CN110407571A - Manufacturing method, product and the application method of electroheating type sintering solid - Google Patents
Manufacturing method, product and the application method of electroheating type sintering solid Download PDFInfo
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- CN110407571A CN110407571A CN201910649884.6A CN201910649884A CN110407571A CN 110407571 A CN110407571 A CN 110407571A CN 201910649884 A CN201910649884 A CN 201910649884A CN 110407571 A CN110407571 A CN 110407571A
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Abstract
A kind of manufacturing method of electroheating type sintering solid, first insulating materials presoma, phasphorus-containing polymer solution are mutually mixed to obtain mixture, mixture is switched into formed body again, formed body is not loose when standing, and is then sintered under the conditions of oxygen barrier to formed body, until the solute carbonization in phasphorus-containing polymer solution is electric conductor, meanwhile after insulating materials presoma is cured as nonconducting insulator, terminate sintering, at this point, can be obtained the electroheating type sintering solid.The electric heating utilization rate of the design is higher.
Description
Technical field
The present invention relates to a kind of production technology of thermo electric material more particularly to a kind of manufacturers of electroheating type sintering solid
Method, product and application method, it is particularly applicable to improve electric heating utilization rate.
Background technique
In existing ground heating type heating, (line with heating function is by metallic resistance silk or carbon for embedded line with heating function usually below ceramic tile
Fiber composition), heat is simultaneously dispersed into interior by line with heating function heating power by ceramic tile surface, carries out heating heat preservation to interior.
The technique of this heating power has the following deficiencies: that 1. electric heating utilization rate is not high, between the heating layer and ceramic tile that line with heating function is formed
It will form interlayer thermal resistance to hinder；2. construction is complicated, need for line with heating function to be embedded in depths, construction in layer, the period is long；3. construction layer
Thickness reduces chamber height.
The information for disclosing the background technology part is merely intended to increase the understanding to the general background of present patent application, without
It should be considered as recognizing or implying in any form that the information constitutes existing skill already known to those of ordinary skill in the art
Art.
Summary of the invention
The purpose of the present invention is overcome the problems, such as the lower defect of electric heating utilization rate existing in the prior art and, one kind is provided
Manufacturing method, product and the application method of the higher electroheating type sintering solid of electric heating utilization rate.
In order to achieve the above object, the technical solution of the invention is as follows: a kind of manufacturing method of electroheating type sintering solid, packet
Include following steps:
First insulating materials presoma, phasphorus-containing polymer solution are mutually mixed to obtain mixture, then mixture is switched to form
Body, formed body is not loose when standing, and is then sintered under the conditions of oxygen barrier to formed body, until in phasphorus-containing polymer solution
After solute carbonization is electric conductor, and insulating materials presoma is cured as nonconducting insulator, terminate sintering, at this point, can obtain
Obtain the electroheating type sintering solid；
The mixture switchs to the method for formed body are as follows: if mixture is loose when standing, to mixture compression moulding to obtain
Formed body, if mixture is not loose when standing, directly using mixture as formed body；
The insulating materials presoma is the mixture of purees, powder or both, and the purees is that powder and water are mixed
It closes and obtains.
The solute of the phasphorus-containing polymer solution be phenolic resin, epoxy resin, polyacrylonitrile, phenyl-diformyl phenylenediamine,
Polyamide, polyvinyl alcohol, cellulose, lignin, any one in fibroin albumen.
The mass percent concentration of the phasphorus-containing polymer solution is 5% -50%.
