CN109361039A - The production method of electrokinetic cell system and control method and lithium battery group - Google Patents
The production method of electrokinetic cell system and control method and lithium battery group Download PDFInfo
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- CN109361039A CN109361039A CN201811171748.2A CN201811171748A CN109361039A CN 109361039 A CN109361039 A CN 109361039A CN 201811171748 A CN201811171748 A CN 201811171748A CN 109361039 A CN109361039 A CN 109361039A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M16/00—Structural combinations of different types of electrochemical generators
- H01M16/003—Structural combinations of different types of electrochemical generators of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers
- H01M16/006—Structural combinations of different types of electrochemical generators of fuel cells with other electrochemical devices, e.g. capacitors, electrolysers of fuel cells with rechargeable batteries
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02N—ELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
- H02N11/00—Generators or motors not provided for elsewhere; Alleged perpetua mobilia obtained by electric or magnetic means
- H02N11/002—Generators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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Abstract
The production method that the present invention discloses a kind of electrokinetic cell system and control method and lithium battery group.Suction ventilator or air blower, which are powered, to be rotated, and air enters lithium battery group in the water of water tank, and the vapor in air is chlorinated calcium uptake and becomes the loss that liquid water makes up water in lithium battery group.Lithium battery charging: lithium salts resolves into lithium metal and acid, consumes a large amount of water and releases oxygen, while releasing a large amount of heat of generation；Hot oxygen and air come out from lithium battery group takes away heat.Lithium battery group electric discharge: the channel between escape pipe and hydrogen fuel cell is connected in solenoid directional control valve energization, and lithium metal and acid, which occur to chemically react, generates lithium salts, is consumed a large amount of water and is released hydrogen, while generating a large amount of heat.Air containing hydrogen, which enters hydrogen fuel cell and oxygen chemical reaction occurs, to be generated water and produces electricl energy and heat.Come out from hydrogen fuel cell be more than 150 DEG C of hot gas enter cogeneration machine generate it is electric.In carbonic acid lithium battery group, the water that carbon dioxide passes through water tank enters carbonic acid lithium battery group.
Description
Technical field:
The present invention relates to a kind of electrokinetic cell system and the production methods of control method and lithium battery group.
Background technique:
Currently, sale lithium battery has ferric phosphate lithium cell and ternary lithium battery in the market.The cathode of ferric phosphate lithium cell is
Lithium, the anode of ferric phosphate lithium cell are ferric phosphates.The cathode of ferric phosphate lithium cell is to use graphite bead mixed as conductor and lithium powder
It is combined, the anode of ferric phosphate lithium cell is to use copper sheet, aluminium sheet or stainless steel plate as conductor to coat LiFePO4 and mine
The hydrate of object oil and hydrogen and oxygen can be allowed to occur the substance that chemical reaction generates water, between the cathode of ferric phosphate lithium cell
There are the insulation diaphragm that lithium ion can be allowed to pass through, plastic shell, battery pack lead, copper socket.The cathode of ternary lithium battery is lithium,
The anode of ternary lithium battery is ter-polymers.The cathode of ternary lithium battery is that graphite bead is used to be blended in as conductor and lithium powder
Together, the anode of ternary lithium battery is to use copper sheet, aluminium sheet revolution stainless steel plate as conductor to coat ter-polymers and mineral oil
Hydrate and can allow hydrogen and oxygen that the substance that chemical reaction generates water occurs, having between the cathode of ternary lithium battery can
Allow the insulation diaphragm that lithium ion passes through, plastic shell, battery pack lead, copper socket.Lithium battery can produce oxygen, lithium battery when charging
Generate hydrogen when electric discharge, have a kind of substance that can allow hydrogen and oxygen that chemical reaction occurs in lithium battery and generate water, this substance with
The increase of charging times and consume, with charging times increase mineral oil contained by moisture it is fewer and fewer, lithium battery
Capacity it is smaller and smaller, the hydrogen and oxygen assembled in lithium battery are more and more, and lithium battery tympanites gets up, until lithium battery loses
Effect.The efficiency for charge-discharge of battery is less than 50 percent, that is to say, that 5 percent of the efficiency of electric car less than electric car
Ten.By patent retrieval look into it is some use graphene as conductor replace cathode of lithium battery conductor graphite bead and use graphite
Alkene as conductor replace lithium battery anode conductor copper sheet, aluminium sheet or stainless steel plate, however the production cost of graphene than
Graphite bead, copper sheet, aluminium sheet and high more of stainless steel plate, conductivity is also less than copper sheet, aluminium sheet and stainless steel plate.Mineral oil is filling
Electric short circuit burning, or even explode.Application number: 201610544773.5 " device for generating power by waste heat and control method and its applications "
It can directly be generated electricity with hot gas or hot liquid.
Summary of the invention:
Electrokinetic cell system is by lithium battery group, hydrogen fuel cell, cogeneration machine, water tank, air solenoid valve, liquefaction dioxy
Change canister, carbon dioxide solenoid valve, suction ventilator or evacuator, solenoid directional control valve and computer controller composition.Lithium battery group 7 connects
There is air inlet pipe, the other end of air inlet pipe is in tank top.The carbon dioxide come out from liquefied carbon dioxide tank is opened by being powered
Carbon dioxide solenoid valve enter in the water of water tank, air by power loss open air solenoid valve 1 enter water tank water in.Lithium
It is connected to escape pipe in battery pack, is connected on escape pipe and is sequentially arranged with suction ventilator or evacuator and solenoid directional control valve.Electromagnetic switch
It is connected to hydrogen fuel cell group in the normally closed outlet of valve, cogeneration machine, electrokinetic cell system are connected in the outlet of hydrogen fuel cell
It is controlled by computer controller.
