CN105776194A - Preparation method of graphene nanoplatelet composite material for 3D printing - Google Patents
Preparation method of graphene nanoplatelet composite material for 3D printing Download PDFInfo
- Publication number
- CN105776194A CN105776194A CN201610111121.2A CN201610111121A CN105776194A CN 105776194 A CN105776194 A CN 105776194A CN 201610111121 A CN201610111121 A CN 201610111121A CN 105776194 A CN105776194 A CN 105776194A
- Authority
- CN
- China
- Prior art keywords
- graphene
- pulverizing chamber
- graphene microchip
- stripping
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/04—Specific amount of layers or specific thickness
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Carbon And Carbon Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention relates to the field of graphene materials, in particular to a preparation method of a graphene nanoplatelet composite material for 3D printing.The method comprises the steps that graphene powder is heated and dispersed and is repeatedly cut and impacted by a blade driven by a rotor of an impact type ultrafine grinder to be ground and stripped, classified screening is performed, qualified materials are subjected to static dispersion, and the graphene nanoplatelet composite material with the layer number of 100-300, uniform dispersity and good fluidity for 3D printing is obtained; continuous large-scale production of the graphene nanoplatelet composite material with the uniform layer number is achieved; in addition, the graphene nanoplatelet composite material is high in yield, low in cost and free of pollution, is applied to 3D printing, can significantly improve mechanical strength, electrical conductivity and heat-conducting property of the material and is beneficial to promoting large-scale application of graphene.
Description
Technical field
The present invention relates to grapheme material field, be specifically related to the preparation method of a kind of graphene microchip composite printed for 3D.
Background technology
Graphene is the another Novel Carbon Nanomaterials being found after CNT, it it is the two-dimentional carbon film of a kind of only one of which atomic thickness, be people find so far a kind of by the material of individual layer atomic building, carbon film is connected into hexagonal network by chemical bond between carbon atom, owing to the chemical bond between carbon atom is made up of sp2 hybridized orbit, therefore Graphene is the most indomitable, possessing the good characteristic that other new materials such as bent, electric conductivity is strong, mechanical strength good, light transmission is good do not possess, these characteristics make the preparation method of Graphene receive much concern all the time.
Graphite, because natively having the bedded structure that can peel off, therefore can carry out peeling off acquisition Graphene by graphite carries out the Strong shear of machinery.The most generally use the strong mechanical shearing of the method such as ball milling, mortar to prepare Graphene.As Chinese invention patent application number 201510073825.0 discloses a kind of tonne of class mechanical stripping device producing Graphene and production method thereof, it is by rotor as a mill, when rotor rotates, the outer surface of rotor and the internal grinding of material bin, so that graphite is stripped thinning acquisition Graphene.Owing to being difficult to separate the Graphene peeled off in time in the process of lapping of strength, easily cause reunion.Therefore, the Graphene obtained in mechanical grinding process, owing to reaching Nano grade, is the most easily reunited and overlapping, so that the Rotating fields hydraulic performance decline of Graphene.Thus affect the commercial application of grapheme material powder.
In order to realize quickly peeling off Graphene, grapheme material powder can also be prepared by oxidation-reduction method, but when preparing grapheme material powder by this kind of method, purpose is crystalline flake graphite deep oxidation, connect various oxy radical equably at graphite flake layer and support the interlamellar spacing of big graphite, then ultrasonic equipment easily peels away graphite flake layer, finally produces Graphene plus chemical substance reduction.But the Graphene that such method is worked it out, strong oxidizing process can cause a large amount of defects of graphene-structured, and these defects cause the significantly decline of Graphene performance.The Graphene additionally aoxidized can not be repaired even across reduction, the defect of the lamellar structure of graphite.
Even if using said method mechanical stripping and redox to obtain Graphene, owing to still there being strong Van der Waals force between graphene sheet layer, the when of being dried or during aft-loaded airfoil, it is easy to secondary between lamella overlapping, thus balances out effect of physics stripping process.Therefore, Graphene is difficult to after being difficult to volume production and reaching nano-scale disperse the defects such as storage to make the application of Graphene by the most hindered.
