CN106118025A - A kind of preparation method of TPU/ carbon nanotube conducting master batch - Google Patents
A kind of preparation method of TPU/ carbon nanotube conducting master batch Download PDFInfo
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
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- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses the preparation method of a kind of TPU/ carbon nanotube conducting master batch, described method is: CNT is carried out high-speed stirred, dispersant is dissolved in liquid in the carbon nanotube dust being sprayed in stirring by the way of spraying simultaneously, carbon nano tube surface is activated, the Activated Carbon Nanotubes obtained adds to TPU material matrix as conductive filler, thus prepares the TPU/ carbon nanotube conducting master batch that electric conductivity is good.TPU/ carbon nanotube conducting master batch prepared by the present invention can be used for preparing antistatic article, and antistatic property is excellent.
Description
One, technical field
The present invention relates to the preparation method of a kind of TPU/ carbon nanotube conducting master batch.
Two, background technology
Thermoplastic polyurethane (TPU) not only has the rubber properties such as the high intensity of cross-linked polyurethane, high abrasion, and has
The thermoplastic property of standby linear polymeric material, so that its application is expanded to plastic applications.Especially recent decades, TPU
Have become as one of macromolecular material with fastest developing speed.TPU film is a kind of important application form of TPU material, in recent years with
High-tech development and progress to have also been obtained and be increasingly widely applied.
Owing to TPU has high intensity, good, weather-proof feature wear-resisting, elastic so that TPU film be widely used in auto industry,
The fields such as the laminating of footwear material, clothing, ready-made clothes, chemical industry, electronics, medical treatment.Wherein, TPU antistatic film is one of them.
TPU antistatic film mainly includes applying antistatic additive to prepare TPU antistatic film, use conductivity type filler to produce
TPU antistatic plastic film, employing coating material production TPU antistatic film etc..
Wherein, conductivity type filler is used to be possible not only to produce TPU antistatic plastic thin film, and due to its antistatic behaviour base
In the electric conductivity of filler, persistency is good compared with surfactant type TPU antistatic film, and antistatic behaviour is by the shadow of ambient humidity
Ring little.
In numerous conductivity type fillers, CNT has good electric conductivity, has again bigger draw ratio simultaneously, because of
And it is well suited for making conductive filler, relative to other metallic particles and graphite granule, its little consumption just can form conductive net,
And its density is more much smaller than metallic particles, it is difficult to the coagulation because of the effect of gravity.These characteristics utilizing CNT are made
Join in plastics for conducting medium, the electric conductivity of plastics can be produced strong impact.At present, CNT is at TPU antistatic
Applied research in material mainly by changing structure and the content of CNT, improves CNT dispersion in TPU
Property, and CNT is carried out surface process and equalize electric conductivity and other properties of TPU anti-static material.
Three, summary of the invention
The invention provides the preparation method of a kind of TPU/ carbon nanotube conducting master batch, the preprocessed modification of CNT
After, add to TPU material matrix as conductive filler, thus prepare the TPU/ carbon nanotube conducting that electric conductivity is good
Master batch.
The technical solution used in the present invention is:
The preparation method of a kind of TPU/ carbon nanotube conducting master batch, said method comprising the steps of:
(1) dispersant A is dissolved in solvent, obtains dispersant solution, then by dispersant solution by high-pressure spraying method
Spray in the CNT of high-speed stirred, after high-speed stirred mixing, prepare Activated Carbon Nanotubes;
Described CNT, dispersant A, the mass fraction ratio of solvent are 85~95:0.1~5:5~10;
(2) Activated Carbon Nanotubes and TPU polymeric matrix material stirring and evenly mixing, then mix with auxiliary agent, squeezes through twin screw
Go out machine to melt extrude pelletize and prepare TPU/ carbon nanotube conducting master batch;
Described TPU polymeric matrix material, Activated Carbon Nanotubes, the mass fraction of auxiliary agent be 70~95 mass parts, 0.01
~30 mass parts, 0.1~20 mass parts;
Described auxiliary agent is one or more the mixing in dispersant B, coupling agent, antioxidant, lubricant;Preferably institute
State auxiliary agent be one or more mixing with dispersant B, more preferably auxiliary agent in coupling agent, antioxidant, lubricant be idol
One or both in connection agent, antioxidant are with dispersant B, the mixing of lubricant.