It is described to be mutually mixed insulating materials presoma, phasphorus-containing polymer solution to obtain mixture, then mixture is turned
Refer to any one in following four technique for formed body:
A technique: being first laid with bottom insulating materials presoma, then one layer of phasphorus-containing polymer solution is arranged on it, then carbon containing
Top layer insulating materials presoma is covered on high polymeric solution to obtain mixture, top layer insulating materials presoma, bottom insulation material
Material precursor contacts with each other, then to mixture compression moulding to obtain formed body, during compacting, phasphorus-containing polymer solution
Pressure-bearing diffusion, and penetrate into the inside of adjacent bottom insulating materials presoma, top layer insulating materials presoma；
B technique: first to the compression moulding of insulating materials presoma to obtain blank body, the blank body is not loose when standing, then by hair
Green body is integrally placed in the inside of phasphorus-containing polymer solution, then to blank body, phasphorus-containing polymer solution altogether space take out it is true
Sky, until phasphorus-containing polymer solution infiltrates through in blank body to obtain impregnating, then by impregnating from phasphorus-containing polymer solution
Middle taking-up is to obtain formed body；
C technique: first placing insulating materials presoma in a reservoir, then addition phasphorus-containing polymer is molten into insulating materials presoma
Then liquid is stirred mixing or ball milling mixing, until insulating materials presoma, phasphorus-containing polymer solution are uniformly mixed to obtain
Flexible body, the flexible body is not loose when standing, then carries out dry method compacting or wet process moulding to flexible body to obtain formed body；
D technique: insulating materials presoma, phasphorus-containing polymer solution, the injection side of the two are first sprayed simultaneously into the container of sealing
To intersecting, insulating materials presoma, phasphorus-containing polymer solution are mutually mixed to obtain mixture in container, stop injection
Afterwards, then to resulting mixture compression moulding to obtain formed body.
In the A technique, phasphorus-containing polymer solution penetrates into adjacent top layer insulating materials forerunner after pressure-bearing diffusion
To form upper infiltration area, lower infiltration area in body, bottom insulating materials presoma, upper infiltration area spreads to top layer insulating materials forerunner
The top surface of body, lower infiltration area spread to the bottom surface of bottom insulating materials presoma.
The powder is powder, production glass made of powder, production porcelain made of production pottery is raw materials used are raw materials used
Powder made of glass is raw materials used or the raw materials used manufactured powder of production cement.
The constituent and its weight part ratio of the powder are as follows: silica 40-70, aluminum oxide 10-30 are remaining
Material 2-20, the clout are sodium oxide molybdena, potassium oxide, calcium oxide, any one or any combination in titanium dioxide.
The oxygen barrier condition are as follows: formed body is enclosed in inert gas or formed body is enclosed in charcoal powder, or at
Space around type body is evacuated.
A kind of electroheating type sintering solid, the manufacturing method according to above-mentioned electroheating type sintering solid are made.
A kind of application method of electroheating type sintering solid, comprising the following steps: above-mentioned electroheating type sintering solid is first obtained,
Conducting resinl is coated on the front and rear end of electroheating type sintering solid again to obtain applying colloid, is then powered to the both ends for applying colloid,
It realizes heating power, or first multiple painting colloids is connected in series to obtain concatermer, then be powered to the both ends of concatermer, it is real
Existing heating power；The voltage of the energization is not higher than 220V.
Compared with prior art, the invention has the benefit that
1, in a kind of manufacturing method of electroheating type sintering solid of the present invention, product and application method, first by insulating materials presoma,
Phasphorus-containing polymer solution is mutually mixed to obtain mixture, then mixture is switched to formed body, and formed body is not loose when standing, with
Afterwards, the carbonization of the solute in phasphorus-containing polymer solution, insulating materials presoma are completed together when being solidificated in sintering, to obtain
The advantages of inside is distributed with the insulator of electric conductor, i.e. electroheating type sintering solid, the design includes: firstly, being powered can produce
The electric conductor of heat is distributed in the inside of insulator, rather than as heat source in the prior art is located at the lower section of ceramic tile, it not will lead to
Interlayer thermal resistance hinders, and thermal losses is low, and heat conduction efficiency is high, can be improved electric heating utilization rate；Secondly, the design is in use, directly
Laying, will not both reduce chamber height, also not need that line with heating function is embedded in depths as the prior art, and it is difficult to reduce construction
Degree, shortens construction period；Again, electric conductor is distributed in inside insulator, and insulator heat conduction non-conducting itself, itself limit
Temperature, fire prevention, electrical isolation, have good safety；4th, the electric conductor that the design uses belongs to carbon material fever, rather than
Metal fever, will not generate the electromagnetic radiation as waves being harmful to the human body.Therefore, not only electric heating utilization rate is higher by the present invention, convenient for applying
Work application, and safety is stronger, will not generate electromagnetic radiation as waves.
