CN105591166B - A kind of TRT and its manufacture method based on carbon material - Google Patents

A kind of TRT and its manufacture method based on carbon material Download PDF

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Publication number
CN105591166B
CN105591166B CN201410576692.4A CN201410576692A CN105591166B CN 105591166 B CN105591166 B CN 105591166B CN 201410576692 A CN201410576692 A CN 201410576692A CN 105591166 B CN105591166 B CN 105591166B
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China
Prior art keywords
carbon material
volatile liquid
electrode
material layer
trt
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CN201410576692.4A
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CN105591166A (en
Inventor
周军
郭万林
丁天朋
薛国斌
李嘉
徐莹
殷俊
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Nanjing University of Aeronautics and Astronautics
Huazhong University of Science and Technology
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Nanjing University of Aeronautics and Astronautics
Huazhong University of Science and Technology
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Priority to CN201410576692.4A priority Critical patent/CN105591166B/en
Priority to PCT/CN2014/092295 priority patent/WO2016061870A1/en
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    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02NELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N3/00Generators in which thermal or kinetic energy is converted into electrical energy by ionisation of a fluid and removal of the charge therefrom
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02NELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N11/00Generators or motors not provided for elsewhere; Alleged perpetua mobilia obtained by electric or magnetic means
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The invention discloses a kind of TRT based on carbon material, it includes electrification component and volatile liquid, wherein electrification component includes the slide glass of electric insulation, is arranged on mutually disjoint first electrode and second electrode on the slide surface, and be globally deposited between two electrodes, and with the carbon material layer of two electrodes formation conductive path;The volatile liquid is immersed in one end of carbon material layer all the time, the other end is then exposed in the environment outside the volatile liquid surface, using difference when liquid gasification departs from different zones between two electrodes with the interphase interaction of carbon material, make to form electrical potential difference between first electrode and second electrode.The invention also discloses corresponding preparation method.By means of the invention it is possible to effectively realize that lasting high voltage electric energy is exported using the interaction of volatile liquid and carbon material, the no light that is particularly suitable for use in and the certain applications moved without external mechanical.

