CA2260470A1 - Structured surfaces having hydrophobic properties - Google Patents
Structured surfaces having hydrophobic properties Download PDFInfo
- Publication number
- CA2260470A1 CA2260470A1 CA002260470A CA2260470A CA2260470A1 CA 2260470 A1 CA2260470 A1 CA 2260470A1 CA 002260470 A CA002260470 A CA 002260470A CA 2260470 A CA2260470 A CA 2260470A CA 2260470 A1 CA2260470 A1 CA 2260470A1
- Authority
- CA
- Canada
- Prior art keywords
- hydrophobic properties
- structured surfaces
- structured surface
- article
- disclosed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B17/00—Methods preventing fouling
- B08B17/02—Preventing deposition of fouling or of dust
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B17/00—Methods preventing fouling
- B08B17/02—Preventing deposition of fouling or of dust
- B08B17/06—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B17/00—Methods preventing fouling
- B08B17/02—Preventing deposition of fouling or of dust
- B08B17/06—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
- B08B17/065—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement the surface having a microscopic surface pattern to achieve the same effect as a lotus flower
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
- B29C59/022—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing characterised by the disposition or the configuration, e.g. dimensions, of the embossments or the shaping tools therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
- B29C59/022—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing characterised by the disposition or the configuration, e.g. dimensions, of the embossments or the shaping tools therefor
- B29C2059/023—Microembossing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0053—Moulding articles characterised by the shape of the surface, e.g. ribs, high polish
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0093—Other properties hydrophobic
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Micromachines (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Materials For Medical Uses (AREA)
Abstract
Disclosed is an article having a structured surface, wherein the structured surface has protuberances having an average height of 50 nm to 10 µm and an average spacing of 50 nm to 10 µm and the structured surface is made of a material which is hydrophobic to such an extent that the material has, when unstructured, a surface energy of 10 to 20 mN/m. The surface has a large contact angle with water, is hardly wetted by water and therefore has a self-cleaning effect. Also disclosed are processes for the production of the article.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19803787.2 | 1998-01-30 | ||
DE19803787A DE19803787A1 (en) | 1998-01-30 | 1998-01-30 | Structured surfaces with hydrophobic properties |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2260470A1 true CA2260470A1 (en) | 1999-07-30 |
CA2260470C CA2260470C (en) | 2007-10-23 |
Family
ID=7856255
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002260470A Expired - Fee Related CA2260470C (en) | 1998-01-30 | 1999-01-28 | Structured surfaces having hydrophobic properties |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0933388B1 (en) |
JP (1) | JPH11286047A (en) |
AT (1) | ATE226227T1 (en) |
CA (1) | CA2260470C (en) |
DE (2) | DE19803787A1 (en) |
DK (1) | DK0933388T3 (en) |
Cited By (12)
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---|---|---|---|---|
WO2005123581A1 (en) * | 2004-06-09 | 2005-12-29 | University Of Florida Research | Ultralyophobe interfaces |
US7972696B2 (en) | 2006-03-30 | 2011-07-05 | Wacker Chemie Ag | Particles with structured surface |
US8163560B2 (en) | 2003-12-04 | 2012-04-24 | Roche Diagnostics Operations, Inc. | Coated test elements |