Electrokinetic cell system is by lithium battery group, hydrogen fuel cell, cogeneration machine, water tank, liquefied carbon dioxide tank, dioxy
Change carbon solenoid valve, air compressor machine or air blower, solenoid directional control valve and computer controller composition.Lithium battery group is connected to air inlet pipe, air inlet
The other end of pipe is in tank top.The carbon dioxide come out from liquefied carbon dioxide tank is by the carbon dioxide electromagnetism opened that is powered
Valve enters in the water of water tank, in the water that the air come out from air compressor machine or air blower enters water tank.Outlet is connected in lithium battery group
It manages, solenoid directional control valve is housed on escape pipe.Hydrogen fuel cell is connected in the normally closed outlet of solenoid directional control valve, hydrogen fuel cell 11
Cogeneration machine is connected in outlet, electrokinetic cell system is controlled by computer controller.
A kind of lithium battery group by multiple groups lithium battery group at.Lithium battery is by porous plastic plate, positive conductor, anode, insulation
Diaphragm, cathode conductor, cathode and shell composition.With a piece of good permeability, the graphene film that reverse osmosis resistance is small, resistivity is small
As cathode of lithium battery conductor, the cathode of lithium battery is that penetrate into cathode conductor graphene film surface be a nanometer lithium；With in addition
Positive conductor of the piece of graphite alkene film as lithium battery, lithium battery anode are one layers be coated on positive conductor graphite alkene film
Cobalt acid lithium, LiMn2O4, lithium nickelate, ter-polymers, LiFePO4 or carbonic acid lithium electrolyte.The positive electrode and negative electrode of lithium battery have
One layer of insulation diaphragm, insulation diaphragm are the thin polymer films that lithium ion can be allowed to pass through.Two slabstones of two groups of adjacent lithium batteries
Calcium chloride is accompanied between black alkene film.The porous plastic plate of two panels is posted on outside the graphene film of multiple groups lithium battery, shell with
There is gap between porous plastic plate.
A kind of production method of lithium battery group: production two panels cellular-plastic panels use piece of graphite alkene film as lithium battery
Nanometer lithium is penetrated into cathode conductor graphene film surface by cathode conductor；Use other piece of graphite alkene film as lithium battery
Positive conductor coats one layer of cobalt acid lithium, LiMn2O4, lithium nickelate, ter-polymers, ferric phosphate on positive conductor graphite alkene film
Lithium or carbonic acid lithium electrolyte；A polymer insulation that lithium ion can be allowed to pass through is pressed from both sides between the positive electrode and negative electrode of lithium battery
Diaphragm；Calcium chloride is coated between the two panels graphene film of two groups of adjacent lithium batteries；It is posted on the porous plastic plate of two panels more
It outside the graphene film of group lithium battery, then is packaged with the material of shell, finally loads onto copper socket.
A kind of lithium battery group by multiple groups lithium battery group at.Lithium battery is by porous plastic plate, positive conductor, anode, insulation
Diaphragm, cathode conductor, cathode and shell composition.With a piece of good permeability, the graphene film that reverse osmosis resistance is small, resistivity is small
As cathode of lithium battery conductor, cathode of lithium battery is the nanometer lithium for penetrating into cathode conductor graphene film surface；With other one
As lithium battery anode conductor, lithium battery anode is to apply for piece good permeability, the graphene film that reverse osmosis resistance is small, resistivity is small
One layer of cobalt acid lithium containing calcium chloride, LiMn2O4, lithium nickelate, ter-polymers, phosphoric acid on positive conductor graphite alkene film
Iron lithium or carbonic acid lithium electrolyte.An insulation diaphragm is accompanied between the positive electrode and negative electrode of lithium battery, insulation diaphragm is can to allow
The thin polymer film that lithium ion passes through.The adjacent public piece of graphite alkene film of two groups of lithium batteries.The porous plastic plate note of two panels
Outside the graphene film of multiple groups lithium battery, there is gap between shell and porous plastic plate.
A kind of production method of lithium battery group: production two panels cellular-plastic panels use piece of graphite alkene film as lithium battery
Nanometer lithium is penetrated into cathode conductor graphene film surface by cathode conductor.Use other piece of graphite alkene film as lithium battery
Positive conductor coats one layer of cobalt acid lithium containing calcium chloride, LiMn2O4, lithium nickelate, ternary on positive conductor graphite alkene film
Polymer, LiFePO4 or carbonic acid lithium electrolyte；Pressing from both sides one between the positive electrode and negative electrode of lithium battery enough allows lithium ion to pass through
Polymer insulation diaphragm；The adjacent public piece of graphite alkene film of two groups of lithium batteries；It is posted on the porous plastic plate of two panels more
It outside the graphene film of group lithium battery, then is packaged with the material of shell, finally loads onto copper socket.
A kind of control method of electrokinetic cell system: when lithium battery group charges or idle, computer controller makes air
Solenoid valve power loss is opened and solenoid directional control valve power loss closes the channel between escape pipe and hydrogen fuel cell 11.Computer controller makes
Suction ventilator or evacuator, which are powered, to be rotated, and air enters in the water of water tank by the air solenoid valve 1 that power loss is opened, and is then worn
The water crossed in water tank enters lithium battery group from air inlet pipe, increases the air humidity in air inlet pipe.Lithium battery group charging: cobalt acid
Lithium, LiMn2O4, lithium nickelate, lithium phosphate or lithium carbonate resolve into lithium and cobalt acid, mangaic acid, nickel acid, phosphoric acid or carbonic acid, consumption are big
The water of amount simultaneously releases oxygen, while generating a large amount of heat, and hot oxygen and air pass through graphene film, insulation diaphragm and more
The plastic plate in hole is sucked out from the shell of lithium battery group by suction ventilator or evacuator, reduces the temperature inside lithium battery group
Degree, so quick charge can be carried out to this lithium battery group.The very big air of humidity is sucked by suction ventilator or evacuator
The vapor of lithium battery group, air group becomes liquid water by the chlorination calcium uptake of 7 the inside of lithium battery group, supplements the anode of lithium battery
The water lost between cathode.Suction ventilator or evacuator in lithium battery group hot oxygen and air be sucked out after pass through electromagnetism
The normally open valve of reversal valve discharges.When lithium battery group is discharged, computer controller makes the energization of air solenoid valve 1 closing and solenoid directional control valve
Be powered the channel connected between escape pipe and hydrogen fuel cell, and computer controller makes suction ventilator or evacuator energization rotation.
