CN215049460U - Alkaloid waste alkaline water treatment system - Google Patents
Alkaloid waste alkaline water treatment system Download PDFInfo
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- CN215049460U CN215049460U CN202022503377.2U CN202022503377U CN215049460U CN 215049460 U CN215049460 U CN 215049460U CN 202022503377 U CN202022503377 U CN 202022503377U CN 215049460 U CN215049460 U CN 215049460U
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Abstract
The utility model belongs to the technical field of industrial wastewater treatment, and relates to an alkaloid waste alkaline water treatment system, which comprises a wastewater pretreatment system, an incineration tower and a biological oxidation system, wherein the incineration tower and the biological oxidation system are respectively communicated with the wastewater pretreatment system; the reaction kettle is communicated with the incineration tower; the distillate storage tank is communicated with the biological oxidation system; the wastewater pretreatment system also comprises a defoaming agent storage tank and a vacuum pump; the defoaming agent storage tank is communicated with the reaction kettle; the vacuum pump is communicated with the distillate storage tank. The utility model discloses the flow is simple, and the practicality is high, and this processing method both the minimizing is solved a small amount of high COD alkaloid waste water and can simply handle a large amount of ordinary waste water simultaneously again, and very big limit has reduced the cost of high COD waste water technology processing, solves the difficult problem of biological oxidation treatment of alkaloid waste water simultaneously, realizes the integrated processing of buck.
Description
Technical Field
The utility model belongs to the technical field of industrial wastewater treatment, a alkaloid buck processing system is related to.
Background
The alkaloid waste alkaline water is waste water liquid obtained by treating plants containing alkaloid through processes of alkaline extraction, concentration, extraction and the like, has the specific gravity of about 1.2, is dark brown in color and peculiar smell, and has COD of about 300000 and 500000 mg/L. At present, 5000-6000 alkaloids separated from plants have various insect action modes such as poison, avoidance, food refusal, growth and development inhibition and the like, and have strong bacteriostatic and bactericidal effects. Therefore, the alkaloid waste alkaline water is treated, and the alkaloid waste alkaline water is applied to other aspects, especially agriculture, so as to achieve the purpose of making the best use of things.
At present, the existing wastewater treatment mainly adopts a physical method, a chemical method and a biological method.
(1) The physical method mainly comprises an adsorption method and a membrane separation method; the physical adsorption method usually adopts activated carbon to adsorb water-soluble dye, but the activated carbon is easy to reach saturation, needs regeneration and has higher regeneration cost, so the method is generally suitable for advanced treatment or wastewater treatment with low concentration and small water quantity; the membrane separation method is to use semipermeable membranes with different pore sizes to filter and separate mixtures with different particle sizes; the method mainly comprises a nanofiltration membrane, a microfiltration membrane, a reverse osmosis membrane and the like, the method has stable water outlet and good effect, but the separation membrane has high cost and is difficult to recycle, so that the technology is difficult to popularize in a large area.
(2) The chemical method mainly comprises a Fenton oxidation method, a coagulation method, an ozone oxidation method and a photocatalytic oxidation method. The Fenton oxidation method uses Fe2+And H2O2The method has the advantages that the sludge treatment capacity is high, the auxiliary material cost is high, and the method is not suitable for high COD wastewater treatment; the coagulation method isThe method has the advantages that micromolecular suspended matters, colloidal substances and the like in the wastewater form macromolecular particles by virtue of intermolecular interaction, and then the macromolecular particles are removed by precipitation or air flotation, so that the coagulation method is low in treatment cost and simple to operate, and is widely applied to the current wastewater treatment process, but the method needs secondary treatment on sludge; the ozone oxidation method has great advantages for treating wastewater chromaticity and reducing COD, but the ozone generator has higher cost and strict operation management requirements, and the effect is unstable in practical application; the photocatalytic oxidation method is to oxidize organic matters in wastewater into carbon dioxide and water by generating free radicals through a photocatalyst, and the application of the photocatalyst in wastewater treatment is limited due to the low utilization rate of the catalyst on sunlight.
