CN107892759A - A kind of preparation method of the super hydrophobic polyurethane foam oil absorption material of fatty acid modifying - Google Patents
A kind of preparation method of the super hydrophobic polyurethane foam oil absorption material of fatty acid modifying Download PDFInfo
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- CN107892759A CN107892759A CN201710973632.XA CN201710973632A CN107892759A CN 107892759 A CN107892759 A CN 107892759A CN 201710973632 A CN201710973632 A CN 201710973632A CN 107892759 A CN107892759 A CN 107892759A
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- polyurethane foam
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- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 43
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 43
- 239000000463 material Substances 0.000 title claims abstract description 32
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 30
- 230000003075 superhydrophobic effect Effects 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 14
- 229930195729 fatty acid Natural products 0.000 title claims abstract description 14
- 239000000194 fatty acid Substances 0.000 title claims abstract description 14
- 150000004665 fatty acids Chemical class 0.000 title claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 13
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 9
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 10
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 8
- 238000007654 immersion Methods 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- 235000021314 Palmitic acid Nutrition 0.000 claims description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 4
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- 239000001361 adipic acid Substances 0.000 claims description 3
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 claims description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 2
- 229940070765 laurate Drugs 0.000 claims description 2
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011148 porous material Substances 0.000 claims description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims 1
- 239000005642 Oleic acid Substances 0.000 claims 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 1
- 235000021313 oleic acid Nutrition 0.000 claims 1
- 239000006260 foam Substances 0.000 abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 23
- 238000000034 method Methods 0.000 abstract description 13
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 239000000356 contaminant Substances 0.000 abstract description 6
- 238000012545 processing Methods 0.000 abstract description 3
- 235000013305 food Nutrition 0.000 abstract description 2
- 238000007725 thermal activation Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
- 239000003502 gasoline Substances 0.000 description 6
- 239000002283 diesel fuel Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- -1 Poly- ammonia Ester Chemical class 0.000 description 1
- 150000001343 alkyl silanes Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010041 electrostatic spinning Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/36—After-treatment
- C08J9/40—Impregnation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/32—Materials not provided for elsewhere for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Public Health (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses a kind of preparation method of the super hydrophobic polyurethane foam oil absorption material of fatty acid modifying, it is characterized in that using aliphatic acid and its salt as modifying agent, polyurethane foam skeleton is handled, then handled foam is subjected to thermal activation treatment, obtains super-hydrophobic foam.Oil suction foam prepared by the present invention has super-hydrophobicity, can be selectively adsorbing and separating oil product in water, and oil absorption is up to the decades of times of itself capacity, and adsorbed oil product can be reclaimed by way of mechanical presses.Foam prepared by the present invention has the characteristics of technique is simple, and cost is cheap, better tolerance, fast water-oil separating efficiency high and swelling rate, can be used widely in the field such as oil contaminants removing, chemicals processing, food production and kitchen in water.
Description
Technical field
The present invention relates to oil absorption material field, and in particular to the super hydrophobic polyurethane bubble simple, inexpensive to a kind of technique
The preparation method of foam oil absorption material.
Background technology
In recent years, oily wastewater pollution event frequently occurs, and the pollution to water environment is increasingly severe, exploitation high efficiency oil-water separation
Material is always focus of concern.In various water-oil separating materials, super hydrophobic material because of it there is strong water to repel
Property, oily compatibility, are expected in water be used widely in terms of the absorption and separation of oil contaminants, cause people greatly to pay close attention to.
