isoamyl formate, isoamyl ure
Brinate, isoeugenyl phenylacetate, iso
Dihydrorabanduryl acetate, isobutyl acetate
, Isobutyl isovalerate, isobutyl isobutyrate
Rate, isobutyl salicylate, isobutylcinnamate
, Isobutyl valerate, isobutyl phenylacetate
Tate, isobutyl butyrate, isobutyl propione
Acetate, isobutylhexanoate, isobutylbenzoe
, Isopregyl acetate, Isopropyl acetate
G, isopropyl isovalerate, isopropyl isobutane
Tyrate, isopropyl cinnamate, isopropylde
Canoate, isopropyl phenyl acetate, isop
Ropyl butyrate, isopropyl hexanoate, iso
Propyl benzoate, isopropyl myristate, a
Sobornyl acetate, isobornyl propionate,
Wintergreen, ethyl 2-tert-butylsik
Lohexyl carbonate, ethyl 2-ethylhexanoe
, Ethyl 2-octenoate, ethyl 2-decenoe
, Ethyl 2-furoate, ethyl 2-hexylacetate
Acetate, ethyl 2-benzylacetoacetate,
Ethyl 2-methyl valerate, ethyl 2-methyl butyrate
, Ethyl 3,5,5-trimethylhexanoate,
Ethyl 3-hydroxybutyrate, ethyl 3-hydrate
Roxyhexanoate, ethyl 3-hydroxy-3-f
Phenylpropionate, ethyl 3-phenylglycidide
G, ethyl 3-phenylpropionate, ethyl o-me
Toxybenzoate, ethyl p-anisate, ethyl
Cetate, ethyl acetoacetate, ethyl isovalere
Ethyl Isobutyrate, Ethyl Octyne Carbonate
Ethyl oleate, ethyl caprinate, ethyl
Caprylate, ethyl caproate, ethyl crotone
Tomato, ethyl gellanate, ethyl safranate, ethyl sulphate
Lysylate, ethyl cyclogeraniate, ethyl cinna
Mate, ethyl valerate, ethyl phenylacetate
Ethyl butyrate, ethyl propionate, ethyl
Heptanoate, ethyl heptine carbonate, ethyl
Pelargonate, ethyl benzoate, ethyl homer
G, ethyl myristate, ethyl methyl p-tolylgly
Cydate, ethyl methyl phenylglycidate, ethyl
Laurate, ethyl lactate, ethyl linalyl acetate
, Ethyl levulinate, ethylene dodecane dioe
Toluene, ethylene brassylate, eugenyl phenylacetate
Tate, octyl acetate, octyl isovaleret
G, octyl isobutyrate, octyl octanoe
Octyl butyrate, octyl heptanoate, o
Octyl formate, osimenyl acetate, caryophyll
Ren Acetate, Cariophyllene Formate, Calixo
, Carbyl acetate, guaiac acetate,
Cuminyl acetate, geranyl acetate, geranyl
Sovalerate, geranyl isobutyrate, geranyl tig
Rate, geranyl phenylacetate, geranyl butyre
, Geranyl propionate, geranyl hexanoe
G, geranyl benzoate, geranyl formate, coni
Ferran, Santaryl acetate, diethyl adipate
G, diethyl succinate, diethyl sebacate, diet
Chill tartrate, diethyl phthalate, diethyl malo
Nate, cyclohexyl acetate, cyclohexyl ether
Sovalerate, cyclohexyl ethyl acetate, shiku
Lohexyl crotonate, cyclohexyl butyrate,
Cis-3-hexenyl 2-methylbutyrate, cis-3
-Hexenyl acetate, cis-3-hexenyl angel
Rate, cis-3-hexenyl isovalerate, cis-
3-hexenyl isobutyrate, cis-3-hexenyl
Caproate, cis-3-hexenyl salicylate, si
Su-3-hexenyl tiglate, cis-3-hexenyl
Valerate, cis-3-hexenylphenylacetate
, Cis-3-hexenyl butyrate, cis-3-hex
Cenylpropionate, cis-3-hexenylbenzoe
, Cis-3-hexenyl formate, cis-3-hex
Xenyl lactate, citryl acetate, citronelli
Luacetate, citronellyl isovalerate, citrone
Rilisobutyrate, citronellil tigrate, citro
Neryl phenyl acetate, citronellyl butyrate,
Citronellyl propionate, Citronellyl hexanoe
, Citronellyl formate, dihydrocarbyl ace
Tate, dihydrocuminyl acetate, dihydroterpi
Nyl acetate, dihydromyrcenyl acetate, dime
Chilsuccinate, dimethylphenylethylcarbinyl
Acetate, dimethyl phthalate, dimethyl benzyl carbonate
Ruvinyl acetate, dimethylbenzylcarbinyl iso
Butyrate, dimethylbenzylcarbinyl butyrate,
Dimethyl benzyl carvinyl propionate, Jasma
, Cinnamyl acetate, cinnamyl isovaleret
Cinnamyl isobutyrate, cinnamyl cinnamate
Cinnamil tigrate, cinnamil butyrate, shi
Nnamyl propionate, cinnamyl benzoate,
Namimil formate, styrylyl acetate, styli
Luisobutyrate, Styralyl propionate, Cedoli
Luacetate, cedryl formate, terpinyl acete
, Terpinyl isovalerate, terpinyl isobutyrate
Rate, terpinyl butyrate, terpinyl propione
, Terpinyl formate, decahydro-β-naphth
Chill formate, decyl acetate, tetrahydrofur
Furyl butyrate, tetrahydrogeranyl acetate,
Tetrahydrofurfuryl acetate, tetrahydro wheat
Luacetate, tetrahydrolinaryl acetate, dode
Syl acetate, trans-2-hexenyl acetate
G, trans-2-hexenyl butyrate, trans-
2-hexenyl propionate, trans-2-hexe
Nylhexanoate, trans-decahydro-β-na
Futyl acetate, trans-decahydro-β-naphth
Chillisobutyrate, Triacetin, Triethylcitre
, Tricyclodecyl acetate, tricyclodeceni
Luacetate, tricyclodecenyl isobutyrate,
Licyclodecenyl propionate, neryl acetate,
Neryl Isobutyrate, Neryl Butyrate, Neryl Pro
Pionate, neryl formate, nonyl acetate, no
Pill acetate, hydrotropic acetate, fe
Nylethyl 2-methylbutyrate, phenylethylacetate
Tate, phenylethyl angelate, phenylethyl
Isovalerate, Phenylethylisobutyrate, Fe
Nylethyl caprylate, phenylethyl salicile
G, phenylethyl cinnamate, phenylethyl tig
Rate, phenylethyl nonanoate, phenylethyl
Valerate, phenylethyl pivalate, phenylethyl
Luphenyl acetate, phenylethyl butyrate,
Phenylethylpropionate, phenylethylbenzoe
, Phenylethyl formate, phenylethyl meta
Acrylate, phenylethylmethylethylcarbinyl
Acetate, phenyl salicylate, Fenkyr acete
Acetate, butyl acetate, butyl angelate, butyl
Isovalerate, butyl isobutyrate, butyl octa
Noate, butyl salicylate, butyl decanoate,
Butyldodecanoate, Butylvalerate, Butylphene
Nyl acetate, butyl butyryl lactate, butyl
Tyrate, butyl propionate, butyl hexanoe
, Butyl levulinate, furfuryl acetate, pre
Nyl acetate, prenyl angelate, prenylben
Zoate, propyl acetate, propyl isovaleret
G, propyl isobutyrate, propyl octanoe
G, propyl cinnamate, propyl trans-2, si
S-4-decadienoate, propylphenylacetate
Propyl butyrate, propyl propionate,
Ropyl hexanoate, propyl heptanoate, pro
Pyrbenzoate, propyl formate, hexyl 2-
Methyl butyrate, hexyl acetate, hexyl iso
Valerate, hexyl isobutyrate, hexyl octa
Noate, hexyl salicylate, hexyl tig gray
G, hexyl phenylacetate, hexyl butyrate
G, hexyl propionate, hexyl hexanoe
Tox, hexyl benzoate, hexyl formate, vesicle
Cole acetate, Vetiveryl acetate, Heptylul
Cetate, heptyl octanoate, heptyl butley
G, heptyl hexanoate, heliotropil acetate
G, benzyl 2-methylbutyrate, benzyl acetate
G, benzyl isovalerate, benzyl isobutyrate
G, benzyl caprylate, benzyl salicylate,
Benzyl cinnamate, benzyl tiglate, benzylide
Decanoate, benzyl valerate, benzyl phenyl
Acetate, benzyl butyrate, benzyl propione
Benzyl, benzyl hexanoate, benzyl benzoate
Tomato, benzyl formate, pentyl salicylate, my
Rardyl acetate, myrcenyl acetate, myrte
Nyl acetate, methyl 1-methyl-3-cyclohexe
Carboxylate, methyl 2-nonenoate, methyl
2-Furoate, methyl 2-methylbutyrate, methyl
3-nonenoate, methyl 9-undecenoate, methyl
Luo-methoxybenzoate, methyl acetate, methyl
Ruatorate, methyl anisate, methyl angele
, Methylisovalerate, methylisobutyrate,
Chillisohexanoate, methyl octanoate, methyl
Luoctin carbonate, methyl oleate, methyl carbonate
Purinate, methyl caprylate, methyl caproie
Tomato, methyl gellanate, methyl salicylate, methyl
Crooctyl carbonate, methyl cyclogeranate,
Methylcyclopentylidene acetate, methyldihydro
Jasmonate, methyl jasmonate, methyl cinna
Mate, methyl decanoate, methyl decyne carbonyl
Tomato, methyl tetradecanoate, methyl dodecanoe
G, methyl trans-2-hexenoate, methyl tiger
Ns-3-hexenoate, methylnonanoate, methyl
Lehydroxyhexanoate, methyl valerate,
Chillphenylacetate, Methylphenylglycide
Tomato, methyl butyrate, methyl heptanoate, methyl
Heptin carbonate, methyl pelargonate, methyl
Benzoate, methyl myristate, methyl laureth
, Methyl lactate, Lavanduryl acetate,
Nalyl acetate, Linalyl isovalerate, Linalyl
Isobutyrate, linalyl octanoate, linalylsi
Mannate, linalyl butyrate, linalyl propione
, Linalyl hexanoate, linalyl benzoate
Torin, Rinalyl Homemate, Rosamusk, Rosepheno
Rosinyl acetate, rosinyl isobutyrate,
Dinyl phenyl acetate, rosinyl butyrate, rosin
Nyl propionate, rosinyl formate, 1,3-di
Methyl-3-butenyl isobutyrate, 1-acetoxy
-2-sec-butyl-1-vinylcyclohexane, 1
-Cyclohex-1-ene isopropyl acetate, 2,
4-dimethyl-3-cyclohexyl methyl acetate,
2,4-hexadienyl isobutyrate, 2-methyl-
2-methylpentylvalerate, 2-methylbutylacetate
Tate, 2-methylbutyl isovalerate, 3-octyl
Luacetate, 3-phenylpropyl isovalerate,
3-phenylpropyl isobutyrate, 3-phenylpropyl
Ropyl propionate, 3-methylpentyl angele
G, 4-methylbenzyl acetate, 5-methyl-3-
Butyltetrahydropyran-4-yl acetate, 6,
10-dimethyl-5,9-undecatrien-2-yl
Acetate, 9-decen-1-ylpropionate,
E. G. Diacetate, E. G. Monobutyl ether
Cetate, L-carbyl propionate, L-perillyl
Acetate, L-bornyl propionate, L-menthine
Luisovalerate, L-menthyl phenylacetate,
P. G. Dibutyrate, P.I. G. Dipropionate, p
-Cresyl caprylate, p-cresyl salicylate,
α-amylcinnamyl acetate, acetyl vanillin,
Anisyl propionate, anisyl formate, isob
Chill 2-furan propionate, isobutyl angele
, Isobutyl crotonate, ethyl acrylate,
Tilcitronellyl oxalate, ethyl stearate,
Ethyl tiglate, ethyl decadienoate, ethyl de
Hydrocyclogeranate, ethyl dodecanoate, ethi
Lutrans-2-hexanoate, ethyl trans-3
-Hexanoate, ethyl nonanoate, ethyl palmi
Tate, ethyl valerate, ethyl pyruvate, euge
Nilformate, oxyoctalin formate, neroli
Dilacetate, nonanediol-1,3-diacetate
Toluene, phenyl glycol diacetate, pseudolinari
L-acetate, butyl 10-undecenoate, butyl
Stearate, butyl formate, butyl lactate,
Furfuryl Valerate, Propyl 2-Flan Acrylate
And 1-ethynylcyclohexene is more preferred.
Syl acetate, 1-octen-3-yl acetate,
2-ethylhexyl acetate, 2-phenoxyethyl
Isobutyrate, 2-phenoxyethyl propione
G, 3,5,5-trimethylhexyl acetate, 3,
7-dimethyl octanyl acetate, 3-phenyl pro
Pill acetate, 9-decen-1-yl acetate, L
-Menthyl acetate, L-menthyl propionate,
o-tert-butylcyclohexyl acetate, p-
tert-butylcyclohexyl acetate, p-cre
Dilacetate, p-cresyl isobutyrate, p-ku
Resin phenylacetate, acetylisoeugeno
Le, acetyl eugenol, anisyl acetate, af
Ermato, amyl acetate, amyl caprylate,
Amyl caproate, Amyl salicylate, Amyl bale
Rate, amyl butyrate, amyl formate, allyl
2-ethyl butyrate, allyl amyl glycolate, a
Ryl isovalerate, allyl octanoate, allyl carbonate
Prilate, allyl caproate, allyl cyclohexyl
L-acetate, allylcyclohexyloxyacetate
Allyl cyclohexyl butyrate, allyl cyclohexyl
Xylpropionate, allyl cinnamate, allyl
Enoxyacetate, allyl butyrate, allyl propylene
Onate, allyl heptanoate, allyl benzoate
Tomato, aldehyde C-16 (strawberry), Aldehi
De C-19 (pineapple), aldehyde C-20
(Raspberry), isoamyl acetate, isoamylua
Angelate, Isoamyl Isovalerate, Isoamyl
Sobutyrate, Isoamyl undecylenate, Isoami
Le octanoate, isoamyl salicylate, isoami
Lucinnamate, isoamyl decanoate, isoamyl
Dodecanoate, isoamyl butyrate, isoamylp
Ropionate, isoamyl hexanoate, isoamyl
Heptin carbonate, isoamyl benzoate, iso
Amyl formate, isoamyl levulinate, isooi
Genyl phenylacetate, isodihydrolavanduli
Luacetate, isobutyl acetate, isobutyl iso
Valerate, isobutyl isobutyrate, isobutyl ether
Lysylate, isobutyl cinnamate, isobutyl barre
Rate, isobutylphenylacetate, isobutylbu
Tyrate, isobutyl propionate, isobutyl hex
Sanoate, isobutyl benzoate, isopregiuria
Cetate, isopropyl acetate, isopropyl iso
Valerate, isopropyl isobutyrate, isopropyl
Lucinnamate, Isopropyl decanoate, Isopro
Pyrphenyl acetate, isopropyl butyrate, a
Sopropyl hexanoate, isopropyl benzoate
G, isopropyl myristate, isobornyl acetate
Toso, isobornyl propionate, winter green
2-ethyl-tert-butylcyclohexylcarbone
Nate, ethyl 2-ethylhexanoate, ethyl 2-
Octenoate, ethyl 2-decenoate, ethyl 2-
Furoate, ethyl 2-hexyl acetoacetate, d
Cyl 2-benzyl acetoacetate, ethyl 2-methyl
Valerate, ethyl 2-methylbutyrate, ethyl 3,
5,5-Trimethylhexanoate, Ethyl 3-hydrate
Roxybutyrate, ethyl 3-hydroxyhexanoe
Ethyl 3-hydroxy-3-phenylpropione
, Ethyl 3-phenylglycidate, ethyl 3-f
Phenylpropionate, ethyl o-methoxybenzoate
Ethyl p-anisate, ethyl acetate, ethyl
Acetoacetate, ethyl isovalerate, ethyl iso
Butyrate, ethyl octyne carbonate, ethyl ole
Ate, ethyl caprynate, ethyl caprylate, d
Chilcaproate, ethyl crotonate, ethyl gerane
, Ethyl safranate, ethyl salicylate, ethyl
Luciclogeraniate, ethylcinnamate, ethylva
Relate, ethyl phenylacetate, ethyl butley
Ethyl propionate, ethyl heptanoate,
Tylheptine carbonate, ethyl pelargonate, et
Cylbenzoate, ethyl formate, ethyl myriste
, Ethylmethyl p-tolylglycidate, ethylmeth
Cylphenylglycidate, ethyl laurate, ethyl
Lactate, ethyl linalyl acetate, ethyl levulin
Nate, ethylene dodecanedioate, ethylene black
Sylates, eugenyl phenyl acetate, octyl lua
Cetate, octyl isovalerate, octyl isobutyrate
Rate, octyl octanoate, octyl butyrate
Octyl heptanoate, octyl formate, octyl heptanoate
Simenyl acetate, caryophyllene acetate, potassium
Ophiren Homemate, Calixor, Calville Acete
, Guaiac acetate, cuminyl acetate,
Geranyl acetate, geranyl isovalerate, gerani
Luisobutyrate, geranyl tiglate, geranilfe
Nyl acetate, geranyl butyrate, geranyl propyl
Onate, geranyl hexanoate, geranyl benzoe
Red, Geranil Homemate, Coniferan, Santaril
Acetate, diethyl adipate, diethyl succine
G, diethyl sebacate, diethyl tartrate, die
Tyl phthalate, diethyl malonate, cyclohexyl
Acetate, cyclohexyl isovalerate, cyclohexyl
Xylethyl acetate, cyclohexyl crotone
G, cyclohexyl butyrate, cis-3-hexenyl
2-methylbutyrate, cis-3-hexenylacetate
G, cis-3-hexenyl angelate, cis-3-h
Xenyl isovalerate, cis-3-hexenyl isob
Tyrate, cis-3-hexenyl caproate, cis-
3-hexenyl salicylate, cis-3-hexenyl thio
Great, cis-3-hexenyl valerate, cis-3
-Hexenyl phenylacetate, cis-3-hexeni
Rubutyrate, cis-3-hexenyl propionate,
Cis-3-hexenyl benzoate, cis-3-hexe
Nilformate, cis-3-hexenyl lactate, shi
Triyl acetate, citronellyl acetate, citronell
Rilisovalerate, citronellylisobutyrate, citronellate
Tronellil tiglate, citronellyl phenylacetate
Tomato, citronellyl butyrate, citronellyl propione
Red, citronellyl hexanoate, citronellyl hoo
Mate, dihydrocarbyl acetate, dihydrocumin
Luacetate, dihydroterpinyl acetate, dihydride
Romycenyl acetate, dimethyl succinate, dime
Cylphenylethylcarbinyl acetate, dimethylphenyl
Talate, dimethylbenzylcarbinyl acetate, di
Methylbenzylcarbinyl isobutyrate, dimethyl ester
Nylcarbyl butyrate, dimethylbenzylcarbi
Nil propionate, jasmar, cinnamyl acete
, Cinnamyl isovalerate, cinnamyl isobutyrate
Rate, cinnamyl cinnamate, cinnamyl tig gray
Tona, cinnamyl butyrate, cinnamyl propione
, Cinnamyl benzoate, cinnamyl formate,
Styralyl acetate, Styralyl isobutyrate, Styralyl
Tyralyl propionate, cedryl acetate, cedori
Ruformate, terpinyl acetate, terpinyl iso
Valerate, terpinyl isobutyrate, terpinylbu
Tylate, terpinyl propionate, terpinyl hoo
Mate, decahydro-β-naphthyl formate, deci
Luacetate, tetrahydrofurfuryl butyrate,
Tetrahydrogeranyl acetate, tetrahydrofurf
Lyl acetate, tetrahydromugyl acetate, tet
Lahydrolinalyl acetate, dodecyl acetate,
Lance-2-hexenyl acetate, trans-2-f
Xenyl butyrate, trans-2-hexenyl propyl
Onate, trans-2-hexenyl hexanoate,
Trans-decahydro-β-naphthyl acetate,
Lance-decahydro-β-naphthyl isobutyrate,
Triacetin, triethyl citrate, tricyclodecyl
Luacetate, tricyclodecenyl acetate, tricy
Clodecenyl isobutyrate, tricyclodecenyl pro
Pionate, neryl acetate, neryl isobutyrate
Tol, neryl butyrate, neryl propionate, neryl
Formate, nonyl acetate, nopyr acetate, ha
Idotropic acetate, phenylethyl 2-methyl
Rubutyrate, phenylethyl acetate, phenyl ether
Chill angelate, phenylethyl isovalerate, fur
Phenylethyl isobutyrate, phenylethyl caprylate
, Phenylethyl salicylate, phenylethyl ester
Namate, phenyl ethyl tiglate, phenyl ethyl
Lunanoate, phenylethyl valerate, phenyl
Ethyl pivalate, phenylethyl phenylacetate
G, phenylethyl butyrate, phenylethyl propy
Onate, phenylethyl benzoate, phenyl ethyl
Ruformate, phenylethylmethacrylate, fe
Nylethylmethylethylcarbinyl acetate, phenyl
Lusalicylate, fenkill acetate, butylacete
Butyl Angelate, Butyl Isovalerate, B
Chillisobutyrate, Butyl octanoate, Butylsa
Lysylate, butyl decanoate, butyl dodecanoe
Butyl valerate, butyl phenyl acetate,
Cylbutyryl lactate, butyl butyrate, butyrup
Ropionate, butyl hexanoate, butyl levuline
, Furfuryl acetate, prenyl acetate,
Renyl angelate, prenyl benzoate, propyl
Acetate, propyl isovalerate, propyl isob
Tyrate, propyl octanoate, propyl cinnamate
Red, propyltrans-2, cis-4-decadienoe
Acetate, propyl phenyl acetate, propyl butyr
G, propyl propionate, propyl hexanoe
, Propyl heptanoate, propyl benzoate,
Propyl formate, hexyl 2-methylbutyrate,
Hexyl acetate, hexyl isovalerate, hex
Luisobutyrate, hexyl octanoate, hexyl
Salicylate, hexyl tiglate, hexyl phenyl
Acetate, hexyl butyrate, hexyl propione
Hex, hexyl hexanoate, hexyl benzoate
Tox, hexyl formate, vesicol acetate, vesic
Beryl acetate, heptyl acetate, heptyl oc
Tanoate, heptyl butyrate, heptyl hexanoe
Red, heliotropyl acetate, benzyl 2-methyl
Butyrate, benzyl acetate, benzyl isovalere
, Benzyl isobutyrate, benzyl caprylate
G, benzyl salicylate, benzyl cinnamate,
Benzyl tigrate, benzyl dodecanoate, benzyl
Valerate, benzylphenylacetate, benzylbu
Tyrate, benzyl propionate, benzyl hexano
Aate, benzyl benzoate, benzyl formate,
Pentyl salicylate, myraldyl acetate, mi
Lucenyl Acetate, Miltenyl Acetate, Methyl 1
-Methyl-3-cyclohexenecarboxylate, methyl
Le 2-nonenoate, methyl 2-furoate, methyl 2
-Methyl butyrate, methyl 3-nonenoate, methyl
9-undecenoate, methyl o-methoxybenzoate
Methyl acetate, methyl acetate, methyl
Nisate, methyl angelate, methyl isovaleret
Tomato, methyl isobutyrate, methyl isohexanoe
Tomato, methyl octanoate, methyl octyne carbon
Tomato, methyl oleate, methyl caprinate, methyl cap
Prilate, methyl caproate, methyl gellanate,
Methyl salicylate, methyl cyclooctyl carbonyl
Tomato, methylcyclogeranate, methylcyclopentylide
Acetate, methyl dihydrojasmonate, methyl
Jasmonate, Methylcinnamate, Methyldecanoe
, Methyldecyne carbonate, methyltetradecano
Ate, methyl dodecanoate, methyl trans-2-
Hexenoate, methyltrans-3-hexenoae
Methyl nonanoate, methyl hydroxyhexano
Ate, methyl valerate, methyl phenylacetate
, Methylphenylglycidate, methylbutyrate,
Methyl heptanoate, methyl heptine carbonate,
Methyl pelargonate, methyl benzoate, methyl mi
Restate, methyl laurate, methyl lactate, la
Banjulyl acetate, linalyl acetate, linally
Luisovalerate, Linalyl Isobutyrate, Linalyl
Octanoate, linalyl cinnamate, linalyl butyrate
Rate, linalyl propionate, linalyl hexanoe
, Linalyl benzoate, linalyl formate,
-Zamsk, rosephenone, rosinyl acetate,
Dinyl isobutyrate, rosinyl phenyl acetate,
Rosinyl butyrate, rosinyl propionate, rosini
An example is Reformate.