Lithium battery group electric discharge: lithium and cobalt acid, mangaic acid, nickel acid, phosphoric acid or carbonic acid occur chemical reaction and generate cobalt acid lithium, LiMn2O4, nickel
Sour lithium, lithium phosphate or lithium carbonate consume a large amount of water and release hydrogen, while generating a large amount of heat；The electric discharge of lithium battery
The half less than charge volume is measured, remaining energy is released in the form of thermal energy and fuel gas hydrogen.Inside lithium battery group
Hot hydrogen be sucked out by suction ventilator or evacuator, then enter hydrogen combustion by the normally close valve for the solenoid directional control valve opened that is powered
Material battery and oxygen occur chemical reaction and generate water and generate electricity, and hydrogen fuel cell can be using hydrogen as the energy of combustion gas
Half be converted into electric energy, remaining half is converted into thermal energy.From hydrogen fuel cell come out be more than 150 DEG C hot gas into
Enter the power generation of cogeneration machine, cogeneration machine can convert electric energy for the half of the thermal energy of the hot gas more than 150 DEG C.Computer
The electricity that lithium battery, hydrogen fuel cell and cogeneration machine generate is adjusted as electric car power supply by controller.In lithium carbonate
In the lithium battery group for doing anode, computer controller makes carbon dioxide solenoid valve be powered when lithium battery group is discharged, from liquefaction titanium dioxide
The carbon dioxide that canister comes out enters in the water of water tank by the carbon dioxide solenoid valve opened that is powered, and carbon dioxide goes out from water tank
To enter in lithium battery group the loss for making up water and carbon dioxide in carbonic acid lithium battery by nearly tracheae.Due to being easy in lithium battery
The substance portion of loss can be supplemented in time, so this lithium battery recharge access times are very high, this lithium battery
Service life it is also very long.
A kind of control method of electrokinetic cell system: when lithium battery group charges or when electric discharge, computer controller makes electromagnetism
Reversal valve power loss closes the channel between the escape pipe and hydrogen fuel cell of container.Computer controller keeps air compressor machine or air blower logical
Electricity rotation, in the water that the air of air compressor machine or air blower out enters water tank.Wet air comes out from water tank passes through air inlet
Pipe enters the loss that lithium battery group makes up water in lithium battery group.Lithium battery charging: cobalt acid lithium, LiMn2O4, lithium nickelate, lithium phosphate or
Person's lithium carbonate resolves into lithium and cobalt acid, mangaic acid, nickel acid, phosphoric acid or carbonic acid, consumes a large amount of water and releases oxygen, releases simultaneously
Generate a large amount of heat, hot oxygen and air pass through graphene film, insulation diaphragm and more under the pressure of air compressor machine or air blower
The plastic plate in hole comes out from the shell of lithium battery group.The very big air of humidity enters lithium battery group by the chlorination inside lithium battery group
Calcium uptake becomes liquid water, supplements the water lost between the positive electrode and negative electrode of lithium battery, passes through after hot-air and oxygen lithium battery
The normally open valve of solenoid directional control valve discharges.Lithium battery group discharge when, computer controller make solenoid directional control valve be powered connect escape pipe with
Channel between hydrogen fuel cell, computer controller make air compressor machine or air blower energization rotation.Lithium battery group electric discharge: lithium and cobalt
Acid, mangaic acid, nickel acid, phosphoric acid or carbonic acid occur chemical reaction and generate cobalt acid lithium, LiMn2O4, lithium nickelate, lithium phosphate or carbonic acid
Lithium consumes a large amount of water and releases hydrogen, while generating a large amount of heat；The discharge capacity of lithium battery less than charge volume half,
Remaining energy is released in the form of thermal energy and fuel gas hydrogen.The air containing hydrogen inside lithium battery group comes out
Enter hydrogen fuel cell by the normally close valve for the solenoid directional control valve opened that is powered afterwards to occur to chemically react generation water and produce with oxygen
Raw electricity, hydrogen fuel cell can be converted into electric energy for hydrogen as the half of the energy of combustion gas, and remaining half is converted into heat
Energy.Coming out from hydrogen fuel cell is more than that 150 DEG C of hot gas enters cogeneration machine and generates electricity, and cogeneration machine can will surpass
The half for crossing the thermal energy of 150 DEG C of hot gas is converted into electric energy.Computer controller is by lithium battery, hydrogen fuel cell and cogeneration
The electricity that machine generates is adjusted as electric car power supply.In the lithium battery group that lithium carbonate does anode, electricity when lithium battery group is discharged
Brain controller makes carbon dioxide solenoid valve be powered, and the carbon dioxide come out from liquefied carbon dioxide tank is by the dioxy opened that is powered
Change carbon solenoid valve to enter in the water of water tank, carbon dioxide, which comes out to enter by nearly tracheae from water tank, makes up lithium carbonate in lithium battery group
The loss of water and carbon dioxide in battery.Substance portion due to being easy loss in lithium battery can be supplemented in time, so this
Kind lithium battery recharge access times are very high, and the service life of this lithium battery is also very long.
