CN105680059A - Novel aluminum-based cathode plant electrolyte battery - Google Patents
Novel aluminum-based cathode plant electrolyte battery Download PDFInfo
- Publication number
- CN105680059A CN105680059A CN201610028027.0A CN201610028027A CN105680059A CN 105680059 A CN105680059 A CN 105680059A CN 201610028027 A CN201610028027 A CN 201610028027A CN 105680059 A CN105680059 A CN 105680059A
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- plant electrolyte
- flake graphite
- plant
- crystalline flake
- negative pole
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
- H01M4/9083—Catalytic material supported on carriers, e.g. powder carriers on carbon or graphite
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hybrid Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention discloses a novel aluminum-based cathode plant electrolyte battery, which comprises a plant electrolyte catalyst pack, an aluminum cathode shell, a cotton paper isolating layer and a flake graphite electrode plate, wherein the plant electrolyte catalyst pack is arranged in the aluminum cathode shell; the cotton paper isolating layer is arranged between the plant electrolyte catalyst pack and the aluminum cathode shell; the flake graphite electrode plate is inserted into the plant electrolyte catalyst pack; and the plant electrolyte catalyst pack is the substance which is formed by mixing a multiwalled carbon nanotube, natural manganese dioxide, acetylene black, nano-titanium dioxide and a plant alkaloid extract solution at the mass ratio of 17 to 43 to 23 to 1 to 16. The novel aluminum-based cathode plant electrolyte battery has the characteristic of automatically restoring power after a discharge cycle is ended. Especially, an A6061 aluminum alloy as an electrode and an environmental-friendly plant electrolyte are adopted by the battery; the materials, such as heavy metals lead and cadmium, and sulfuric acid, with secondary environmental pollution are avoided; and the novel aluminum-based cathode plant electrolyte battery is mainly applied to power supplies of civilian lighting markets, electronic digital devices and the like.
Description
Technical field
The present invention relates to battery technology field, specifically a kind of novel aluminium based negative pole plant electrolyte battery.
Background technology
Battery refers to fill electrolyte solution and metal electrode with the segment space of the cup of generation current, groove or other containers or clad vessel, and chemical energy can change into the device of electric energy. Have positive pole, negative pole point. Along with the progress of science and technology, battery general reference can produce the packaged unit of electric energy. Such as solar cell. The performance perameter of battery mainly contains electromotive force, capacity, specific energy and resistance. Utilize battery as energy derive, can obtain that there is stabilized voltage, steady current, long-time stable is powered, by the electric current that ectocine is very little, and battery structure is simple, easy to carry, discharge and recharge is easy to operation, not by the impact of outside climatic and temperature, stable and reliable for performance, all respects in modern society lives play great role. The potential pollution of the old and useless battery used has caused the extensive concern of various circles of society. China is No.1 drying battery production and consumption big country in the world, has data to show, China has 1400 Duo Jia battery manufacturing enterprises for 2012, and the turnout of drying battery in 1980 exceedes the U.S. and leaps to the first in the world. The turnout of Chinese drying battery in 1998 reaches 14,000,000,000, and the same year world's drying battery ultimate production be about 30,000,000,000. Old and useless battery contains the material of the secondary environmental pollution such as heavy metal lead, cadmium, sulfuric acid, is also the material that human body harm is bigger.
Summary of the invention
It is an object of the invention to provide and a kind of there is the novel aluminium based negative pole plant electrolyte battery that can automatically recover electric power, environmental protection after a discharge cycle completes, to solve in above-mentioned background technology the problem proposed.
For achieving the above object, the present invention provides following technical scheme:
A kind of novel aluminium based negative pole plant electrolyte battery, comprise plant electrolyte catalysis bag, aluminum honeycomb shell, cotton paper sealing coat and crystalline flake graphite battery lead plate, plant electrolyte catalysis bag is inserted in aluminum honeycomb shell, and cotton paper sealing coat is set between plant electrolyte catalysis bag and aluminum honeycomb shell, in crystalline flake graphite battery lead plate insertion plant electrolyte catalysis bag.
As the scheme that the present invention is further: plant electrolyte catalysis bag is that multi-walled carbon nano-tubes, natural manganese dioxide, acetylene black, nano titanium oxide, vegeto-alkali extracting solution carry out mixed material according to the mass ratio of 17:43:23:1:16, and wherein the composition in vegeto-alkali extracting solution comprises: tea, sisal hemp, arabiancoffee, cocoa powder, pseudo-ginseng, borneol, loose stasis of blood grass, Sheepear Inula Herb, Ningpo Yam Rhizome, Rhizoma dioscoreae, hardship galingal, Herba Erodii, tea-polyphenol, Folium Agaves variegatae.