The (K) nitrogen-containing and / or sulfur-containing and / or halogen-containing compound used in the present invention is nitrogen, sulfur,
It is not particularly limited as long as it is a fragrant organic compound containing halogen in the molecule, 2-tert-butylquinoline, 2-isobutylquinoline, 5,6,7,8-tetrahydroquinoxaline, 5-methyl-3 -Heptanone oxime, 5-methylquinoline, 6-isopropylquinoline, 8-mercaptomenthone, p-methylquinoline, α
-Amylcinamic aldehyde-methyl anthranilate Schiff base, isobutylquinoline, India-
Indole-hydroxy citronella ruschiff base
, Ethyl anthranilate, geranyl nitrile, citronellyl nitrile, dimethyl sulfide, stemon, thiogeraniol, thiotapineol, thiolinaro
Le, triplar-methyl anthranilate Schiff base
Hydroxycitronellal-methyl anthranil
Toschiff base, buccoxime, methyl N-methylanthranilate, methylanthranilate, 1-methylpyrrole, 2- (1,4,8-trimethyl-3,7-nonadienyl) pyridine, 2 (4) -(2-Pinene-10-
Ilmethyl) pyridine, 2,3,5-trimethylpyrazine, 2,3-diethyl-5-methylpyrazine, 2,3-
Diethylpyrazine, 2,3-dimethylpyrazine, 2,
4,6-Trimethyl-4,5-dihydro-1,3,5-
Dithiazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, 2,6-lutidine, 2-acetyl-3-
Ethylpyrazine, 2-acetylthiazole, 2-acetylpyrazine, 2-acetylpyridine, 2-acetylpyrrole, 2-amylpyridine, 2-isobutyl-3-methoxypyrazine, 2-isobutylthiazole, 2-isobutylpyridine, 2- Isopropyl-4-methylthiazole, 2-ethyl-3,5 (3,6) -dimethylpyrazine, 2-ethyl-3-methylpyrazine, 2-ethyl-5
-Methylpyrazine, 2-ethylthiophenol, 2-ethylpyrazine, 2-ethylbenzenethiol, 2-naphthylmercaptan, 2-pentylpyridine, 2-methyl-3-butanethiol, 2-methyl-3-furanthiol, 2-methyl-4-propyl-1,3-oxathiane, 2-methyl-4-methoxythiazole, 2-methyl-5-vinylpyrazine, 2-methyl-5-methylthiofuran, 2-methylpyrazine, 2-methylbenzo Kizo
2-methoxy-3-isopropylpyrazine, 2-methoxy-3-ethylpyrazine, 2-methoxy-3-methylpyrazine, 2-mercaptoacetic acid, 3,
7-dimethyl-2,6-nonadienonitrile, 3-acetylpyridine, 3-isobutylpyridine, 3-thiophenecarboxaldehyde, 3-methylindole, 3-
Methylthio-1-hexanol, 4- (1,4,8-trimethyl-3,7-nonadienyl) pyridine, 4,5-
Dimethyl thiazole, 4-methyl-5-thiazole ethanol, 4-methyl-5-thiazole ethanol acetate, 4-methyl-5-vinyl thiazole, 4-methyl thiazole, 5,6,7,8-tetrahydroquinoxaline, 5-acetyl -2,4-dimethylthiazole, 5-
Ethyl-2-methylpyridine, 5-methyl-2-thiophenecarboxaldehyde, 5-methyl-6,7-dihydrocyclopentapyrazine, 5-methylquinoxaline,
6 (p) -tert-butylquinoline, 6-sec-butylquinoline, 8-sec-butylquinoline, n-butyl anthranilate, N-methyl-N-pentyl-2-
Methylbutyramide, o-thiocresol, S-furfurylthioacetate, S-furfurylthiopropionate, S-methylthiobutyrate, S-methylmethanethiosulfonate, allyl sulfide, cis-3-hexenyl anthranilate, Isoamyl mercaptan, isoquinoline, ethyl 3-methylthiopropionate, ethylthioacetate, ethylmethylthioacetate, quinoline, cuminylnitrile, di-n-propyl disulfide, diallyl disulfide, diallyl sulfide, cis-3-hexenyl anthranilate, Dithiospirofuran, dibutyl sulfide, dipropyl disulfide, dipropyl trisulfide, dimethyl disulfide, dimethyl trisulfide, cinnamyl anthranilate, cinnamyl nitrile Sukato - le, styryl Cyanamid id, thiazole, thiophene, deca hydro cyclododecanone oxazolidinedione - le, tetrahydro -p- methylquinoline,
Tetrahydrothiophene, tetrahydrothiophene-3
-One, tetrahydropyrrole, tetramethylpyrazine, dodecanonitrile, trithioacetone, tridecene-2-nitrile, trimethylthiazole, piperidine,
Piperine, pyrazine, pyridine, phenylethyl anthranilate, butyl sulfide, furfuryl disulfide, furfuryl methyl sulfide, furfuryl mercaptan, benzothiazole, mint sulfide, methyl 3
-Methylthiopropionate, methyl N-2'-methylpentylidene anthranilate, methylthiomethylpyrazine, methyl nicotine, methylfurfuryl disulfide, methylpropylacetaldehyde-methylanthranilate Schiff base, methylpropyl disulfide, Methyl propyl trisulfide, methyl methyl thioacetate, methoxy pyrazine, menthyl anthranilate, limonene thiol, allyl isothiocyanate,
Allyl mercaptan, isopropyl mercaptan, capsaicin, quinine, thirazine, nonanoyl vanillyl amide, paradichlorobenzene, bromostyrene, benzyl isothiocyanate, benzyl cyanide, methional, methionol, and mercaptoacetic acid are exemplified. .