Further, in preferred steps (2), the formula of raw material is: TPU polymeric matrix material, Activated Carbon Nanotubes, dispersion
The mass fraction of agent B is 70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass parts.
Further, in preferred steps (2), the formula of raw material is: TPU polymeric matrix material, Activated Carbon Nanotubes, dispersion
Agent B, the mass fraction of coupling agent are 70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~5 mass
Part.
Further, in preferred steps (2), the formula of raw material is: TPU polymeric matrix material, Activated Carbon Nanotubes, dispersion
Agent B, the mass fraction of antioxidant are 70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~2 mass
Part.
Further, in preferred steps (2), the formula of raw material is: TPU polymeric matrix material, Activated Carbon Nanotubes, dispersion
Agent B, the mass fraction of lubricant are 70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~10 mass
Part.
Further, in preferred steps (2), the formula of raw material is: TPU polymeric matrix material, Activated Carbon Nanotubes, dispersion
Agent B, coupling agent, the mass fraction of antioxidant be 70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~
5 mass parts, 0.01~2 mass parts.
Further, in preferred steps (2), the formula of raw material is: TPU polymeric matrix material, Activated Carbon Nanotubes, dispersion
Agent B, coupling agent, the mass fraction of lubricant be 70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~
5 mass parts, 0.01~10 mass parts, wherein dispersant B, coupling agent, total mass fraction of lubricant are 0.2~20 mass
Part.
Further, in preferred steps (2), the formula of raw material is: TPU polymeric matrix material, Activated Carbon Nanotubes, dispersion
Agent B, antioxidant, the mass fraction of lubricant be 70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~
2 mass parts, 0.01~10 mass parts, wherein dispersant B, antioxidant, total mass fraction of lubricant are 0.2~20 mass
Part.
Further, in preferred steps (2), the formula of raw material is: TPU polymeric matrix material, Activated Carbon Nanotubes, point
Powder B, coupling agent, antioxidant, the mass fraction of lubricant are 70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass
Part, 0.01~5 mass parts, 0.01~2 mass parts, 0.01~10 mass parts, wherein dispersant B, coupling agent, antioxidant, lubrication
Total mass fraction of agent is 0.2~20 mass parts.
Further, in preferred steps (2), the formula of raw material is: TPU polymeric matrix material, Activated Carbon Nanotubes, point
Powder B, coupling agent, antioxidant, the mass fraction of lubricant be 70~95 mass parts, 0.1~30 mass parts, 1~10 mass parts,
0.01~3 mass parts, 0.01~2 mass parts, 0.01~3 mass parts.
Further, in preferred steps (2), the formula of raw material is: TPU polymeric matrix material, Activated Carbon Nanotubes, point
Powder B, coupling agent, antioxidant, the mass fraction of lubricant be 70~95 mass parts, 1~30 mass parts, 1~10 mass parts,
0.01~3 mass parts, 0.01~2 mass parts, 0.01~3 mass parts.
In described method, dispersant A and dispersant B are for distinguishing the dispersant used in different step, and A, B do not have
Chemical sense.
Described dispersant A and dispersant B each stand alone as dodecylbenzene sodium sulfonate, polyvinylpyrrolidone, polyethylene
Alcohol, xanthan gum, sodium lauryl sulphate, Triton X-100, sodium carboxymethyl cellulose, Dihexadecylphosphate, Ah
Draw primary glue, cetyl trimethylammonium bromide, alkyl phenol ethylene oxide condensation substance emulsifying agent, cetyl trimethyl sodium bromide,
One or more mixture in Kynoar.
In described step (1), described solvent is water, DMF, N-Methyl pyrrolidone, n-butyl alcohol, chlorine
One or more mixture in imitative, dehydrated alcohol, acetone, petroleum ether, ethyl acetate, butyl acetate;
In described step (1), described CNT is one or both in multi-walled carbon nano-tubes, SWCN
Mixture, preferably multi-walled carbon nano-tubes.
In described step (2), described TPU polymeric matrix material is particle or pulverulent material, and TPU polymer is preferably used
Pulverulent material, mean diameter be 0.5 μm to the melt index of 5mm, preferably TPU polymeric matrix material be 2-100g/10min,
Preferably 10-30g/10min, the beneficially CNT dispersion in TPU matrix.