As the scheme that the present invention is further: the diameter of multi-walled carbon nano-tubes is 8-13nm.
As the scheme that the present invention is further: nano titanium oxide is 8nm nano titanium oxide.
As the scheme that the present invention is further: aluminum honeycomb shell adopts A6061 aluminum alloy material.
As the scheme that the present invention is further: cotton paper sealing coat adopts cotton paper.
As the scheme that the present invention is further: crystalline flake graphite battery lead plate adopts crystalline flake graphite.
As the scheme that the present invention is further: the heat treatment process of crystalline flake graphite battery lead plate: 1) hardening step: be put on fire by crystalline flake graphite battery lead plate, refining temperature is 500 DEG C of heating 1 minute, drops in 10 DEG C of cold water, repeatedly processes 10 times; 2) dry encapsulation: after naturally air-dry for the crystalline flake graphite battery lead plate after quenched, puts into dry protection against the tide, dust-proof aluminum plastic bag for subsequent use; 3) cutting assembling: the specification that the crystalline flake graphite battery lead plate of quenching is cut into needs.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention provides a kind of novel aluminium based negative pole plant electrolyte battery, it is combine the characteristic that nano titanium oxide protects water catalysis by hydrogen storage material of the multi-walled carbon nano-tubes of 8-13nm, makes nano titanium oxide metal fuel battery can again suck in oxygen and multi-walled carbon nano-tubes the hydrogen evolution fuel cell stored after completing a discharge cycle from air and produce electric power. There is the characteristic that can automatically recover electric power after a discharge cycle completes. The present invention especially uses A6061 aluminium alloy for electrode and environment-friendlyplant plant electrolytic solution, avoids the material of the secondary environmental pollution such as heavy metal lead, cadmium, sulfuric acid, is mainly used in civilian illumination market, the power supplys such as electronic digital electronics.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention;
Fig. 2 is the discharge curve of the embodiment of the present invention;
Fig. 3 is the discharge curve of the embodiment of the present invention;
In figure: 1-aluminum honeycomb shell, 2-cotton paper sealing coat, 3-crystalline flake graphite battery lead plate, 4-plant electrolyte catalysis bag.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only the present invention's part embodiment, instead of whole embodiments. Based on the embodiment in the present invention, those of ordinary skill in the art, not making other embodiments all obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
Refer to Fig. 1, in the embodiment of the present invention, a kind of novel aluminium based negative pole plant electrolyte battery, comprise plant electrolyte catalysis bag 4, aluminum honeycomb shell 1, cotton paper sealing coat 2 and crystalline flake graphite battery lead plate 3, plant electrolyte catalysis bag 4 is inserted in aluminum honeycomb shell 1, and cotton paper sealing coat 2 is set between plant electrolyte catalysis bag 4 and aluminum honeycomb shell 1, crystalline flake graphite battery lead plate 3 inserts in plant electrolyte catalysis bag 4.
1. structure explanation
The present invention is achieved in that and uses crystalline flake graphite sheet as positive electrode material, A6061 aluminium alloy is negative pole, positive and negative electrode central filler be that 10nm multi-walled carbon nano-tubes, natural manganese dioxide, acetylene black, 8nm nano titanium oxide, vegeto-alkali extracting solution are according to the plant electrolyte catalysis bag 4 of: 17:43:23:1:16 ratio mixing. The crystalline flake graphite battery lead plate 3 of positive pole is positioned in the middle of aluminum honeycomb shell 1. Aluminum honeycomb shell 1 is double does container and negative pole. Adopt cotton paper as cotton paper sealing coat 2 between positive electrode material and aluminum honeycomb shell 1.Avoid positive and negative electrode to contact to be short-circuited.
2. battery electrolyte explanation
Replacing chemical bases to reach the object vegeto-alkali extracting solution of environmental protection with vegeto-alkali, it mainly acts on is the Cl produced in dilution process of charging2Gas. Composition in vegeto-alkali extracting solution comprises: tea, sisal hemp, arabiancoffee, cocoa powder, pseudo-ginseng, borneol, loose stasis of blood grass, Sheepear Inula Herb, Ningpo Yam Rhizome, Rhizoma dioscoreae, bitter galingal, Herba Erodii, tea-polyphenol, Folium Agaves variegatae. In Folium Agaves variegatae containing Folium Agaves variegatae soap glucoside (a-gavoside) A, B, C, C ', D, E, F, G, H, sea Ke's sapogenin (hecogenin), 9-removes hydrogen sea Ke's sapogenin (9-dehy-drophecogenin), for accusing sapogenin (tigogenin), Lip river Ke's sapogenin (rokoge-nin), 1,3,7-trimethylammonium-2,6-two oxypurine.