The preparation method of super hydrophobic surface has sol-gel process, spraying process, method of electrostatic spinning, chemical vapour deposition technique, hydro-thermal method and divided
Sub- self-assembly method etc., but the preparation technology of these methods is relatively complicated, cost is high, and would generally be used in preparation process poisonous
Solvent, bring new environmental pollution.Therefore, on the premise of high water-oil separating efficiency is ensured, the ring of water-oil separating material is realized
Prepared by border friendly, technique is simplified and cost degradation is its key that energy large-scale application is handled in oily pollution conscientiously.Poly- ammonia
Ester foam is a kind of high polymer material with unique three-dimensional mesh space structure, because big porosity, good chemistry are steady
Qualitative and high resiliency etc., become the excellent carrier of sorbing material preparation.However, due to stronger hydrophily, polyurethane foam
Foam is unable to oil contaminants in selective absorption water, therefore, limits its application in water in oil contaminants adsorbing separation.It is existing
In foam of polymers super-hydrophobicization technology, someone handles foam of polymers to obtain hydrophobic oleophilic oil using graphene, alkyl silane
Material.Although existing method improves the hydrophobicity of foam of polymers, modifying agent is expensive, causes product cost to increase
Add, it is therefore desirable to research and develop a kind of method modified polyurethane foam cheap, technique is simple and environmentally-friendly, promote it in sea, river
Application in stream and the processing of lake oily pollution.
The content of the invention
It is an object of the present invention to provide the method that a kind of directly modification of aliphatic acid causes polyurethane foam super-hydrophobicization, thus will
Aliphatic acid NW-TFT prepares super-hydrophobic oil absorption material, to realize it in oil absorption and profit point to polyurethane foam surface
From the application of aspect.
To achieve the above object of the invention, the concrete technical scheme that uses of the present invention for：
A kind of preparation method of the super hydrophobic polyurethane foam oil absorption material of fatty acid modifying, comprises the following steps：By fat
Fat acid is added in solvent, and stirring is made into the adipic acid solution that concentration is 0.01-20%；Then polyurethane foam is immersed in fat
In acid solution, in 25-65 DEG C of stirring reaction 0.5-20 hour；Finally the polyurethane foam after immersion is heated at 60-120 DEG C
0.5-24 hours are handled, that is, obtain the super hydrophobic polyurethane foam of fatty acid modifying.
Preferably, the average pore size chi of the polyurethane foam is 100-300 μm.On this condition, modified material
Hydrophobicity and Oil keeping are good.
Preferably, aliphatic acid includes but is not limited to capric acid, laurate, palmitic acid, myristic acid, palmitic acid, stearic acid, oil
Acid.
Preferably, the mass concentration of the aliphatic acid is 0.01-10%.
Preferably, solvent includes but is not limited to methanol, ethanol, butanol, pentanediol, acetone, isopropanol, benzene, chloroform, tetrachloro
Change carbon.
Preferably, the control of the mass ratio of polyurethane foam and solvent is in the range of 0.03%-3.0%.
Super-hydrophobic foam obtained by the present invention is applied to separating for water-insoluble organic solvent and oil product and water.
The invention also discloses the super hydrophobic polyurethane foam oil suction material of the fatty acid modifying prepared by above-mentioned preparation method
Material.The super hydrophobic polyurethane foam oil absorption material of the fatty acid modifying is up to 45 times to the adsorbance of organic solvent and oil, weight
Multiple usability is good, after it is recycled 98 times, still has higher absorption multiplying power；Available in water at oily adsorbing separation
Reason, therefore the invention also discloses its application in water-oil separating material.
Compared with prior art, the present invention has advantages below：1. use cheap polyurethane sponge and aliphatic acid
As raw material, preparation process only needs immersion and thermal activation, and super-hydrophobic oil absorption material can be obtained using conventional equipment, operates
It is extremely simple, other methods are contrasted, cost is greatly lowered；2. the super hydrophobic polyurethane foam has higher oil suction multiplying power,
Up to deadweight decades of times；Water repellency and oily compatibility with height, can be rapidly to different water-insoluble organic in water
Solvent and oil product carry out selective absorption, so as to realize the effect of water-oil separating；3. the oil absorption material for preparing of the present invention have compared with
Low density and higher elasticity, the water surface can be swum in after absorption oil, be the oil of recyclable absorption by simple extruding, and
Rear oil suction multiplying power is repeatedly used without being remarkably decreased；4. oil absorption material prepared by the present invention can not only meet oil contaminants in water
The demand of cleaning, the fields such as Automobile Service, kitchen, food processing and industrial oily waste water purification can also be applied to.