In described step (2), described coupling agent be in titante coupling agent, silane coupling agent one or both with
On mixture;Described titante coupling agent can be isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, isopropyl
Three (dioctyl phosphoric acid acyloxy) titanate esters, isopropyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanate esters, single alcoxyl
One or more mixed in base unsaturated fatty acid titanate esters or Di(dioctylpyrophosphato) ethylene titanate
Compound;Described silane coupler can use KH550, one or both in KH560, KH570, KH792, DL602, DL171
Above mixture;
Described antioxidant is preferably 1098,168,1010,1076, DLTP, one or more in MB, 164,264
Mixture.
Described lubricant is fatty acid, aliphatic amide type and ester lubricant, paraffin class lubricant, metallic soap salt profit
One or more mixing in lubrication prescription, low-molecular-weight wax, further, described lubricant is preferably PE wax, montanin wax, silicone
One or more mixture in powder, stearic acid, oleic acid, calcium stearate, ethylene bis stearic acid amide, erucyl amide.
In described step (2), the processing technique of described double screw extruder is screw speed 100~1000r/min, extrusion
Temperature is 180-250 DEG C.
Described double screw extruder melt extrudes pelletize, and pelletize mode has multiple, optional water cooling bracing pelletizing, air-cooled tie rod
Pelletizing, die face are earnestly, cut under water.The method being well known to those skilled in the art.
High-pressure spraying method used when preparing Activated Carbon Nanotubes is that dispersant solution is passed through high-pressure spray device with spray
The form of mist sprays into the CNT of high-speed stirred, and described high-pressure spray device can use high-pressure spraying machine, pass through high-pressure hydraulic pump
Spray form is become to spray in material through high-pressure nozzle dispersant solution.Described high-pressure spraying machine still belongs to for CNT pretreatment
First.Dispersant solution is atomized by high-pressure spraying method, obtains a large amount of fine droplet after atomization, significantly increases solution and carbon nanometer
The contact area of pipe, beneficially carbon nanotube particulate are coated with by auxiliary agent, strengthen its dispersibility.
In described high-pressure spraying method, spray rate is generally 10~100ml/min;
Atomized particle size is 0.1~1um.
When preparing Activated Carbon Nanotubes, the rotating speed of described high-speed stirred is 300~1500 turns/min.
The time of described high-speed stirred mixing is generally 0~1 hour, preferably 5~40 minutes.
The present invention carries out high-speed stirred to CNT, to its surface pretreatment, simultaneously by dispersant, surface activity
The auxiliary agents such as agent are dissolved in liquid in the carbon nanotube dust being sprayed in stirring by the way of spraying so that CNT table
Face activation, simultaneously by the material uniform wet such as dispersant, surfactant, causes to be formed between CNT and repels, and can be same
The bulk density of Shi Tigao CNT, to obtain optimal dispersion effect and good processability.
The present invention, by preprocessed for CNT modified, adds to TPU material matrix as conductive filler, thus
Prepare TPU/ carbon nanotube conducting master batch.Compared with traditional antistatic modified material of TPU, reaching same electric conductivity bar
Under part, the Activated Carbon Nanotubes implant consumption that the present invention uses can reduce by more than 5 times, therefore can make TPU inherently
Characteristic hardly suffers from impact, and the mechanical property and processing characteristics impact on composite is relatively low, also assures that anti-simultaneously
The persistency of antistatic property.Therefore, the TPU conductive agglomerate that the present invention provides can expand the range of TPU antistatic article,
Improve the service life of goods.
Four, detailed description of the invention
With specific embodiment, technical scheme is described further below, but the protection content of the present invention is not
It is limited to this.