2, it in a kind of manufacturing method of electroheating type sintering solid of the present invention, product and application method, is distributed in formed body
Solute in the only phasphorus-containing polymer solution in portion, is not electric conductor, the solute can just be carbonized in follow-up sintering as energy
The electric conductor of heating power, rather than electric conductor (such as carbon fiber) is directly placed into sintering solid and carries out assembly, the design
Advantage includes: not need specially to produce carbon fiber, cost is extremely cheap firstly, eliminate special carbon fiber manufacture link；Its
Secondary, the easy brittle failure dispersion of carbon fiber is not easy to be placed directly within the inside of formed body or sintering solid, unless using special auxiliary agent
Carbon fiber is pre-processed；Again, compare carbon fiber, and the plasticizing capacity of phasphorus-containing polymer solution is stronger, energy and insulation material
Material precursor carry out the very high mixing of the uniformity, during mixture switchs to formed body, or to formed body before sintering into
During row plasticity, the changeability of shape is very strong, complicated structure design and Compound Machining is able to satisfy, to meet different
Application demand.Therefore, not only cost of manufacture is lower by the present invention, and application range is wider, and does not need auxiliary agent processing, more energy saving
Environmental protection.
3, in a kind of manufacturing method of electroheating type sintering solid of the present invention, product and application method, in use, either
Colloid or concatermer are applied, domestic common various everyday power sources, including domestic power supply, battery etc. are suitable for, using difficulty
Lower, in addition, the external form of product can also specially be designed according to various demands, product type is abundant, adapts to all kinds of civilian need
It asks.Therefore, application range of the invention is wider.
Detailed description of the invention
Fig. 1 is upper infiltration area, lower infiltration area, bottom insulating materials presoma, top layer insulating materials presoma in the present invention
A kind of relative position schematic diagram.
Fig. 2 is upper infiltration area, lower infiltration area, bottom insulating materials presoma, top layer insulating materials presoma in the present invention
Another relative position schematic diagram.
Fig. 3 is a kind of cross-sectional view of impregnating in the present invention.
Fig. 4 is another cross-sectional view of impregnating in the present invention.
Fig. 5 is into sealing container while to spray the operation of insulating materials presoma, phasphorus-containing polymer solution in the present invention
Schematic diagram.
Fig. 6 is the energization schematic diagram that colloid is applied in the present invention.
Fig. 7 is the energization schematic diagram of concatermer in the present invention.
In figure: upper infiltration area 1, lower infiltration area 2, bottom insulating materials presoma 3, top layer insulating materials presoma 4, gluing
Body 5, conducting resinl 51, concatermer 6, infiltration area 7, non-infiltration area 8, sealing container 9, insulation jet port 91, solution jet port 92,
Mixture 93.
Specific embodiment
Below in conjunction with Detailed description of the invention and specific embodiment, the present invention is described in further detail.
Referring to Fig. 1-Fig. 7, a kind of manufacturing method of electroheating type sintering solid, comprising the following steps:
First insulating materials presoma, phasphorus-containing polymer solution are mutually mixed to obtain mixture, then mixture is switched to form
Body, formed body is not loose when standing, and is then sintered under the conditions of oxygen barrier to formed body, until in phasphorus-containing polymer solution
After solute carbonization is electric conductor, insulating materials presoma is cured as nonconducting insulator, terminate sintering, at this point, can be obtained
The electroheating type sintering solid；
The mixture switchs to the method for formed body are as follows: if mixture is loose when standing, to mixture compression moulding to obtain
Formed body, if mixture is not loose when standing, directly using mixture as formed body；
The insulating materials presoma is the mixture of purees, powder or both, and the purees is that powder and water are mixed
It closes and obtains.
The solute of the phasphorus-containing polymer solution be phenolic resin, epoxy resin, polyacrylonitrile, phenyl-diformyl phenylenediamine,
Polyamide, polyvinyl alcohol, cellulose, lignin, any one in fibroin albumen.
