CN108711514A - The preparation method of Filamentous dye-sensitized solar cell anode - Google Patents
The preparation method of Filamentous dye-sensitized solar cell anode Download PDFInfo
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- CN108711514A CN108711514A CN201810526874.9A CN201810526874A CN108711514A CN 108711514 A CN108711514 A CN 108711514A CN 201810526874 A CN201810526874 A CN 201810526874A CN 108711514 A CN108711514 A CN 108711514A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 67
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 41
- -1 polyoxyethylene Polymers 0.000 claims abstract description 41
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 28
- 239000006256 anode slurry Substances 0.000 claims abstract description 28
- ZVZFHCZCIBYFMZ-UHFFFAOYSA-N 6-methylheptoxybenzene Chemical compound CC(C)CCCCCOC1=CC=CC=C1 ZVZFHCZCIBYFMZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 14
- 239000012153 distilled water Substances 0.000 claims abstract description 14
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 14
- 150000002334 glycols Chemical class 0.000 claims abstract description 14
- 239000004570 mortar (masonry) Substances 0.000 claims abstract description 14
- 230000010355 oscillation Effects 0.000 claims abstract description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 14
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 26
- 235000019441 ethanol Nutrition 0.000 claims description 26
- 229910052707 ruthenium Inorganic materials 0.000 claims description 26
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 15
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims description 13
- 238000004140 cleaning Methods 0.000 claims description 13
- 239000000975 dye Substances 0.000 claims description 13
- 239000011521 glass Substances 0.000 claims description 13
- 230000001699 photocatalysis Effects 0.000 claims description 13
- 238000007650 screen-printing Methods 0.000 claims description 13
- 239000002002 slurry Substances 0.000 claims description 13
- 238000002791 soaking Methods 0.000 claims description 13
- CFJRPNFOLVDFMJ-UHFFFAOYSA-N titanium disulfide Chemical compound S=[Ti]=S CFJRPNFOLVDFMJ-UHFFFAOYSA-N 0.000 claims description 13
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 13
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2027—Light-sensitive devices comprising an oxide semiconductor electrode
- H01G9/2031—Light-sensitive devices comprising an oxide semiconductor electrode comprising titanium oxide, e.g. TiO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Catalysts (AREA)
- Hybrid Cells (AREA)
- Photovoltaic Devices (AREA)
Abstract
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:Step 1:The titanium dioxide of 5.2g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol to isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed and obtains anode slurry, and the anode slurry configured is positioned in refrigerator and is stored for future use.
Description
Technical field
The present invention relates to a kind of preparation methods of Filamentous dye-sensitized solar cell anode.
Background technology
The preparation process of Filamentous dye-sensitized solar cell anode is sufficiently complex in the prior art, and holds in sintering process
Easily reunite, influences general effect.
Invention content
The present invention proposes a kind of preparation method of Filamentous dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5.1g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
The ability that the Filamentous dye-sensitized solar cell anode being obtained by this method generates photoelectric current is strong, and performance is stablized,
The present invention is simple, easy to spread.
