CN106876147A - Self-charging energy device based on fabric and preparation method thereof - Google Patents

Self-charging energy device based on fabric and preparation method thereof Download PDF

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Publication number
CN106876147A
CN106876147A CN201710035582.0A CN201710035582A CN106876147A CN 106876147 A CN106876147 A CN 106876147A CN 201710035582 A CN201710035582 A CN 201710035582A CN 106876147 A CN106876147 A CN 106876147A
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China
Prior art keywords
flexible
fabric
self
device based
charging energy
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CN201710035582.0A
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Chinese (zh)
Inventor
张海霞
宋宇
黄佳欢
张进鑫
缪立明
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Peking University
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Peking University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/08Structural combinations, e.g. assembly or connection, of hybrid or EDL capacitors with other electric components, at least one hybrid or EDL capacitor being the main component
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/84Processes for the manufacture of hybrid or EDL capacitors, or components thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors

Abstract

The invention provides a kind of self-charging energy device based on fabric and preparation method thereof.The equipment includes:Flexible electrode, solid electrolyte and flexible partition, solid electrolyte is covered in the both sides of flexible partition, the flexible partition of both sides covering solid electrolyte is sandwiched in the middle of two panels flexible fabric electrode, solid electrolyte and flexible fabric electrode contact obtain flexible super capacitor.Flexible fabric electrode and flexible super capacitor are attached at clothing surface, and flexible fabric electrode is connected with flexible super capacitor by rectifier bridge.The self-charging energy device based on fabric that the present invention is provided, using general flexible fabric electrode, it is easy to be attached at all kinds of clothing surfaces, can be applied in energy acquisition and energy storage device simultaneously, and preparation process is simple, integrated level are high.