In consideration of it, graphene microchip is to solve the optimal selection of Graphene application.Graphene microchip is a kind grapheme material, and its lamella average thickness is within 15nm, and does not meets the definition of the Graphene less than 10 layers of strict demand.But remain the mechanical strength of excellence, conduction, heat conductivility.Present invention seek to address that mass production and the dispersive property of graphene microchip, to reach the application in 3D prints.
Summary of the invention
Being difficult to scattered defect, and the layer of the Graphene the most overlapping defect assembled for the application in 3D prints of current Graphene, the present invention proposes the preparation method of a kind of graphene microchip composite printed for 3D.Graphite heating is first disperseed by the method, the blade driven by the rotor of Type Impact Superfine Mill carries out shearing repeatedly, impact to graphite, graphite linings is made to peel off, after classified screening, qualified material after electrostatic dispersion, be uniformly dispersed, good fluidity for 3D print graphene microchip composite.
For solve the problems referred to above, the present invention by the following technical solutions:
A kind of preparation method of the graphene microchip composite printed for 3D, it is characterized in that: first graphite powder is added heat partition, the blade driven by the rotor of Type Impact Superfine Mill carries out shearing repeatedly, impact to graphite, make graphite pulverize to peel off, after classified screening, qualified material through electrostatic dispersion, obtain the number of plies 100 layers-300 layers be uniformly dispersed, the graphene microchip composite printed for 3D of good fluidity, concrete grammar is as follows:
(1) graphite powder and the dispersant that weight portion is 0.5-2.0 that weight portion is 90-100 are added heat partition in heated at high speed formula mixer, heated at high speed formula mixer rotating speed is 300-500rpm, heating-up temperature is 80-110 DEG C, and heating jitter time is 20-30min, obtains mixed material；
(2) mixed material step (1) obtained is sent into and is pulverized stripping in Type Impact Superfine Mill, and material enters the first pulverizing chamber under air-flow drives and pulverizes stripping for the first time；In the first pulverizing chamber, material is sheared, is impacted by revolution first order rotor banding cutting blade repeatedly at a high speed, crushing material is made to peel off, qualified thin material enters the second pulverizing chamber with air-flow, the defective rotated blanking device of thick material returns the first pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(3) qualified thin material enters the second pulverizing chamber fine crushing stripping further with air-flow；In the second pulverizing chamber, material is sheared, is impacted by revolution second level rotor banding cutting blade repeatedly at a high speed, the further fine crushing of material is made to peel off, sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan, the defective rotated blanking device of thick material returns the second pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(4), after sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan in step (3), by turbine bypass machine sizing screening, the number of plies uniform graphene microchip at 100-300 layer is obtained；
(5) the graphene microchip electrostatic dispersion that step (4) obtained processes, and is uniformly dispersed, the graphene microchip composite printed for 3D of good fluidity.
Described graphite powder is the one in expanded graphite, thermal cracking graphite, and particle diameter is between 1mm and 5mm.
Described dispersant is calgon, any one in sodium tripolyphosphate, lauryl sodium sulfate, polyacrylamide.
Described first order rotor speed is 3500-6000rpm.
The blade that described first order rotor drives is high hardness wear-resisting tooth profile metal cutter.
Described second level rotor speed is 5000-9000rpm.
The blade that described second level rotor drives is high hardness wear-resisting tooth profile metal cutter.