CN102424354A (en) * | 2011-08-23 | 2012-04-25 | 东南大学 | Rough surface for fractal structure |
US20130095290A1 (en) * | 2005-12-15 | 2013-04-18 | Essilor International (Compagnie Generale D'optique) | Article Coated with an Ultra High Hydrophobic Film and Process for Obtaining Same |
CN103464686A (en) * | 2013-09-27 | 2013-12-25 | 昆山凯诺尔金属制品有限公司 | Forming die |
US8714085B2 (en) | 2007-05-16 | 2014-05-06 | Heidelberger Druckmaschinen Ag | Surface with a surface structure for contacting printing material, machine for processing material and method for producing areas with a surface structure |
WO2014091489A1 (en) * | 2012-12-13 | 2014-06-19 | Technion Research & Development Foundation Limited | Hydrophobic and oleophobic surfaces and uses thereof |
US9339996B2 (en) | 2010-07-09 | 2016-05-17 | 3M Innovative Properties Company | Durable hydrophobic structured surface |
CN106048665A (en) * | 2016-07-07 | 2016-10-26 | 广东工业大学 | Method for preparing metal-base super-oleophobic composite casting layer by using hot compression deformation process |
CN106086944A (en) * | 2016-07-07 | 2016-11-09 | 广东工业大学 | A kind of method preparing the superoleophobic compound cast layer of Metal Substrate based on swelling effect |
US9625065B2 (en) | 2004-09-03 | 2017-04-18 | Loewenstein Medical Technology S.A. | Plastics for medical technical devices |
Families Citing this family (79)
Publication number | Priority date | Publication date | Assignee | Title |
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CZ301248B6 (en) | 1998-12-24 | 2009-12-23 | Qiagen Gmbh | Structured ultraphobic surface, process of its preparation and use |
EP1055924A3 (en) * | 1999-05-26 | 2001-10-31 | Siemens Aktiengesellschaft | Surface structure of windows of optical measuring devices |
DE19928863A1 (en) * | 1999-06-24 | 2001-01-04 | Continental Ag | Vehicle tires |
DE19937707C2 (en) * | 1999-08-10 | 2003-03-27 | Baerlocher Gmbh | Tool surfaces with a defined microstructure for the rejection of deposits |
DE19943299A1 (en) | 1999-09-10 | 2001-03-22 | Binder Gottlieb Gmbh & Co | Surface for an object, including processes for its manufacture and its use |
DE19950452A1 (en) * | 1999-10-20 | 2001-04-26 | Creavis Tech & Innovation Gmbh | Structured surfaces with cell adhesion and cell proliferation inhibiting properties |
DE29919506U1 (en) * | 1999-11-05 | 2000-02-24 | Creavis Tech & Innovation Gmbh | Microstructured pipettes as dosing systems |
DE19958764A1 (en) * | 1999-12-07 | 2001-06-13 | Erlus Baustoffwerke | Method for producing a self-cleaning property of a ceramic surface or a surface formed from concrete or a concrete-like material |
DE10004465A1 (en) | 2000-02-02 | 2001-08-16 | Pari Gmbh | Inhalation nebulizer, comprises a liquid reservoir with an artificial surface structure comprising protrusions and indentations |
DE10007340A1 (en) * | 2000-02-18 | 2001-08-30 | Siemens Ag | Liquid pump e.g. for waste water - has interior of pump housing provided with hydrophobic surface for providing lotus-effect |
US6641767B2 (en) | 2000-03-10 | 2003-11-04 | 3M Innovative Properties Company | Methods for replication, replicated articles, and replication tools |
US20030096083A1 (en) * | 2000-03-20 | 2003-05-22 | Robert Morgan | Surface, method for the production therof and an object provided with said surface |
DE10047124A1 (en) * | 2000-03-20 | 2001-10-18 | Induflex Sondermaschb | Surface, process for its manufacture and object with the surface |
DE20006010U1 (en) | 2000-03-31 | 2000-07-13 | Creavis Tech & Innovation Gmbh | Containers with structured liquid-repellent and liquid-wetting parts of the inner surface |
DE10016485A1 (en) | 2000-04-01 | 2001-10-11 | Dmc2 Degussa Metals Catalysts | Glass, ceramic and metal substrates with a self-cleaning surface, process for their production and their use |