3. cell power generation know-why
Burning reduction reaction (galvanic cell) generating and fuel cell power generation two kinds of combined reactions. Crucial innovative point combines the characteristic that nano titanium oxide protects water catalysis, makes nano titanium oxide metal fuel battery can again suck in oxygen and multi-walled carbon nano-tubes the hydrogen evolution fuel cell stored after completing a discharge cycle from air and produce electric power. There is the characteristic that can automatically recover electric power after a discharge cycle completes.
The concrete implementation step of described novel aluminium based negative pole plant electrolyte battery and operating process as follows described in.
One. the proportioning operating process of plant electrolyte catalysis bag
1. anode catalytic packs work
10nm multi-walled carbon nano-tubes, natural manganese dioxide, acetylene black, 8nm nano titanium oxide/vegeto-alkali extracting solution are made pasty state catalysis bag after mixing according to the blending ratio of 17:43:23:1:16.
2. plant electrolyte catalysis bag is put into opaque glass tank sealed storage 48 hours, storing temp < 30 DEG C.
3. the plant electrolyte catalysis bag made is distributed into the commodity ionogen finished product of bottle as plant electrolyte battery.
Two. crystalline flake graphite battery lead plate thermal treatment flow process
1. hardening step
Being put on fire by crystalline flake graphite battery lead plate, refining temperature is 500 DEG C of heating 1 minute, drops in 10 DEG C of cold water, repeatedly processes 10 times, make quenched after crystalline flake graphite battery lead plate present porous and anti-blocking and fall to consider to be worth doing.
2. dry encapsulation
After naturally air-dry for the crystalline flake graphite battery lead plate after quenched, crystalline flake graphite battery lead plate is put into dry moistureproof, dustproof aluminum plastics bag and is produced for subsequent use.
3. cutting assembling
The crystalline flake graphite battery lead plate of quenching is cut into 65mm*58mm specification, and 1 corresponding battery cell of crystalline flake graphite battery lead plate is assembled.
Three. number of assembling steps
Plant electrolyte catalysis bag and the obtained aluminium base battery of plant electrolyte of A6061 aluminum honeycomb shell assembling (battery product carries out PACK assembling and places after having assembled, can preserve for sale for a long time when not discharging)
Four. the aluminium base battery structure of plant electrolyte
When battery is assembled, A6061 aluminum honeycomb shell can not contact with against short-circuit with plant electrolyte catalysis bag, and centre establishes the cotton paper sealing coat so that toughness is stronger to isolate, and serves as electrolyte membrance simultaneously.
Being tested by obtained novel aluminium based negative pole plant electrolyte battery, discharge curve is as Figure 2-3.
To those skilled in the art, it is clear that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit or the essential characteristic of the present invention, it is possible to realize the present invention in other specific forms.Therefore, no matter from which point, embodiment all should be regarded as exemplary, and right and wrong are restrictive, the scope of the present invention is limited by claims instead of above-mentioned explanation, it is intended that all changes in the implication of the equivalent important document dropping on claim and scope included in the present invention.
In addition, it is to be understood that, although this specification sheets is described according to enforcement mode, but not each enforcement mode only comprises an independent technical scheme, this kind of narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment through appropriately combined, can also form other enforcement modes that it will be appreciated by those skilled in the art that.
Claims (8)
1. a novel aluminium based negative pole plant electrolyte battery, it is characterized in that, comprise plant electrolyte catalysis bag, aluminum honeycomb shell, cotton paper sealing coat and crystalline flake graphite battery lead plate, plant electrolyte catalysis bag is inserted in aluminum honeycomb shell, and cotton paper sealing coat is set between plant electrolyte catalysis bag and aluminum honeycomb shell, in crystalline flake graphite battery lead plate insertion plant electrolyte catalysis bag.
2. novel aluminium based negative pole plant electrolyte battery according to claim 1, it is characterized in that, plant electrolyte catalysis bag is that multi-walled carbon nano-tubes, natural manganese dioxide, acetylene black, nano titanium oxide, vegeto-alkali extracting solution carry out mixed material according to the mass ratio of 17:43:23:1:16; Wherein the composition in vegeto-alkali extracting solution comprises: tea, sisal hemp, arabiancoffee, cocoa powder, pseudo-ginseng, borneol, loose stasis of blood grass, Sheepear Inula Herb, Ningpo Yam Rhizome, Rhizoma dioscoreae, bitter galingal, Herba Erodii, tea-polyphenol, Folium Agaves variegatae.