The (L) natural fragrance used in the present invention is not particularly limited, and almond oil, anise oil, abies fa oil, amyris oil, angelica oil, ambaglis tincture, amber sage, amblet seed oil, and Iran. Iran Oil, Incense Oil, Wintergreen Oil, Elemi Oil, Oak Moss Absolute, Oak Moss Essence, Oak Moss Oil, Opoponax Oil, Oris Absolute, Orange Oil, Orange Flower Absolute, Cascailla Oil, Casterium Resinoid, Cassia China Oil, Cassie Absolute, Cassia oil, Kananga Java oil, Camomile oil blue, Chamomile oil, Calams oil, Cardamom oil, Galva Muir oil, caraway oil, guaiac wood oil, guaiac oil, cumin oil, clove bourbon oil, clove oil, costas oil, copaiba balsam, copaiba oil, coriander oil, cypress oil, sandalwood oil, cistrabudnam oil, Cedar wood oil, citronella oil, civet absolute,
Jasmine absolute, juniper berry oil,
Camphor oil, john kill absolute, ginger oil, ginger glass oil, cinnamon ceylon oil, sweet fennel oil, stilx oil, spike lavender oil, spearmint oil, sage oil, sage clarley oil, geranium oil, geranium glass oil, geranium bourbon Oil, celery oil, thyme oil, tarragon oil, tangerine oil, tuberose absolute, true balsam, true balsam oil, tonka beans oil, nutmeg oil, narcissus absolute, neroli vigarade oil, verbena oil, violet leave absolute, pine oil, basil oil , Parsley seed oil, patchouli oil, vanilla oil, vanilla cash register Id, hyssop oil, bitter almond oil, bitter fennel oil, cypress oil, hiba oil, pimento berry oil, hyacinth absolute, petit grain oil, butchu oil, bay oil, petit grain grass oil, petit grain paraguay oil, petit grain bergamot oil, petit grain mandarin , Pettigrain Lemon Oil, Vetiver Oil Java, Vetiver Bourbon, Penny Royal Oil, Pepper Oil, Peppermint Oil, Peruvian Balsam, Peruvian Balsam Oil, Bergamot Oil,
Benzoin oil, benzoin resinoid, boad rose oil, borax oil, hollywood oil, marjoram oil, mandarin oil, mimosa absolute, mill oil, musk ton tincture, mace oil, melissa oil, eucalyptus oil, lime oil,
Lavandin oil, Labdanum oil, lavender oil, roux oil, lemon oil, lemongrass oil,
Rose de may, rose bulgarian oil, rosemary oil, roman chamomile oil, laurel oil,
Examples include lovage oil. These natural materials can also be used in various forms such as essential oils, resinoids, balsams, absolutes, concretes and tinctures.

Chemical names of the product names and common names in the above materials are shown below. Dupical (Quest); 4-
(Tricycle [5.2.1.0 ^2,6 ] decy
lidene-8) butanal Jasmal; 3-Pentylte
trahydropyran-4-yl acetat
e Aphermate (IFF); α,
3,3-Trimethylcyclohexanem
Ethyl formate florarozon (IFF); p-
Ethyl-α, α-dimethylhydroci
nnamaldehyde cyclogalvanate,
Dragoco); Allyl cyclohexyl
oxyacetate Estragol, Methyl
chavicol Revofix (Rhubofix, Firmenic
h); Spiro [1,4-methanonaphth
halogene-2 (1H), 2'-oxirane],
3,4,4a, 5,8,8a, -hexahydro-
3 ′, 7-dimethyl (1), Spiro [1,
4-methanonaphthalene- (2
H), 2'-Oxiran], 3, 4, 4a, 5, 8,
8a-hexahydro-3 ', 6-dimethy
Tripral, a mixture of isomers of l (2) (Triplal, IFF); Dimet
hyl tetrahydrobenzaldehyd
e Coabon (Koavone, IFF); 4-Methy
len-3,5,6,6-tetramethyl-
2-heptanone Limetol; 2,2,6-Trim
Ethyl-6-vinyl tetrahydro
yran ambroxane; Ambroxan (Henkel) Damascon; α-Damascone, β-Damas
cone, γ-Damascone, δ-Damasc
one Damascenone; α-Damascenone, β-Dam
Ascene, γ-Damascone ionone; α-Ione, β-Ione, γ-
Ionene methylionone; α-n-Methylionone,
β-n-Methylionone, γ-n-Meth
ylionone, α-iso-Methyliono
ne, β-iso-Methylionone, γ-i
so-Methylionone sandals; Bacdanol (IFF); 2-Ethy
l-4- (2,2,3-trimethyl-3-cy
clopenten-1-yl) -2-buten-1
-Ol Brahamanol (Dragoco); 2-Met
hyl-4- (2,2,3-trimethyl-3-
Cyclopenten-1-yl) butanolol Madranol (Dragoco); β-2,2,3
-Tetramethyl-3-cyclopentene
nyl-2-butenol Sandalore (Givaudan); 3-Met
hyl-5- (2,2,3-trimethylcyc
lopent-3-en-1-yl) -pentan-
2-ol 3,3-Dimethyl-5- (2,2,3-tri
methylcyclopenten-1-yl) -p
ent-4-en-2-ol, methyl sade
Musks such as flor (TPC) and Sandeol (MS); Cashmeren (IFF), Galaxo
lid (IFF), Tonalide (PFW), P
hantolide, Versalide, Exalt
olde, Exaltone, Oxalide, 12
-Oxahexadecanolide, Ethyl
nebrassylate, Musk ketone,
Celestolide (IFF), Traceoli
de (Quest), Ethylenedocan
edioate, 5-Cyclohexadecen-
1-one and the like iso-E-super; Iso-E-Super (IF
F) 7-Acetyl-1,2,3,4,5,6,7,8-
octahydro-1,1,6,7-tetrame
thym-naphthalene timbelol; Timberol (Dragoco) 1- (2,2,6-Trimethylcyclohexe)
xan-1-yl) -hexan-3-ol iron; α-Irone, β-Irone γ-Iron
e, α-Dynascon; α-Dynascene (Firm
enich) 1- (5,5-Dimethyl cyclohexe
n-1-yl) -4-penten-1-one The above-mentioned mixed material for each functional group and the prepared composition prepared by mixing the mixed material are preferably used by examining the addition concentration depending on the purpose of use. For example, when it is used only for the purpose of deodorizing, it is desirable to prepare and use it so that the added concentration is less than the threshold value of the composition.
Because, as the generally known deodorizing mechanism, physical adsorption, chemical neutralization and sensory deodorization are known, and as a mechanism when a fragrance is used, chemical neutralization and sensory deodorization are known. It is said to be the main, but in any case, if the perfume material is contained in the deodorant composition above the threshold value, there is a possibility that a deodorant effect and a flavoring effect will appear, and This is because the deodorizing effect may not be obtained.

When used for masking, the
In order to make the effect of
Density is 1 to 10 times the threshold⁷Double the concentration, more preferably
10 ^TwoDouble to 10⁶Be prepared and used so that
Is desirable. In this area of use,
With the deodorizing effect of each component, the presence or absence of olfactory
Shows a masking effect when the stimulus reaches the nostrils,
The synergistic effect can reduce unpleasant odor and offensive odor.
it can. A clear scent effect in this concentration range
May not be indicated.

Further, in order to reduce unpleasant odors and offensive odors and to obtain a pleasant sensation, the composition should be prepared and used such that the concentration added is 10 ^{5 to} 10 ⁷ times the threshold value. Is desirable. In this usage area, a pleasant fragrance (fragrance) effect is obtained together with a masking effect, and a product having high commercial value is obtained by the synergistic effect.

In the present invention, the threshold value means a minimum stimulus amount in which a sensory organ can sense a stimulus such as smell, taste and sound in physiological terms. The limit concentration of a scented substance capable of perceiving an odor with the sense of smell is called the scent threshold of that scented substance. It is usually expressed in units such as ppm, ppb, mg / l, molar concentration, and number of molecules. It can be said that the lower this value is, the stronger the odor of the substance. Although one threshold value is statistically specified for one fragrant substance, the same substance may have a concentration in water or a diluting solvent, or may have a concentration in the air. The threshold includes a detection threshold and a recognition threshold. The detection threshold is the concentration at which the odor is first felt by gradually increasing the concentration from the odorless stage, and the cognitive threshold is the concentration at which the odor can be identified first. Hen). The threshold in the present invention refers to a cognitive threshold. The threshold value of the fragrance is described in various documents, for example, 1-p- which is a characteristic aroma component of grapefruit.
Menten-8-thiol is 1.0 × 10 ⁻⁴ pp in water
It is known that b shows the lowest threshold value among commonly known substances, and that cis-3-hexen-1-ol, which is a typical fragrance, shows 6.6 × 10 ⁻¹ partial pressure ppb in air. Has been. However, as described above, since the threshold value has different units and numerical values depending on the medium actually used, the method of obtaining it by a simple experiment is generally used. That is, when a fragrance is used in water, a large number of samples obtained by sequentially diluting the fragrance as an aqueous solution are prepared, and two skilled panelists are allowed to evaluate two fragrant samples and one unperfumed sample. This is a method of recognizing the maximum concentration with a correct answer rate of less than 50% as a threshold value. The threshold value of the mixed fragrance containing a plurality of fragrance components can be measured in the same manner.

In many cases, the composition of the present invention can be more effectively practiced by adding a surfactant. Examples of such a surfactant include carboxylic acid type anionic surfactants such as aliphatic monocarboxylic acid salt, polyoxyethylene alkyl ether carboxylate, N-acyl sarcosine salt and N-acyl glutamate, dialkyl sulfosuccinic acid. Salts, alkane sulfonates, alpha olefin sulfonates, linear alkylbenzene sulfonates, alkyl (branched) benzene sulfonates, naphthalene sulfonate-formaldehyde condensates, alkylnaphthalene sulfonates, N-methyl-N
-Sulfonic acid type anionic surfactants such as acyl taurine salts, alkyl sulfates, polyoxyethylene alkyl ether sulfates, sulfate ester type anionic surfactants such as fat and oil sulfate ester salts, alkyl phosphates, polyoxyethylene alkyl ethers Phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkylphenyl ether phosphate, etc. phosphate ester type anionic surfactants, glycerin fatty acid ester, sorbitan fatty acid ester, sucrose fatty acid ester, etc. ester type nonionic interface Activator, polyoxyethylene alkyl ether, polyoxyethylene alkylphenyl ether, ether type nonionic surfactant such as polyoxyethylene polyoxypropylene glycol, fatty acid polyethylene glycol Ester, ether type nonionic surfactant such as fatty acid polyoxyethylene sorbitan, alkanolamide type nonionic surfactant such as fatty acid alkanolamide, alkylamine salt type such as monoalkylamine salt, dialkylamine salt and trialkylamine salt Quaternary ammonium salts such as cationic surfactants, alkyl trimethyl ammonium chloride, alkyl trimethyl ammonium bromide, alkyl trimethyl ammonium iodide, dialkyl dimethyl ammonium chloride, dialkyl dimethyl ammonium bromide, dialkyl dimethyl ammonium iodide alkyl benzyl dimethyl ammonium chloride -Type cationic surfactants, alkyl betaines, carboxybetaine-type amphoteric surfactants such as fatty acid amidopropyl betaine, 2-alkoxy -N-carboxymethyl-N-hydroxyethyl-imidazolinium betaine and other 2-alkylimidazoline-derived amphoteric surfactants, glycine-type amphoteric surfactants such as alkyldiethylenetriaminoacetic acid and dialkyldiethylenetriaminoacetic acid, alkylamine oxides And aminopoxide-type amphoteric surfactants such as When these surfactants are used, the concentration added is 0.001 to 10
Weight percent is generally used, and often 0.1 to 10 weight percent is often used. If it is less than 0.001% by weight, the effect of addition is small, and if it exceeds 10% by weight, the development of aroma tends to be suppressed, which may have a negative effect on the purpose of flavoring. To get it. However, since this can be said to be a rather preferable effect in terms of deodorizing effect, when the main purpose is the deodorizing effect, the surfactant can be used in the range of 10 to 95% by weight.