Specific implementation mode
Embodiment 1
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5.1g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 2
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5.2g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 3
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5.3g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 4
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5.4g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 5
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5.5g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 6
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5.6g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 7
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5.7g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 8
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5.8g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 9
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5.9g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 10
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 6g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Embodiment 11
A kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, Nml is added(It should
The volume percent of solution is that 10%, N chooses from following numerical value:3.1,3.2,3.3,3.4,3.5,3.6,3.7,3.8,3.9,
4.0), M ml ethanol solution(The volume percent of the solution is that 15%, M chooses from following numerical value:3.1,3.2,3.3,
3.4,3.5,3.6,3.7,3.8,3.9,4.0), 1 gram of polyethylene glycol to isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram
Polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, are uniformly mixed and obtain anode slurry, and the anode slurry configured is placed
It is stored for future use in refrigerator;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
Claims (1)
1. a kind of preparation method of filiform dye-sensitized solar cell anode, includes the following steps:
Step 1:The titanium dioxide of 5.2g is put into mortar and is fully ground, the acetone soln of appropriate distilled water, 3.5ml is added
(The volume percent of the solution is 10%), 2ml ethanol solution(The volume percent of the solution is 15%), 1 gram of polyethylene glycol
To isooctyl phenyl ether, 2 grams of polyoxyethylene glycols, 1 gram of polyoxyethylene fatty alcohol, sonic oscillation after twenty minutes, is uniformly mixed
Anode slurry is obtained, and the anode slurry configured is positioned in refrigerator and is stored for future use;
Step 2:Conductive FTO glass cuts cleaned in advance, and puts it into titanium tetrachloride solution, at a temperature of 700C
2 hours are stood, then taking-up is dried spare;
Step 3:Above-mentioned slurry is imprinted on through on titanium tetrachloride treated FTO conducting surfaces using the method for silk-screen printing, it is dry
It is placed in device after ten minutes, is put into Muffle furnace and is calcined, the setting condition of temperature is:It is kept for 15 minutes under the conditions of 3050;
Step 4:It is cooled to room temperature taking-up, and is put it into titanium disulfide solution, 1 hour is stood at a temperature of 800C, with
Taking-up is dried spare afterwards;
Step 5:It is put into Muffle furnace under the conditions of 5000C and is calcined 40 minutes;
Step 6:It is put into bis- (isothiocyano) bis- (2,2&apos of two-tetrabutylammoniums-of 0.0004mol/L;Bipyridyl -4,4'Dicarboxyl)
Ruthenium(It is commonly called as N719 ruthenium dyes, molecular formula:C58H86N8O8RuS2)Soaking at room temperature 24 hours in solution, up to two after ethyl alcohol cleaning
Photocatalytic titanium oxide anode.
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102013340A (en) * | 2009-09-04 | 2011-04-13 | 华东理工大学 | Dye sensitized solar cell and preparation method thereof |
US20130171502A1 (en) * | 2011-12-29 | 2013-07-04 | Guorong Chen | Hybrid electrode and surface-mediated cell-based super-hybrid energy storage device containing same |
CN103700502A (en) * | 2013-12-30 | 2014-04-02 | 中国科学院上海硅酸盐研究所 | Method for preparing titanium dioxide photo-anode of DSSC (Dye-Sensitized Solar Cell) |
CN104332311A (en) * | 2014-10-25 | 2015-02-04 | 陕西玉航电子有限公司 | Preparation method of flexible titanium-based titanium dioxide thin film photo-anode |
CN108711516A (en) * | 2016-07-11 | 2018-10-26 | 王瑞明 | The preparation method of Filamentous dye-sensitized solar cell anode |
-
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102013340A (en) * | 2009-09-04 | 2011-04-13 | 华东理工大学 | Dye sensitized solar cell and preparation method thereof |
US20130171502A1 (en) * | 2011-12-29 | 2013-07-04 | Guorong Chen | Hybrid electrode and surface-mediated cell-based super-hybrid energy storage device containing same |
CN103700502A (en) * | 2013-12-30 | 2014-04-02 | 中国科学院上海硅酸盐研究所 | Method for preparing titanium dioxide photo-anode of DSSC (Dye-Sensitized Solar Cell) |
CN104332311A (en) * | 2014-10-25 | 2015-02-04 | 陕西玉航电子有限公司 | Preparation method of flexible titanium-based titanium dioxide thin film photo-anode |
CN108711516A (en) * | 2016-07-11 | 2018-10-26 | 王瑞明 | The preparation method of Filamentous dye-sensitized solar cell anode |
Non-Patent Citations (1)
Title |
---|
NAOTO UMEZAWA等: ""Optimizing optical absorption of TiO2 by alloying with TiS2"", 《APPLIED PHYSICS LETTERS》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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