Detailed description of the invention:
Further specific detailed description is done to the present invention with reference to the accompanying drawings and detailed description.
Fig. 1 is equipped with the structural schematic diagram of the electrokinetic cell system of the present invention of suction ventilator.
Fig. 2 is equipped with the structural schematic diagram of the electrokinetic cell system of the present invention of air blower.
Fig. 3 be two groups of lithium batteries adjacent in the present invention two panels graphene film between accompany calcium chloride lithium battery cut
Face schematic diagram.
Fig. 4 is the lithium battery schematic cross-section that anode electrolyte contains calcium chloride in the present invention.
Specific embodiment:
Shown in Fig. 1, electrokinetic cell system is by lithium battery group 7, hydrogen fuel cell 11, cogeneration machine 12, water tank 5, air
Solenoid valve 1, liquefied carbon dioxide tank 3, carbon dioxide solenoid valve 4, suction ventilator 9 or evacuator, solenoid directional control valve 10 and computer
Controller composition.Lithium battery group 7 is connected to air inlet pipe 6, and the other end of air inlet pipe 6 is at 5 top of water tank.From liquefied carbon dioxide tank 3
Carbon dioxide out enters in the water of water tank 5 by the carbon dioxide solenoid valve 4 opened that is powered, and air is opened by power loss
Air solenoid valve 1 enters in the water of water tank 5.It is connected to escape pipe in lithium battery group, is connected on escape pipe 8 and is sequentially arranged with 9 machine of air draught
Or evacuator and solenoid directional control valve 10.Hydrogen fuel cell group 11, hydrogen fuel electricity are connected in the normally closed outlet of solenoid directional control valve 10
Cogeneration machine 12 is connected in the outlet in pond, electrokinetic cell system is controlled by computer controller.
Shown in Fig. 2, electrokinetic cell system is by lithium battery group 7, hydrogen fuel cell 11, cogeneration machine 12, water tank 5, liquefaction
Carbon dioxide tank 3, carbon dioxide solenoid valve 4, air compressor machine or air blower 2, solenoid directional control valve 10 and computer controller composition.Lithium electricity
Pond group 7 is connected to air inlet pipe 6, and the other end of air inlet pipe 6 is at 5 top of water tank.The carbon dioxide warp come out from liquefied carbon dioxide tank 3
It crosses the carbon dioxide solenoid valve 4 for being powered and opening to enter in the water of water tank 5, the air come out from air compressor machine or air blower 2 enters water
In the water of case 5.It is connected to escape pipe 8 in lithium battery group 7, solenoid directional control valve 10 is housed on escape pipe 8.Solenoid directional control valve 10 it is normally closed
It is connected to hydrogen fuel cell 11 in outlet, cogeneration machine 12 is connected in the outlet of hydrogen fuel cell 11, electrokinetic cell system is by electricity
The control of brain controller.
Shown in Fig. 3, a kind of lithium battery group 7 by multiple groups lithium battery group at.Lithium battery is led by porous plastic plate 702, anode
Body, anode 704, insulation diaphragm 705, cathode conductor, cathode 706 and shell 701 form.With a piece of good permeability, reverse osmosis resistance
The graphene film 703 that power is small, resistivity is small is used as cathode of lithium battery conductor, and the cathode 706 of lithium battery is to penetrate into cathode to lead
703 surface of body graphene film is a nanometer lithium；With other a piece of good permeability, the graphene that reverse osmosis resistance is small, resistivity is small
Positive conductor of the film 703 as lithium battery, lithium battery anode 704 are one layers be coated on positive conductor graphite alkene film 703
Cobalt acid lithium, LiMn2O4, lithium nickelate, ter-polymers, LiFePO4 or carbonic acid lithium electrolyte.The anode 704 of lithium battery and negative
There is one layer of insulation diaphragm 705 in pole 706, and insulation diaphragm 705 is the thin polymer film that lithium ion can be allowed to pass through.Two groups of adjacent lithiums
Calcium chloride is accompanied between the two panels graphene film 703 of battery.The porous plastic plate of two panels is posted on the graphene of multiple groups lithium battery
, there is gap in 703 outside of film between shell 701 and porous plastic plate 702.
Shown in Fig. 3, a kind of production method of lithium battery group: production two panels cellular-plastic panels 702, with piece of graphite alkene film
703 are used as cathode of lithium battery conductor, and nanometer lithium is penetrated into 703 surface of cathode conductor graphene film；With other piece of graphite
Alkene film 703 is used as lithium battery anode conductor, coats one layer of cobalt acid lithium, LiMn2O4, nickel on positive conductor graphite alkene film 703
Sour lithium, ter-polymers, LiFePO4 or carbonic acid lithium electrolyte；One is pressed from both sides between the anode 704 and cathode 706 of lithium battery
The polymer insulation diaphragm 705 that lithium ion can be allowed to pass through；It is applied between the two panels graphene film 703 of two groups of adjacent lithium batteries
Upper calcium chloride；It is posted on the outside of graphene film 703 of multiple groups lithium battery with the porous plastic plate 702 of two panels, then with shell 701
Material is packaged, and finally loads onto copper socket.