In the present invention, a solvent can be further used. Examples of such a solvent include water, methanol, ethanol, diethyl ether, dipropyl ether, diglycerin, polyethylene glycol, animal fats and oils, vegetable fats and oils, and the like, and the material of the present invention may be used as a solvent. it can. For example, pinene, dipentene, camphene, limonene, dicyclopentadiene, liquid paraffin, ethylene glycol, propylene glycol,
Diethylene glycol, dipropylene glycol, butylene glycol, butane-1,3-diol, butane-
2,3-diol, pentamethylene glycol, neopentyl glycol, 2-methylbutane-2,3-diol, 2-methylbutane-2,4-diol, hexylene glycol, hexamethylene glycol, benzyl alcohol, styralyl alcohol, phenyl Ethyl alcohol, phenoxyethyl alcohol, ethylene glycol monoalkyl ether, propylene glycol monoalkyl ether, diethylene glycol monoalkyl ether, dipropylene glycol monoalkyl ether, butylene glycol monoalkyl ether, butane-1,3-diol monoalkyl ether, butane-
2,3-diol monoalkyl ether, pentamethylene glycol monoalkyl ether, neopentyl glycol monoalkyl ether, 2-methylbutane-2,
3-diol monoalkyl ether, 2-methylbutane-2,4-diol monoalkyl ether, hexylene glycol monoalkyl ether, hexamethylene glycol monoalkyl ether, ethylene glycol dialkyl ether, propylene glycol dialkyl ether, diethylene glycol dialkyl ether, dipropylene Glycol dialkyl ether, butylene glycol dialkyl ether, butane-1,3-diol dialkyl ether, butane-2,3-diol dialkyl ether, pentamethylene glycol dialkyl ether, neopentyl glycol dialkyl ether,
2-methylbutane-2,3-diol dialkyl ether, 2-methylbutane-2,4-diol dialkyl ether, hexylene glycol dialkyl ether, hexamethylene glycol dialkyl ether, glyoxal, acetone, 2-butanone, diacetone alcohol, mesityl Oxide, holone, isophorone, ethyl acetate, ethylene glycol monoester, propylene glycol monoester, glycerin monoester, diethylene glycol monoester, dipropylene glycol monoester, butylene glycol monoester, butane-1,3-diol monoester, butane- 2,3-diol monoester, pentamethylene glycol monoester, neopentyl glycol monoester, 2-methylbutane -2,3-diol monoester, 2-methylbutane-2,4-diol monoester, hexylene glycol monoester, hexamethylene glycol monoester, ethylene glycol diester, propylene glycol diester, glycerin diester, diethylene glycol diester, dipropylene Glycol diester, butylene glycol diester, butane-1,3-diol diester, butane-
2,3-diol diester, pentamethylene glycol diester, neopentyl glycol diester, 2
-Methylbutane-2,3-diol diester, 2-methylbutane-2,4-diol diester, hexylene glycol diester, hexamethylene glycol diester, ethylene glycol monoalkyl ether monoester, propylene glycol monoalkyl ether monoester, diethylene glycol monoalkyl Ether monoester, dipropylene glycol monoalkyl ether monoester, butylene glycol monoalkyl ether monoester, butane-1,3-diol monoalkyl ether monoester, butane-2,3-
Diol monoalkyl ether monoester, pentamethylene glycol monoalkyl ether monoester,
Neopentyl glycol monoalkyl ether monoester, 2-methylbutane-2,3-diol monoalkyl ether monoester, 2-methylbutane-2,4-
Diol monoalkyl ether monoester, hexylene glycol monoalkyl ether monoester, hexamethylene glycol monoalkyl ether monoester, glycerine triester, oxalic acid diester, malonic acid diester, succinic acid diester, glutaric acid diester, tartaric acid diester, malic acid Diester, citric acid triester, and the like. These solvents are used for formulation for the purpose of dilution, volatilization, sustained release, retention effect, homogenization, nonuniformity, etc.
It is used in the range of 95 to 95% by weight. If it is less than 5% by weight, the effect of addition is weak, and if it exceeds 95% by weight, the masking effect may be weakened.

The masking composition of the present invention is preferably used for hair cosmetics, particularly preferably for permanent wave agents and hair dyes.

The permanent waving agent as used in the present invention is a medicated cosmetic used for imparting a permanent wave to the hair to express fashion, and is usually the first
A two-component system using a reducing agent such as thioglycolic acid and an alkaline agent such as ammonia as the agent and an oxidizing agent such as sodium bromate as the second agent is used.
For more information on permanent wave agents, please refer to the well-known and conventional techniques collection (fragrances), Part III. Fragrances for cosmetics (June 2001
Issued by the Japan Patent Office on March 15). When the composition of the present invention is used as a permanent waving agent, for example, when it is used as the first agent, it is often used in combination with an oxidizing agent and an alkaline agent. Hydrogen, saturated tertiary alcohols, aromatic alcohols, acetals and ketals, ethers, tertiary esters, and essential oils containing these components as main components are often used. For example, when used as a second agent, they are used for reduction. Stable hydrocarbons, alcohols, phenols, acetals,
Many ketals, ethers, synthetic musks, acids, lactones, esters and natural flavors are used. Specific examples of the composition of the present invention include (A) hydrocarbons (preferably saturated) as materials stable to oxidation, alkali and reduction.
(B) alcohols (preferably tertiary alcohols),
(C) Phenols (preferably phenol ethers), (F) ethers, (G) synthetic musks, (H)
Acids, (I) lactones, (J) esters (preferably tertiary), (D) aldehydes and / or acetals (acetals are preferably used in alkaline preparations), (E) ketones and / or Alternatively, ketals (ketals are preferably used in alkaline preparations) and (L) natural flavors are mainly used, and (K) nitrogen-containing and / or sulfur-containing and / or halogen-containing compounds are used as accents. The permanent waving agent to which the masking composition of the present invention is added in an appropriate amount is a permanent waving agent having an excellent feeling in use in which the ammonia odor, sulfur odor, mercaptan odor, base odor, etc. are masked. That is, the present invention provides the masking composition of the present invention at 1 × 1.
0 ^-7 to 5.0 is also a permanent wave agent comprising by weight%. If the added concentration is less than 1 × 10 ⁻⁷ % by weight, it is difficult to obtain the masking effect as described above, and if the added concentration exceeds 5.0% by weight, there is no difference from the use of a normal fragrance.

Examples of the reducing agent used in the permanent waving agent of the present invention include thioglycolic acid salts such as thioglycolic acid and ammonium thioglycolate,
Cysteine, cysteic acid salts such as cysteine hydrochloride, and the like, and the compounding amount of the reducing agent is preferably 4.0 to 11.0% by weight in the first agent of the perm agent composition. Also,
From the viewpoint of preventing excessive damage to hair, dithiodiglycolate or the like can be added. Also, from the viewpoint of hair wave-forming ability, an alkaline agent such as ammonia, monoethanolamine, triethanolamine, aminomethylpropanol, ammonium hydrogencarbonate, sodium hydroxide, potassium hydroxide, arginine, lysine, etc. is added to the first agent. It can be blended. The blending amount of the above-mentioned alkaline agent is such that the pH of the first agent of the permanent agent composition is adjusted to 6 to 12. In this pH range, the penetrability of the reducing agent is good and the wave forming ability is excellent.

Examples of the oxidizing agent used in the permanent waving agent of the present invention include bromates such as potassium bromate and sodium bromate, hydrogen peroxide, persulfates, perborates, percarbonates, and percarbonates. Examples thereof include iodate. The compounding amount of the above-mentioned oxidizing agent is the second agent of the permanent agent composition,
1.0 to 10.0% by weight is preferable.

Further, in addition to the above-mentioned essential components, other optional components can be added to the permanent waving agent of the present invention within a range that does not impair the effects of the present invention. Such optional components include natural and synthetic polymer compounds such as xanthan gum, carboxyvinyl polymer, leosane, carboxymethylcellulose, ethylcellulose, hydroxyethylcellulose, crosslinked polyacrylic acid, polyvinyl alcohol, hyaluronic acid; avocado oil, jojoba oil, macadamian nuts. Glycerides such as oil, soybean oil, corn oil, cottonseed oil and olive oil; waxes such as beeswax and lanolin; hydrocarbons such as liquid paraffin, solid paraffin, isoparaffin and squalane; cetyl alcohol, stearyl alcohol, 2-octyldodecanol, Linear and branched higher alcohols such as isostearyl alcohol; polyhydric alcohols such as propylene glycol, glycerin, 1,3-butylene glycol, dipropylene glycol and sorbitol Coles; isopropyl myristate, octyldecyl myristate, etc .; amide acids such as oleic acid diethanolamide, lauric acid diethanolamide; silicone derivatives such as dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, amino-modified silicone Cation activators such as stearyl trimethyl ammonium chloride and distearyl dimethyl ammonium chloride; anion activators such as polyoxyethylene alkyl ether sulfates, higher fatty acid salts, alkyl ether sulfates, alkaroylmethyl taurine salts; lauryl dimethylamide betaine; Amphoteric activators such as undecyl-N-hydroxyethyl-N-carboxymethyl imidazolinium betaine, coconut fatty acid amide propyl dimethyl acetic acid betaine Nonionic activators such as polyoxyethylene alkyl ethers; protein derivatives such as collagen and keratin hydrolysates and amino acid salts; plant extracts, herbal medicines, vitamin preparations, UV absorbers such as oxybenzone, preservatives such as parabens, EDTA salts Metal sequestering agents such as and dyes.

The hair dye referred to in the present invention is 1. To dye gray hair to hide it or make it inconspicuous 2. For the purpose of decoration, which is to decolorize and lighten the original black hair, or to change it into various color tones, it is roughly divided into two purposes, permanent hair dye, semi-permanent hair dye, There are three types of temporary hair dyes. For details of hair dye,
Collection of conventional techniques (fragrance) Part III Fragrance for cosmetics (Heisei 13
June 15, 2015 issued by the Japan Patent Office). When the composition of the present invention is used for a hair dye, for example, when it is used for a permanent hair dye, it is often used in combination with an oxidizing agent, so that a saturated hydrocarbon stable against oxidation, saturated Tertiary alcohol, aromatic alcohol, acetal and ketal,
A large amount of ethers, tertiary esters and essential oils mainly containing these components are used. For example, when they are used for semi-permanent hair dyes, they are often used as acidic preparations, so they are acidic and unstable acetals. , Ketal, and primary esters are often refrained from being used, and when used as a temporary hair dye, for example, there are no particular restrictions.
It can be used based on any subject and preference.
Specific examples of the composition of the present invention include (A) hydrocarbons (preferably saturated) as materials that are stable to oxidation,
(B) alcohols (preferably tertiary alcohols),
(C) Phenols (preferably phenol ethers), (F) ethers, (G) synthetic musks, (H)
Focusing on acids, (I) lactones, (J) esters (preferably tertiary), (D) aldehydes and / or acetals, (E) ketones and / or ketals, and (L) natural flavors And (K) nitrogen-containing and / or sulfur-containing and / or halogen-containing compound is used as an accent.
The hair dye to which an appropriate amount of the masking composition of the present invention has been added is a hair dye having an excellent feeling in use in which the ammonia odor and the base odor are masked. That is, the present invention is also a hair dye containing 1 × 10 ^{−7 to} 5.0% by weight of the masking composition of the present invention. If the added concentration is less than 1 × 10 ⁻⁷ % by weight, it is difficult to obtain the masking effect as described above, and if the added concentration exceeds 5.0% by weight, there is no difference from the use of a normal fragrance.

The oxidative dyes used in the hair dye composition of the present invention include, for example, phenylenediamines, aminophenols, toluylenediamines, aminonitrophenols, diphenylamines, diaminophenylamines, Examples thereof include N-phenylphenylenediamines, diaminopyridines, resorcin, pyrogallol, catechol, aminocresols, and salts thereof. The blending amount of the oxidative dye is not particularly limited as long as it is within the range generally used for oxidative hair dyes. In the present invention, a color tone adjusting agent that changes the color tone in combination with an oxidative dye, which is a main component, is generally included as the oxidative dye of the present invention.

The hair dye that is the subject of the present invention is not particularly limited, and various types of hair dyes are the subject, usually consisting of a combination of an oxidizing dye and an oxidizing agent.
There are also a dosage form, a one-part type which is used as a powder formulation by mixing with water at the time of use, and a multi-part formulation of three or more agents.

Examples of the oxidizing agent used in the present invention include hydrogen peroxide, persulfate, perborate, bromate, periodate, urea peroxide and the like.

The hair dye of the present invention may contain other components usually used in hair dyes, as long as the effects of the present invention are not impaired. For example, glycerin, propylene glycol, dipropylene glycol, polyethylene glycol, chondroitin sulfate, hyaluronate, diglycerin, 1,3-butylene glycol, sorbitate.
Moisturizers such as alcohol, lanolin, squalane, liquid paraffin, petrolatum, higher fatty acids, higher alcohols, triglycerides, oil components such as ester oils, dimethylsiloxane, methylphenylsiloxane, dimethylsiloxane.
Silicones such as methyl (polyoxyethylene) siloxane copolymer, rubbery dimethyl polysiloxane and amino-modified polysiloxane can be mentioned. Also, thioglycol-
Antioxidants and stabilizers such as phosphates, L-ascorbates, bisulfites, hydrosulfites, sulfites, ammonia water, alkanolamines, ammonium carbonate, sodium hydrogen carbonate, sodium hydroxide, water It is also possible to add an alkaline agent such as potassium oxide or aminomethyl propanol.

It is also possible to use an amphipathic substance or a surfactant as the emulsifier. Nonionic surfactants include polyoxyethylene alkyl ethers, polyoxyethylene hydrogenated castor oil derivatives, polyoxyethylene fatty acid esters, polyoxyethylene polyhydric alcohol fatty acid partial esters, polyoxyethylene alkylphenyl ethers. Such as polyoxyethylene-based surfactants, octyl glucoside, octyl polyglycoside, isostearyl glucoside, isostearyl maltoside, isostearyl polyglycoside and other alkyl polyglucosides, polyglycerin fatty acid ester, polyglycerin alkyl ether, etc. Examples thereof include sugar alcohol ethers such as polyglycerin-based surfactants, multi-toloxyalkyl ethers, sorbitol alkyl ethers, fatty acid diethyl amides, higher fatty acid salts, and polyols. Anionic surfactants such as ciethylene alkyl sulfates, alkyl sulfates, alkylbenzene sulfonates, alkyl phosphates, etc., cationic surfactants such as alkyl trimethyl ammonium salts, dialkyl dimethyl ammonium salts, alkyl dimethyl amine oxides, imidazo Amphoteric surfactants such as lithium betaine and dimethylalkaroyl lysine, and other surfactants can be used as appropriate.

Examples of the sequestering agent and preservative include hydroxyethanediphosphonates, phenacetin, EDTA and its salts, parabens, stannates and the like. Further, carboxymethyl cellulose, carboxyvinyl polymer, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, xanthan gum, carrageenan, alginate, pectin,
Thickeners such as ferracene, gum arabic, gatch gum, karaya gum, tragacanth gum, agar powder, bentonite, and crosslinkable polyalkyl acid salts can also be used within the range where the effect of the present invention is not impaired.