AU2001270488A1 (en) | 2000-04-14 | 2001-10-30 | Nanogate Technologies Gmbh | Ceramic material surface with hydrophobic or ultraphobic properties and method for the production thereof |
DE10028772B4 (en) * | 2000-06-07 | 2005-03-17 | Technische Universität Dresden | Aluminum material with ultrahydrophobic surface, process for its preparation and use |
FR2811316B1 (en) * | 2000-07-06 | 2003-01-10 | Saint Gobain | TRANSPARENT TEXTURE SUBSTRATE AND METHODS OF OBTAINING SAME |
EP1207189A3 (en) * | 2000-11-17 | 2002-12-11 | Basf Aktiengesellschaft | Method for coating apparatus or parts of apparatus |
DE10062203A1 (en) * | 2000-12-13 | 2002-06-20 | Creavis Tech & Innovation Gmbh | Metallic embossing tool or embossing roller, used for embossing hydrophobic polymers to provide a surface structure to the polymer, is rendered hydrophobic before the first embossing step |
DE10064093C1 (en) * | 2000-12-21 | 2002-05-29 | Alfred Friedrich Mayr | Surface structuring for objects |
DE10063739B4 (en) * | 2000-12-21 | 2009-04-02 | Ferro Gmbh | Substrates with self-cleaning surface, process for their preparation and their use |
DE10064520A1 (en) * | 2000-12-22 | 2002-07-04 | Daimler Chrysler Ag | Method for producing structured surface with self-cleaning effect on vehicles, comprises producing micro- or nano-structure on carrier by anodic oxidation and transferring this structure to the surface |
DE10065797A1 (en) * | 2000-12-30 | 2002-07-04 | Creavis Tech & Innovation Gmbh | Device for accelerating condensation using structured surfaces |
DE10100383A1 (en) * | 2001-01-05 | 2002-07-11 | Degussa | Process for applying a fluoroalkyl functional organopolysiloxane coating with stable water and oil repellent properties to polymeric substrates |
DE10106213A1 (en) | 2001-02-10 | 2002-08-22 | Dmc2 Degussa Metals Catalysts Cerdec Ag | Self-cleaning paint coatings and methods and means of making the same |
DE10126117A1 (en) * | 2001-05-29 | 2002-12-19 | Ccs Technology Inc | Optic fiber cable for data transmission suspended from pylons or laid in drainpipes, has a hydrophobic and bristle surface structure to repel any surface particles or fluid |
DE10129116A1 (en) * | 2001-06-16 | 2002-12-19 | Creavis Tech & Innovation Gmbh | Polymer fibers containing surface particles and having very good self-cleaning properties, useful for the preparation of covering elements subjected to high loads, e.g. dirt and water |
EP1404508A1 (en) * | 2001-06-21 | 2004-04-07 | Bernd Späth | Body with improved surface properties |
DE10159767A1 (en) * | 2001-12-05 | 2003-06-18 | Degussa | Process for the manufacture of articles with anti-allergic surfaces |
DE10162457A1 (en) * | 2001-12-19 | 2003-07-03 | Degussa | Surface-structured internals for multi-phase separators |
DE10205007A1 (en) * | 2002-02-07 | 2003-08-21 | Creavis Tech & Innovation Gmbh | Process for the production of protective layers with dirt and water repellent properties |
DE10205782A1 (en) * | 2002-02-13 | 2003-08-21 | Degussa | Shaped body with a self-cleaning surface and a surface structure with hills formed by structure forming particles useful for drinking vessels, storage vessels, storage barrels, spraying protection devices, and textiles |
DE10207194C1 (en) | 2002-02-21 | 2003-06-12 | Binder Gottlieb Gmbh & Co | Self-cleaning material surface has a basic structure, and shaped capillary structures in a hydrophobic action to shed water drops and the like |
US6946170B2 (en) | 2002-02-21 | 2005-09-20 | Gottlieb Binder Gmbh & Company | Self-cleaning display device |
DE10208930A1 (en) * | 2002-02-28 | 2003-09-11 | Rauschert Verfahrenstechnik Gm | Use of moldings |
DE10210673A1 (en) * | 2002-03-12 | 2003-09-25 | Creavis Tech & Innovation Gmbh | Injection molded body with self-cleaning properties and method for producing such injection molded body |