Description

Self-charging energy device based on fabric and preparation method thereof
Technical field
The present invention relates to wearable electronic technical field, more particularly to a kind of self-charging energy device based on fabric And preparation method thereof.
Background technology
It is to meet nowadays fast-developing one kind of portable electronic that wearable electronic is processed in light, flexible substrate Effective and feasible scheme, and for these wearable devices, how effectively to carry out energy acquisition with supply is highly important portion Point.In recent years, some integrated self-driven energy systems start to be applied in wearable device, and show very stable property Energy.Wherein, extraneous vibration is effectively gathered by friction generator and electric energy and can be converted into, be stored in ultracapacitor, can be with The energy supply demand of low-power electronic devices is met, by the extensive concern of scientific research scholar.
For such wearable energy unit with self-charging ability, Wang Zhonglin professors seminar has carried out substantial amounts of spy Rope, it is proposed that a kind of by gathering the solar energy in ambient light and the energy acquisition device of the mechanical energy of human motion simultaneously, deposits It is stored in flexible super capacitor, it is possible to the fibrous self-driven fabric device of steady operation in a variety of contexts, shows Preferable performance.Additionally, compared to energy storage devices such as rechargeable battery and traditional capacitors, ultracapacitor has Gao Gong The advantage such as rate density, charge/discharge rates are fast, cyclical stability is strong, flexible solid-state super capacitor can meet wearable device With the demand of flexible electronic device, it is adaptable in all kinds of flexible wearable equipment.
However, existing ultracapacitor passes through solar cell for supplying power, it is contemplated that solar cell depends on ambient light The influence in source, can not Real-time Collection energy, application scenario be subject to a definite limitation, on the other hand, in existing ultracapacitor Fibrous energy acquisition it is complex with memory device preparation technology, be not particularly suited for large-scale batch production.
The content of the invention
The embodiment provides a kind of self-charging energy device based on fabric and preparation method thereof, to realize leading to With while suitable for energy acquisition and energy stores self-charging energy device.
To achieve these goals, this invention takes following technical scheme.
According to an aspect of the invention, there is provided a kind of self-charging energy device based on fabric, including:Flexible electrical Pole, solid electrolyte and flexible partition, the solid electrolyte is covered in the both sides of the flexible partition, and both sides are covered into solid-state The flexible partition of electrolyte is sandwiched in the middle of two panels flexible fabric electrode, and the solid electrolyte connects with the flexible fabric electrode Touch, obtain flexible super capacitor.
Further, flexible fabric electrode and the flexible super capacitor are attached at clothing surface, and it is described soft Property textile electrode is connected with the flexible super capacitor by rectifier bridge.
Further, the flexible electrode is that flexible fabric adheres to multi-walled carbon nano-tubes, and the solid electrolyte is gel Polymer, the flexible partition is flexible semipermeable membrane material.
According to another aspect of the present invention, there is provided a kind of preparation method of the self-charging energy device based on fabric, Including:
Step 1, CNT is mixed with surfactant sodium dodecyl base benzene sulfonic acid sodium salt by weighing, and be added to from In sub- water, the CNT dissolves in deionized water with the surfactant sodium dodecyl base benzene sulfonic acid sodium salt, obtains carbon and receives Mitron solution;
Step 2, by way of drying is added dropwise the carbon nano-tube solution is dropped in into flexible fabric surface, and dried Operation, repeatedly to the carbon nano-tube solution concentration saturation on flexible fabric surface after dropwise addition drying operation, as flexible fabric electrode;
Step 3, gelatin polymer is added in deionized water by the method for magnetic agitation, it is transparent to solution, obtain Gel polymer solution, using the gel polymer solution as solid electrolyte;
Step 4, flexible partition is immersed in the solid electrolyte, set standing time, cover flexible partition both sides One layer of solid electrolyte;
Step 5, stress press by way of, flexible partition is sandwiched in the middle of two panels flexible fabric electrode, obtain super Capacitor;
Step 6, the ultracapacitor is placed in baking oven, after removing the hydrone remained in ultracapacitor, will be super Level capacitor is attached at clothing surface, obtains wearable flexible super capacitor;
Flexible fabric electrode seam is woven in clothing surface, single face friction generator is obtained;
The single face friction generator is integrated by rectifier bridge with the wearable flexible solid-state supercapacitor Connection, obtains the self-charging energy device based on fabric.
Further, described step 1 also includes:
By the method for water bath sonicator, the CNT is set to be connect with the surfactant sodium dodecyl base benzene sulfonic acid sodium salt Touch, dissolving in deionized water, obtains carbon nano-tube solution.
Further, the ultrasonic temperature in the water bath sonicator is normal temperature, and ultrasonic time is 4-6 hours
Further, the CNT in the step 1 and the surfactant sodium dodecyl base benzene sulfonic acid sodium salt Quality is respectively 30-150mg, and the volume of the deionized water is 30-150ml.
Further, the size of the flexible fabric in the step 2 is 0.01-100cm2, single drying temperature is 80 DEG C, single drying time is 0.5 hour.
Further, the drying temperature of the baking oven in the step 6 is 45 DEG C, and drying time is 12 hours.
Further, the gelatin polymer in the step 3 include polyvinyl alcohol and phosphoric acid, polyvinyl alcohol and sulfuric acid or The polymer of person's polyvinyl alcohol and lithium chloride.