(3) The biological treatment method is characterized in that microorganisms use organic pollutants in water as substrates to carry out aerobic metabolism, and after a series of biochemical reactions, energy is released step by step, and finally inorganic matters at low energy positions are stabilized to meet the requirement of harmlessness so as to return to the natural environment or further treat the organic pollutants. But the alkaloid industrial wastewater has obvious effect of sterilizing microorganisms and is not suitable for direct biological oxidation treatment.
However, since the alkaline waste water in the alkaloid industry has bactericidal effect and high COD, the existing treatment method cannot effectively treat the wastewater, and thus, the need for developing a treatment method with reduced amount and simple process is very urgent.
SUMMERY OF THE UTILITY MODEL
To the technical problem who exists among the current alkali waste water treatment that contains alkaloid industry, the utility model provides a contain alkaloid alkali waste water processing system, the flow is simple, and the practicality is high, and this processing method both reduces to solve a small amount of high COD alkaloid waste water and can simply handle a large amount of ordinary waste water simultaneously again, and very big limit has reduced the cost of high COD waste water technology processing, solves the difficult problem that alkaloid waste water is difficult to the biological oxidation treatment simultaneously, realizes the integrated processing of alkali waste water.
In order to realize the purpose, the utility model discloses a technical scheme is:
an alkaloid waste alkaline water treatment system comprises a waste water pretreatment system, and an incineration tower and a biological oxidation system which are respectively communicated with the waste water pretreatment system.
Further, the wastewater pretreatment system comprises a reaction kettle, a condenser and a distillate storage tank which are communicated in sequence; the defoaming agent storage tank is communicated with the incineration tower through the reaction kettle; the vacuum pump is communicated with the incineration tower through a distillate storage tank.
The wastewater pretreatment system also comprises a defoaming agent storage tank and a vacuum pump; the defoaming agent storage tank is communicated with the reaction kettle; the vacuum pump is communicated with the distillate storage tank.
Further, the incineration tower is a plasma incineration tower.
Furthermore, the biological oxidation system comprises a biological aerobic tank, and the distillate storage tank is communicated with the biological aerobic tank through an infusion pump.
The utility model has the advantages that:
1. in the utility model, the alkaloid waste alkaline water treatment system comprises a waste water pretreatment system, an incineration tower and a biological oxidation system which are respectively communicated with the waste water pretreatment system, wherein the waste water pretreatment system comprises a reaction kettle, a condenser and a distillate storage tank which are sequentially communicated; the reaction kettle is communicated with the incineration tower; the distillate storage tank is communicated with the biological oxidation system. 75% of water in the alkaloid waste alkali water is distilled out through a waste water pretreatment system, the distillate has low COD (chemical oxygen demand), is easy to biodegrade, and can be directly subjected to traditional aerobic biological treatment; the residual liquid of 25 percent is organic matters with high boiling point, difficult volatilization and high COD for incineration treatment, the treatment flow is simple, and the practicability is high.
2. The utility model discloses in, the COD of alkaloid waste alkali aquatic is 300000 ~ 500000mg/L, and after the preliminary treatment, COD in the distillate is about 8000mg/L, send to the biological good oxygen pond in the COD clearance of handling to reach more than 99%, accomplish the advanced treatment of high COD alkaloid waste water. The pretreatment method solves the problem that the alkaloid wastewater can not be directly subjected to biological oxidation treatment, and greatly reduces the treatment cost of the high COD wastewater.
3. The utility model injects the alkaloid waste alkaline water into the reaction kettle, and adds the waste acid into the reaction kettle to carry out neutralization reaction, so that the pH value of the alkaloid waste alkaline water is 6-7; adding the defoaming agent in the defoaming agent storage tank into the reaction kettle, and stirring for defoaming; further carrying out reduced pressure distillation on the pretreated alkaloid alkali waste water to obtain distillate and residual liquid; the distillate is sent to a biological oxidation system for biochemical treatment; and (5) delivering the residual liquid to an incineration tower for incineration treatment. Because the pretreatment changes the waste water into common waste water with low COD and solid organic waste (a small amount of organic waste liquid with high COD), the pretreatment method realizes the reduction treatment of the biological waste alkaline water with high COD, simultaneously, the generated small amount of organic waste liquid is easy to carry out the subsequent incineration treatment, the waste water with low COD reaches the water inlet condition of the biological oxidation treatment, and finally, the advanced treatment of the waste water with high COD is realized.