Brief description of the drawings
Fig. 1 is the stereoscan photograph (SEM) of Stearate Modified polyurethane foam in example 1
Fig. 2 is the stereoscan photograph (SEM) of original polyurethane foam
Fig. 3 is the wettability optical photograph and water contact angle figure of Stearate Modified polyurethane foam in embodiment 1.In figure
Display water droplet is not penetrated into foam, spherical in shape in foam surface, and the measured value of contact angle is 152 °.
Fig. 4 is the oil-wet optical photograph of Stearate Modified polyurethane foam in embodiment 1.Show that gasoline contact is original
Rapidly permeated into after polyurethane foam in foam.
Fig. 5 is the water droplet contact angle schematic diagram of original polyurethane foam.Water drop contact original polyurethane foam is shown in figure
After spread out and penetrate into foam.
Specific embodiment
With reference to embodiment, the present invention will be further described.It is but all the present invention's the invention is not limited in this
All any modification, equivalent and improvement done within spirit and principle etc., should be included in the scope of the protection.
Experimental method described in following embodiments, it is conventional method unless otherwise specified；The kit material, such as
Without specified otherwise, commercially obtain.
Embodiment 1：
The stearic acid solution that mass concentration is 3% is prepared by solvent of ethanol, then soaks 0.5g polyurethane foams completely
Not in the above-mentioned solution of 100mL, sealed reaction vessel, stirred 24 hours at 30 DEG C.Then, modifying agent immersion treatment is crossed
Foam is placed in heat-activated 1 hour at 100 DEG C, you can obtains the polyurethane foam oil absorption material with super-hydrophobicity.This implementation
Oil suction multiplying power of the super-hydrophobic foam obtained in example to chloroform, gasoline and diesel oil is respectively 41.2,19.6 and 22.6g/g.Scanning
Electron micrograph is visible, and the microstructure on the high oil absorption foam framework surface obtained through Stearate Modified occurs significantly to become
Change, foam surface is evident that attachment (Fig. 1), and original foam surface is relatively smooth (Fig. 2), it was confirmed that stearic acid
The presence of modifying foam surface micronano level structure layer, thus the hydrophobic oleophilic oil of original foam is improved.Oil suction foam has
Standby good water repellency and oleophylic performance, water droplet can not penetrate into foam inside, but be held in foam table for a long time with spherical shape
Face, water contact angle is up to 152 ° (Fig. 3)；And gasoline is dripped and can rapidly permeated into inside it in foam surface, only oil is left on surface
Mark (Fig. 4).For unmodified original foam, water droplet can then rapidly permeate into foam inside ° (Fig. 5), thus be selected without profit
Selecting property, it is impossible to optionally adsorb oil contaminants in water.
Embodiment 2：
The stearic acid solution that mass concentration is 3% is prepared by solvent of chloroform, then soaks 0.5g polyurethane foams completely
Not in the above-mentioned solution of 100mL, sealed reaction vessel, stirred 1 hour at 40 DEG C.Then, modifying agent immersion treatment is crossed
Foam is placed in heat-activated 24 hours at 60 DEG C, you can obtains the polyurethane foam oil absorption material with super-hydrophobicity.This implementation
Oil suction multiplying power of the super-hydrophobic foam obtained in example to chloroform, gasoline and diesel oil is respectively 44,21.8 and 24.5g/g.
Embodiment 3：
The bay acid solution that mass concentration is 0.5% is prepared by solvent of ethanol, it is then that 0.5g polyurethane foams is complete
It is immersed in the above-mentioned solution of 100mL, sealed reaction vessel, is stirred 1 hour at 65 DEG C.Then, by modifying agent immersion treatment mistake
Foam be placed in heat-activated 0.5 hour at 100 DEG C, you can obtain with super-hydrophobicity polyurethane foam oil absorption material.This
Oil suction multiplying power of the super-hydrophobic foam obtained in embodiment to chloroform, gasoline and diesel oil is respectively 39.5,18.2 and 20.3g/g.