The technical scheme provided by embodiments of the invention described above can be seen that provided in an embodiment of the present invention based on fabric Self-charging energy device, using general flexible fabric electrode, it is easy to be attached at all kinds of clothing surfaces, can be applied to simultaneously In energy acquisition and energy storage device, preparation process is simple, integrated level are high.
The additional aspect of the present invention and advantage will be set forth in part in the description, and these will become from the following description Obtain substantially, or recognized by practice of the invention.
Brief description of the drawings
Technical scheme in order to illustrate more clearly the embodiments of the present invention, below will be to that will use needed for embodiment description Accompanying drawing be briefly described, it should be apparent that, drawings in the following description are only some embodiments of the present invention, for this For the those of ordinary skill of field, without having to pay creative labor, other can also be obtained according to these accompanying drawings Accompanying drawing.
Fig. 1 is a kind of structural representation of self-charging energy device based on fabric provided in an embodiment of the present invention.
Fig. 2 is flexible fabric electrode stereoscan photograph of the invention.
Fig. 3 is the output voltage waveforms of single face friction generator of the invention.
Fig. 4 is the charge waveforms of self-charging energy device of the invention.
Specific embodiment
Embodiments of the present invention are described below in detail, the example of the implementation method is shown in the drawings, wherein ad initio Same or similar element or element with same or like function are represented to same or similar label eventually.Below by ginseng The implementation method for examining Description of Drawings is exemplary, is only used for explaining the present invention, and is not construed as limiting the claims.
Those skilled in the art of the present technique are appreciated that unless expressly stated, singulative " " used herein, " one It is individual ", " described " and " being somebody's turn to do " may also comprise plural form.It is to be further understood that what is used in specification of the invention arranges Diction " including " refer to the presence of the feature, integer, step, operation, element and/or component, but it is not excluded that in the presence of or addition One or more other features, integer, step, operation, element, component and/or their group.It should be understood that when we claim unit Part is " connected " or during " coupled " to another element, and it can be directly connected or coupled to other elements, or can also exist Intermediary element.Additionally, " connection " used herein or " coupling " can include wireless connection or coupling.Wording used herein "and/or" includes one or more associated any cells for listing item and all combines.
Those skilled in the art of the present technique are appreciated that unless otherwise defined, all terms used herein (including technology art Language and scientific terminology) have with art of the present invention in those of ordinary skill general understanding identical meaning.Should also Understand, those terms defined in such as general dictionary should be understood that the meaning having with the context of prior art The consistent meaning of justice, and unless defined as here, will not be with idealizing or excessively formal implication be explained.
For ease of the understanding to the embodiment of the present invention, done by taking several specific embodiments as an example further below in conjunction with accompanying drawing Explanation, and each embodiment does not constitute the restriction to the embodiment of the present invention.
Embodiment one
The embodiment of the present invention devises a kind of general wearable electrode, while being applied to energy acquisition and energy stores Device, by collecting the energy of the various forms of motion of human body, its efficient storage is got up, and is that all kinds of wearable devices are directly supplied Can, realize the target of the self-charging energy device based on fabric.
The invention provides a kind of self-charging energy device based on fabric, the device includes:Flexible electrode, solid state electrolysis Matter and flexible partition.The flexible electrode be flexible fabric adhere to multi-walled carbon nano-tubes (carbon nanotube, CNT) or its He has the electrode of flexible speciality;The solid electrolyte is gelatin polymer, including polyvinyl alcohol (polyvinyl Alcohol, PVA) and phosphoric acid (H3PO4), sulfuric acid (H2SO4) or lithium chloride (LiCl) etc. polymer;The flexible partition is soft Property semipermeable membrane material, such as serial barrier films of commercialization NKK TF44.
Present invention also offers a kind of manufacture method of the self-charging energy device based on fabric, comprise the following steps:
Step 1), by weighing CNT and surfactant sodium dodecyl base benzene sulfonic acid sodium salt (sodium dodecyl Benzene sulfonate, SDBS) during mixing adds deionized water (deionized water, DI);
The quality of CNT and SDBS can be respectively 30-150mg, and the volume of DI is 30-150ml.
Step 2), by the method for water bath sonicator, CNT is fully contacted with SDBS, be dissolved completely in DI, obtain carbon and receive Mitron solution (CNT ink);
Wherein, ultrasonic temperature is normal temperature, and ultrasonic time is 4-6 hours.
Step 3), by way of drying is added dropwise, CNT ink are dropped in into flexible fabric surface, and carry out drying operation, it is many It is fully saturated to the CNT concentration of flexible fabric after secondary dropwise addition drying, as flexible fabric electrode;
The size of flexible fabric is 0.01-100cm2, single drying temperature is 80 DEG C, and single drying time is 0.5 Hour.
Step 4), by the method for magnetic agitation, by PVA, H3PO4Add in DI, the lower high-speed stirred of magnetic force auxiliary is extremely molten Liquid is as clear as crystal, obtains gelatin polymer, used as solid electrolyte;