Embodiment 1~16
According to the form below 1 takes each raw material, is dissolved in solvent by dispersant, obtains dispersant solution, is then led to by dispersant solution
Cross high pressure spray process and spray into the CNT (diameter 1~30nm, length 1~100 μm, bulk density 0.02g/mL) of high-speed stirred
In, technological parameter is as shown in table 1, after high-speed stirred mixing, prepares Activated Carbon Nanotubes;
Table 1
The performance test results such as table 2 below of the Activated Carbon Nanotubes prepared
Table 2
Dispersibility experiment detection by the following method: the Activated Carbon Nanotubes 10mg that embodiment 1~16 prepares is separately added into
10mL prepares in the solvent (seeing table 1) used by this Activated Carbon Nanotubes, and ultrasonic disperse 30 minutes obtains suspension, stands, goes out
When being the most substantially layered, the record time is the holding time, and acquired results refers to table 2.Holding time is the longest, shows that its dispersibility is more
Good.The most pretreated CNT cannot form stable suspension.
Above-mentioned test result indicate that, after pretreatment, the bulk density of CNT improve about 10 times (untreated
The bulk density of CNT is about 0.02g/mL), dispersibility is all significantly increased.
Embodiment 17~32
Activated Carbon Nanotubes and TPU polymer pulverulent material prepared by embodiment 1~16 (mean diameter 100 μm~
2mm) stirring and evenly mixing, consumption is shown in Table 3, and then the auxiliary agent with table 4 mixes, and melt extrudes through double screw extruder, stretches, cools down and cut
Grain prepares TPU/ carbon nanotube conducting master batch;The processing technique of double screw extruder is screw speed 200r/min, extrusion temperature
It it is 180 DEG C.
The content of carbon nanotubes of the TPU/ carbon nanotube conducting master batch prepared is as shown in table 5.
The content of carbon nanotubes of conductive agglomerate of embodiment 17,21,24 preparation more than 10%, the conduction of these high-loads
Master batch is conducive to production and sales.When subsequent production is applied can by the conductive agglomerate of high content of carbon nanotubes again with TPU matrix
Material and the mixing of other auxiliary agent, prepare antistatic article.
Concrete, the TPU/ carbon nanotube conducting master batch embodiment 17~32 prepared is according to the formula of table 5 and TPU base material
Mixing, and add the auxiliary agents such as flow ability modifying agent, thermal oxidation stabilizer, antifriction liniment, prepare antistatic film through blow moulding machine blowing, press
Sheet resistance according to " GB/T1410-2006 solid insulating material specific insulation and surface resistivity test method " testing film
Rate, result is as shown in table 5.
Table 3
Table 4
Table 5
In table 5, thermal oxidation stabilizer is 1098, and flow ability modifying agent is erucyl amide, and antifriction liniment is nano-calcium carbonate.
Embodiment data show, the surface resistivity of antistatic article prepared by conductive agglomerate prepared by the present invention is preferable,
In the case of content of carbon nanotubes 2~4wt.%, surface resistivity is 103~106About Ω, antistatic property is good.
Claims (10)
1. the preparation method of a TPU/ carbon nanotube conducting master batch, it is characterised in that said method comprising the steps of:
(1) dispersant A is dissolved in solvent, obtains dispersant solution, then dispersant solution is sprayed into by high-pressure spraying method
In the CNT of high-speed stirred, after high-speed stirred mixing, prepare Activated Carbon Nanotubes;
(2) Activated Carbon Nanotubes and TPU polymeric matrix material stirring and evenly mixing, then mix with auxiliary agent, through double screw extruder
Melt extrude pelletize and prepare TPU/ carbon nanotube conducting master batch
Described TPU polymeric matrix material, Activated Carbon Nanotubes, the mass fraction of auxiliary agent be 70~95 mass parts, 0.01~30
Mass parts, 0.1~20 mass parts;
Described auxiliary agent is one or more the mixing in dispersant B, coupling agent, antioxidant, lubricant.
2. the method for claim 1, it is characterised in that in described step (1), described CNT, dispersant A, solvent
Mass fraction ratio be 85~95:0.1~5:5~10.
3. the method for claim 1, it is characterised in that described dispersant A and dispersant B each stand alone as dodecyl
Benzene sulfonic acid sodium salt, polyvinylpyrrolidone, polyvinyl alcohol, xanthan gum, sodium lauryl sulphate, Triton X-100, carboxylic
Sodium carboxymethylcellulose pyce, Dihexadecylphosphate, arabic gum, cetyl trimethylammonium bromide, alkyl phenol ethylene oxide are condensed
One or more mixture in thing emulsifying agent, cetyl trimethyl sodium bromide, Kynoar.