The mass percent concentration of the phasphorus-containing polymer solution is 5% -50%.
It is described to be mutually mixed insulating materials presoma, phasphorus-containing polymer solution to obtain mixture, then mixture is turned
Refer to any one in following four technique for formed body:
A technique: being first laid with bottom insulating materials presoma 3, then one layer of phasphorus-containing polymer solution is arranged on it, then carbon containing
Top layer insulating materials presoma 4 is covered on high polymeric solution to obtain mixture, top layer insulating materials presoma 4, bottom insulation
Material precursor 3 contacts with each other, then to mixture compression moulding to obtain formed body, during compacting, phasphorus-containing polymer
The diffusion of solution pressure-bearing, and penetrate into the inside of adjacent bottom insulating materials presoma 3, top layer insulating materials presoma 4；
B technique: first to the compression moulding of insulating materials presoma to obtain blank body, the blank body is not loose when standing, then by hair
Green body is integrally placed in the inside of phasphorus-containing polymer solution, then to blank body, phasphorus-containing polymer solution altogether space take out it is true
Sky, until phasphorus-containing polymer solution infiltrates through in blank body to obtain impregnating, then by impregnating from phasphorus-containing polymer solution
Middle taking-up is to obtain formed body；
C technique: first placing insulating materials presoma in a reservoir, then addition phasphorus-containing polymer is molten into insulating materials presoma
Then liquid is stirred mixing or ball milling mixing, until insulating materials presoma, phasphorus-containing polymer solution are uniformly mixed to obtain
Flexible body, the flexible body is not loose when standing, then carries out dry method compacting or wet process moulding to flexible body to obtain formed body；
D technique: insulating materials presoma, phasphorus-containing polymer solution, the injection side of the two are first sprayed simultaneously into the container of sealing
To intersecting, insulating materials presoma, phasphorus-containing polymer solution are mutually mixed to obtain mixture in container, stop injection
Afterwards, then to resulting mixture compression moulding to obtain formed body.
In the A technique, phasphorus-containing polymer solution penetrates into adjacent top layer insulating materials presoma after pressure-bearing diffusion
4, to form upper infiltration area 1, lower infiltration area 2 in bottom insulating materials presoma 3, upper infiltration area 1 spreads to top layer insulating materials
The top surface of presoma 4, lower infiltration area 2 spread to the bottom surface of bottom insulating materials presoma 3.
The powder is powder, production glass made of powder, production porcelain made of production pottery is raw materials used are raw materials used
Powder made of glass is raw materials used or the raw materials used manufactured powder of production cement.
The constituent and its weight part ratio of the powder are as follows: silica 40-70, aluminum oxide 10-30 are remaining
Material 2-20, the clout are sodium oxide molybdena, potassium oxide, calcium oxide, any one or any combination in titanium dioxide.
The oxygen barrier condition are as follows: formed body is enclosed in inert gas or formed body is enclosed in charcoal powder, or at
Space around type body is evacuated.
A kind of electroheating type sintering solid, the manufacturing method according to above-mentioned electroheating type sintering solid are made.
A kind of application method of electroheating type sintering solid, comprising the following steps: above-mentioned electroheating type sintering solid is first obtained,
Conducting resinl 51 is coated on the front and rear end of electroheating type sintering solid again to obtain applying colloid 5, then to the both ends for applying colloid 5
It is powered, realizes heating power, or be first connected in series multiple painting colloids 5 to obtain concatermer 6, then to the two of concatermer 6
End is powered, and realizes heating power；The voltage of the energization is not higher than 220V.
The principle of the present invention is described as follows:
" production pottery raw materials used manufactured powder, makes original used in glass at the raw materials used manufactured powder of production porcelain in the present invention
Powder made of expecting or the raw materials used manufactured powder of production cement " refers to: in the prior art, production pottery, porcelain, glass or water
During mud, the floury structure that required raw material are broken into, such as kaolin, receive feldspar, potassium feldspar, quartz, mica,
Powder made by spodumene, montmorillonite, illite, talcum or cordierite.
Inert gas in the present invention includes but is not limited to nitrogen, argon gas, hydrogen.