Step 5), flexible partition is immersed into PVA/H3PO4In solid electrolyte, place five minutes, be fully contacted both, One layer of solid electrolyte of flexible partition both sides uniform fold;
Step 6), by way of stress is pressed, flexible partition is sandwiched in the middle of two panels flexible fabric electrode, apply certain Stress, be fully contacted three, obtain the ultracapacitor of sandwich structure;
Step 7), by way of constant temperature drying, ultracapacitor is placed in baking oven, remove device in remain moisture Son, is attached at normal laundry surface, obtains wearable flexible super capacitor;
Wherein, drying temperature is 45 DEG C, and drying time is 12 hours.
Step 8), by obtained flexible fabric electrode seam be woven in normal laundry surface, obtain single face friction generator;
Step 9), obtained single face friction generator and wearable flexible solid-state supercapacitor are passed through into rectifier bridge It is integrated and connected, obtains the self-charging energy based on fabric and take.
Made as described above step, its process sequence not immobilizes, according to actual needs can adjust process sequence or Delete processing step.
Embodiment two
Reference picture 1, Fig. 1 is the structural representation of self-charging energy device of the present invention based on fabric, and its structure includes:It is soft Property textile electrode 1, flexible fabric electrode 2, PVA/H3PO4Solid electrolyte 3, flexible partition 4, PVA/H3PO4Solid electrolyte 5, Flexible fabric electrode 6.Reference picture 2, Fig. 2 is the stereoscan photograph of flexible fabric electrode of the invention.Reference picture 3, Fig. 3 is this The output voltage waveforms of the single face friction generator of invention.Reference picture 4, Fig. 4 is filling for self-charging energy device of the invention Electrical waveform.Then the preparation process of Fig. 1 shown devices is as follows:
Step 1:CNT and SDBS powder are obtained by weighing mode, by the two well mixed addition DI;
Step 2:By the method for water bath sonicator, ultrasound 4 hours, make CNT abundant with SDBS under the solution normal temperature that will be obtained Contact, and be dissolved completely in DI, obtain finely dispersed CNT ink;
Step 3:Using the technique that drying is added dropwise, by CNT ink drop coatings on flexible fabric surface, dried after permeating completely, Repeat fully saturated to the CNT concentration of flexible fabric after dropwise addition is dried repeatedly, as flexible electrode 1,2,6;
Step 4:By the method for magnetic agitation, as clear as crystal PVA/H is obtained3PO4Solid electrolyte, by flexible partition 4 Immersion, placement makes it be fully contacted with electrolyte in five minutes, both sides uniform folds solid electrolyte 3,5;
Step 5:By way of pressing laminating, the flexible partition 4 of both sides covering solid electrolyte 3,5 is sandwiched in two panels soft Property textile electrode 2, in the middle of 6, be fully contacted, obtain the flexible super capacitor of sandwich structure, be placed in constant temperature oven, remove The hydrone remained in device, obtains the flexible super capacitor of sandwich structure;
Step 6:Flexible fabric electrode 1 and flexible super capacitor are attached at clothing surface, are connected by rectifier bridge, obtained To the self-charging energy device based on fabric.
Fig. 4 is the charge waveforms of self-charging energy device of the invention, reference picture 4, the self-charging energy of the embodiment of the present invention Flexible super capacitor can be charged to 100mV by amount equipment during human body is commonly run in 6 minutes.
In sum, the self-charging energy device based on fabric provided in an embodiment of the present invention has the following advantages:
1st, the self-charging energy device based on fabric proposed by the present invention, using general flexible fabric electrode, it is easy to paste All kinds of clothing surfaces are invested, can be applied to simultaneously in energy acquisition and energy storage device, preparation process is simple, integrated level It is high.
2nd, the self-charging energy device based on fabric proposed by the present invention is compared with other energy units, not by external environment Influence, directly gather the various forms of motion energy of human body, realizing external mechanical can arrive the highly effective gathering of electric energy and store.
3rd, manufacture method proposed by the present invention is processed using laboratory basic technology and prepared, and is not related to high cost to process work Skill, the characteristics of with low cost, preparation for processing is simple, with can large-scale batch production possibility.
One of ordinary skill in the art will appreciate that:Accompanying drawing is the schematic diagram of one embodiment, module in accompanying drawing or Flow is not necessarily implemented necessary to the present invention.
Each embodiment in this specification is described by the way of progressive, identical similar portion between each embodiment Divide mutually referring to what each embodiment was stressed is the difference with other embodiment.Especially for device or For system embodiment, because it is substantially similar to embodiment of the method, so describing fairly simple, related part is referring to method The part explanation of embodiment.Apparatus and system embodiment described above is only schematical, wherein the conduct Separating component explanation unit can be or may not be it is physically separate, the part shown as unit can be or Person may not be physical location, you can with positioned at a place, or can also be distributed on multiple NEs.Can be with root Some or all of module therein is factually selected the need for border to realize the purpose of this embodiment scheme.Ordinary skill Personnel are without creative efforts, you can to understand and implement.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any one skilled in the art the invention discloses technical scope in, the change or replacement that can be readily occurred in, Should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with scope of the claims It is defined.