Description

A kind of TRT and its manufacture method based on carbon material
Technical field
The invention belongs to new energy equipment field, more particularly, to a kind of TRT based on carbon material and Its manufacture method.
Background technology
In recent years, with the lasting reduction and the gradually aggravation of environmental problem of fossil fuel, green energy resource device is ground Study carefully and using having obtained vigorous growth, including solar cell, wind-driven generator, thermoelectric conversion element, novel electromechanical transducing Device etc..However, further investigations have shown that, the application scenario of above-mentioned new energy equipment nevertheless suffers from some limitations, example As solar cell can not work in no light;Novel electromechanical energy transducer needs external mechanical motion to be operated.Cause This, how no light and without external mechanical move environment in produce electric energy just turn into energy field merit attention it is important Technical problem.
The content of the invention
For the disadvantages described above or Improvement requirement of prior art, the invention provides a kind of TRT based on carbon material And its manufacture method, wherein by its key component such as carbon material layer, volatile liquid, electrode setting mode and working mechanism Studied, mutually effectively should be able to realize lasting high voltage electric energy using the interaction of volatile liquid and carbon material Output, the no light that is particularly suitable for use in and the certain applications moved without external mechanical.
To achieve the above object, should according to one aspect of the present invention there is provided a kind of TRT based on carbon material TRT includes electrification component and volatile liquid, it is characterised in that:
The electrification component includes the slide glass of electric insulation, be arranged on the slide surface mutually disjoint first electrode and the Two electrodes, and the carbon material layer being similarly disposed on the carrier surface, the wherein carbon material are selected from carbon black, CNT, carbon One or more in particle or graphene, and be deposited on slide glass and be interconnected to form carbon material layer, in addition whole carbon Material layer is overlapped between the first electrode and second electrode, and forms conductive path with the two electrodes;The carbon material The volatile liquid is immersed in one end of layer all the time, and the other end is then exposed in the environment outside the volatile liquid surface; In this way, when in use, due to liquid surface tension and itself gasify, volatile liquid can constantly along carbon material layer from Immersion end is moved to other end, with the difference of the interphase interaction of carbon material when being departed from using liquid gasification in the different zones of two ends It is different, make to form electrical potential difference between first electrode and second electrode.
As it is further preferred that the volatile liquid is preferably pure water, the aqueous solution of salt and organic solvent etc..
As it is further preferred that the electrode needs to seal off solution.
As it is further preferred that above-mentioned TRT can also include temperature control unit, humidity controlling unit, wind speed The gentle pressure control unit of control unit, wherein temperature control unit are used to improve the environment temperature residing for volatile liquid, humidity Control unit is used to reduce the ambient humidity residing for volatile liquid, and blast velocity control unit is used to improve the volatile liquid table The flow rate of gas in face, air pressure control unit is used to reduce the ambient pressure residing for the volatile liquid, in this way, altogether Same-action is to improve the output electric energy of TRT.
It is another aspect of this invention to provide that it is used for the method for TRT of the preparation based on carbon material there is provided a kind of, its It is characterised by, this method comprises the following steps:
(a) preparation process of electrification component:
Suitable shape is made in slide glass selected from electrically insulating material, its surface cleaning is clean, then using conduction material Two mutually disjoint electrodes are made on its surface for material;
(b) preparation process of carbon material layer:
By carbon material deposition on slide glass, carbon material is set to be interconnected to form carbon material layer, and whole carbon material layer is taken Connect between two electrodes, and form conductive path therewith;
(c) number of assembling steps:
Volatile liquid is immersed into carbon material layer one end all the time, the other end is then exposed to outside the volatile liquid surface Environment in, thus complete the preparation process of whole TRT.
As it is further preferred that in step (b), the carbon material layer also includes the operation of annealing, to change The electricity output ability of kind carbon material layer.
As it is further preferred that in step (b), after the carbon material layer is formed, preferably also including use etc. Its performs processing to ion pair, improves the interaction strength between volatile liquid and carbon material.
In general, possess following compared with prior art, mainly by the contemplated above technical scheme of the present invention Technological merit:
1st, the set-up mode and working mechanism to its key component such as carbon material layer, volatile liquid and two electrodes are passed through Studied, test shows, in use, due to the surface tension of liquid and itself gasification, volatile liquid can be continuous Along carbon material layer from immersion end moved to other end, using in the different zones of two ends liquid gasification depart from when with carbon material it The difference of interphase interaction, makes to form electrical potential difference between first electrode and second electrode.
2nd, studied by generation type and its subsequent treatment to carbon material layer, can with high efficiency, be easy to manipulation Mode in slide surface formation carbon material, and obtain of a relatively high and stable electric energy output;
3rd, export continual and steady according to the TRT compact overall structure of the present invention, easily prepared, electric energy, and entirely Preparation process is also very convenient, with low cost, and is conducive to large batch of processing and manufacturing, is therefore particularly suitable for no light and nothing The certain applications for needing external mechanical to move.
Brief description of the drawings
Fig. 1 is the apparatus structure schematic diagram according to the preferred embodiment of the present invention;
Fig. 2 is to carry out actual survey according to the device that the length and width of structure design shown in Fig. 1 are respectively 2.5 centimetres and 1 centimetre The obtained voltage-time signals figure of examination;
In all of the figs, identical reference is used for representing identical element or structure, wherein:
11- slide glass 12- electrode 13- carbon material layer 14- volatile liquids
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and It is not used in the restriction present invention.As long as in addition, technical characteristic involved in each embodiment of invention described below Not constituting conflict each other can just be mutually combined.
Fig. 1 is the apparatus structure schematic diagram according to the preferred embodiment of the present invention.As shown in figure 1, the TRT is mainly wrapped Include electrification component and volatile liquid 14, wherein electrification component includes slide glass 11 (for example glass, quartz and using ceramics as representative Electrically insulating material in one kind), be deposited thereon two electrodes 12 and carbon material layer 13 in face, wherein carbon material layer 13 be by Carbon material is connected with each other composition, and whole carbon material layer is overlapped between the first electrode and second electrode, and with this two Individual electrode formation conductive path.Volatile liquid 14 can be it is appropriate possess volatile solution, it can volatilize and can Parent is moistened with carbon material, preferably, pure water, the aqueous solution of salt and organic solvent etc., these liquid is employed in the present invention Body is test indicate that can play good generating effect.
Volatile liquid 14 is immersed into the one end of carbon material layer 13 all the time, the other end is then exposed to the volatile liquid surface Outside environment in, be consequently formed it is a kind of can automatically from liquid obtain energy device.When in use, due to the table of liquid Face tension force and itself gasification, volatile liquid can be moved constantly along carbon material layer from immersion end to other end, utilize two ends With the difference of the interphase interaction of carbon material when liquid gasification departs from different zones, make shape between first electrode and second electrode Into electrical potential difference.;
It will be detailed below mainly wrapping according to the technological process for being used to manufacture above-mentioned TRT of the present invention, this method Include the following steps:
(a) preparation process of electrification component:
Suitable shape is made in slide glass selected from electrically insulating material, its surface cleaning is clean, then using conduction material Two mutually disjoint electrodes are made on its surface for material;
(b) preparation process of carbon material layer:
By carbon material deposition on slide glass, carbon material is set to be interconnected to form carbon material layer, and whole carbon material layer is taken Connect between two electrodes, and form conductive path therewith;
(c) number of assembling steps:
Volatile liquid is immersed into selected carbon material layer one end all the time, the other end is then exposed to outside the volatile liquid Environment in, thus complete the preparation process of whole TRT.
The TRT based on carbon material obtained to more than is subjected to actual test below.As shown in Figure 2, even if In the case of no light and without the driving of any external mechanical, length and width are respectively 2.5 centimetres and 1 centimetre designed according to this invention The voltage that is exported of device still can reach 1 volt in a short time, and can keep for a long time, thus demonstrate according to The present invention real value and potentially use prospect.
As it will be easily appreciated by one skilled in the art that the foregoing is merely illustrative of the preferred embodiments of the present invention, it is not used to The limitation present invention, any modifications, equivalent substitutions and improvements made within the spirit and principles of the invention etc., it all should include Within protection scope of the present invention.