4. the method for claim 1, it is characterised in that in described step (1), described solvent is water, N, N-dimethyl methyl
In amide, N-Methyl pyrrolidone, n-butyl alcohol, chloroform, dehydrated alcohol, acetone, petroleum ether, ethyl acetate, butyl acetate one
Kind or two or more mixture.
5. the method for claim 1, it is characterised in that in described step (2), the formula of described raw material is one of following:
Formula (one) TPU polymeric matrix material, Activated Carbon Nanotubes, the mass fraction of dispersant B be 70~95 mass parts,
0.01~30 mass parts, 0.1~10 mass parts;
Formula (two) TPU polymeric matrix material, Activated Carbon Nanotubes, dispersant B, the mass fraction of coupling agent are 70~95 matter
Amount part, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~5 mass parts;
Formula (three) TPU polymeric matrix material, Activated Carbon Nanotubes, dispersant B, the mass fraction of antioxidant are 70~95 matter
Amount part, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~2 mass parts;
Formula (four) TPU polymeric matrix material, Activated Carbon Nanotubes, dispersant B, the mass fraction of lubricant are 70~95 matter
Amount part, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~10 mass parts;
Formula (five) TPU polymeric matrix material, Activated Carbon Nanotubes, dispersant B, coupling agent, the mass fraction of antioxidant are
70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~5 mass parts, 0.01~2 mass parts;
Formula (six) TPU polymeric matrix material, Activated Carbon Nanotubes, dispersant B, coupling agent, the mass fraction of lubricant are
70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~5 mass parts, 0.01~10 mass parts, Qi Zhongfen
Powder B, coupling agent, total mass fraction of lubricant are 0.2~20 mass parts;
Formula (seven) TPU polymeric matrix material, Activated Carbon Nanotubes, dispersant B, antioxidant, the mass fraction of lubricant are
70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~2 mass parts, 0.01~10 mass parts, Qi Zhongfen
Powder B, antioxidant, total mass fraction of lubricant are 0.2~20 mass parts;
Formula (eight) TPU polymeric matrix material, Activated Carbon Nanotubes, dispersant B, coupling agent, antioxidant, the quality of lubricant
Number be 70~95 mass parts, 0.01~30 mass parts, 0.1~10 mass parts, 0.01~5 mass parts, 0.01~2 mass parts,
0.01~10 mass parts, wherein dispersant B, coupling agent, antioxidant, total mass fraction of lubricant are 0.2~20 mass parts.
6. the method for claim 1, it is characterised in that in described step (2), described coupling agent is titanate ester coupling
One or more mixture in agent, silane coupling agent.
7. the method for claim 1, it is characterised in that in described step (2), described antioxidant is 1098,168,
1010,1076, one or more the mixture in DLTP, MB, 164,264.
8. the method for claim 1, it is characterised in that in described step (2), described lubricant is fatty acid, fat
In race's amide-type and ester lubricant, paraffin class lubricant, metallic soap salt lubricant, low-molecular-weight wax one or more
Mixing.
9. method as claimed in claim 8, it is characterised in that described lubricant be PE wax, montanin wax, silicone powder, stearic acid,
One or more mixture in oleic acid, calcium stearate, ethylene bis stearic acid amide, erucyl amide.
10. the method for claim 1, it is characterised in that in described step (2), the formula of raw material is: TPU polymer base
Body material, Activated Carbon Nanotubes, dispersant B, coupling agent, antioxidant, the mass fraction of lubricant be 70~95 mass parts, 1~
30 mass parts, 1~10 mass parts, 0.01~3 mass parts, 0.01~2 mass parts, 0.01~3 mass parts.
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CN111040111A (en) * | 2019-08-23 | 2020-04-21 | 苏州纤创智造新材料科技有限公司 | Antistatic thermoplastic polyurethane and preparation method thereof |
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CN101724981A (en) * | 2009-11-05 | 2010-06-09 | 南京大学 | Method for preparing multi-wall carbon nano-tube loaded thermoplastic polyurethane film |
CN103173003A (en) * | 2013-02-27 | 2013-06-26 | 国家纳米科学中心 | Carbon nanotube-water-soluble polymer composite flexible electric-heating film as well as preparation method and use thereof |
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