Shown in Fig. 4, a kind of lithium battery group 7 by multiple groups lithium battery group at.Lithium battery is led by porous plastic plate 702, anode
Body, anode 704, insulation diaphragm 705, cathode conductor, cathode 706 and shell 701 form.With a piece of good permeability, reverse osmosis resistance
The graphene film 703 that power is small, resistivity is small is used as cathode of lithium battery conductor, and cathode of lithium battery 706 is to penetrate into cathode conductor
The nanometer lithium on 703 surface of graphene film；It is thin in addition a piece of good permeability, the graphene that reverse osmosis resistance is small, resistivity is small
Film 703 is used as lithium battery anode conductor, and lithium battery anode 704 is that one layer be coated on positive conductor graphite alkene film 703 contains
Cobalt acid lithium, LiMn2O4, lithium nickelate, ter-polymers, LiFePO4 or the carbonic acid lithium electrolyte of calcium chloride.The anode of lithium battery
An insulation diaphragm 705 is accompanied between 704 and cathode 706, insulation diaphragm 705 is the polymer thin that lithium ion can be allowed to pass through
Film.The adjacent public piece of graphite alkene film 703 of two groups of lithium batteries.The porous plastic plate 702 of two panels is posted on multiple groups lithium battery
, there is gap in 703 outside of graphene film between shell 701 and porous plastic plate 702.
Shown in Fig. 4, a kind of production method of lithium battery group: production two panels cellular-plastic panels 702, with piece of graphite alkene film
703 are used as cathode of lithium battery conductor, and nanometer lithium is penetrated into 703 surface of cathode conductor graphene film.With other piece of graphite
Alkene film 703 is used as lithium battery anode conductor, and one layer of cobalt acid containing calcium chloride is coated on positive conductor graphite alkene film 703
Lithium, LiMn2O4, lithium nickelate, ter-polymers, LiFePO4 or carbonic acid lithium electrolyte；In the anode 704 and cathode of lithium battery
A polymer insulation diaphragm 705 for enough allowing lithium ion to pass through is pressed from both sides between 706；The adjacent public piece of graphite alkene of two groups of lithium batteries
Film 703；It is posted on the outside of graphene film 703 of multiple groups lithium battery with the porous plastic plate 702 of two panels, then with shell 701
Material is packaged, and finally loads onto copper socket.
Shown in Fig. 1, Fig. 3 and Fig. 4, a kind of control method of electrokinetic cell system: lithium battery group 7 charge when or the free time
When, computer controller makes 1 power loss of air solenoid valve opening and 10 power loss of solenoid directional control valve close escape pipe 8 and hydrogen fuel cell 11
Between channel.Computer controller makes suction ventilator 9 or evacuator energization rotation, air pass through the air electromagnetism that power loss is opened
Valve 1 enters in the water of water tank 5, and the water then passed through in water tank 5 enters lithium battery group 7 from air inlet pipe 6, increases in air inlet pipe 6
Air humidity.Lithium battery group 7 charge: cobalt acid lithium, LiMn2O4, lithium nickelate, lithium phosphate or lithium carbonate resolve into lithium and cobalt acid,
Mangaic acid, nickel acid, phosphoric acid or carbonic acid, consume a large amount of water and release oxygen, while generating a large amount of heat, hot oxygen and sky
Gas passes through graphene film 703, insulation diaphragm 705 and porous plastic plate 702 from the shell 701 of lithium battery group 7 by suction ventilator 9
Or evacuator sucks out, and reduces the temperature inside lithium battery group 7, so can be carried out quickly to this lithium battery group 7
Charging.The very big air of humidity sucks lithium battery group 7 by suction ventilator 9 or evacuator, and the vapor of air group is by lithium battery
The chlorination calcium uptake of 7 the inside of group becomes liquid water, supplements the water lost between the anode 704 of lithium battery and cathode 706.Suction ventilator
9 or evacuator in lithium battery group 7 hot oxygen and air be sucked out after discharged by 10 normally open valves of solenoid directional control valve.Lithium
Battery pack 7 discharge when, computer controller make air solenoid valve 1 be powered close and solenoid directional control valve 10 be powered connect escape pipe 8 and
Channel between hydrogen fuel cell 11, computer controller make suction ventilator 9 or evacuator energization rotation.Lithium battery group 7 is discharged:
Lithium and cobalt acid, mangaic acid, nickel acid, phosphoric acid or carbonic acid occur chemical reaction generate cobalt acid lithium, LiMn2O4, lithium nickelate, lithium phosphate or
Person's lithium carbonate consumes a large amount of water and releases hydrogen, while generating a large amount of heat；The discharge capacity of lithium battery is less than charge volume
Half, remaining energy are released in the form of thermal energy and fuel gas hydrogen.The hot hydrogen of 7 the inside of lithium battery group is by air draught
Machine 9 or evacuator are sucked out, then through the normally close valve for the solenoid directional control valve 10 opened that energization enter hydrogen fuel cell 11 with
Oxygen occurs chemical reaction and generates water and generate electricity, and hydrogen fuel cell 11 can be using hydrogen as the half of the energy of combustion gas
It is converted into electric energy, remaining half is converted into thermal energy.From hydrogen fuel cell 11 come out be more than 150 DEG C hot gas entrance more than
Thermal electric generator 12 generates electricity, and cogeneration machine 12 can convert electric energy for the half of the thermal energy of the hot gas more than 150 DEG C.Computer
The electricity that lithium battery, hydrogen fuel cell 11 and cogeneration machine 12 generate is adjusted as electric car power supply by controller.In carbon
Sour lithium is done in the lithium battery group 7 of anode 704, and computer controller makes carbon dioxide solenoid valve 4 be powered when lithium battery group 7 is discharged, from
The carbon dioxide that liquefied carbon dioxide tank 3 comes out enters in the water of water tank 5 by the carbon dioxide solenoid valve 4 opened that is powered, and two
Carbonoxide comes out from water tank 5 enters in lithium battery group 7 damage for making up water and carbon dioxide in carbonic acid lithium battery by nearly tracheae 6
It loses.Substance portion due to being easy loss in lithium battery can be supplemented in time, so the use time of this lithium battery recharge
Number is very high, and the service life of this lithium battery is also very long.