3. novel aluminium based negative pole plant electrolyte battery according to claim 2, it is characterised in that, the diameter of multi-walled carbon nano-tubes is 8-13nm.
4. novel aluminium based negative pole plant electrolyte battery according to claim 2, it is characterised in that, nano titanium oxide is 8nm nano titanium oxide.
5. novel aluminium based negative pole plant electrolyte battery according to claim 1, it is characterised in that, aluminum honeycomb shell adopts A6061 aluminum alloy material.
6. novel aluminium based negative pole plant electrolyte battery according to claim 1, it is characterised in that, cotton paper sealing coat adopts cotton paper.
7. novel aluminium based negative pole plant electrolyte battery according to claim 1, it is characterised in that, crystalline flake graphite battery lead plate adopts crystalline flake graphite.
8. novel aluminium based negative pole plant electrolyte battery according to claim 1, it is characterized in that, the heat treatment process of crystalline flake graphite battery lead plate: 1) hardening step: be put on fire by crystalline flake graphite battery lead plate, refining temperature is 500 DEG C of heating 1 minute, drop in 10 DEG C of cold water, repeatedly process 10 times; 2) dry encapsulation: after naturally air-dry for the crystalline flake graphite battery lead plate after quenched, puts into dry protection against the tide, dust-proof aluminum plastic bag for subsequent use; 3) cutting assembling: the specification that the crystalline flake graphite battery lead plate of quenching is cut into needs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610028027.0A CN105680059A (en) | 2016-01-15 | 2016-01-15 | Novel aluminum-based cathode plant electrolyte battery |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610028027.0A CN105680059A (en) | 2016-01-15 | 2016-01-15 | Novel aluminum-based cathode plant electrolyte battery |
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| CN105680059A true CN105680059A (en) | 2016-06-15 |
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| CN201610028027.0A Pending CN105680059A (en) | 2016-01-15 | 2016-01-15 | Novel aluminum-based cathode plant electrolyte battery |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107275652A (en) * | 2017-06-30 | 2017-10-20 | 佛山市能翼科技有限公司 | catalyst, preparation method and zinc-air battery |
| CN110034341A (en) * | 2019-04-26 | 2019-07-19 | 张健 | A kind of neutral electrolyte |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1280398A (en) * | 2000-03-14 | 2001-01-17 | 南京师范大学 | Method for preparing fuel cell anode catalysts |
| CN1387274A (en) * | 2002-07-09 | 2002-12-25 | 中国科学院长春应用化学研究所 | Process for praparing non-Pt composite electrocatalyst for cathode of fuel battery |
| US20050252081A1 (en) * | 2004-05-14 | 2005-11-17 | Ju-Yong Kim | Reformer for fuel cell system and method of manufacturing reaction substrate used for the same |
| CN102121073A (en) * | 2011-01-11 | 2011-07-13 | 中南大学 | Method for preparing rare-earth aluminum alloy electrode material |
| CN104285335A (en) * | 2012-05-09 | 2015-01-14 | 索尼公司 | Direct aluminum fuel cell and electronic device |
-
2016
- 2016-01-15 CN CN201610028027.0A patent/CN105680059A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1280398A (en) * | 2000-03-14 | 2001-01-17 | 南京师范大学 | Method for preparing fuel cell anode catalysts |
| CN1387274A (en) * | 2002-07-09 | 2002-12-25 | 中国科学院长春应用化学研究所 | Process for praparing non-Pt composite electrocatalyst for cathode of fuel battery |
| US20050252081A1 (en) * | 2004-05-14 | 2005-11-17 | Ju-Yong Kim | Reformer for fuel cell system and method of manufacturing reaction substrate used for the same |
| CN102121073A (en) * | 2011-01-11 | 2011-07-13 | 中南大学 | Method for preparing rare-earth aluminum alloy electrode material |
| CN104285335A (en) * | 2012-05-09 | 2015-01-14 | 索尼公司 | Direct aluminum fuel cell and electronic device |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107275652A (en) * | 2017-06-30 | 2017-10-20 | 佛山市能翼科技有限公司 | catalyst, preparation method and zinc-air battery |
| CN110034341A (en) * | 2019-04-26 | 2019-07-19 | 张健 | A kind of neutral electrolyte |
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Application publication date: 20160615 |
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