DE10223234B4 (en) | 2002-05-24 | 2005-02-03 | MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. | Process for the preparation of microstructured surfaces with increased adhesion and adhesion-enhancing modified surfaces |
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DE10233829A1 (en) * | 2002-07-25 | 2004-02-12 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Process for preparation of surfaces with selfcleaning properties by application of nano particles with production of a lotus effect useful for coating objects subjected to high soiling and water loads, e.g. in outdoor sports |
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DE10306893A1 (en) | 2003-02-18 | 2004-08-26 | Basf Ag | Process for finishing textile material to impart water and soil repellence to e.g. natural, modified and/or synthetic fibers, yarn (precursor), thread or fabric, uses organic polymer and particulate (in)organic solid in aqueous medium |
DE10315128A1 (en) | 2003-04-03 | 2004-10-14 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Process for suppressing mold formation using hydrophobic substances and an anti-mold agent for parts of buildings |
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US7524531B2 (en) | 2005-04-27 | 2009-04-28 | Ferro Corporation | Structured self-cleaning surfaces and method of forming same |
US20070028588A1 (en) * | 2005-08-03 | 2007-02-08 | General Electric Company | Heat transfer apparatus and systems including the apparatus |
US20070031639A1 (en) * | 2005-08-03 | 2007-02-08 | General Electric Company | Articles having low wettability and methods for making |
KR101194646B1 (en) | 2005-12-30 | 2012-10-24 | 엘지디스플레이 주식회사 | Fabricating method of soft mold |
GB0610550D0 (en) * | 2006-05-26 | 2006-07-05 | Univ Cambridge Tech | Ultrahydrophobic surfaces and methods for their production |
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US20080047940A1 (en) * | 2006-08-28 | 2008-02-28 | Xinghua Li | Article with multiple surface depressions and method for making the same |
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US7732497B2 (en) | 2007-04-02 | 2010-06-08 | The Clorox Company | Colloidal particles for lotus effect |
US8105721B2 (en) | 2007-04-04 | 2012-01-31 | GM Global Technology Operations LLC | Microtextured fuel cell elements for improved water management |
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US9239558B2 (en) * | 2009-03-11 | 2016-01-19 | Xerox Corporation | Self-releasing nanoparticle fillers in fusing members |
US20100285272A1 (en) * | 2009-05-06 | 2010-11-11 | Shari Elizabeth Koval | Multi-length scale textured glass substrates for anti-fingerprinting |
DE102009051598B4 (en) | 2009-11-02 | 2022-10-06 | Vereinigung zur Förderung des Instituts für Kunststoffverarbeitung in Industrie und Handwerk an der Rhein.-Westf. Technischen Hochschule Aachen e.V. | Process for the production of devices with microstructures made of plastic by means of stretching for the purpose of self-cleaning, such devices and their use |
DE102010017429A1 (en) * | 2010-06-17 | 2011-12-22 | Bergische Universität Wuppertal | Printing method for producing UV-curable and printable foil coating on printable substrate to produce printed product utilized as e.g. packaging medium, involves drying metal particle-containing paint and/or printing ink after time delay |
DE102010024559A1 (en) | 2010-06-22 | 2011-12-22 | Süd-Chemie AG | Process for producing hydrophobic surfaces |
DE102010026490A1 (en) * | 2010-07-07 | 2012-01-12 | Basf Se | Process for the production of finely structured surfaces |
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SE540714C2 (en) | 2015-06-18 | 2018-10-16 | Stora Enso Oyj | Container with oleophilic pattern on a sealing surface |
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JPS63212545A (en) * | 1987-03-02 | 1988-09-05 | 日本板硝子株式会社 | Antifouling nonreflective plate |