Described Type Impact Superfine Mill includes hopper, charger, casing, first order rotor, addendum cone, second level rotor, blocking material ring, fan, valve, deslagging spiral, the first pulverizing chamber, the second pulverizing chamber.First carry out adding dirt count in heated at high speed formula mixer by material, reduce Van der Waals force between graphite linings, making graphite linings be more easy to be stripped, then sent into by material in Type Impact Superfine Mill, material enters the first pulverizing chamber under air-flow drives and pulverizes stripping for the first time；In the first pulverizing chamber, material is sheared, is impacted by revolution first order rotor banding cutting blade repeatedly at a high speed, crushing material is made to peel off, qualified thin material enters the second pulverizing chamber with air-flow, the defective rotated blanking device of thick material returns the first pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；Qualified thin material enters the second pulverizing chamber fine crushing stripping further with air-flow；In the second pulverizing chamber, material is sheared, is impacted by the second level rotor banding cutting blade of higher rotating speed revolution further repeatedly, make materials fineization pulverize to peel off, obtain sheet high-specific surface area material, and the defective rotated blanking device of thick material returns the second pulverizing chamber and again pulverizes stripping, material is difficult to the particle pulverized and the impurity that is mixed into falls into deslagging spiral and is automatically drained out outside machine；Sheet high-specific surface area material sends into the further sizing screening of turbine bypass machine with air-flow and fan, then processes by electrostatic dispersion, obtain the number of plies be 100-300 layer be uniformly dispersed, the graphene microchip composite for 3D printing of good fluidity.
Although Graphene has the mechanical strength of excellence, conduction, heat conductivility, but reunite owing to Graphene can produce self, not only break up its scattered uniformity, compactness, and reduce mobility, it is applied to reunite when 3D prints, the internal stress that produces is concentrated, and not only may block printing head, mechanical strength, conduction, heat conductivility also can be caused to decline.In order to promote the extensive application of grapheme material, the present invention proposes the preparation method of a kind of graphene microchip composite printed for 3D, the method can the acquisition number of plies of volume production at being uniformly dispersed of 100-300 layer, the graphene microchip composite printed for 3D of good fluidity, production process is pollution-free, low energy consumption, concise in technology, and production cost is low；The graphene microchip not only number of plies of preparation uniformly, dispersiveness and good fluidity, and have the mechanical strength of excellence, conduction, heat conductivility concurrently, and good lubrication, high temperature resistant and anticorrosion properties, the graphene composite material of the present invention is used for 3D printing consumables, the mechanical strength of 3D printing consumables, conduction, heat conductivility will be significantly improved.
The preparation method of a kind of graphene microchip composite printed for 3D of the present invention, compared with prior art, its prominent feature and excellent effect are:
1, utilizing Type Impact Superfine Mill to shear, impact, successively twice classification grinding peels off graphite linings, it is ensured that the uniform quality of the graphene microchip composite printed for 3D obtained.
2, utilizing and add heat partition pretreating graphite, reduce Van der Waals force between graphite linings, make graphite linings more be easily peeled, the graphene microchip simultaneously prepared processes through electrostatic dispersion, makes the graphene composite material good fluidity of preparation, is uniformly dispersed, is difficult to reunite.
3, preparation method of the present invention is easily controllable, can realize the closed production of serialization, puts into little, low cost, non-environmental-pollution, yield height, has significant market using value.
Accompanying drawing explanation
For further illustrating the preparation method of a kind of graphene microchip composite printed for 3D, illustrated by accompanying drawing.
Accompanying drawing 1: for Type Impact Superfine Mill schematic diagram.1-hopper, 2-charger, 3-casing, 4-first order rotor, 5-addendum cone, 6-second level rotor, 7-blocking material ring, 8-fan, 9-valve, 10-deslagging spiral, 11-the first pulverizing chamber, 12-the second pulverizing chamber.
Detailed description of the invention
Below by way of detailed description of the invention, the present invention is described in further detail, but this should not being interpreted as, the scope of the present invention is only limitted to Examples below.In the case of without departing from said method thought of the present invention, the various replacements made according to ordinary skill knowledge and customary means or change, should be included in the scope of the present invention.