Claims (2)

1. a kind of TRT based on carbon material, the TRT includes electrification component and volatile liquid, it is characterised in that:
The electrification component includes the slide glass of electric insulation, is arranged on mutually disjoint first electrode and the second electricity on the slide surface Pole, and the carbon material layer being similarly disposed on the slide surface, the wherein carbon material are selected from carbon black, CNT, carbon particle Or the one or more in graphene, and be deposited on the slide glass and be interconnected to form the carbon material layer, it is whole in addition The individual carbon material layer is overlapped between the first electrode and second electrode, and forms conductive path with the two electrodes;Institute The volatile liquid is immersed in the one end for stating carbon material layer all the time, and the other end is then exposed to outside the volatile liquid surface In environment;In this way, when in use, due to the surface tension of liquid and itself gasification, volatile liquid can be constantly along carbon Material layer is moved from immersion end to other end, when being departed from using liquid gasification in the different zones of two ends between carbon material mutually The difference of effect, makes to form electrical potential difference between the first electrode and the second electrode;
In addition, above-mentioned TRT also includes temperature control unit, humidity controlling unit, blast velocity control unit and air pressure control list Member, the wherein temperature control unit are used to improve the environment temperature residing for volatile liquid, and the humidity controlling unit is used to reduce Ambient humidity residing for volatile liquid, the blast velocity control unit is used for the gas flowing speed for improving the volatile liquid surface Rate, the air pressure control unit is used to reduce the ambient pressure residing for the volatile liquid, and in this way, collective effect is to carry The output electric energy of high TRT.
2. TRT as claimed in claim 1, it is characterised in that the volatile liquid be pure water, the aqueous solution of salt or Person's organic solvent.
CN201410576692.4A 2014-10-24 2014-10-24 A kind of TRT and its manufacture method based on carbon material Active CN105591166B (en)

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PCT/CN2014/092295 WO2016061870A1 (en) 2014-10-24 2014-11-26 Carbon material-based power generation device and method for manufacturing same

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CN110417295A (en) * 2019-07-23 2019-11-05 大连理工大学 A kind of power generating device based on liquid evaporation

Citations (2)

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CN102307024A (en) * 2011-06-21 2012-01-04 南京航空航天大学 Graphene-based fluid power generating device for fluctuation sensing device
CN102647113A (en) * 2012-04-23 2012-08-22 许子寒 Graphene power-generation device

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US20070248767A1 (en) * 2006-04-19 2007-10-25 Asm Japan K.K. Method of self-cleaning of carbon-based film
JP2011154914A (en) * 2010-01-28 2011-08-11 Nsk Ltd Power generation element
KR101221501B1 (en) * 2011-06-10 2013-01-15 동국대학교 산학협력단 Apparatus of generating electricity by using nano-wires
CN204190653U (en) * 2014-10-24 2015-03-04 华中科技大学 A kind of Blast Furnace Top Gas Recovery Turbine Unit (TRT) based on volatile liquid

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102307024A (en) * 2011-06-21 2012-01-04 南京航空航天大学 Graphene-based fluid power generating device for fluctuation sensing device
CN102647113A (en) * 2012-04-23 2012-08-22 许子寒 Graphene power-generation device

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