When being sintered in the present invention to formed body, the temperature of sintering is 1000-1400 DEG C, and the time of sintering is 1-
3h。
Referring to Fig. 1, the upper infiltration area 1 in Fig. 1 is located at the inside of top layer insulating materials presoma 4, and lower infiltration area 2 is located at bottom
The inside of layer insulating materials presoma 3.Referring to fig. 2, the upper infiltration area 1 in Fig. 2 spreads to the top of top layer insulating materials presoma 4
Except face, or even exudation top layer insulating materials presoma 4, similarly, lower infiltration area 2 spreads to bottom insulating materials presoma 3
Except bottom surface, or even exudation bottom insulating materials presoma 3.In addition, in the present invention when phasphorus-containing polymer solution is arranged, setting
Mode includes any one or any combination in smearing, spray, dripping.
Referring to Fig. 3, blank body is not impregnated with all by phasphorus-containing polymer solution in figure, has been permeated so existing in impregnating
Area 7 and non-infiltration area 8 just do not have phasphorus-containing polymer solution in non-infiltration area 8.Referring to fig. 4, in figure blank body by carbon containing height
Copolymer solution is all impregnated with from the inside to the outside, so infiltration area 7 are only existed in impregnating, without non-infiltration area 8.In addition, this
In invention when blank body to be integrally placed in phasphorus-containing polymer solution to obtain impregnating, although emphasizing to have carried out taking out simultaneously true
Do-nothing operation, the negative pressure which forms can not only be conducive to phasphorus-containing polymer solution and permeate into blank body, and can improve infiltration
The uniformity.But if not vacuumizing, and only naturally osmotic and feasible, it is only ineffective.
Referring to Fig. 5, insulating materials presoma, phasphorus-containing polymer solution are respectively through the jet port 91, solution jet port 92 of insulating
It is sprayed into sealing container 9, the injection direction of the two intersects, and insulating materials presoma, phasphorus-containing polymer solution are sealing
It is mutually mixed in container 9 to obtain mixture 93.
Embodiment 1:
A kind of manufacturing method of electroheating type sintering solid, comprising the following steps: first laying bottom insulating materials presoma 3, then
One layer of phasphorus-containing polymer solution is set thereon, covers top layer insulating materials presoma 4 on phasphorus-containing polymer solution then to obtain
To mixture, top layer insulating materials presoma 4, bottom insulating materials presoma 3 contact with each other, then to mixture compression moulding with
Formed body is obtained, during compacting, the diffusion of phasphorus-containing polymer solution pressure-bearing, and penetrate into adjacent bottom insulating materials forerunner
The inside of body 3, top layer insulating materials presoma 4, formed body is not loose when standing, and then carries out under the conditions of oxygen barrier to formed body
Sintering, until the solute carbonization in phasphorus-containing polymer solution is electric conductor, insulating materials presoma is cured as nonconducting insulation
After body, terminate sintering, at this point, can be obtained the electroheating type sintering solid.
The insulating materials presoma be purees, powder or both mixture, the purees be powder with
Water is obtained by mixing, the constituent and its weight part ratio of the powder are as follows: silica 66, aluminum oxide 20, and clout 5,
The clout is sodium oxide molybdena, potassium oxide, calcium oxide, any one or any combination in titanium dioxide.
The solute of the phasphorus-containing polymer solution be phenolic resin, epoxy resin, polyacrylonitrile, phenyl-diformyl phenylenediamine,
Polyamide, polyvinyl alcohol, cellulose, lignin, any one in fibroin albumen, the quality hundred of the phasphorus-containing polymer solution
Dividing specific concentration is 10%.
Embodiment 2:
Basic content with embodiment 1, the difference is that:
It is first laid with first layer insulating materials presoma, then first layer phasphorus-containing polymer solution is set on it, then in first layer
Second layer insulating materials presoma is covered on phasphorus-containing polymer solution, then is arranged on the top surface of second layer insulating materials presoma
Second layer phasphorus-containing polymer solution, then on the second layer phasphorus-containing polymer solution overlays third layer insulating materials presoma with
To mixture, second layer insulating materials presoma and first layer insulating materials presoma, third layer insulating materials presoma all phases
Mutually contact, then to mixture compression moulding to obtain formed body.