Embodiment 1
A kind of preparation method of the graphene microchip composite printed for 3D:
(1) graphite powder and the dispersant that weight portion is 0.5 that weight portion is 90 being added in heated at high speed formula mixer heat partition, heated at high speed formula mixer rotating speed is 300rpm, and heating-up temperature is 80 DEG C, and heating jitter time is 20min, obtains mixed material；
(2) mixed material step (1) obtained is sent into and is pulverized stripping in Type Impact Superfine Mill, and material enters the first pulverizing chamber under air-flow drives and pulverizes stripping for the first time；In the first pulverizing chamber, material is sheared, is impacted by revolution first order rotor banding cutting blade repeatedly at a high speed, crushing material is made to peel off, qualified thin material enters the second pulverizing chamber with air-flow, the defective rotated blanking device of thick material returns the first pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(3) qualified thin material enters the second pulverizing chamber fine crushing stripping further with air-flow；In the second pulverizing chamber, material is sheared, is impacted by revolution second level rotor banding cutting blade repeatedly at a high speed, the further fine crushing of material is made to peel off, sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan, the defective rotated blanking device of thick material returns the second pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(4), after sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan in step (3), by turbine bypass machine sizing screening, the number of plies uniform graphene microchip at 100-300 layer is obtained；
(5) the graphene microchip electrostatic dispersion that step (4) obtained processes, and is uniformly dispersed, the graphene microchip composite printed for 3D of good fluidity.
Embodiment 2
A kind of preparation method of the graphene microchip composite printed for 3D:
(1) graphite powder and the dispersant that weight portion is 2.0 that weight portion is 100 being added in heated at high speed formula mixer heat partition, heated at high speed formula mixer rotating speed is 500rpm, and heating-up temperature is 110 DEG C, and heating jitter time is 30min, obtains mixed material；
(2) mixed material step (1) obtained is sent into and is pulverized stripping in Type Impact Superfine Mill, and material enters the first pulverizing chamber under air-flow drives and pulverizes stripping for the first time；In the first pulverizing chamber, material is sheared, is impacted by revolution first order rotor banding cutting blade repeatedly at a high speed, crushing material is made to peel off, qualified thin material enters the second pulverizing chamber with air-flow, the defective rotated blanking device of thick material returns the first pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(3) qualified thin material enters the second pulverizing chamber fine crushing stripping further with air-flow；In the second pulverizing chamber, material is sheared, is impacted by revolution second level rotor banding cutting blade repeatedly at a high speed, the further fine crushing of material is made to peel off, sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan, the defective rotated blanking device of thick material returns the second pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(4), after sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan in step (3), by turbine bypass machine sizing screening, the number of plies uniform graphene microchip at 100-300 layer is obtained；
(5) the graphene microchip electrostatic dispersion that step (4) obtained processes, and is uniformly dispersed, the graphene microchip composite printed for 3D of good fluidity.
Embodiment 3
A kind of preparation method of the graphene microchip composite printed for 3D:
(1) graphite powder and the dispersant that weight portion is 0.8 that weight portion is 91 being added in heated at high speed formula mixer heat partition, heated at high speed formula mixer rotating speed is 400rpm, and heating-up temperature is 90 DEG C, and heating jitter time is 25min, obtains mixed material；
(2) mixed material step (1) obtained is sent into and is pulverized stripping in Type Impact Superfine Mill, and material enters the first pulverizing chamber under air-flow drives and pulverizes stripping for the first time；In the first pulverizing chamber, material is sheared, is impacted by revolution first order rotor banding cutting blade repeatedly at a high speed, crushing material is made to peel off, qualified thin material enters the second pulverizing chamber with air-flow, the defective rotated blanking device of thick material returns the first pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(3) qualified thin material enters the second pulverizing chamber fine crushing stripping further with air-flow；In the second pulverizing chamber, material is sheared, is impacted by revolution second level rotor banding cutting blade repeatedly at a high speed, the further fine crushing of material is made to peel off, sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan, the defective rotated blanking device of thick material returns the second pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(4), after sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan in step (3), by turbine bypass machine sizing screening, the number of plies uniform graphene microchip at 100-300 layer is obtained；
(5) the graphene microchip electrostatic dispersion that step (4) obtained processes, and is uniformly dispersed, the graphene microchip composite printed for 3D of good fluidity.