Shown in Fig. 2, Fig. 3 and Fig. 4, a kind of control method of electrokinetic cell system: lithium battery group 7 charge when or electric discharge
When, computer controller makes 10 power loss of solenoid directional control valve close the channel between the escape pipe 8 and hydrogen fuel cell 11 of container.Computer
Controller makes air compressor machine or the energization rotation of air blower 2, and the air come out from air compressor machine or air blower 2 enters in the water of water tank 5.Tide
Wet air comes out the loss for making up water in lithium battery group 7 into lithium battery group 7 by air inlet pipe 6 from water tank 5.Lithium battery fills
Electricity: cobalt acid lithium, LiMn2O4, lithium nickelate, lithium phosphate or lithium carbonate resolve into lithium and cobalt acid, mangaic acid, nickel acid, phosphoric acid or carbon
Acid consumes a large amount of water and releases oxygen, while releasing a large amount of heat of generation, and hot oxygen and air are in air compressor machine or air blower 2
Pressure under pass through graphene film 703, insulation diaphragm 705 and porous plastic plate 702 go out from the shell 701 of lithium battery group 7
Come.The very big air of humidity enters lithium battery group 7 and becomes liquid water, supplement lithium electricity by the chlorination calcium uptake of 7 the inside of lithium battery group
The water lost between the anode 704 and cathode 706 in pond passes through the normally open valve of solenoid directional control valve 10 after hot-air and oxygen lithium battery
Discharge.When lithium battery group 7 is discharged, computer controller make solenoid directional control valve 10 be powered connect escape pipe 8 and hydrogen fuel cell 11 it
Between channel, computer controller makes air compressor machine or air blower 2 be powered rotation.Lithium battery group 7 is discharged: lithium and cobalt acid, mangaic acid, nickel
Acid, phosphoric acid or carbonic acid occur chemical reaction and generate cobalt acid lithium, LiMn2O4, lithium nickelate, lithium phosphate or lithium carbonate, and consumption is a large amount of
Water and release hydrogen, while generating a large amount of heat；The discharge capacity of lithium battery less than charge volume half, remaining energy with
The form of thermal energy and fuel gas hydrogen releases.The air containing hydrogen of the inside of lithium battery group 7 come out after by being powered
The normally close valve of the solenoid directional control valve 10 of opening enters hydrogen fuel cell 11 and oxygen occurs chemical reaction and generates water and generate electricity
Amount, hydrogen fuel cell 11 can be converted into electric energy for hydrogen as the half of the energy of combustion gas, and remaining half is converted into thermal energy.
Coming out from hydrogen fuel cell 11 is more than that 150 DEG C of hot gas enters the power generation of cogeneration machine 12, and cogeneration machine 12 can
Electric energy is converted by the half of the thermal energy of the hot gas more than 150 DEG C.Computer controller is by lithium battery, hydrogen fuel cell 11 and remaining
The electricity that thermal electric generator 12 generates is adjusted as electric car power supply.In the lithium battery group 7 that lithium carbonate does anode 704, lithium electricity
Computer controller makes carbon dioxide solenoid valve 4 be powered when pond group 7 is discharged, the carbon dioxide warp come out from liquefied carbon dioxide tank 3
It crosses the carbon dioxide solenoid valve 4 for being powered and opening to enter in the water of water tank 5, carbon dioxide comes out from water tank 5 to be entered by nearly tracheae 6
The loss of water and carbon dioxide in carbonic acid lithium battery is made up in lithium battery group 7.Due to being easy the substance portion energy of loss in lithium battery
Enough to be supplemented in time, so this lithium battery recharge access times are very high, the service life of this lithium battery is also very
It is long.
Claims (8)
1. a kind of electrokinetic cell system, it is characterised in that: electrokinetic cell system is by lithium battery group (7), hydrogen fuel cell (11), remaining
Thermal electric generator (12), water tank (5), air solenoid valve (1), liquefied carbon dioxide tank (3), carbon dioxide solenoid valve (4), suction ventilator
(9) or evacuator, solenoid directional control valve (10) and computer controller composition, lithium battery group (7) are connected to air inlet pipe (6), air inlet pipe
(6) the other end is at the top of water tank (5), and the carbon dioxide come out from liquefied carbon dioxide tank (3) is by the dioxy opened that is powered
Change carbon solenoid valve (4) to enter in the water of water tank (5), air enters the water of water tank (5) by the air solenoid valve (1) that power loss is opened
In, it is connected to escape pipe in lithium battery group, is connected on escape pipe (8) and is sequentially arranged with air draught (9) machine or evacuator and electromagnetic switch
Valve (10) is connected to hydrogen fuel cell group (11) in the normally closed outlet of solenoid directional control valve (10), is connected in the outlet of hydrogen fuel cell
Cogeneration machine (12), electrokinetic cell system is controlled by computer controller.
2. a kind of electrokinetic cell system, it is characterised in that: electrokinetic cell system is by lithium battery group (7), hydrogen fuel cell (11), remaining
Thermal electric generator (12), water tank (5), liquefied carbon dioxide tank (3), carbon dioxide solenoid valve (4), air compressor machine or air blower (2), electricity
Magnetic reversal valve (10) and computer controller composition, lithium battery group (7) are connected to air inlet pipe (6), and the other end of air inlet pipe (6) is in water tank
(5) top, the carbon dioxide come out from liquefied carbon dioxide tank (3) enter by the carbon dioxide solenoid valve (4) opened that is powered
In the water of water tank (5), the air come out from air compressor machine or air blower (2) enters in the water of water tank (5), and lithium battery group connects on (7)
Have escape pipe (8), solenoid directional control valve (10) are housed on escape pipe (8), hydrogen combustion is connected in the normally closed outlet of solenoid directional control valve (10)
Expect battery (11), is connected to cogeneration machine (12) in the outlet of hydrogen fuel cell (11), electrokinetic cell system is by computer controller
Control.