As the pH buffering agent, phosphoric acid, citric acid, malic acid, lactic acid, oxalic acid, hydrochloric acid and salts thereof can be appropriately added. In addition to the above, colorants, water, alcohols and the like can be appropriately added.

Most of the hair dyes are oxidatively decolorized and then dyed as the first step. As is clear from the mechanism, the masking composition of the present invention is naturally applied to a hair decolorizing agent.

[0045]

EXAMPLES Next, the present invention will be described more specifically with reference to examples. (Hereinafter, unless otherwise specified, the numerical values in the formulation indicate parts by weight.) Examples 1 to 350: (A) Hydrocarbons, (B) Alcohols, (C) Phenols, (D) Aldehydes as well as/
Or acetals, (E) ketones and / or ketals, (F) ethers, (G) synthetic musks, (H) acids, (I) lactones, (J) esters, (K) nitrogen-containing And / or sulfur-containing and / or halogen-containing compound, (L)
Tables 1 to 35 show the formulation examples containing at least one or more flavors selected from the group consisting of natural flavors. All of them had a fantastic scent and were excellent in palatability. In the classification, A to L represent the above (A) to (L), Sur represents a surfactant, Sol represents a solvent, and "dimethyl sulfide (1%)" represents "1% ethanol solution of dimethyl sulfide". In the prescription, ~ means "total 1
Align with 00 ”.

[Test Example 1] Regarding the above Examples 1 to 343, the threshold value was measured by a specialized panel consisting of 6 men in their 30s to 60s. An aqueous solution was prepared by adding 1% of a 1% alcohol solution of the composition of each example, and 3 of non-perfume 1 and perfume 2 was prepared.
Sensory evaluation by sniffing was performed by the point identification method, and the correct answer rate was 5
If it exceeds 0%, it is further diluted 10 times for evaluation, and this is repeated n times, and the highest concentration at which the accuracy rate is less than 50% is taken as the threshold value. Table 36 shows the n value of each evaluation result. n = 2
Corresponds to 1 ppm.

Examples 351 to 590 and Comparative Examples 1 to 9
6: Permanent wave agent disodium edetate 0.5, stearyl trimethyl ammonium chloride aqueous solution 1, propylene glycol 1, polyoxyethylene sorbitan monolaurate 1, methyl paraoxybenzoate 0.1, ammonium thioglycolate 13.5, strong Ammonia water 2, citric acid 0.5, ammonium bicarbonate 2.5, purified water 77.9 first agent for permanent wave, sodium bromate 8, polyoxyethylene lauryl ether sodium sulfate 5,
Polyoxyethylene tridecyl ether 1, isopropyl palmitate 2, chloride-ortho- (2-hydroxy-
3,8-Trimethylammonio) propyl 0.2, methyl paraoxybenzoate 0.1, anhydrous sodium sulfate 1, 48% sodium hydroxide aqueous solution (pH adjusting agent) appropriate amount, citric acid (pH adjusting agent) appropriate amount, purified water 83 Of the permanent wave agent of the present invention (Examples 351 to 351), and the composition of Examples 1 to 240 was added to the first agent at various concentrations during the production process.
590) was obtained. Further, permanent waving agents (Comparative Examples 1 to 96) added in different concentrations from the above were prepared.

Examples 591-680 and Comparative Examples 97-1
32: Hair dye (1 formulation) Benzyl alcohol 10, Black No. 401 0.5, Orange 2
No. 05, ethanol 15, polyether modified silicone 1, xanthan gum 1, lactic acid 4, sodium hydroxide 0.2, water 67.7 was prepared, and the composition of Examples 241 to 330 was prepared. Hair dye of the present invention (Examples 591 to 680)
Got Further, hair dyes (Comparative Examples 97 to 132) added in different concentrations from the above were prepared.

Examples 681 to 770 and Comparative Example 133 to
168: Hair dye (two-component type) isopropanol 5, polyoxyethylene (5E.
O. ) Octyl phenyl ether 5, isostearic acid 10, polyoxyethylene (5EO) oleyl ether 10, propylene glycol 10, sodium pyrrolidonecarboxylate 2, ammonium thioglycolate 1, L-ascorbic acid 0.5, EDTA 0.5 , Ammonia water 7, paraphenylenediamine 1, purified water 48, and a first agent for a two-component oxidative hair dye, 30% hydrogen peroxide solution 15, methylparaben 0.1, sodium stannate 0.
1, liquid paraffin 5, stearyl alcohol 3, sodium lauryl sulfate 0.5, polyoxyethylene (20
E. O. ) A second agent for a two-component oxidative hair dye consisting of 0.5 of cetyl ether, an appropriate amount of phosphate buffer (adjusted to pH 3), and 75.8 of purified water was prepared. The composition was added at various concentrations during the manufacturing process to obtain hair dyes of the present invention (Examples 681 to 740). Similarly, the compositions of Examples 61 to 90 were added to the second agent at various concentrations during the production process to obtain hair dyes of the present invention (Examples 741 to 770). Also, unlike the above concentrations, the first agent or the second agent
Hair dye added to the composition (Comparative Examples 133 to 156 and 157)
~ 168) were prepared.

[Test Example 2] Regarding the above Examples 351 to 770 and Comparative Examples 1 to 168, a sensory evaluation of deodorant effect, masking effect, and flavoring effect was carried out by a specialized panel consisting of 6 men in their 30s to 60s. went. The evaluation is a five-level evaluation,
×: no effect, Δ: slightly effective, ○: effective,
⊚: Excellent effect, ◎ ◎: Too strong effect. The results are shown in Tables 37-50. In all the test examples, the masking composition of the present invention showed excellent effects.

[0051]

EFFECTS OF THE INVENTION According to the present invention, materials usually used as materials for compounded fragrances are classified according to functional groups (A) hydrocarbons,
(B) alcohols, (C) phenols, (D) aldehydes and / or acetals, (E) ketones and / or ketals, (F) ethers, (G) synthetic musks, (H) Acids, (I) lactones, (J) esters, (K) nitrogen-containing and / or sulfur-containing and / or halogen-containing compounds, and (L) natural flavors are classified into 12 types and at least selected from these groups. A desired masking composition for hair cosmetics can be easily prepared by appropriately blending one or more materials at a specific concentration, as compared with the conventional case.

[0052]

[Table 1]

[0053]

[Table 2]

[0054]

[Table 3]

[0055]

[Table 4]

[0056]

[Table 5]

[0057]

[Table 6]

[0058]

[Table 7]

[0059]

[Table 8]

[0060]

[Table 9]

[0061]

[Table 10]

[0062]

[Table 11]

[0063]

[Table 12]

[0064]

[0065]

[Table 13]

[0066]

[Table 14]

[0067]

[Table 15]

[0068]

[Table 16]

[0069]

[Table 17]

[0070]

[Table 18]

[0071]

[Table 19]

[0072]

[Table 20]

[0073]

[Table 21]

[0074]

[Table 22]

[0075]

[Table 23]

[0076]

[Table 24]

[0077]

[Table 25]

[0078]

[Table 26]

[0079]

[Table 27]

[0080]

[Table 28]

[0081]

[Table 29]

[0082]

[Table 30]

[0083]

[Table 31]

[0084]

[Table 32]

[0085]

[Table 33]

[0086]

[Table 34]

[0087]

[Table 35]

[0088]

[Table 36]

[0089]

[Table 37]

[0090]

[Table 38]

[0091]

[Table 39]

[0092]

[Table 40]

[0093]

[Table 41]

[0094]

[Table 42]

[0095]

[Table 43]

[0096]

[Table 44]

[0097]

[Table 45]

[0098]

[Table 46]

[0099]

[Table 47]

[0100]

[Table 48]

[0101]

[Table 49]

[0102]

[Table 50]

   ─────────────────────────────────────────────────── ─── Continued front page    F-term (reference) 4C083 AA122 AB032 AB082 AB272                       AB312 AB352 AB412 AC022                       AC072 AC102 AC112 AC122                       AC152 AC172 AC182 AC242                       AC302 AC352 AC372 AC402                       AC422 AC442 AC482 AC532                       AC552 AC612 AC642 AC692                       AC712 AC772 AC782 AC792                       AC842 AC902 AD042 AD052                       AD162 AD222 AD352 AD412                       AD532 AD642 BB01 BB41                       CC31 CC34 CC36 EE18 EE21

Claims (25)