Embodiment 4
A kind of preparation method of the graphene microchip composite printed for 3D:
(1) graphite powder and the dispersant that weight portion is 1.4 that weight portion is 96 being added in heated at high speed formula mixer heat partition, heated at high speed formula mixer rotating speed is 450rpm, and heating-up temperature is 100 DEG C, and heating jitter time is 20min, obtains mixed material；
(2) mixed material step (1) obtained is sent into and is pulverized stripping in Type Impact Superfine Mill, and material enters the first pulverizing chamber under air-flow drives and pulverizes stripping for the first time；In the first pulverizing chamber, material is sheared, is impacted by revolution first order rotor banding cutting blade repeatedly at a high speed, crushing material is made to peel off, qualified thin material enters the second pulverizing chamber with air-flow, the defective rotated blanking device of thick material returns the first pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(3) qualified thin material enters the second pulverizing chamber fine crushing stripping further with air-flow；In the second pulverizing chamber, material is sheared, is impacted by revolution second level rotor banding cutting blade repeatedly at a high speed, the further fine crushing of material is made to peel off, sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan, the defective rotated blanking device of thick material returns the second pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(4), after sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan in step (3), by turbine bypass machine sizing screening, the number of plies uniform graphene microchip at 100-300 layer is obtained；
(5) the graphene microchip electrostatic dispersion that step (4) obtained processes, and is uniformly dispersed, the graphene microchip composite printed for 3D of good fluidity.
Embodiment 5
A kind of preparation method of the graphene microchip composite printed for 3D:
(1) graphite powder and the dispersant that weight portion is 1.8 that weight portion is 95 being added in heated at high speed formula mixer heat partition, heated at high speed formula mixer rotating speed is 360rpm, and heating-up temperature is 85 DEG C, and heating jitter time is 30min, obtains mixed material；
(2) mixed material step (1) obtained is sent into and is pulverized stripping in Type Impact Superfine Mill, and material enters the first pulverizing chamber under air-flow drives and pulverizes stripping for the first time；In the first pulverizing chamber, material is sheared, is impacted by revolution first order rotor banding cutting blade repeatedly at a high speed, crushing material is made to peel off, qualified thin material enters the second pulverizing chamber with air-flow, the defective rotated blanking device of thick material returns the first pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(3) qualified thin material enters the second pulverizing chamber fine crushing stripping further with air-flow；In the second pulverizing chamber, material is sheared, is impacted by revolution second level rotor banding cutting blade repeatedly at a high speed, the further fine crushing of material is made to peel off, sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan, the defective rotated blanking device of thick material returns the second pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(4), after sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan in step (3), by turbine bypass machine sizing screening, the number of plies uniform graphene microchip at 100-300 layer is obtained；
(5) the graphene microchip electrostatic dispersion that step (4) obtained processes, and is uniformly dispersed, the graphene microchip composite printed for 3D of good fluidity.
Claims (5)
1. the preparation method of the graphene microchip composite printed for 3D, it is characterized in that: first graphite powder is added heat partition, the blade driven by the rotor of Type Impact Superfine Mill carries out shearing repeatedly, impact to graphite, make graphite pulverize to peel off, after classified screening, qualified material through electrostatic dispersion, obtain the number of plies 100 layers-300 layers be uniformly dispersed, the graphene microchip composite printed for 3D of good fluidity, concrete grammar is as follows:
(1) graphite powder and the dispersant that weight portion is 0.5-2.0 that weight portion is 90-100 are added heat partition in heated at high speed formula mixer, heated at high speed formula mixer rotating speed is 300-500rpm, heating-up temperature is 80-110 DEG C, and heating jitter time is 20-30min, obtains mixed material；
(2) mixed material step (1) obtained is sent into and is pulverized stripping in Type Impact Superfine Mill, and material enters the first pulverizing chamber under air-flow drives and pulverizes stripping for the first time；In the first pulverizing chamber, material is sheared, is impacted by revolution first order rotor banding cutting blade repeatedly at a high speed, crushing material is made to peel off, qualified thin material enters the second pulverizing chamber with air-flow, the defective rotated blanking device of thick material returns the first pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(3) qualified thin material enters the second pulverizing chamber fine crushing stripping further with air-flow；In the second pulverizing chamber, material is sheared, is impacted by revolution second level rotor banding cutting blade repeatedly at a high speed, the further fine crushing of material is made to peel off, sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan, the defective rotated blanking device of thick material returns the second pulverizing chamber and again pulverizes stripping, and the particle being difficult to pulverize in material falls into deslagging spiral with the impurity being mixed into and is automatically drained out outside machine；
(4), after sheet high-specific surface area material sends into turbine bypass machine with air-flow and fan in step (3), by turbine bypass machine sizing screening, the number of plies uniform graphene microchip at 100-300 layer is obtained；
(5) the graphene microchip electrostatic dispersion that step (4) obtained processes, and is uniformly dispersed, the graphene microchip composite printed for 3D of good fluidity.