Drawings
FIG. 1 is a schematic view of the system for treating the alkaloid waste alkaline water of the present invention;
wherein:
1-a reaction kettle; 2-a defoaming agent storage tank; 3-a condenser; 4-distillate storage tank, P1-regulating pump; p2 — feed pump; p3-infusion pump; p4-vacuum pump.
Detailed Description
The present invention will now be described in detail with reference to the accompanying drawings and examples.
The utility model provides an alkaloid buck processing system includes waste water pretreatment systems and burns tower and biological oxidation system that is linked together with waste water pretreatment systems respectively.
The utility model provides a wastewater pretreatment system, which comprises a reaction kettle 1, a condenser 3 and a distillate storage tank 4 which are communicated in sequence; the reaction kettle 1 is communicated with the incineration tower; the distillate storage tank 4 is communicated with the biological oxidation system.
The utility model provides a wastewater pretreatment system, which also comprises a defoaming agent storage tank 2 and a vacuum pump P4; the defoaming agent storage tank 2 is communicated with the incineration tower through the reaction kettle 1; the vacuum pump P4 is communicated with the incineration tower through a distillate storage tank 4. The incineration tower is a plasma incineration tower.
The utility model provides a biological oxidation system includes biological good oxygen pond, and distillate storage tank 4 is linked together with biological good oxygen pond through transfer pump P3.
The utility model provides an alkaloid buck processing system handles alkaloid buck includes following step:
1) carrying out neutralization reaction, heating and reduced pressure distillation on alkaloid alkali waste water by a waste water pretreatment system to obtain distillate and residual liquid;
the utility model discloses in, the concrete implementation process of step 1) is:
1.1) injecting the alkaloid alkali waste water into a reaction kettle 1, adding waste acid into the reaction kettle 1, and performing neutralization reaction to ensure that the pH value of the alkaloid alkali waste water is 6-7;
1.2) heating the reaction kettle 1, and simultaneously starting a condenser 3 and a vacuum pump P4 to perform reduced pressure distillation, wherein the distillation temperature is 50-70 ℃, and the operation pressure is-0.10 Mpa to-0.08 Mpa;
the utility model discloses in, the proportion of alkaloid buck is 1.1 ~ 1.25, and pH is 10 ~ 12, and COD is 300000 ~ 500000 mg/L.
In the utility model, the waste acid is waste sulfuric acid, waste nitric acid or waste phosphoric acid; the volume ratio of the alkali waste water to the waste acid is 16-20: 1.
In the utility model, after the neutralization reaction is finished, the defoaming agent is added into the reaction kettle 1 through the defoaming agent storage tank 2, and then the step 1.2 is carried out; the defoaming agent is a silicon polyether defoaming agent; the volume ratio of the alkaloid alkali waste water to the defoaming agent is 30-40: 1.
2) The distillate is sent to a biological oxidation system for biochemical treatment until the COD of the effluent is less than 300 mg/L; the residual liquid is sent to an incineration tower for incineration treatment, and the NOx content in the incineration flue gas is lower than 200mg/m3The dioxin emission value in the smoke is less than 0.4ng/m3The discharge values of mercury, cadmium and lead are respectively less than 0.2mg/m3、0.1mg/m3、1.6mg/m3。
Example 1
Referring to fig. 1, in the present embodiment, the wastewater pretreatment system includes a reaction kettle 1, a condenser 3, and a distillate storage tank 4, which are sequentially communicated; the reaction kettle 1 is communicated with the incineration tower; the distillate storage tank 4 is communicated with the biological oxidation system. The wastewater pretreatment system also comprises a defoaming agent storage tank 2 and a vacuum pump P4; the defoaming agent storage tank 2 is communicated with the incineration tower through the reaction kettle 1; the vacuum pump P4 is communicated with the incineration tower through a distillate storage tank 4. The incineration tower is a plasma incineration tower. The biological oxidation system comprises a biological aerobic tank, and the distillate storage tank 4 is communicated with the biological aerobic tank through an infusion pump P3.