JP3139566B2 (en) * | 1992-04-08 | 2001-03-05 | ダイワ精工株式会社 | Fishing rod |
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JP3397215B2 (en) * | 1993-09-17 | 2003-04-14 | 松下電器産業株式会社 | Hydrophilic lipophilic film and method for producing the same |
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DE4426012C2 (en) * | 1994-07-22 | 1998-05-20 | Roland Man Druckmasch | Erasable printing form, its use and methods for erasing and regenerating the printing form |
EP0772514B1 (en) * | 1994-07-29 | 1998-12-23 | Wilhelm Barthlott | Self-cleaning surfaces of objects and process for producing same |
-
1998
- 1998-01-30 DE DE19803787A patent/DE19803787A1/en not_active Withdrawn
- 1998-12-21 EP EP98124383A patent/EP0933388B1/en not_active Revoked
- 1998-12-21 DK DK98124383T patent/DK0933388T3/en active
- 1998-12-21 AT AT98124383T patent/ATE226227T1/en not_active IP Right Cessation
- 1998-12-21 DE DE59805966T patent/DE59805966D1/en not_active Revoked
-
1999
- 1999-01-27 JP JP11018681A patent/JPH11286047A/en active Pending
- 1999-01-28 CA CA002260470A patent/CA2260470C/en not_active Expired - Fee Related
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8163560B2 (en) | 2003-12-04 | 2012-04-24 | Roche Diagnostics Operations, Inc. | Coated test elements |
US7851056B2 (en) | 2004-06-09 | 2010-12-14 | University Of Florida Research Foundation, Inc. | Ultralyophobe interfaces |
WO2005123581A1 (en) * | 2004-06-09 | 2005-12-29 | University Of Florida Research | Ultralyophobe interfaces |
US9625065B2 (en) | 2004-09-03 | 2017-04-18 | Loewenstein Medical Technology S.A. | Plastics for medical technical devices |
US20130095290A1 (en) * | 2005-12-15 | 2013-04-18 | Essilor International (Compagnie Generale D'optique) | Article Coated with an Ultra High Hydrophobic Film and Process for Obtaining Same |
US7972696B2 (en) | 2006-03-30 | 2011-07-05 | Wacker Chemie Ag | Particles with structured surface |
US8409710B2 (en) | 2006-03-30 | 2013-04-02 | Wacker Chemie Ag | Particles with structured surface |
US8714085B2 (en) | 2007-05-16 | 2014-05-06 | Heidelberger Druckmaschinen Ag | Surface with a surface structure for contacting printing material, machine for processing material and method for producing areas with a surface structure |
US9339996B2 (en) | 2010-07-09 | 2016-05-17 | 3M Innovative Properties Company | Durable hydrophobic structured surface |
CN102424354A (en) * | 2011-08-23 | 2012-04-25 | 东南大学 | Rough surface for fractal structure |
CN102424354B (en) * | 2011-08-23 | 2014-08-06 | 东南大学 | Rough surface for fractal structure |
CN104995261A (en) * | 2012-12-13 | 2015-10-21 | 工业研究与发展基金会有限公司 | Hydrophobic and oleophobic surfaces and uses thereof |
WO2014091489A1 (en) * | 2012-12-13 | 2014-06-19 | Technion Research & Development Foundation Limited | Hydrophobic and oleophobic surfaces and uses thereof |
CN103464686B (en) * | 2013-09-27 | 2016-04-27 | 无锡市众鑫机械制造有限公司 | A kind of mould |
CN103464686A (en) * | 2013-09-27 | 2013-12-25 | 昆山凯诺尔金属制品有限公司 | Forming die |
CN106048665A (en) * | 2016-07-07 | 2016-10-26 | 广东工业大学 | Method for preparing metal-base super-oleophobic composite casting layer by using hot compression deformation process |
CN106086944A (en) * | 2016-07-07 | 2016-11-09 | 广东工业大学 | A kind of method preparing the superoleophobic compound cast layer of Metal Substrate based on swelling effect |
Also Published As
Publication number | Publication date |
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ATE226227T1 (en) | 2002-11-15 |
CA2260470C (en) | 2007-10-23 |
EP0933388B1 (en) | 2002-10-16 |
EP0933388A2 (en) | 1999-08-04 |
JPH11286047A (en) | 1999-10-19 |
EP0933388A3 (en) | 1999-08-18 |
DK0933388T3 (en) | 2003-02-24 |
DE19803787A1 (en) | 1999-08-05 |
DE59805966D1 (en) | 2002-11-21 |
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