A kind of preparation method of the graphene microchip composite printed for 3D, it is characterised in that: graphite powder is the one in expanded graphite, thermal cracking graphite, and particle diameter is between 1mm and 5mm.
A kind of preparation method of graphene microchip composite printed for 3D, it is characterised in that: described dispersant is calgon, any one in sodium tripolyphosphate, lauryl sodium sulfate, polyacrylamide.
A kind of preparation method of the graphene microchip composite printed for 3D, it is characterised in that: described first order rotor speed is 3500-6000rpm, and the blade that first order rotor drives is high hardness wear-resisting tooth profile metal cutter；Described second level rotor speed is 5000-9000rpm, and the blade that second level rotor drives is high hardness wear-resisting tooth profile metal cutter.
A kind of preparation method of the graphene microchip composite printed for 3D, it is characterized in that: when graphene microchip composite prepared by described method is applied to 3D printing, the mechanical strength of material, conduction, heat conductivility can be significantly improved.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610111121.2A CN105776194B (en) | 2016-02-29 | 2016-02-29 | A kind of preparation method of graphene microchip composite for 3D printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610111121.2A CN105776194B (en) | 2016-02-29 | 2016-02-29 | A kind of preparation method of graphene microchip composite for 3D printing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105776194A true CN105776194A (en) | 2016-07-20 |
| CN105776194B CN105776194B (en) | 2017-09-05 |
Family
ID=56403843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610111121.2A Expired - Fee Related CN105776194B (en) | 2016-02-29 | 2016-02-29 | A kind of preparation method of graphene microchip composite for 3D printing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105776194B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106315575A (en) * | 2016-08-19 | 2017-01-11 | 北京旭碳新材料科技有限公司 | 3D printing material and 3D printing product based on oxidized graphene and preparation methods of 3D printing material and 3D printing product |
| CN106348286A (en) * | 2016-08-19 | 2017-01-25 | 北京旭碳新材料科技有限公司 | Graphene oxide compound with plasticity, electrode and preparation method of graphene oxide compound and electrode |
| CN109019576A (en) * | 2018-09-05 | 2018-12-18 | 七台河宝泰隆石墨烯新材料有限公司 | A kind of technique of physical method production graphene |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080048152A1 (en) * | 2006-08-25 | 2008-02-28 | Jang Bor Z | Process for producing nano-scaled platelets and nanocompsites |
| US20130087446A1 (en) * | 2011-10-11 | 2013-04-11 | Aruna Zhamu | One-step production of graphene materials |
| CN103977870A (en) * | 2014-05-26 | 2014-08-13 | 北京航空航天大学 | Process and device for preparing graphene precursor two-dimension nanoscale graphite powder by adopting airflow crushing and peeling method |
| CN104843680A (en) * | 2015-04-03 | 2015-08-19 | 北京理工大学 | Method for batch preparation of graphene from microcrystalline graphite |
-
2016
- 2016-02-29 CN CN201610111121.2A patent/CN105776194B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080048152A1 (en) * | 2006-08-25 | 2008-02-28 | Jang Bor Z | Process for producing nano-scaled platelets and nanocompsites |
| US20130087446A1 (en) * | 2011-10-11 | 2013-04-11 | Aruna Zhamu | One-step production of graphene materials |
| CN103977870A (en) * | 2014-05-26 | 2014-08-13 | 北京航空航天大学 | Process and device for preparing graphene precursor two-dimension nanoscale graphite powder by adopting airflow crushing and peeling method |
| CN104843680A (en) * | 2015-04-03 | 2015-08-19 | 北京理工大学 | Method for batch preparation of graphene from microcrystalline graphite |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106315575A (en) * | 2016-08-19 | 2017-01-11 | 北京旭碳新材料科技有限公司 | 3D printing material and 3D printing product based on oxidized graphene and preparation methods of 3D printing material and 3D printing product |