In the embodiment, the top of the reaction kettle 1 is respectively communicated with a defoaming agent storage tank 2 and a condenser 3; the top of the reaction kettle 1 is also respectively communicated with a regulating pump P1 and a feeding pump P2; a stirring device is also arranged in the reaction kettle 1 for stirring; the bottom of the reaction kettle 1 is communicated with an incineration tower; the condenser 3 is communicated with a distillate storage tank 4, the distillate storage tank 4 is communicated with a biological aerobic pool through an infusion pump P3, and the distillate storage tank 4 is also communicated with a vacuum pump P4.
Taking specific alkaloid waste alkaline water as an example, the process for treating the alkaloid waste alkaline water by using the treatment system of the embodiment is adopted.
In this example, the density of the alkali waste water of alkaloid industry is 1.1, the pH is 10, and the COD is 300000 mg/L. The waste acid is waste sulfuric acid. The volume ratio of the alkaloid waste alkaline water to the waste acid is 20: 1.
1) Carrying out neutralization reaction, heating and reduced pressure distillation on alkaloid alkali waste water by a waste water pretreatment system to obtain distillate and residual liquid;
the specific implementation process is as follows:
1.1) injecting the alkaloid waste alkaline water into a reaction kettle 1, adding waste acid into the reaction kettle 1, and carrying out neutralization reaction to ensure that the pH value of the alkaloid waste alkaline water is 6;
in the embodiment, after the neutralization reaction is finished, adding a defoaming agent into the reaction kettle 1 through a defoaming agent storage tank 2, and then performing the step 1.2), wherein the defoaming agent is a silicon polyether defoaming agent; the volume ratio of the alkaloid alkali waste water to the defoaming agent is 40: 1.
1.2) heating the reaction kettle 1, simultaneously starting a condenser 3 and a vacuum pump P4 for reduced pressure distillation, and taking the volume of distillate reaching two thirds of the volume of the added alkaloid waste alkali water as a reference after the distillation is finished; the distillation temperature is 50 ℃, and the operation pressure is-0.08 MPa;
2) the distillate is sent to a biological oxidation system for biochemical treatment; and (5) delivering the residual liquid to an incineration tower for incineration treatment.
In this example, the biochemical treatment process was: the distillate wastewater enters a grid well of a sewage treatment station, enters an adjusting tank for homogenizing and equalizing after removing particle impurities, is conveyed to a biological contact oxidation tank by a lifting pump for acidification, hydrolysis, nitrification and denitrification to reduce the concentration of organic matters and remove part of ammonia nitrogen, then flows into the biological contact oxidation tank for aerobic biochemical reaction, most of organic pollutants are degraded through biological oxidation and adsorption, the effluent automatically flows into a secondary sedimentation tank for solid-liquid separation, the supernatant of the sedimentation tank flows into a disinfection tank, is dissolved by adding chlorine tablets in a contact manner, and is discharged after reaching standards after harmful strains in the water are killed. The COD of the effluent is less than 300 mg/L.
In the embodiment, the incineration treatment is plasma incineration, and specifically comprises a plasma generator, a plasma arc power supply, protective gas, cooling water, an incinerator, and a matched feeding, air supplying, air exhausting, slag discharging, control console and the like, wherein the cracking temperature is higher than 1200 ℃, organic matters including infectious viruses, germs and other toxic and harmful substances are all cracked and decomposed to generate flue gas, the flue gas enters a reaction tower, CaO is sprayed into the reaction tower through a nozzle to react with acid gases such as sulfur dioxide, hydrogen chloride and the like in the flue gas, and most of the acid gases such as sulfur dioxide, hydrogen chloride and the like are removed; the flue gas is discharged from the top of the reaction tower. And adding activated carbon powder into the flue at the outlet to further remove dioxin and heavy metals in the flue gas. The flue gas is filtered by a bag-type dust collector and then discharged into a chimney through a draught fan. The NOx content in the incineration flue gas is lower than 200mg/m3The emission value of dioxin in the smoke is small by 0.4ng/m3The discharge values of mercury, cadmium and lead are respectively less than 0.2mg/m3、0.1mg/m3、1.6mg/m3。
Example 2
Taking specific alkaloid waste alkaline water as an example, the treatment system of the utility model is adopted to treat the alkaloid waste alkaline water.