The mass percent concentration of phasphorus-containing polymer solution is 5%, the constituent and its weight part ratio of powder are as follows: two
Silica 40, aluminum oxide 30, clout 15.
Embodiment 3:
Basic content with embodiment 1, the difference is that:
First to the compression moulding of insulating materials presoma to obtain blank body, the blank body is not loose then blank body is whole when standing
Body be placed in phasphorus-containing polymer solution inside, then to blank body, phasphorus-containing polymer solution altogether space vacuumize, up to
Phasphorus-containing polymer solution infiltrates through in blank body to obtain impregnating, then impregnating is taken out from phasphorus-containing polymer solution with
Obtain formed body.
The mass percent concentration of phasphorus-containing polymer solution is 22%, the constituent and its weight part ratio of powder are as follows: two
Silica 40, aluminum oxide 10, clout 20.
Embodiment 4:
Basic content with embodiment 1, the difference is that:
Insulating materials presoma is first placed in a reservoir, then phasphorus-containing polymer solution is added into insulating materials presoma, then
It is stirred mixing or ball milling mixing, until insulating materials presoma, phasphorus-containing polymer solution are uniformly mixed to obtain flexible body,
The flexible body is not loose when standing, then carries out dry method compacting or wet process moulding to flexible body to obtain formed body.
The mass percent concentration of phasphorus-containing polymer solution is 35%, the constituent and its weight part ratio of powder are as follows: two
Silica 70, aluminum oxide 10, clout 2.
Embodiment 5:
Basic content with embodiment 1, the difference is that:
Insulating materials presoma, phasphorus-containing polymer solution first are sprayed simultaneously into sealing container 9, insulating materials presoma is through insulating
Jet port 91 sprays into sealing container 9, and phasphorus-containing polymer solution sprays into sealing container 9 through solution jet port 92, the spray of the two
It penetrates direction to intersect, insulating materials presoma, phasphorus-containing polymer solution are mutually mixed to obtain mixture in sealing container 9
93, after stopping injection, then to resulting 93 compression moulding of mixture to obtain formed body.
The mass percent concentration of phasphorus-containing polymer solution is 50%, the constituent and its weight part ratio of powder are as follows: two
Silica 50, aluminum oxide 15, clout 10.
The foregoing is merely better embodiment of the invention, protection scope of the present invention is not with above embodiment
Limit, as long as those of ordinary skill in the art's equivalent modification or variation made by disclosure according to the present invention, should all be included in power
In the protection scope recorded in sharp claim.
Claims (10)
1. a kind of manufacturing method of electroheating type sintering solid, it is characterised in that the manufacturing method the following steps are included:
First insulating materials presoma, phasphorus-containing polymer solution are mutually mixed to obtain mixture, then mixture is switched to form
Body, formed body is not loose when standing, and is then sintered under the conditions of oxygen barrier to formed body, until in phasphorus-containing polymer solution
After solute carbonization is electric conductor, and insulating materials presoma is cured as nonconducting insulator, terminate sintering, at this point, can obtain
Obtain the electroheating type sintering solid；
The mixture switchs to the method for formed body are as follows: if mixture is loose when standing, to mixture compression moulding to obtain
Formed body, if mixture is not loose when standing, directly using mixture as formed body；
The insulating materials presoma is the mixture of purees, powder or both, and the purees is that powder and water are mixed
It closes and obtains.
2. a kind of manufacturing method of electroheating type sintering solid according to claim 1, it is characterised in that: described carbon containing high poly-
The solute of object solution is phenolic resin, epoxy resin, polyacrylonitrile, phenyl-diformyl phenylenediamine, polyamide, polyvinyl alcohol, fiber
Element, lignin, any one in fibroin albumen.
3. a kind of manufacturing method of electroheating type sintering solid according to claim 1 or 2, it is characterised in that: described carbon containing
The mass percent concentration of high polymeric solution is 5% -50%.