3. a kind of electrokinetic cell system according to claim 1 or claim 2, it is characterised in that: the lithium battery group (7) is by multiple groups lithium
Battery composition, lithium battery by porous plastic plate (702), positive conductor, anode (704), insulation diaphragm (705), cathode conductor,
Cathode (706) and shell (701) composition, with a piece of good permeability, the graphene film that reverse osmosis resistance is small, resistivity is small
(703) it is used as cathode of lithium battery conductor, the cathode (706) of lithium battery is to penetrate into cathode conductor graphene film (703) surface
Nanometer lithium, use other a piece of good permeability, reverse osmosis resistance is small, resistivity is small graphene film (703) is as lithium battery
Positive conductor, lithium battery anode (704) be one layer of cobalt acid lithium being coated on positive conductor graphite alkene film (703), LiMn2O4,
Lithium nickelate, ter-polymers, LiFePO4 or carbonic acid lithium electrolyte, the anode (704) of lithium battery and cathode (706) have one layer
Insulation diaphragm (705), insulation diaphragm (705) are the thin polymer films that lithium ion can be allowed to pass through, two groups of adjacent lithium batteries
Calcium chloride is accompanied between two panels graphene film (703), the porous plastic plate of two panels is posted on the graphene film of multiple groups lithium battery
(703), there is gap in outside between shell (701) and porous plastic plate (702).
4. a kind of production method of lithium battery group, it is characterised in that: production two panels cellular-plastic panels (702), with piece of graphite alkene
Film (703) is used as cathode of lithium battery conductor, nanometer lithium is penetrated into cathode conductor graphene film (703) surface, in addition
Piece of graphite alkene film (703) is used as lithium battery anode conductor, coats one layer of cobalt acid on positive conductor graphite alkene film (703)
Lithium, LiMn2O4, lithium nickelate, ter-polymers, LiFePO4 or carbonic acid lithium electrolyte, in the anode (704) of lithium battery and negative
A polymer insulation diaphragm (705) that lithium ion can be allowed to pass through, the two panels of two groups of adjacent lithium batteries are pressed from both sides between pole (706)
Graphene film coats calcium chloride between (703), and the graphene for being posted on multiple groups lithium battery with the porous plastic plate of two panels (702) is thin
It outside film (703), then is packaged with the material of shell (701), finally loads onto copper socket.
5. a kind of electrokinetic cell system according to claim 1 or claim 2, it is characterised in that: the lithium battery group (7) is by multiple groups lithium
Battery composition, lithium battery by porous plastic plate (702), positive conductor, anode (704), insulation diaphragm (705), cathode conductor,
Cathode (706) and shell (701) composition, with a piece of good permeability, the graphene film that reverse osmosis resistance is small, resistivity is small
(703) it is used as cathode of lithium battery conductor, cathode of lithium battery (706) penetrates into cathode conductor graphene film (703) surface
Nanometer lithium, use other a piece of good permeability, reverse osmosis resistance is small, resistivity is small graphene film (703) as lithium battery just
Pole conductor, lithium battery anode (704) are one layer of cobalt acid containing calcium chloride being coated on positive conductor graphite alkene film (703)
Lithium, LiMn2O4, lithium nickelate, ter-polymers, LiFePO4 or carbonic acid lithium electrolyte, the anode (704) and cathode of lithium battery
(706) insulation diaphragm (705) is accompanied between, insulation diaphragm (705) is the thin polymer film that lithium ion can be allowed to pass through, phase
The adjacent public piece of graphite alkene film (703) of two groups of lithium batteries, the porous plastic plate of two panels (702) are posted on the stone of multiple groups lithium battery
Outside black alkene film (703), there is gap between shell (701) and porous plastic plate (702).
6. a kind of production method of lithium battery group, it is characterised in that: production two panels cellular-plastic panels (702), with piece of graphite alkene
Film (703) is used as cathode of lithium battery conductor, nanometer lithium is penetrated into cathode conductor graphene film (703) surface, in addition
Piece of graphite alkene film (703) is used as lithium battery anode conductor, coats one layer on positive conductor graphite alkene film (703) and contains
Cobalt acid lithium, LiMn2O4, lithium nickelate, ter-polymers, LiFePO4 or the carbonic acid lithium electrolyte of calcium chloride, lithium battery just
A polymer insulation diaphragm (705) for enough allowing lithium ion to pass through, two groups of adjacent lithiums are pressed from both sides between pole (704) and cathode (706)
The public piece of graphite alkene film (703) of battery, the graphene film of multiple groups lithium battery is posted on the porous plastic plate of two panels (702)
(703) outside, then be packaged with the material of shell (701), finally load onto copper socket.