Specifically, the alkaloid alkali waste water is matrine industrial alkali waste water, the density of the alkaloid industrial alkali waste water is 1.25, the pH value is 12, and the COD is 500000 mg/L; the processing steps are as follows:
1) carrying out neutralization reaction, heating and reduced pressure distillation on alkaloid alkali waste water by a waste water pretreatment system to obtain distillate and residual liquid;
1.1) injecting 1000kg of matrine industrial alkali waste water into a reaction kettle 1 through a feed pump P2, adding about 60kg of industrial waste concentrated sulfuric acid through an adjusting pump P1, stirring for reaction, controlling the pH value to be 7, and completing neutralization;
adding about 25kg of defoaming agent into the reaction kettle 1 through a defoaming agent storage tank 2, uniformly stirring, and digesting bubbles generated by neutralization reaction;
1.2) starting a condenser 3 and a vacuum pump P4 for reduced pressure distillation, controlling the distillation temperature at 70 ℃ and the operation pressure at-0.09 Ma, and finally obtaining distillate and residual liquid; stopping distillation when the distillate reaches above 700 kg;
2) the residual liquid is discharged from the reaction kettle 1 quickly and sent to a plasma incineration tower for incineration treatment, so that wall adhesion and caking are prevented; and meanwhile, collecting distillate, detecting that the COD of the distillate is 8000mg/L, sending the distillate to a biological aerobic tank for aerobic biological treatment, wherein the removal rate of the COD after the treatment reaches more than 99 percent, thereby completing the deep treatment of the high-COD matrine industrial alkaline waste water.
In this example, the biochemical treatment and the plasma incineration treatment were referred to in example 1.
In the embodiment, after reduced pressure distillation, 75% of water in the matrine industrial waste alkali water is distilled, the COD of the distillate is low, and the distillate is easily biodegraded and can be subjected to traditional aerobic biological treatment; the residual 25 percent of residual concentrated solution belongs to organic matters with high boiling point, difficult volatilization and high COD for incineration treatment. The method greatly reduces the cost of the high COD wastewater process treatment, solves the problem that the matrine wastewater is difficult to biologically oxidize, and has simple flow and high practicability.
The treatment method provided by the embodiment not only reduces and solves a small amount of high COD alkaloid wastewater, but also can simply treat a large amount of common wastewater, and finally achieves the comprehensive treatment of matrine industrial alkali waste water.
Claims (2)
1. An alkaloid buck processing system, its characterized in that: the alkaloid waste alkaline water treatment system comprises a waste water pretreatment system, and an incineration tower and a biological oxidation system which are respectively communicated with the waste water pretreatment system;
the wastewater pretreatment system comprises a reaction kettle (1), a condenser (3) and a distillate storage tank (4) which are communicated in sequence; the reaction kettle (1) is communicated with the incineration tower; the distillate storage tank (4) is communicated with the biological oxidation system;
the wastewater pretreatment system also comprises an antifoaming agent storage tank (2) and a vacuum pump (P4); the defoaming agent storage tank (2) is communicated with the incineration tower through the reaction kettle (1); the vacuum pump (P4) is communicated with the incineration tower through a distillate storage tank (4);
the incineration tower is a plasma incineration tower.
2. The system for treating alkali waste water according to claim 1, wherein: the biological oxidation system comprises a biological aerobic tank, and the distillate storage tank (4) is communicated with the biological aerobic tank through an infusion pump (P3).
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| CN112456729A (en) * | 2020-11-03 | 2021-03-09 | 陕西中环信环保科技有限公司 | System and method for treating alkali waste water |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112456729A (en) * | 2020-11-03 | 2021-03-09 | 陕西中环信环保科技有限公司 | System and method for treating alkali waste water |
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