[Claims] 1. (A) hydrocarbons, (B) alcohols,
(C) Phenols, (D) Aldehydes and / or acetals, (E) Ketones and / or ketals,
(F) ethers, (G) synthetic musks, (H) acids,
(I) Lactones, (J) esters, (K) nitrogen-containing and / or sulfur-containing and / or halogen-containing compounds, and (L) at least one or more perfume selected from the group consisting of natural perfumes. A masking composition for hair cosmetics, comprising: 2. The content of (A) hydrocarbons is 5 to 90% by weight, the content of (B) alcohols is 10 to 90% by weight,
(C) Phenolic content is 1 to 50% by weight, (D)
The content of aldehydes and / or acetals is 5 to 5
0% by weight, the content of (E) ketones and / or ketals is 10 to 80% by weight, and the content of (F) ethers is 1
˜50% by weight, the content of (G) synthetic musks is 0.1
30% by weight, the content of (H) acids is 0.1 to 20% by weight, the content of (I) lactones is 0.1 to 30% by weight,
(J) Ester content is 10 to 90% by weight, (K)
The content of nitrogen-containing and / or sulfur-containing and / or halogen-containing compound is 0 to 10% by weight, and the content of (L) natural fragrance is 0 to
70% by weight of the masking composition for hair cosmetics according to claim 1. 3. The hydrocarbon (A) is 1,3,5-undecatriene, p-cymene, α-pinene, α-ferrandrene, β-caryophyllene, β-pinene, Δ-carene,
Alloocimene, ocimene, dihydromyrcene, dipentene, sclarene, cedrene, terpinene, terpinolene, valenecene, bisaborene, farnesene, myrcene, limonene, longifolene, adamantane, isolongifolene, camphene, guayen, diphenyl, diphenylmethane, biphenyl, 3,7. -Dimethyl-1,3,6-octatriene, 4-isopropyl-
1-methyl-2-propenylbenzene, 7-methyl-3
-Methylene-1,6-octadiene, p-ethylstyrene, α-p-dimethylstyrene, isoprene, undecatriene, undecane, octadecadiene, octadecane, octadecene, octane, octene, cumene, sabinene, cyclohexane, cyclohexene, cyclo Pentadiene, dicyclopentadiene, styrene, decalin,
Decane, tetradecane, tetralin, dodecane, tridecane, tridecene, naphthalene, nonane, nonene, norbornane, norbornene, hexadecane, hexane, heptadecadiene, heptadecane, heptadecene, heptane, pentadecane The masking composition for hair cosmetics according to claim 1 or 2. 4. The alcohol (B) is 10-undecenol, 1-octen-3-ol, 2,6-nonadienol, 2-tert-butylcyclohexanol, 2-ethylhexanol, 2-heptanol, 3,5. 5-trimethylhexanol, 3-octanol, 3-phenylpropyl alcohol, L-menthol, n-decyl alcohol, p, α-dimethylbenzyl alcohol, p-
tert-butylcyclohexanol, p-methyldimethylbenzylcarbinol, α, 3,3-trimethyl-
2-norbornanemethanol, α-n-amylcinnamic alcohol, α-fenkyl alcohol, β-phenylethyl alcohol, anis alcohol, amber core, ambrinol, isononyl alcohol, isophytol, isopulegol, isoborneol, ethyl linalool, Octanol, carveol, geraniol, santalol, cis-3-hexen-1-ol,
Cis-6-nonenol, citronellol, dihydro-α
-Terpineol, dihydrocitronellol, dihydromyrcenol, dihydrolinalool, dimethylphenylethylcarbinol, dimethylbenzylcarbinol,
Cynamic alcohol, styralyl alcohol, cedrol, terpineol, terpinen-4-ol, timbelol, tetrahydrogeraniol, tetrahydromyrcenol, tetrahydromugol, tetrahydrolinalool, nerol, nerolidol, nonanol, nonyl alcohol, nopol, hydrotropil Alcohol, bacdanol, patchouli alcohol, farnesol, phytol, phenylethylmethylethylcarbinol, phenoxyethyl alcohol, furfuryl alcohol, vetiverol, perilla alcohol, benzyl alcohol, mayol, myrcenol, myrtenol, lavandulol, linalool, 1- ( 2,2,6-trimethylcyclohexanyl) -hexan-3-ol,
1,1-dimethyl-3-phenylpropanol, 1-decanol, 1-dodecanol, 1-nonen-3-ol, 1-heptanol, 1-penten-3-ol,
2,2-dimethyl-3-phenylpropanol, 2,4
-Dimethyl-3-cyclohexene-1-methanol,
2,4-dimethylbenzyl alcohol, 2,4-hexadienol, 2,5,5-trimethyloctahydro-
2-naphthol, 2,6-dimethylheptan-2-ol, 2-isobutyl-4-hydroxy-4-methyltetrahydropyran, 2-undecanol, 2-octanol, 2-nonanol, 2-phenylpropyl alcohol, 2- Methyl-3-buten-2-ol, 2-methyl-4- (2,2,3-trimethyl-3-cyclopentenyl) -2-butenol, 2-methyl-4- (2,2,
3-trimethyl-3-cyclopentenyl) -butanol, 2-methyloctanol, 2-methyldecanol,
2-methoxy-2-phenylethyl alcohol, 3,3
-Dimethyl-Δ2, β-norbornane-2-ethanol, 3,4,5,6,6-pentamethyl-2-heptanol, 3,6-dimethyloct-3-ol, 3,7-
Dimethyl-1-octanol, 3,7-Dimethyl-7-
Methoxyoct-2-ol, 3-tunanol, 3-dodecanol, 3-heptanol, 3-methyl-1-phenyl-3-pentanol, 3-methyl-2-butene-1.
-Ol, 3-methyl-5- (2,2,3-trimethyl-3-cyclopentenyl) -pentan-2-ol, 3
-Methyl-5-phenylpentanol, 3-methylpentanol, 4-isopropylcyclohexanol, 4-
Tuanol, 4-methyl-3-decen-5-ol, 5
-Methyl-2-phenyl-2-hexanol, 6,8-
Dimethyl-2-nonanol, 9-decenol, 9-decen-1-ol, E.I. G. Monobutyl ether, sec
-Undecyl alcohol, sec-octyl alcohol, sec-nonyl alcohol, α, α, p-trimethylphenylethyl alcohol, α, α-dimethylphenylethyl alcohol, α-isobutylphenylethyl alcohol, α-bisabolol, α-propylphenyl Ethyl alcohol, β, γ-hexenol, β-caryophyllene alcohol, γ-4-dimethyl-3-cyclohexene-1-propanol, aloosimenol, ambestol, isocamphylcyclohexanol, isocyclogeraniol, isodihydrolavandulol , Isobutylbenzyl carbinol, undecanol, ethylene glycol, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monopropyl ether Ether, ethylene glycol monomethyl ether, ocimenol, camemecol D
H, cumin alcohol, geranyl linalool, sabinene hydrate, diethylene glycol, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol monopropyl ether, diethylene glycol monomethyl ether, cyclohexylethyl alcohol, cyclomethylene citronellol, cis-4-hexen-1-ol , Cis-p
-Isopropylcyclohexylmethanol, dihydrocarbeol, dipropylene glycol, dipropylene glycol monoethyl ether, dipropylene glycol monobutyl ether, dipropylene glycol monopropyl ether, dipropylene glycol monomethyl ether, dimethyloctanol, dimethylvinylcarbinol, sclareol, deca Hydro-β-naphthol, tetrahydroaroosimenol, trans-2-octanol, trans-2-hexenol, trans-
3-hexen-1-ol, neopentyl glycol,
Hydrocinnamic alcohol, vanillyl alcohol, pinocarveol, butane-1,3-diol, butane-1,3-diol monoethyl ether, butane-
1,3-diol monobutyl ether, butane-1,3
-Diol monopropyl ether, butane-1,3-diol monomethyl ether, butane-2,3-diol, butane-2,3-diol monoethyl ether, butane-2,3-diol monobutyl ether, butane-
2,3-diol monopropyl ether, butane-2,
3-diol monomethyl ether, butylene glycol, propylene glycol, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol monopropyl ether, propylene glycol monomethyl ether, hexamethylene glycol, hexylene glycol, pentamethylene glycol, muguet alcohol, methyl The masking composition for hair cosmetics according to any one of claims 1 to 3, which is at least one kind of synthetic fragrance selected from β-phenylethyl alcohol and methyl sundeflor. 5. The (C) phenols are p-cresol, isoeugenol, estragole, eugenol, hinokitiol, benzylisoeugenol, benzyleugenol, methylisoeugenol, methyleugenol, yarayala, 2,6-dimethoxyphenol, 4-. Ethyl guaiacol, 4-methyl guaiacol, 5-propenyl guaetol, β-naphthol isobutyl ether, p-allylphenol, p-ethylphenol, isosaflor, ethylisoeugenol, catechol dimethyl ether, carvacrol, guaiacol, creozole, safrole, Dihydroeugenol, thymol, chabicol, hydroquinone dimethyl ether,
The masking composition for hair cosmetics according to any one of claims 1 to 4, wherein the masking composition is at least one synthetic fragrance selected from banitrop, bromelia, methoxybenzene, resorcinol dimethyl ether, and shogaol. . 6. The (D) aldehydes and / or acetals are 10-undecenal, 2,4-dimethyl-4,4.
a, 5,9b-Tetrahydroindeno [1,2d]-
1,3-dioxin, 2,4-decadienal, 2,6
-Nonadienal, 2-butyl-4,4,6-trimethyl-1,3-dioxane, 2-hexyl-5-methyl-
1,3-dioxolane, 2-methylundecanal, 2
-Methyl undecanal dimethyl acetal, 3-ethyl-2,4-dioxaspiro [5.5] undec-8-
Ene, 3-ethyl-8 (9), 11-dimethyl-2,4
-Dioxaspiro [5.5] undec-8-ene, 3-
Propylbicyclo [2.2.1] -hepta-5-ene-
2-carboxaldehyde, 4-isopropyl-5,5
-Dimethyl-1,3-dioxane, 4-heptenal,
5-methyl-5-propyl-2- (1-methylbutyl)
-1,3-dioxane, o-methoxycinnamic aldehyde, o-methoxybenzaldehyde, p-tolylaldehyde, α-n-hexylcinnamic aldehyde,
α-amylcinnamic aldehyde, acetaldehyde, acetaldehyde ethyl linalyl acetal, acetaldehyde diethyl acetal, anisaldehyde,
Aldehyde C-10, Aldehyde C-11, Aldehyde C-12, Aldehyde C-6, Aldehyde C
-6 DEA, aldehyde C-6 DMA, aldehyde C-6 PG acetal, aldehyde C-8, aldehyde C-8 DEA, aldehyde C-8DM
A, aldehyde C-9, aldehyde C-9 DE
A, aldehyde C-9 DMA, isocyclocitral, ethyl vanillin, cantoxal, cucumber aldehyde, cumin aldehyde, geranial, cyclamen aldehyde, cis-6-nonenal, citral, citronellal, citronellyl oxyacetaldehyde, sinensal, dupicar, trans- 2-hexenal, trans-2-hexenal diethyl acetal, tripral, neral, hydrotropaldehyde, vanillin, hydroxycitronellal, phenylacetaldehyde, phenylacetaldehyde P.
G. Acetal, phenylacetaldehyde dimethyl acetal, furfural, floralozone, heliotropin, helional, perilaldehyde, bergamar,
Belt acetal, bernaldehyde, benzaldehyde, homomylacaldehyde, mylacaldehyde, melonal, lillard, lilial, 2,4,6-
Triisopropyl-1,3,5-trioxane, 2,4
-Undecadienal, 2,4-octadienal,
2,4-Dioxa-3-methyl-7,10-methanospiro [5.5] -undecane, 2,4-dodecadienal, 2,4-nonadienal, 2,4-hexadienal, 2,4-heptadienal, 2 , 5,6-Trimethyl-4-heptenal, 2,6,10-trimethyl-
5,9-Undecadienal, 2-methyl-3- (4-
Methylphenyl) -propanal, 2-methyl-4-
(2,6,6-trimethyl-2-cyclohexenyl)-
3-butenal, 2-methylbutanal, 3-phenylpropionic aldehyde, 3-phenylpropionic aldehyde dimethyl acetal, 3-methyl-5-phenylvaleraldehyde, 4- (2,2,6-trimethyl-2 (1 ) -Cyclohexene) -2-methylbutanal, 4- (4-methyl-3-cyclohexe-1-ylidene) -pentanal, 4-methyl-2-phenyl-2-
Pentenal, 5- (hydroxymethyl) -2-furfural, 5,9-dimethyl-4,9-decadienal,
5-methylfurfural, n-valeraldehyde, p-
tert-butyl hydrocinnamic aldehyde, p
-Isobutyl-α-methylhydrocinnamic aldehyde, p-isopropyl hydrotropaldehyde, p
-Methyl hydrotropaldehyde, p-methylphenylacetaldehyde, p-methylphenoxyacetaldehyde, p-methoxybenzaldehyde, α-n-amylcinnamic aldehyde diethyl acetal, α-amylcinnamic aldehyde dimethyl acetal, α-
Camphoren aldehyde, α-methyl cinnamic aldehyde, β-methyl hydrocinnamic aldehyde, γ-n-hexyl cinnamic aldehyde, acetaldehyde ethyl isoeugenyl acetal, acetaldehyde ethyl cis-3-hexenyl acetal, acetaldehyde ethyl phenyl ethyl acetal, Acetaldehyde ethylhexyl acetal, acetaldehyde citronellyl ethyl acetal, acetaldehyde citronellyl methyl acetal, acetaldehyde phenylethyl n-propyl acetal, aldehyde C-1
3, aldehyde C-14, aldehyde C-5, aldehyde C-7, aldehyde C-7 DEA, aldehyde C-7 DMA, isovaleraldehyde, octahydro-4,7-methano-1H-indenecarboxaldehyde, caryophyllene aldehyde , Geranyloxyacetaldehyde, safranal, salicylaldehyde, cyclocitral, cis-3-hexenal, cis-3-hexenal diethyl acetal, cis-4-decenal, citral PG acetal, citral diethyl acetal, citral dimethyl acetal, citronellal EG acetal, dihydroindenyl-2,
4-dioxane, dimethyl octanal, cinnamic aldehyde, decanal diethyl acetal, decanal dimethyl acetal, tetrahydrocitral, dodecanal dimethyl acetal, trans-2-undecenal, trans-2-decen-1-al, trans-2- Dodecenal, trans-2-tridecenal,
Trans-2-nonenal, trans-2-heptenal, trans-2-pentenal, trans-4-decenal, trimethylundecenal, trimethyldecadienal, hydrotroperaldehyde E. G. Acetal, hydrotropalaldehyde dimethyl acetal, vanillin P.I. G. Acetal, paraaldehyde, hydroxycitronellal diethyl acetal, phenylacetaldehyde 2,3-butylene glycol acetal, phenylacetaldehyde 2,4-dihydroxy-4-methylpentane acetal, phenylacetaldehyde diisobutyl acetal, phenoxyacetaldehyde,
Furfuryl acrolein, heptanal E. G. Acetal, heliotropin diethyl acetal, heliotropin dimethyl acetal, benzaldehyde P.I. G. Acetal, benzaldehyde glyceryl acetal, benzaldehyde diethyl acetal, benzaldehyde dimethyl acetal, formaldehyde cyclododecylethyl acetal, methyl decanal, methylnonylacetaldehyde dimethyl acetal, methyl vanillin,
Methoxydicyclopentadienecarboxaldehyde,
The masking composition for hair cosmetics according to claim 1, which is at least one kind of synthetic fragrance selected from methoxy citronellal. 7. The (E) ketones and / or ketals are 2
-Sec-butylcyclohexanone, 2-acetyl-
3,3-dimethylnorbornane, 2-acetyl-5-methylfuran, 2-acetylfuran, 2-butyl-1,4
-Dioxaspiro [4,4] nonane, 2-hexylcyclopentanone, 3-hydroxy-4,5-dimethyl-2
-(5H) -furanone, 5-ethyl-3-hydroxy-4-methyl-2 [5H] -furanone, 6-methyl-
3,5-heptadien-2-one, d-pulegone, L-
Carvone, o-tert-butylcyclohexanone, p
-Tert-butylcyclohexanone, p-methylacetophenone, p-methoxyacetophenone, α-dynascon, α-phencon, β-methylnaphthylketone,
Acetyl Cedrene, Acetophenone, Anisylacetone, Allyl α-ionone, Ionone, Iso E Super, Isojasmon, Isodamascon, Isolongiforanone, Iron, Ethylisoamylketone, Ethylmaltol, Kashmeran, Calone, Camphor, Coabon, Cycloten, Cis-jasmone, dihydrocarvone, dihydrojasmone, dibenzyl ketone, cedrenone, damascon, damascenone, trimofix O,
Noot Katong, Furaneol, Puri Katong, Florex, Beltfix, Verbenone, Benzophenone,
Maltol, methylionone, methylcyclopentenolone, methylheptenone, menthone, raspberry ketone,