7. a kind of control method of electrokinetic cell system, it is characterised in that: when lithium battery group (7) charges or idle, computer
Controller makes air solenoid valve (1) power loss opening and solenoid directional control valve (10) power loss close escape pipe (8) and hydrogen fuel cell
(11) channel between, computer controller make suction ventilator (9) or evacuator energization rotation, air pass through the sky that power loss is opened
Pneumoelectric magnet valve (1) enters in the water of water tank (5), then passes through the inner water of water tank (5) from air inlet pipe (6) and enters lithium battery group (7),
Increase the inner air humidity of air inlet pipe (6)；Lithium battery group (7) charging: cobalt acid lithium, LiMn2O4, lithium nickelate, lithium phosphate or carbon
Sour lithium resolves into lithium and cobalt acid, mangaic acid, nickel acid, phosphoric acid or carbonic acid, consumes a large amount of water and releases oxygen, while generating big
The heat of amount, hot oxygen and air pass through graphene film (703), insulation diaphragm (705) and porous plastic plate (702) from lithium
The shell (701) of battery pack (7) is sucked out by suction ventilator (9) or evacuator, reduces the internal temperature of lithium battery group (7)
Degree, the very big air of humidity is by suction ventilator (9) or evacuator sucking lithium battery group (7), and the vapor of air group is by by lithium
Chlorination calcium uptake inside battery pack (7) becomes liquid water, supplements and loses between the anode (704) of lithium battery and cathode (706)
Water, suction ventilator (9) or evacuator the inner hot oxygen of lithium battery group (7) and air are sucked out after by solenoid directional control valve
(10) normally open valve discharges；When lithium battery group (7) is discharged, computer controller makes air solenoid valve (1) energization closing and electromagnetic switch
The channel between escape pipe (8) and hydrogen fuel cell (11) is connected in valve (10) energization, and computer controller makes suction ventilator (9) or takes out
Vacuum machine, which is powered, to be rotated；Lithium battery group (7) electric discharge: chemical reaction life occurs for lithium and cobalt acid, mangaic acid, nickel acid, phosphoric acid or carbonic acid
At cobalt acid lithium, LiMn2O4, lithium nickelate, lithium phosphate or lithium carbonate, consumes a large amount of water and release hydrogen, lithium battery group (7)
The hydrogen of the inside is sucked out by suction ventilator (9) or evacuator, then by the normally closed of the solenoid directional control valve (10) opened that be powered
Valve enters hydrogen fuel cell (11) and oxygen occurs chemical reaction and generates water and generate electricity, comes out from hydrogen fuel cell (11)
It is more than that 150 DEG C of hot gas enters cogeneration machine (12) power generation, computer controller is by lithium battery, hydrogen fuel cell (11)
The electricity generated with cogeneration machine (12) is adjusted as electric car power supply；The lithium battery group of positive (704) is done in lithium carbonate
(7) inner, computer controller makes carbon dioxide solenoid valve (4) to be powered when lithium battery group (7) is discharged, from liquefied carbon dioxide tank (3)
Carbon dioxide out enters in the water of water tank (5) by the carbon dioxide solenoid valve (4) opened that is powered, and carbon dioxide is from water tank
(5) it comes out and enters lithium battery group (7) inner loss for making up water and carbon dioxide in carbonic acid lithium battery by nearly tracheae (6).
8. a kind of control method of electrokinetic cell system, it is characterised in that: when lithium battery group (7) charges or when electric discharge, computer
Controller makes solenoid directional control valve (10) power loss close the channel between the escape pipe (8) and hydrogen fuel cell (11) of container, computer
Controller makes air compressor machine or air blower (2) energization rotation, and the air come out from air compressor machine or air blower (2) enters water tank (5)
In water, wet air comes out from water tank (5) and makes up water in lithium battery group (7) into lithium battery group (7) by air inlet pipe (6)
Loss；Lithium battery charging: cobalt acid lithium, LiMn2O4, lithium nickelate, lithium phosphate or lithium carbonate resolve into lithium and cobalt acid, mangaic acid, nickel
Acid, phosphoric acid or carbonic acid, consume a large amount of water and release oxygen, while generating a large amount of heat, and hot oxygen and air are in pneumatics
Graphene film (703), insulation diaphragm (705) and porous plastic plate (702) are passed through under the pressure of machine or air blower (2) from lithium
The shell (701) of battery pack (7) comes out, and the very big air of humidity enters lithium battery group (7) by the chlorination inside lithium battery group (7)
Calcium uptake becomes liquid water, supplements the water lost between the anode (704) of lithium battery and cathode (706), after hot-air lithium battery
It is discharged by the normally open valve of solenoid directional control valve (10)；When lithium battery group (7) is discharged, computer controller keeps solenoid directional control valve (10) logical
The channel between escape pipe (8) and hydrogen fuel cell (11) is electrically connected, computer controller turns air compressor machine or air blower (2) energization
It is dynamic；Lithium battery group (7) electric discharge: lithium and cobalt acid, mangaic acid, nickel acid, phosphoric acid or carbonic acid occur chemical reaction and generate cobalt acid lithium, mangaic acid
Lithium, lithium nickelate, lithium phosphate or lithium carbonate consume a large amount of water and release hydrogen, contain hydrogen inside lithium battery group (7)
Air come out after enter hydrogen fuel cell (11) and oxygen by the normally close valve for the solenoid directional control valve (10) opened that is powered and occur
Chemical reaction generates water and simultaneously generates electricity, and coming out from hydrogen fuel cell (11) is more than that 150 DEG C of hot gas enters waste heat and sends out
Motor (12) power generation, computer controller by lithium battery group (7), hydrogen fuel cell (11) and cogeneration machine (12) generate it is electric into
Row is adjusted to electric car power supply；In the lithium battery that lithium carbonate does positive (704), computer is controlled when lithium battery group (7) is discharged
Instrument makes carbon dioxide solenoid valve (4) to be powered, and the carbon dioxide come out from liquefied carbon dioxide tank (3) is by the dioxy opened that is powered
Change carbon solenoid valve (4) to enter in the water of water tank (5), carbon dioxide comes out from water tank (5) enters lithium battery group by air inlet pipe (6)
Make up the loss of carbon dioxide in carbonic acid lithium battery.
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| US20210313634A1 (en) * | 2020-04-01 | 2021-10-07 | Global Graphene Group, Inc. | Graphene-enabled battery fast-charging and cooling system and method of operating same |
| US11958382B2 (en) * | 2020-04-01 | 2024-04-16 | Honeycomb Battery Company | Graphene-enabled battery fast-charging and cooling system and method of operating same |
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