Claims (10)

1. a kind of self-charging energy device based on fabric, it is characterised in that including:Flexible electrode, solid electrolyte and flexibility Barrier film, the solid electrolyte is covered in the both sides of the flexible partition, by the flexible partition folder of both sides covering solid electrolyte In the middle of two panels flexible fabric electrode, the solid electrolyte and the flexible fabric electrode contact obtain flexible super electric capacity Device.
2. the self-charging energy device based on fabric according to claim 1, it is characterised in that by flexible fabric electrode with The flexible super capacitor is attached at clothing surface, and the flexible fabric electrode passes through with the flexible super capacitor Rectifier bridge is connected.
3. the self-charging energy device based on fabric according to claim 1, it is characterised in that the flexible electrode is soft Property fabric attachment multi-walled carbon nano-tubes, the solid electrolyte be gelatin polymer, the flexible partition be flexible semi-transparent membrane material Material.
4. a kind of preparation method of the self-charging energy device based on fabric, it is characterised in that including:
Step 1, CNT is mixed with surfactant sodium dodecyl base benzene sulfonic acid sodium salt by weighing, and be added to deionized water In, the CNT dissolves in deionized water with the surfactant sodium dodecyl base benzene sulfonic acid sodium salt, obtains CNT Solution;
Step 2, by way of drying is added dropwise the carbon nano-tube solution is dropped in into flexible fabric surface, and carry out drying behaviour Make, repeatedly to the carbon nano-tube solution concentration saturation on flexible fabric surface after dropwise addition drying operation, as flexible fabric electrode;
Step 3, gelatin polymer is added in deionized water by the method for magnetic agitation, it is transparent to solution, obtain gel Polymer solution, using the gel polymer solution as solid electrolyte;
Step 4, flexible partition is immersed in the solid electrolyte, set standing time, flexible partition both sides is covered one layer Solid electrolyte;
Step 5, stress press by way of, flexible partition is sandwiched in the middle of two panels flexible fabric electrode, obtain super capacitor Device;
Step 6, the ultracapacitor is placed in baking oven, after removing the hydrone remained in ultracapacitor, by super electricity Container is attached at clothing surface, obtains wearable flexible super capacitor;
Flexible fabric electrode seam is woven in clothing surface, single face friction generator is obtained;
The single face friction generator is integrated and connected with the wearable flexible solid-state supercapacitor by rectifier bridge, Obtain the self-charging energy device based on fabric.
5. the preparation method of the self-charging energy device based on fabric according to claim 4, it is characterised in that described Step 1 also includes:
By the method for water bath sonicator, the CNT is set to be contacted with the surfactant sodium dodecyl base benzene sulfonic acid sodium salt, it is molten Solution in deionized water, obtains carbon nano-tube solution.
6. the preparation method of the self-charging energy device based on fabric according to claim 5, it is characterised in that the water Ultrasonic temperature in bath ultrasound is normal temperature, and ultrasonic time is 4-6 hours.
7. the preparation method of the self-charging energy device based on fabric according to claim 1, it is characterised in that the step The CNT and the quality of the surfactant sodium dodecyl base benzene sulfonic acid sodium salt in rapid 1 are respectively 30-150mg, described to go The volume of ionized water is 30-150ml.
8. the preparation method of the self-charging energy device based on fabric according to claim 1, it is characterised in that the step The size of the flexible fabric in rapid 2 is 0.01-100cm2, single drying temperature is 80 DEG C, and single drying time is 0.5 small When.
9. the preparation method of the self-charging energy device based on fabric according to claim 1, it is characterised in that the step The drying temperature of the baking oven in rapid 6 is 45 DEG C, and drying time is 12 hours.
10. the preparation method of the self-charging energy device based on fabric according to claim 1, it is characterised in that described Gelatin polymer in step 3 includes gathering for polyvinyl alcohol and phosphoric acid, polyvinyl alcohol and sulfuric acid or polyvinyl alcohol and lithium chloride Compound.
CN201710035582.0A 2017-01-18 2017-01-18 Self-charging energy device based on fabric and preparation method thereof Pending CN106876147A (en)

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CN108162523A (en) * 2017-12-19 2018-06-15 李帛樟 A kind of waterproof and breathable nanometer generating cloth and preparation method thereof
CN108539837A (en) * 2018-04-04 2018-09-14 中国地质大学(武汉) Wearable graphite ene-type electret self power generation and the integrated weaved cloth of super capacitor
CN108666146A (en) * 2018-05-04 2018-10-16 东华大学 A kind of compound space fabric of deposition nano-carbon material and its preparation and application
CN109326458A (en) * 2018-09-30 2019-02-12 成都信息工程大学 A kind of preparation method of flexible miniature supercapacitor
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CN107622875B (en) * 2017-09-04 2019-03-22 吉林大学 A kind of preparation method of the wearable device of the self-powered of electromagnetic shielding
CN108162523A (en) * 2017-12-19 2018-06-15 李帛樟 A kind of waterproof and breathable nanometer generating cloth and preparation method thereof
CN108162523B (en) * 2017-12-19 2020-02-14 李帛樟 Waterproof breathable nano power generation cloth and preparation method thereof
CN108539837A (en) * 2018-04-04 2018-09-14 中国地质大学(武汉) Wearable graphite ene-type electret self power generation and the integrated weaved cloth of super capacitor
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CN109326458A (en) * 2018-09-30 2019-02-12 成都信息工程大学 A kind of preparation method of flexible miniature supercapacitor
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CN111525831A (en) * 2020-04-29 2020-08-11 西北工业大学 Self-energy-storage nano generator device capable of being woven and manufacturing method
CN111525831B (en) * 2020-04-29 2023-09-22 西北工业大学 Self-energy-storage weaved nano generator device and preparation method thereof

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