1- (4-methoxyphenyl) -1-penten-3-one, 1- (p-menthen-6-yl) -1-propanone, 1-acetyl-3,3-dimethyl-1-cyclohexene, 2- ( 1-cyclohexen-1-yl) cyclohexanone, 2,2,5,5-tetramethyl-4-isopropyl-1,3-dioxane, 2,2,5-trimethyl-5-pentylcyclopentanone, 2,3,3 5-trimethylcyclohexen-4-yl-1-methyl ketone,
2,3-hexadione, 2,3-heptanedione, 2,
3-pentadione, 2,4-di-tert-butylcyclohexanone, 2,5,5-trimethyl-2-phenyl-1,3-dioxane, 2,6,10-trimethyl-1
-Acetyl-2,5,9-cyclododecatriene, 2,
6,6, -Trimethyl-2-cyclohexene-1,4-
Dione, 2-n-butylidene-3,5,5 (3,3,3
5) -Trimethylcyclohexanone, 2-n-heptylcycloheptanone, 2'-acetonaphthone, 2-undecanone, 2-octanone, 2-cyclopentylcyclopentanone, 2-tridecanone, 2-nonanone, 2-hydroxy-6-isopropyl. -3-Methyl-2-cyclohexenone, 2-butanone, 2-heptanone, 2-heptylcyclopentanone, 2-pentanone, 2-pentyl-2-cyclopentenone, 2-pentylcyclopentanone, 3,3- Dimethyl cyclohexyl methyl ketone,
3,4-dimethyl-1,2-cyclopentadione, 3,
4-hexadione, 3,5-dimethyl-1,2-cyclopentadione, 3-acetyl-2,5-dimethylfuran, 3-octanone, 3-nonanone, 3-hydroxymethyl-2-nonanone, 3-hexanone, 3-heptanone, 3-hepten-2-one, 3-methyl-4-phenyl-3-buten-2-one, 3-methyl-5- (2,
2,3-trimethyl-3-cyclopentenyl) -3-penten-2-one, 3-methyl-5-propyl-2-cyclohexenone, 4- (4-hydroxy-3-methoxyphenyl) -2-butanone, 4- (4-methoxyphenyl) -3-buten-2-one, 4 (5) -acetyl-
7,7,9 (7,9,9) -trimethylbicyclo [4.
3.0] Nona-1-ene, 4,7-dihydro-2- (3
-Pentanyl) -1,3-dioxepin, 4,7-dihydro-2-isoamyl-2-methyl-1,3-dioxepin, 4-tert-amylcyclohexanone, 4-oxoisophorone, 4-cyclohexenyl-4-methyl −
2-pentanone, 4-heptanone, 4-methyl-3-penten-2-one, 4-methyl-4-phenyl-2-pentanone, 4-methylene-3,5,6,6-tetramethyl-2-heptanone , 5-cyclohexadecen-1-one, 5-hydroxy-4-octanone, 5-phenyl-5-methyl-3-hexanone, 5-methyl-2,3-
Hexadione, 7-methyl-3,5-dihydro-2H-
Benzodioxepin-3-one, p-hydroxyphenylbutanone, p-methoxyphenylacetone, α-methylanisalacetone, acetylisovaleryl, acetylcaryophyllene, acetyldimethyltetrahydrobenzindane, acetoin, acetoketal, acetophenone neopentyl glycol Acetal, acetone, atrinone, anisylideneacetone, amylcyclopentanone, ethyl acetoacetate E.I. G. Ketal, ethyl acetoacetate propylene glycol acetal,
Oxocedran, krypton, geranylacetone, diacetyl, diacetone alcohol, diosphenol, cyclohexanone, cyclohexenone, cyclopentanone, cis-2-acetonyl-4-methyltetrahydropyran, dimethyloctenone, zingerol, cedranone, vitalide, piperitenone, piperitone. , Piperonylacetone, farnesylacetone, pseudoionone, butylideneacetone, furfural acetone, propiophenone, heliotropylacetone, verdoxane, benzylideneacetone, homofuraneol, mesityl oxide, methyl α-furylketone, methylisopropylketone, methylyriton , At least one synthetic fragrance selected from methylcedrilone and methyltetrahydrofuranone Hair cosmetic masking composition for according to claims 1 to 6, symptoms. 8. The (F) ethers are 1,4-cineole,
1,8-cineole, p-cresyl methyl ether, β
-Caryophyllene oxide, β-naphthyl isobutyl ether, β-naphthyl ethyl ether, β-naphthyl methyl ether, anethole, ambroxane, isoamyl phenyl ethyl ether, isobornyl methyl ether, glycalva, cyclumber, diphenyl oxide, sedlumbar, sedryl Methyl ether, theaspirane, nerol oxide, phenylethyl methyl ether, madrox, linalool oxide, rimitol, rubofix, ruboflor, rose oxide, rose furan, 13-oxabicyclo [10.
3.0] Pentadecane, 1-methylcyclododecylmethyl ether, 2,2,6-trimethyl-6-vinyltetrahydropyran, 2,2-dimethyl-5- (1-methyl-1-propenyl) -tetrahydrofuran, 2- Ethylidene-6-isopropoxybicyclo [2.2.1] heptane, 2-oxaspiro [4.7] dodecane, 2-butyl-4,6-dimethyldihydropyran, 2-methyl-2.
-Butenyl phenyl ethyl ether, 3,3,5-trimethylcyclohexyl ethyl ether, 3-oxabicyclo [10.3.0] -pentadec-6-ene, 4-allylanisole, 5-isopropenyl-2-methyl- Two
-Vinyl tetrahydrofuran, 8,9-epoxy cedrene, n-decyl vinyl ether, tert-butyl hydroquinone dimethyl ether, α-cedrene epoxide, α-terpinyl methyl ether, allyl phenyl ethyl ether, isoamyl benzyl ether, isolongifolene epoxide , Ethyl o-methoxybenzyl ether, ocimene epoxide, geranyl ethyl ether, cyclodecenyl methyl ether, cyclohexyl ethyl ether, cyclohexyl phenyl ethyl ether, citroxide, citronellyl ethyl ether,
Dibenzyl ether, juniparome, cedrol methyl ether, decyl methyl ether, tricyclodecenyl methyl ether, trimethylcyclododecatriene epoxide, methylphenyl ethyl ether, methylhexyl ether, methylbenzyl ether, limonene oxide, 1,2-dimethoxybenzene , 1,3-dimethoxybenzene, 1,4-dimethoxy-2-tert-
Butylbenzene, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, ethylene glycol dipropyl ether, ethylene glycol dimethyl ether, diethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, diethylene glycol dipropyl ether, diethylene glycol dimethyl ether, dimethyl ether, tetrahydrofuran, propylene glycol diethyl ether The masking composition for hair cosmetics according to claim 1, which is at least one kind of synthetic fragrance selected from propylene glycol dimethyl ether. 9. (G) Synthetic musks are 10-oxahexadecanolide, 11-oxahexadecanolide, 12-oxahexadecanolide, ambrettolide, ambreton, ezaltolide, egisalton, galaxolide, cyclohexahexa. At least one selected from decanolide, cyclopentadecanolide, cyclopentadecanone, civetone, cerbolide, celestolide, tonalide, phantolide, pentalide, formylethyltetramethyltetralin, musktibeten, muscone, mosken, muskambret, versalid 9. The masking composition for hair cosmetics according to claim 1, which is a synthetic fragrance. 10. The (H) acids are phenylacetic acid, 2-ethylbutyric acid, 2-ethylhexanoic acid, 2-decenoic acid, 2-hexenoic acid and 2-methyl-2-. Pentenoic acid, 2-methylbutyric acid, 2-methylheptanoic acid, 4-pentenoic acid, 4-methylpentanoic acid, acetic acid, isovaleric acid, isobutyric acid, undecanoic acid Ic acid, undecylenic acid, octanoic acid, oleic acid, geraniic acid, synthetic acid, stearic acid, tigric acid, decanoic acid, dodecanoic acid, tridecanoic acid, nonanoic Acid, Valeric Acid, Hydrocinnamic Acid, Pyrvic Acid, Butyric Acid, Propionic Acid, Hexanoic Acid, Heptanoic Acid, Mystic Acid, Lactic Acid, Linoleic Acid, Linolenic Acid , Reblic Acid,
Oxalic acid, glutaric acid, citric acid, succinic acid, tartaric acid, terephthalic acid, vanillic acid, valine, phytic acid, fumaric acid, benzoic acid, malic acid, mareic acid, It is at least 1 sort (s) of synthetic fragrance | flavor selected from malonic acid, It is characterized by the above-mentioned.
9. A masking composition for hair cosmetics according to item 9. 11. The lactone (I) is 6-methylcoumarin, α-angelicalactone, γ-n-butyrolactone, γ-undecalactone, γ-octalactone, γ-.
Decalactone, γ-nonalactone, γ-valerolactone, γ-hexalactone, γ-heptalactone, δ-2
-Decenolactone, δ-undecalactone, δ-octalactone, δ-decalactone, δ-tetradecalactone, δ-dodecalactone, δ-tridecalactone, δ-
Nonalactone, δ-hexalactone, ε-decalactone, ε-dodecalactone, whiskey lactone, coumarin, dihydrojasmon lactone, jasmine lactone, jasmolactone, methyl γ-decalactone, menthalactone, 4,6,6 (4,4,4) 6) -trimethyltetrahydropyran-2-one, 7-decene-1,4-lactone, octahydrocoumarin, dihydrocoumarin,
Dodecalactone, 3-n-butylidenephthalide, 3-n
A masking composition for hair cosmetics according to any one of claims 1 to 10, which is at least one synthetic fragrance selected from -butylphthalide, 3-propylidenephthalide, and 3-propylphthalide. 12. The (J) ester is 1-ethynylcyclohexyl acetate, 1-octen-3-yl acetate, 2-ethylhexyl acetate, 2-phenoxyethyl isobutyrate, 2-phenoxyethyl propionate, 3,5. , 5-trimethylhexyl acetate,
3,7-Dimethyloctanyl acetate, 3-phenylpropyl acetate, 9-decen-1-yl acetate, L-menthyl acetate, L-menthyl propionate, o-tert-butylcyclohexyl acetate, p-tert-butylcyclohexyl acetate,
p-cresyl acetate, p-cresyl isobutyrate, p-cresyl phenylacetate, acetylisoeugenol, acetyleugenol, anisyl acetate, afermate, amyl acetate, amyl caprylate, amyl caproate, amyl salicylate, amyl Valerate, amyl butyrate, amyl formate, allyl 2-ethyl butyrate, allyl amyl glycolate, allyl isovalerate, allyl octanoate, allyl caprylate, allyl caproate, allyl cyclohexyl acetate, allyl cyclohexyloxyacetate. , Allyl cyclohexyl butyrate, allyl cyclohexyl propionate, allyl cinnamate, allyl phenoxyacetate, allyl butyrate,
Allyl propionate, allyl heptanoate, allyl benzoate, aldehyde C-16 (strawberry), aldehyde C-19 (pineapple), aldehyde C-20 (raspberry), isoamyl acetate, isoamyl angelate, isoamyl isovalerate, Isoamyl isobutyrate, isoamyl undecylenate, isoamyl octanoate, isoamyl salicylate, isoamyl cinnamate, isoamyl decanoate, isoamyl decanoate, isoamyl butyrate, isoamyl propionate, isoamyl hexanoate, isoamyl heptine carbonate , Isoamyl benzoate, isoamyl formate, isoamyl levulinate, isoeugenyl phenylacetate, isodihydrolabanduryl acetate , Isobutyl acetate, isobutyl isovalerate, isobutyl isobutyrate, isobutyl salicylate, isobutyl cinnamate, isobutyl valerate, isobutylphenyl acetate, isobutyl butyrate, isobutyl propionate, isobutyl hexanoate, isobutyl benzoate, isopregyl acetate , Isopropyl acetate, isopropyl isovalerate, isopropyl isobutyrate, isopropyl cinnamate, isopropyl decanoate, isopropyl phenyl acetate, isopropyl butyrate, isopropyl hexanoate, isopropyl benzoate, isopropyl myristate, isobornyl acetate, isobor Nilpropionate,
Wintergreen, ethyl 2-tert-butylcyclohexyl carbonate, ethyl 2-ethylhexanoate, ethyl 2-octenoate, ethyl 2-decenoate, ethyl 2-furoate, ethyl 2-hexyl acetoacetate, ethyl 2-benzylacetoacetate,
Ethyl 2-methylvalerate, ethyl 2-methylbutyrate, ethyl 3,5,5-trimethylhexanoate,
Ethyl 3-hydroxybutyrate, ethyl 3-hydroxyhexanoate, ethyl 3-hydroxy-3-phenylpropionate, ethyl 3-phenylglycidate, ethyl 3-phenylpropionate, ethyl o-methoxybenzoate, ethyl p-anisate. , Ethyl acetate, ethyl acetoacetate, ethyl isovalerate, ethyl isobutyrate, ethyl octocarbonate, ethyl oleate, ethyl caprynate, ethyl caprylate, ethyl caproate, ethyl crotonate, ethyl gellanate, ethyl safranate , Ethyl salicylate, ethyl cyclogeraniate, ethyl cinnamate, ethyl valerate, ethyl phenylacetate, ethyl butyrate, ethyl propionate, ethyl heptanoate, ether Luheptin carbonate, ethyl pelargonate, ethyl benzoate, ethyl formate, ethyl myristate, ethyl methyl p-tolyl glycidate, ethyl laurate, ethyl lactate, ethyl linalyl acetate, ethyl levulinate, ethylene dodecanedioate, ethylene brush Rate, eugenyl phenyl acetate, octyl acetate, octyl isovalerate, octyl isobutyrate, octyl octanoate, octyl butyrate, octyl heptanoate, octyl formate, ocimenyl acetate, caryophyllene acetate, caryophyllene formate, Calixol, carbyl acetate, guaiac acetate, cuminyl acetate, geranyl acetate, geranyl isovalerate, geranyl Sobuchireto, geranyl tiglate, geranyl phenylacetate, geranyl butyrate, geranyl propionate, geranyl hexanoate, geranyl benzoate, geranyl formate, Koniferan, Santa Lil acetate,
Diethyl adipate, diethyl succinate, diethyl sebacate, diethyl tartrate, diethyl phthalate, diethyl malonate, cyclohexyl acetate,
Cyclohexyl isovalerate, cyclohexyl ethyl acetate, cyclohexyl crotonate, cyclohexyl butyrate, cis-3-hexenyl 2-methylbutyrate, cis-3-hexenyl acetate, cis-3-
Hexenyl angelate, cis-3-hexenyl isovalerate, cis-3-hexenyl isobutyrate, cis-3-hexenyl caproate, cis-3-hexenyl salicylate, cis-3-hexenyl tiglate, cis-3 -Hexenyl valerate, cis-3-hexenyl phenyl acetate, cis-3-hexenyl butyrate,
Cis-3-hexenyl propionate, cis-3-hexenyl benzoate, cis-3-hexenyl formate, cis-3-hexenyl lactate, citryl acetate, citronellyl acetate, citronellyl isovalerate, citronellyl isobutyrate , Citronellyl tiglate, citronellyl phenylacetate, citronellyl butyrate, citronellyl propionate, citronellyl hexanoate, citronellyl formate, dihydrocarbyl acetate, dihydrocuminyl acetate, dihydroterpinyl acetate, dihydromil Cenyl acetate, dimethyl succinate, dimethyl phenyl ethyl carvinyl acetate, dimethyl phthalate,
Dimethylbenzylcarbinyl acetate, dimethylbenzylcarbinyl isobutyrate, dimethylbenzylcarbinyl butyrate, dimethylbenzylcarbinyl propionate, jasmar, cinnamyl acetate, cinnamyl isovalerate, cinnamyl isobutyrate, cinnamyl cinna Mate, cinnamyl tiglate, cinnamyl butyrate, cinnamyl propionate, cinnamyl benzoate, cinnamyl formate, styralyl acetate, styralyl isobutyrate, styrylyl propionate, cedolyl acetate, sedryl formate , Terpinyl acetate, terpinyl isovalerate, terpinyl isobutyrate, terpinyl butyrate, terpinyl propionate, terpinyl formate, decahydro-β-na Tyl formate, decyl acetate, tetrahydrofurfuryl butyrate, tetrahydrogeranyl acetate, tetrahydrofurfuryl acetate, tetrahydromugyl acetate, tetrahydrolinalyl acetate, dodecyl acetate, trans-2-hexenyl acetate, trans-2-hexenyl butyrate, trans-2 -Hexenyl propionate, trans-2-hexenyl hexanoate, trans-decahydro-β-naphthyl acetate, trans-decahydro-β-naphthyl isobutyrate, triacetin, triethyl citrate, tricyclodecyl acetate, tricyclo Decenyl acetate, tricyclodecenyl isobutyrate, tricyclodecenyl propionate, neryl acetate, neryl isobutyrate , Neryl butyrate, neryl propionate, neryl formate, nonyl acetate, nopyru acetate, hydrotropic acetate, phenylethyl 2-methylbutyrate, phenylethyl acetate, phenylethyl angelate, phenylethyl isovalerate, phenylethyl iso Butyrate, phenylethyl caprylate, phenylethyl salicylate, phenylethyl cinnamate, phenylethyl tiglate, phenylethyl nonanoate, phenylethyl valerate, phenylethyl pivalate, phenylethyl phenylacetate, phenylethyl butyrate, phenylethyl prolate Peonate,