| CN106348286A (en) * | 2016-08-19 | 2017-01-25 | 北京旭碳新材料科技有限公司 | Graphene oxide compound with plasticity, electrode and preparation method of graphene oxide compound and electrode |
| CN106348286B (en) * | 2016-08-19 | 2018-10-23 | 北京旭碳新材料科技有限公司 | Have plastic graphene oxide compound and electrode and their preparation method |
| CN106315575B (en) * | 2016-08-19 | 2018-10-23 | 北京旭碳新材料科技有限公司 | 3D printing material and 3D printing product based on graphene oxide and their preparation method |
| CN109019576A (en) * | 2018-09-05 | 2018-12-18 | 七台河宝泰隆石墨烯新材料有限公司 | A kind of technique of physical method production graphene |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105776194B (en) | 2017-09-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104425823B (en) | A kind of artificial graphite cathode material for lithium ion batteries and preparation method thereof | |
| CN105024075A (en) | Negative electrode material for quickly rechargeable graphite lithium-ion battery and preparation method of negative electrode material | |
| CN105776194A (en) | Preparation method of graphene nanoplatelet composite material for 3D printing | |
| CN102569755B (en) | Graphite carbon negative electrode material for lithium ion battery, and preparation method thereof | |
| TW200830617A (en) | Negative electrode material for lithium ion secondary battery and method for producing the same | |
| CN110000388B (en) | Preparation method of novel graphene nanosheet reinforced metal-based composite material | |
| CN103811758B (en) | A kind of preparation method of synthetic graphite particle negative material | |
| CN108565437B (en) | Si-C composite material and its preparation method and application | |
| CN110400927A (en) | A kind of silicon-carbon composite anode material for lithium ion battery and preparation method thereof | |
| CN105776192B (en) | A kind of method for continuous preparation graphene microchip of being delaminated using grinding | |
| CN106006624B (en) | A kind of dry state air-flow stripping prepares the method and grapheme material of grapheme material | |
| CN103794765A (en) | Lithium ion battery graphite negative electrode material and preparation method thereof | |
| CN105417534B (en) | A kind of utilization screw mechanism for biomass grapheme material method | |
| WO2015118755A1 (en) | Negative electrode material for lithium ion secondary battery, negative electrode, and lithium ion secondary battery | |
| CN108735528A (en) | A kind of preparation process of the super capacitor electrode slice containing PTFE fiber | |
| CN105024043A (en) | Rapidly-charged graphite lithium ion battery anode material and preparation method thereof | |
| CN105858641B (en) | Graphene production method | |
| CN106276881A (en) | The preparation method of a kind of Graphene and Graphene | |
| CN106967438A (en) | A kind of preparation method of lightning protection resistance-reducing grounding module material | |
| CN106833083A (en) | Compound microplate of a kind of Graphene for electrically-conducting paint and preparation method thereof | |
| CN104269564B (en) | The preparation method of bipolar plates used for all-vanadium redox flow battery | |
| US11773027B1 (en) | Preparation method and product of metal-matrix composite reinforced by nanoscale carbon materials | |
| WO2019218506A1 (en) | Amorphous carbon material, and preparation method and use | |
| CN103801439B (en) | The process equipment of high speed disintegrator and ultra micro graphite powder | |
| JP6403540B2 (en) | Negative electrode material for lithium ion secondary battery and method for producing the same, negative electrode for lithium ion secondary battery, and lithium ion secondary battery |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wei Ying Inventor before: Chen Qing Inventor before: Ye Renhai |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180116 Address after: No. 28, building No. 28, No. 1, Xinhua Street, Xincheng, Hohhot City, the Inner Mongolia Autonomous Region, No. 14 Patentee after: Wei Ying Address before: Qingyang District of Chengdu City, Sichuan province 610091 Dragon Industrial Port East Road 4 Patentee before: Chengdu Xinkeli Chemical Sci-Tech Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170905 Termination date: 20190228 |