4. a kind of manufacturing method of electroheating type sintering solid according to claim 1 or 2, it is characterised in that: it is described will be exhausted
Edge material precursor, phasphorus-containing polymer solution are mutually mixed to obtain mixture, then by mixture switch to formed body refer to it is following
Any one in four kinds of techniques:
A technique: being first laid with bottom insulating materials presoma (3), then one layer of phasphorus-containing polymer solution is arranged on it, is then containing
Top layer insulating materials presoma (4) are covered on carbon high polymeric solution to obtain mixture, top layer insulating materials presoma (4), bottom
Layer insulating materials presoma (3) contacts with each other, then to mixture compression moulding to obtain formed body, during compacting, contains
The diffusion of carbon high polymeric solution pressure-bearing, and penetrate into adjacent bottom insulating materials presoma (3), top layer insulating materials presoma (4)
Inside；
B technique: first to the compression moulding of insulating materials presoma to obtain blank body, the blank body is not loose when standing, then by hair
Green body is integrally placed in the inside of phasphorus-containing polymer solution, then to blank body, phasphorus-containing polymer solution altogether space take out it is true
Sky, until phasphorus-containing polymer solution infiltrates through in blank body to obtain impregnating, then by impregnating from phasphorus-containing polymer solution
Middle taking-up is to obtain formed body；
C technique: first placing insulating materials presoma in a reservoir, then addition phasphorus-containing polymer is molten into insulating materials presoma
Then liquid is stirred mixing or ball milling mixing, until insulating materials presoma, phasphorus-containing polymer solution are uniformly mixed to obtain
Flexible body, the flexible body is not loose when standing, then carries out dry method compacting or wet process moulding to flexible body to obtain formed body；
D technique: insulating materials presoma, phasphorus-containing polymer solution, the injection side of the two are first sprayed simultaneously into the container of sealing
To intersecting, insulating materials presoma, phasphorus-containing polymer solution are mutually mixed to obtain mixture in container, stop injection
Afterwards, then to resulting mixture compression moulding to obtain formed body.
5. a kind of manufacturing method of electroheating type sintering solid according to claim 4, it is characterised in that: in the A technique,
Phasphorus-containing polymer solution penetrates into adjacent top layer insulating materials presoma (4), bottom insulating materials forerunner after pressure-bearing diffusion
To form upper infiltration area (1), lower infiltration area (2) in body (3), upper infiltration area (1) spreads to top layer insulating materials presoma (4)
Top surface, lower infiltration area (2) spread to the bottom surface of bottom insulating materials presoma (3).
6. a kind of manufacturing method of electroheating type sintering solid according to claim 1 or 2, it is characterised in that: the powdery
Object is made of powder, production glass made of powder, production porcelain made of production pottery is raw materials used are raw materials used are raw materials used
Powder or the raw materials used manufactured powder of production cement.
7. a kind of manufacturing method of electroheating type sintering solid according to claim 1 or 2, it is characterised in that: the powdery
The constituent and its weight part ratio of object are as follows: silica 40-70, aluminum oxide 10-30, clout 2-20, the clout
For any one or any combination in sodium oxide molybdena, potassium oxide, calcium oxide, titanium dioxide.
8. a kind of manufacturing method of electroheating type sintering solid according to claim 1 or 2, it is characterised in that: described oxygen barrier
Condition are as follows: formed body is enclosed in inert gas or formed body is enclosed in the space quilt in charcoal powder or around formed body
It vacuumizes.
9. a kind of electroheating type sintering solid, it is characterised in that: the electroheating type sintering solid is according to of any of claims 1 or 2
The manufacturing method of electroheating type sintering solid is made.
10. a kind of application method of electroheating type sintering solid, it is characterised in that the application method is the following steps are included: first obtain
Electroheating type sintering solid as claimed in claim 9, then coat on the front and rear end of electroheating type sintering solid conducting resinl (51) with
It obtains applying colloid (5), is then powered to the both ends for applying colloid (5), realizes heating power, or first multiple painting colloids (5) are carried out
It is connected in series to obtain concatermer (6), then is powered to the both ends of concatermer (6), realize heating power；The voltage of the energization is not
Higher than 220V.
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