Phenylethyl benzoate, phenylethyl formate, phenylethyl methacrylate, phenylethylmethylethylcarbinyl acetate, phenyl salicylate, phenethyl acetate, butyl acetate, butyl angelate, butyl isovalerate, butyl isobutyrate, butyl octano Ate, butyl salicylate, butyl decanoate, butyl dodecanoate, butyl valerate, butyl phenyl acetate, butyl butyryl lactate, butyl butyrate, butyl propionate, butyl hexanoate, butyl levulinate, furfuryl acetate , Prenyl acetate, prenyl angelate, prenyl benzoate, propyl acetate, propyl isovalerate, propyl isobutyrate, propyl octano Over door, propyl cinnamate,
Propyl trans-2, cis-4-decadienoate,
Propyl phenyl acetate, propyl butyrate, propyl propionate, propyl hexanoate, propyl heptanoate, propyl benzoate, propyl formate, hexyl 2-methyl butyrate, hexyl acetate, hexyl isovalerate, hexyl isobutyrate, Hexyl octanoate, hexyl salicylate, hexyl tiglate, hexyl phenylacetate, hexyl butyrate, hexyl propionate, hexyl hexanoate, hexyl benzoate, hexyl formate, beticol acetate, vetiberyl acetate, heptyl acetate, heptyl octa Noate, heptyl butyrate, heptyl hexanoate, heliotropyl acetate, benzyl 2-methylbutyrate, benzylacete , Benzyl isovalerate, benzyl isobutyrate, benzyl caprylate, benzyl salicylate, benzyl cinnamate, benzyl tiglate, benzyl dodecanoate, benzyl valerate, benzyl phenyl acetate, benzyl butyrate, benzyl propionate, benzyl Hexanoate, benzyl benzoate, benzyl formate, pentyl salicylate, myraldyl acetate, myrcenyl acetate, mirtenyl acetate, methyl 1-methyl-3-cyclohexenecarboxylate, methyl 2
-Nonenoate, methyl 2-furoate, methyl 2-methylbutyrate, methyl 3-nonenoate, methyl 9-
Undecenoate, methyl o-methoxybenzoate,
Methyl acetate, methyl atralate, methyl anisate, methyl angelate, methyl isovalerate, methyl isobutyrate, methyl isohexanoate, methyl octanoate, methyl octyne carbonate, methyl oleate, methyl caprynate, methyl Caprylate, methyl caproate, methyl gellanate, methyl salicylate, methyl cyclooctyl carbonate, methyl cyclogeranate, methyl cyclopentylidene acetate, methyl dihydrojasmonate, methyl jasmonate, methyl cinnamate, methyl decanoate , Methyldecyne carbonate, methyltetradecanoate,
Methyl dodecanoate, methyl trans-2-hexenoate, methyl trans-3-hexenoate, methyl hydroxyhexanoate, methyl valerate, methyl phenyl acetate, methyl phenyl glycidate,
Methyl butyrate, methyl heptanoate, methyl heptine carbonate, methyl pelargonate, methyl benzoate, methyl myristate, methyl laurate, methyl lactate, lavandulyl acetate, linalyl acetate, linalyl isovalerate, linalyl isobutyrate, Linalyl octanoate, Linalyl cinnamate, Linalyl butyrate, Linalyl propionate,
Linalyl hexanoate, linalyl benzoate, linalyl formate, rosamsk, rosephenone, rosinyl acetate, rosinyl isobutyrate, rosinyl phenyl acetate, rosinyl butyrate, rosinyl propionate, rosinyl formate, 1, 3-dimethyl-
3-butenyl isobutyrate, 1-acetoxy-2-s
ec-Butyl-1-vinylcyclohexane, 1-cyclohex-1-eneisopropyl acetate, 2,4-dimethyl-3-cyclohexylmethyl acetate, 2,4-
Hexadienyl isobutyrate, 2-methyl-2-methylpentyl valerate, 2-methylbutyl acetate,
2-methylbutyl isovalerate, 3-octyl acetate, 3-phenylpropyl isovalerate, 3-phenylpropyl isobutyrate, 3-phenylpropyl propionate, 3-methylpentyl angelate, 4-
Methyl benzyl acetate, 5-methyl-3-butyltetrahydropyran-4-yl acetate, 6,10-dimethyl-5,9-undecatrien-2-yl acetate, 9-decen-1-yl propionate, E ． G. Diacetate, E. G. Monobutyl ether acetate,
L-carbyl propionate, L-perylyl acetate, L-bornyl propionate, L-menthyl isovalerate, L-menthyl phenyl acetate, P.I. G.
Dibutyrate, P.I. G. Dipropionate, p-cresyl caprylate, p-cresyl salicylate, α-amyl cinnamyl acetate, acetyl vanillin, anisyl propionate, anisyl formate, isobutyl 2-
Furan propionate, isobutyl angelate, isobutyl crotonate, ethyl acrylate, ethyl citronellyl oxalate, ethyl stearate, ethyl tiglate, ethyl decadienoate, ethyl dehydrocyclogeranate, ethyl trans-2-hexanoate, Ethyl trans-3-hexanoate, ethyl palmitate, ethyl pyruvate, eugenyl formate,
Oxyoctaline formate, nerolidyl acetate,
At least one selected from nonanediol-1,3-diacetate, phenylglycol diacetate, pseudolinalyl acetate, butyl 10-undecenoate, butyl stearate, butyl formate, butyl lactate, furfuryl valerate, propyl 2-furan acrylate. The masking composition for hair cosmetics according to claim 1, wherein the masking composition is one kind of synthetic fragrance. 13. (K) The nitrogen-containing and / or sulfur-containing and / or halogen-containing compound is 2-tert-butylquinoline,
2-isobutylquinoline, 5,6,7,8-tetrahydroquinoxaline, 5-methyl-3-heptanone oxime, 5-methylquinoline, 6-isopropylquinoline,
8-mercaptomenthone, p-methylquinoline, α-amylcinamic amide-methyl anthranilate Schiff base, isobutyl quinoline, indole, indole-hydroxy citronellal Schiff base,
Ethyl anthranilate, geranyl nitrile, citronellyl nitrite, dimethyl sulfide, Stemon, thiogeraniol, thiota-pineol, thiolinalol, tripral-methyl anthranilate Schiff base,
Hydroxycitronellal-methyl anthranilate
Schiff base, buccoxime, methyl N-methyl anthranilate, methyl anthranilate, 1-methylpyrrole, 2- (1,4,8-trimethyl-3,7-nonadienyl) pyridine, 2 (4) -(2-Pinen-10-ylmethyl) pyridine, 2,3,5-trimethylpyrazine, 2,3-diethyl-5-methylpyrazine, 2,3-
Diethylpyrazine, 2,3-dimethylpyrazine, 2,
4,6-Trimethyl-4,5-dihydro-1,3,5-
Dithiazine, 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, 2,6-lutidine, 2-acetyl-3-
Ethylpyrazine, 2-acetylthiazole, 2-acetylpyrazine, 2-acetylpyridine, 2-acetylpyrrole, 2-amylpyridine, 2-isobutyl-3-methoxypyrazine, 2-isobutylthiazole, 2-isobutylpyridine, 2- Isopropyl-4-methylthiazole, 2-ethyl-3,5 (3,6) -dimethylpyrazine, 2-ethyl-3-methylpyrazine, 2-ethyl-5
-Methylpyrazine, 2-ethylthiophenol, 2-ethylpyrazine, 2-ethylbenzenethiol, 2-naphthylmercaptan, 2-methyl-3-butanethiol,
2-methyl-3-furanthiol, 2-methyl-4-propyl-1,3-oxathiane, 2-methyl-4-methoxythiazole, 2-methyl-5-vinylpyrazine, 2
-Methyl-5-methylthiofuran, 2-methylpyrazine, 2-methylbenzoxazole, 2-methoxy-3-
Isopropylpyrazine, 2-methoxy-3-ethylpyrazine, 2-methoxy-3-methylpyrazine, 2-mercaptoacetic acid, 3,7-dimethyl-2,6-
Nonadienonitrile, 3-acetylpyridine, 3-isobutylpyridine, 3-thiophenecarboxaldehyde, 3-methylindole, 3-methylthio-1-hexanol, 4- (1,4,8-trimethyl-3,7 -Nonadienyl) pyridine, 4,5-dimethylthiazole,
4-methyl-5-thiazoleethanol, 4-methyl-
5-thiazole ethanol acetate, 4-methyl-5
-Vinylthiazole, 4-methylthiazole, 5,6
7,8-Tetrahydroquinoxaline, 5-acetyl-
2,4-dimethylthiazole, 5-ethyl-2-methylpyridine, 5-methyl-2-thiophenecarboxaldehyde, 5-methyl-6,7-dihydrocyclopentapyrazine, 5-methylquinoxaline, 6 (p) -tert.
-Butylquinoline, 6-sec-butylquinoline, 8-
sec-butyl quinoline, n-butyl anthranil-
, N-methyl-N-pentyl-2-methylbutyramide, o-thiocresol, S-furfurylthioacetate, S-furfurylthiopropionate, S-methylthiobutyrate, S-methylmethanethiosulfonate,
Allyl sulfide, cis-3-hexenyl anthranilate, isoamyl mercaptan, isoquinoline, ethyl 3-methylthiopropionate, ethylthioacetate, ethylmethylthioacetate, quinoline, cuminylnitrile, di-n-propyldisulfide, diallyl disulfide, diallyl Sulfide, cis-3-hexenyl anthranilate, dithiospirofuran, dibutyl sulfide, dipropyl disulfide, dipropyl trisulfide, dimethyl disulfide, dimethyl trisulfide, cinnamyl anthranilate, cinnamyl nitrile, skatole, Styryl cyanide, thiazole,
Thiophene, decahydrocyclododecaxazole,
Tetrahydro-p-methylquinoline, tetrahydrothiophene, tetrahydrothiophen-3-one, tetrahydropyrrole, tetramethylpyrazine, dodecanonitrile, trithioacetone, tridecene-2-nitrile, trimethylthiazole, piperidine, piperine, pyrazine, pyridine , Phenylethyl anthranilate, butyl sulfide, furfuryl disulfide, furfuryl methyl sulfide, furfuryl mercaptan, benzothiazole, mint sulfide, methyl 3-methylthiopropionate, methyl N-2'-methylpentylidene anthranilate -Methyl, methylthiomethylpyrazine, methylnicotinate, methylfurfuryl disulfide, methylpropylacetaldehyde-methylanthranilate Schiff base, methylpropionate Rudisulfide, methylpropyl trisulfide, methylmethylthioacetate, methoxypyrazine, menthyl anthranilate, limonenethiole, allyl isothiocyanate, allyl mercaptan, isopropyl mercaptan, capsaicin, quinine, thirazine, nonanoyl vanillyl. A synthetic perfume selected from the group consisting of amide, paradichlorobenzene, bromostyrene, benzylisothiocyanate, benzyl cyanide, methional, methionol and mercaptoacetic acid. 12. A masking composition for hair cosmetics according to item 12. 14. (L) The natural fragrance is almond oil, anise oil, abies fa oil, amyris oil,
Angelica Oil, Ambergris tincture, Amber Sage, Amblet Seed Oil, Ylang Ylang Oil, Incense Oil, Wintergreen Oil, Elemi Oil, Oak Moss Absolute, Oak Moss Essence, Oak Moss Oil, Opoponax Oil,
Oris Absolute, Orange Oil, Orange Flower Absolute, Cascarilla Oil, Castor Resinoid, Cassia China Oil, Cassie Absolute, Cassia Oil, Cananga Java Oil, Camomile Oil Blue, Camomil Oil, Columns Oil, Cardamom Oil, Galvanum Oil, Caraway Oil , Guaiac wood oil, guaiac oil, cumin oil, clove bourbon oil, clove oil, costas oil, copaiba balsam, copaiba oil, coriander oil, cypress oil, sandalwood oil, cistrabudanum oil, cedarwood oil, citronella oil , Civet Absolute, Jasmine Absolute, Juniper Berry Oil, Camouflage Le, John Kill Absolute, Ginger Oil, Ginger Glass Oil, Cinnamon Ceylon Oil, Sweet Fennel Oil, Stilax Oil, Spike Lavender Oil, Spearmint Oil, Sage Oil, Sage Clarry Oil, Geranium Oil, Geranium Glass Oil, Geranium Bourbon Oil , Celery oil, thyme oil, tarragon oil, tangerine oil, tuberose absolute, true balsam, true balsam oil, tonka beans oil, nutmeg oil, narcissus absolute, neroli vigarade oil, verbena oil, violet leave absolute, pine oil, basil oil, Parsley seed oil, patchouli oil, vanilla oil, vanilla resinoid, hisso Oil, bitter almond oil, bitter fennel oil, cypress oil, hiba oil, pimento berry oil, hyacinth absolute, petitgrain oil, butchu oil, bay oil, pettigrain grass oil, pettigrain paraguay oil, pettigrain bergamot oil, pettigrain mandarin, pettigrain. Lemon oil, vetiver oil Java, vetiver bourbon, penny royal oil, pepper oil, peppermint oil, peruvian balsam, peruvian balsam oil, bergamot oil, benzoin oil, benzoin resinoid, boad rose oil, linden oil, hollywood oil,
Marjoram oil, mandarin oil, mimosa absolute, mill oil, musk tonkin tincture, mace oil, melissa oil, eucalyptus oil, lime oil, lavandine oil, labdanum oil, lavender oil, roux oil, lemon oil, lemongrass oil, rose de may, rose bulgaria oil The masking composition for hair cosmetics according to claim 1, which is at least one natural flavor selected from rosemary oil, roman chamomile oil, laurel oil and lovage oil. 15. The masking composition for hair cosmetics according to claim 1, further comprising 0.001 to 10% by weight of a surfactant. 16. The masking composition for hair cosmetics according to claim 1, which further comprises a solvent in an amount of 5 to 95% by weight. 17. The masked unpleasant odor is one or more of a base odor, an amine odor, an ammonia odor, a sulfur odor, an acid odor, a rust odor, a cigarette odor, an animal odor, and a halogen odor. The masking composition for hair cosmetics according to claim 1. 18. The masking composition according to claim 1, wherein the hair cosmetic composition is a permanent waving agent. 19. The masking composition according to claim 1, wherein the hair cosmetic composition is a hair dye. 20. A hair cosmetic comprising the masking composition according to claim 1 in an amount of 1 × 10 ^{−7 to} 5.0% by weight. 21. A masking composition according to claim 18
A permanent waving agent containing x10 ^{-7 to} 5.0% by weight. 22. A masking composition according to claim 19
× 10 ^{−7 to} 5.0% by weight of a hair dye composition. 23. A method for masking hair cosmetics, which comprises adding 1 × 10 ^{−7 to} 5.0% by weight of the masking composition according to claim 1. 24. A masking composition according to claim 18
A method for masking a permanent waving agent, which comprises adding 10 ^{−7 to} 5.0% by weight. 25. A masking composition according to claim 19
A method for masking a hair dye, which comprises adding 10 ^{7 to} 5.0% by weight.