Embodiment 4：
The stearic acid solution that mass concentration is 0.5% is prepared by solvent of ethanol, then soaks 3g polyurethane foams completely
Not in the above-mentioned solution of 100mL, sealed reaction vessel, stirred 10 hours at 30 DEG C.Then, modifying agent immersion treatment is crossed
Foam is placed in heat-activated 12 hours at 60 DEG C, you can obtains the polyurethane foam oil absorption material with super-hydrophobicity.This implementation
Oil suction multiplying power of the super-hydrophobic foam obtained in example to chloroform, gasoline and diesel oil is respectively 44.0,24.5 and 24.8g/g.
Claims (6)
1. the preparation method of the super hydrophobic polyurethane foam oil absorption material of a kind of fatty acid modifying, it is characterised in that including following
Step：Aliphatic acid is added in solvent, stirring is made into the adipic acid solution that concentration is 0.01-20%；Then by polyurethane foam
It is immersed in adipic acid solution, in 25-65 DEG C of stirring reaction 0.5-20 hour；Finally by the polyurethane foam after immersion in 60-
Heat 0.5-24 hours at 120 DEG C, that is, obtain the super hydrophobic polyurethane foam of fatty acid modifying.
2. the preparation method of the super hydrophobic polyurethane foam oil absorption material of fatty acid modifying as claimed in claim 1, its feature exist
In polyurethane foam average pore size in 100-600 μ ms.
3. the preparation method of the super hydrophobic polyurethane foam oil absorption material of fatty acid modifying as claimed in claim 1, its feature exist
In aliphatic acid be capric acid, laurate, palmitic acid, myristic acid, palmitic acid, stearic acid, oleic acid.
4. the preparation method of the super hydrophobic polyurethane foam oil absorption material of fatty acid modifying according to claim 1, its feature
The mass concentration for being the aliphatic acid is 0.01-10%.
5. the preparation method of the super hydrophobic polyurethane foam oil absorption material of fatty acid modifying as claimed in claim 1, its feature exist
In solvent be methanol, ethanol, butanol, pentanediol, acetone, isopropanol, benzene, chloroform, carbon tetrachloride.
6. the preparation method of the super hydrophobic polyurethane foam oil absorption material of fatty acid modifying as claimed in claim 1, its feature exist
In the control of the mass ratio of polyurethane foam and solvent in the range of 0.03%-3.0%.
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| CN201710973632.XA CN107892759A (en) | 2017-10-19 | 2017-10-19 | A kind of preparation method of the super hydrophobic polyurethane foam oil absorption material of fatty acid modifying |
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| CN201710973632.XA CN107892759A (en) | 2017-10-19 | 2017-10-19 | A kind of preparation method of the super hydrophobic polyurethane foam oil absorption material of fatty acid modifying |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109621923A (en) * | 2018-12-13 | 2019-04-16 | 沈阳建筑大学 | A kind of super-hydrophobic oleophylic sponge material and preparation method thereof and water-oil separating application |
| CN111363193A (en) * | 2020-03-06 | 2020-07-03 | 郑州峰泰纳米材料有限公司 | Melamine foam |
| CN112495353A (en) * | 2020-10-27 | 2021-03-16 | 上海工程技术大学 | Integrated device for continuously recovering thin oil film on water surface |
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2017
- 2017-10-19 CN CN201710973632.XA patent/CN107892759A/en active Pending
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|---|---|---|---|---|
| US4161460A (en) * | 1974-11-08 | 1979-07-17 | R. B. Cybernetris (1970) Ltd. | Method of enhancing oleophilic and hydrophobic properties of absorbent material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109621923A (en) * | 2018-12-13 | 2019-04-16 | 沈阳建筑大学 | A kind of super-hydrophobic oleophylic sponge material and preparation method thereof and water-oil separating application |
| CN111363193A (en) * | 2020-03-06 | 2020-07-03 | 郑州峰泰纳米材料有限公司 | Melamine foam |
| CN111363193B (en) * | 2020-03-06 | 2022-08-05 | 郑州峰泰纳米材料有限公司 | Melamine foam |
| CN112495353A (en) * | 2020-10-27 | 2021-03-16 | 上海工程技术大学 | Integrated device for continuously recovering thin oil film on water surface |
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